{"id":241263,"date":"2022-08-22T07:25:00","date_gmt":"2022-08-21T23:25:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=241263"},"modified":"2022-08-21T20:25:09","modified_gmt":"2022-08-21T12:25:09","slug":"%e4%b8%8d%e5%af%b9%e7%a7%b0%e5%90%88%e6%88%90%ef%bc%81nature-communications%ef%bc%9a%e4%b8%99%e4%ba%8c%e9%85%b8%e9%85%af%e4%b8%8d%e5%af%b9%e7%a7%b0%e8%bf%98%e5%8e%9f%e6%b3%95%e5%90%88%e6%88%90%ce%b1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=241263","title":{"rendered":"\u4e0d\u5bf9\u79f0\u5408\u6210\uff01Nature communications\uff1a\u4e19\u4e8c\u9178\u916f\u4e0d\u5bf9\u79f0\u8fd8\u539f\u6cd5\u5408\u6210\u03b1-\u53d4\u80fa\u548c\u53d4\u9187\u7684\u591a\u79cd\u65b9\u6cd5"},"content":{"rendered":"<p><strong>\u4e0d\u5bf9\u79f0\u5408\u6210\uff01<\/strong><strong><em>Nature communications<\/em><\/strong><strong>\uff1a\u4e19\u4e8c\u9178\u916f\u4e0d\u5bf9\u79f0\u8fd8\u539f\u6cd5\u5408\u6210<\/strong><strong>\u03b1-<\/strong><strong>\u53d4\u80fa\u548c\u53d4\u9187\u7684\u591a\u79cd\u65b9\u6cd5<\/strong><\/p>\n<p><strong>lwbsyf<\/strong><\/p>\n<p><strong>01<\/strong><strong>\u3001\u5bfc\u8bfb<\/strong><\/p>\n<p>\u00a0\u5177\u6709\u56db\u53d6\u4ee3\u03b1-\u78b3\u7684\u80fa\u548c\u9187\u662f\u751f\u7269\u6d3b\u6027\u5929\u7136\u4ee3\u8c22\u7269\u4e2d\u5e38\u89c1\u7684\u7ed3\u6784\u7247\u6bb5\u3002\u8fd9\u4e9b\u5b8c\u5168\u53d6\u4ee3\u7684\u78b3\u53ef\u4ee5\u901a\u8fc7\u589e\u5f3a\u7ed3\u6784\u591a\u6837\u6027\u548c\u4eb2\u8102\u6027\u6765\u4fc3\u8fdb\u836f\u7269\u7684\u7814\u53d1\uff0c\u56e0\u6b64\uff0c\u5bf9\u03b1-\u53d4\u80fa\u548c\u53d4\u9187\uff0c\u7279\u522b\u662f\u6c28\u57fa\u9178\u3001\u7f9f\u57fa\u916f\u548c\u4e8c\u9187\u7b49\u591a\u5b98\u80fd\u56e2\u5316\u884d\u751f\u7269\u7684\u9ad8\u6548\u7acb\u4f53\u9009\u62e9\u6027\u6784\u5efa\u4e00\u76f4\u662f\u7814\u7a76\u7684\u70ed\u70b9\u3002\u5229\u7528\u4e00\u7cfb\u5217\u5177\u6709\u56db\u9f7f\u914d\u4f53\u7684\u53cc\u6838\u950c\u914d\u5408\u7269\u5bf9\u5168\u78b3\u548c\u5364\u7d20\u53d6\u4ee3\u7684\u4e19\u4e8c\u9178\u916f\u7684\u53bb\u5bf9\u79f0\u5316\u8fd8\u539f\u5df2\u7ecf\u5b9e\u73b0\u3002\u5728\u8fd9\u79cd\u53bb\u5bf9\u79f0\u5316\u8303\u5f0f\u4e2d\u5305\u542b\u6c28\u57fa\u548c\u6c27\u4e19\u4e8c\u9178\u916f\u5b9e\u73b0\u4e86\u5bf9\u6620\u4f53\u5bcc\u96c6\u7684\u03b1-\u53d4\u80fa\u548c\u53d4\u9187\u5feb\u901f\u591a\u6837\u7684\u5408\u6210\uff0c\u4f46\u8fd9\u4e9b\u542b\u6c2e\/\u542b\u6c27\u5e95\u7269\u8fd8\u5b58\u5728\u4ee5\u4e0b\u6311\u6218\uff1a<\/p>\n<ul>\n<li>\u4e0e\u60f0\u6027\u70f7\u57fa\u548c\u82b3\u57fa\u4e0d\u540c\uff0c\u9178\u6027\u6c2e\/\u6c27\u53d6\u4ee3\u57fa\u53ef\u4ee5\u4f7f\u542b\u6709Lewis\u9178\u6027\u548cBr\u00f8nsted\u78b1\u6027\u950c\u4e2d\u5fc3\u7684\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u5931\u6d3b\u3002<\/li>\n<li>\u7531\u4e8e\u53bb\u5bf9\u79f0\u7684\u5bf9\u6620\u4f53\u9009\u62e9\u5f52\u7ed3\u4e3a\u4e24\u4e2a\u03b1\u53d6\u4ee3\u57fa\u4e4b\u95f4\u7684\u5c3a\u5bf8\u5dee\u5f02\uff0c\u4e00\u5bf9\u5c3a\u5bf8\u8f83\u5c0f\u7684\u78b3\u53d6\u4ee3\u57fa\u901a\u5e38\u662f\u5f62\u6210\u56db\u5143\u7acb\u4f53\u4e2d\u5fc3\u7684\u5148\u51b3\u6761\u4ef6\u3002\u6c28\u57fa\u548c\u6c27\u4e19\u4e8c\u9178\u916f\u7684\u8303\u56f4\u9700\u8981\u50ac\u5316\u5242\u6765\u9002\u5e94\u4e0d\u540c\u5f62\u72b6\u548c\u5c3a\u5bf8\u7684\u6742\u539f\u5b50\u53d6\u4ee3\u57fa\uff0c\u4ee5\u5bf9\u6bd4\u4e0d\u540c\u7684\u78b3\u4fa7\u94fe\u3002<\/li>\n<li>\u53bb\u5bf9\u79f0\u5316\u4ea7\u7269\u7684\u5408\u6210\u5e94\u7528\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u6c2e\/\u6c27\u53d6\u4ee3\u57fa\u7684\u884d\u751f\u6f5c\u529b\u3002<\/li>\n<\/ul>\n<p>\u56e0\u6b64\uff0c\u4e3a\u80fa\u548c\u9187\u9009\u62e9\u7a33\u5065\u4e14\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u53bb\u9664\u7684\u4fdd\u62a4\u57fa\u56e2\u5e76\u975e\u6613\u4e8b\u3002<\/p>\n<p><strong>02<\/strong><strong>\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u9999\u6e2f\u5927\u5b66\u5316\u5b66\u7cfb\u9ec4\u91cd\u884c\u6559\u6388\u56e2\u961f\u8bc1\u660e\u4e86\u4e00\u5957\u54cc\u5576\u9187\u884d\u751f\u7684\u56db\u9f7f\u914d\u4f53\u53ef\u4ee5\u5bb9\u7eb3\u5404\u79cd\u7c7b\u578b\u7684\u6c2e\/\u6c27\u53d6\u4ee3\u4e19\u4e8c\u9178\u916f\uff0c\u4ee5\u63d0\u4f9b\u5bcc\u542b\u5bf9\u6620\u4f53\u7684\u6c22\u5316\u7845\u70f7\u5316\uff08\u7845\u6c22\u5316\uff09\u4ea7\u7269\u3002\u867d\u7136\u7c7b\u4f3c\u7684\u4e19\u4e8c\u9178\u916f\u4e4b\u524d\u5df2\u7ecf\u53bb\u5bf9\u79f0\u5316\uff0c\u4f46\u8fd9\u4e9b\u8f6c\u5316\u662f\u5206\u5b50\u5185\u7684\uff0c\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u53ea\u80fd\u5f97\u5230\u624b\u6027\u6742\u73af\uff0c\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u8fd8\u539f\u548c\u5206\u5b50\u95f4\u53bb\u5bf9\u79f0\u5316\u6709\u7740\u4e30\u5bcc\u7684\u5e94\u7528\u6f5c\u529b\u3002\u4f8b\u5982\uff0c\u6c28\u57fa\u4e19\u4e8c\u9178\u7684\u53bb\u5bf9\u79f0\u4ea7\u7269\u53ef\u4ee5\u88ab\u89c6\u4e3a\u9ad8\u5ea6\u5b98\u80fd\u5316\u7684\u6c28\u57fa\u9187\/\u916f\u548c\u4e1d\u6c28\u9178\u884d\u751f\u7269\uff0c\u4f46\u6c27\u4e19\u4e8c\u9178\u916f\u53ef\u4ee5\u4ea7\u751f\u5bcc\u6c27\u624b\u6027\u5206\u5b50\uff0c\u5982\u4e8c\u9187\u548c\u7518\u6cb9\u9178\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6c28\u57fa\u548c\u6c27\u53d6\u4ee3\u57fa\u4e0d\u53c2\u4e0e\u6c22\u5316\u7845\u70f7\u57fa\u5316\uff0c\u56e0\u6b64\u83b7\u5f97\u4e86\u5e7f\u6cdb\u7684\u53d6\u4ee3\u57fa\uff0c\u5305\u62ec\u919a\u3001\u80fa\u548c\u9170\u80fa\u3002\u5f53\u4e0e\u5927\u91cf\u76f8\u5bb9\u4fa7\u94fe\uff08\u5373R1\uff09\u8026\u5408\u65f6\uff0c\u901a\u8fc7\u53bb\u5bf9\u79f0\u5316\u7684\u53ef\u8bbf\u95ee\u7ed3\u6784\u7684\u591a\u6837\u6027\u8fdb\u4e00\u6b65\u6269\u5927\uff0c\u5e76\u4fc3\u8fdb\u8fd8\u539f\u540e\u884d\u751f\u4e3a\u66f4\u590d\u6742\u7684\u624b\u6027\u542b\u6c2e\u548c\u542b\u6c27\u5206\u5b50\u3002<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong><em>Diverse synthesis of \u03b1-tertiary amines andtertiary alcohols via desymmetric reduction of malonic esters<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><em>Nature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241270\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-3.png\" alt=\"\" width=\"692\" height=\"330\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-3.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72471-3-300x143.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/p>\n<p><strong>03<\/strong><strong>\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>1.\u5f00\u53d1\u4e86\u4e00\u79cd\u901a\u8fc7\u4e19\u4e8c\u9178\u916f\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u03b1-\u56db\u53d6\u4ee3\u80fa\u548c\u9187\u7684\u65b9\u6cd5\uff1b<\/p>\n<p>2.\u8be5\u4e0d\u5bf9\u79f0\u5408\u6210\u65b9\u6cd5\u57fa\u4e8e\u4e00\u5957\u53cc\u6838\u950c\u50ac\u5316\u5242\u548c\u54cc\u5576\u9187\u884d\u751f\u7684\u56db\u9f7f\u914d\u4f53\u6765\u5b9e\u73b0\uff0c\u53ef\u4ee5\u5bb9\u7eb3\u5404\u79cd\u5404\u6837\u7684\u6742\u539f\u5b50\u53d6\u4ee3\u57fa\uff0c\u5305\u62ec\u4ef2\u9170\u80fa\u3001\u53d4\u80fa\u548c\u4e0d\u540c\u5c3a\u5bf8\u7684\u919a\u3002<\/p>\n<p><strong>04<\/strong><strong>\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241271\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-3.png\" alt=\"\" width=\"1064\" height=\"930\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-3.png 1064w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-3-300x262.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-3-768x671.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72472-3-1024x895.png 1024w\" sizes=\"(max-width: 1064px) 100vw, 1064px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u624b\u6027<\/strong><strong>\u03b1-<\/strong><strong>\u53d4\u80fa\u548c\u53d4\u9187\u7684\u5408\u6210<\/strong><strong> \u00a9 2022 The Author(s) <\/strong><\/p>\n<p>\uff08a\uff09 \u624b\u6027\u03b1-\u53d4\u80fa\u548c\u53d4\u9187\u7684\u5408\u6210\u3002\u4eb2\u6838\u8bd5\u5242\u662fNu\uff0c\u4eb2\u7535\u8bd5\u5242\u662fE;<\/p>\n<p>\uff08b\uff09 \u6c28\u57fa\u548c\u6c27\u4e19\u4e8c\u9178\u916f\u7684\u8fd8\u539f\u53bb\u5bf9\u79f0\u5316\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241272\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-3.png\" alt=\"\" width=\"1074\" height=\"688\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-3.png 1074w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-3-300x192.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-3-768x492.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72473-3-1024x656.png 1024w\" sizes=\"(max-width: 1074px) 100vw, 1074px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u6c28\u57fa\u548c\u6c27\u4e19\u4e8c\u9178\u916f\u8fd8\u539f\u53bb\u5bf9\u79f0\u5316\u7684\u4f18\u5316<\/strong><strong> \u00a9 2022 The Author(s) <\/strong><\/p>\n<p>\uff08a\uff09 \u914d\u4f53\u652f\u67b6\u7684\u4f18\u5316; \uff08b\uff09 \u516d\u79cd\u4ee3\u8868\u6027\u6c28\u57fa\u548c\u6c27\u6c28\u9178\u916f\u7684\u68c0\u6d4b\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241273\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-2.png\" alt=\"\" width=\"1087\" height=\"1355\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-2.png 1087w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-2-241x300.png 241w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-2-768x957.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72474-2-821x1024.png 821w\" sizes=\"(max-width: 1087px) 100vw, 1087px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u6c28\u57fa\u4e19\u4e8c\u9178\u916f\u7684\u8303\u56f4<\/strong><strong> \u00a9 2022 The Author(s)<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241274\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-3.png\" alt=\"\" width=\"998\" height=\"876\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-3.png 998w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-3-300x263.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72475-3-768x674.png 768w\" sizes=\"(max-width: 998px) 100vw, 998px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u6c27\u4e19\u4e8c\u9178\u916f\u7684\u4e0d\u5bf9\u79f0\u7845\u6c22\u5316\u53cd\u5e94<\/strong><strong> \u00a9 2022 The Author(s)<\/strong><\/p>\n<p>\uff08a\uff09 \u6c27\u4e19\u4e8c\u9178\u916f\u5728\u4e0d\u5bf9\u79f0\u7845\u6c22\u5316\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\uff1b<\/p>\n<p>\uff08b\uff09 \u6c27\u4e19\u4e8c\u9178\u916f\u7684\u52a8\u529b\u5b66\u62c6\u5206\u548c\u620a\u4e8c\u9178\u4e8c\u4e59\u916f\u7684\u53bb\u5bf9\u79f0\u5316\u5c1d\u8bd5\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241275\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476.png\" alt=\"\" width=\"1086\" height=\"896\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476.png 1086w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-300x248.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-768x634.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72476-1024x845.png 1024w\" sizes=\"(max-width: 1086px) 100vw, 1086px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u53bb\u5bf9\u79f0\u4ea7\u54c1\u7684\u5408\u6210\u5e94\u7528<\/strong><strong> \u00a9 2022 The Author(s) <\/strong><\/p>\n<p>\uff08a\uff09\u3001\u919a\u7684\u8131\u4fdd\u62a4\u53ca\u67e0\u6aac\u9178\u7684\u5408\u6210\uff1b<\/p>\n<p>\uff08b\uff09\u3001\u82c4\u80fa\u7684\u6c22\u8131\u4fdd\u62a4\u53ca\u9ea6\u7532\u5185\u9170\u8132B\u7684\u5408\u6210\uff1b<\/p>\n<p>\uff08c\uff09\u3001conagenin\u7684\u665a\u671f\u53bb\u5bf9\u79f0\u5316\u65b9\u6cd5\uff1b<\/p>\n<p>\uff08d\uff09\u3001\u901a\u8fc7\u73af\u4e19\u4e8c\u9178\u916f\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u624b\u6027Trolox\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241276\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477.png\" alt=\"\" width=\"1269\" height=\"643\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477.png 1269w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-300x152.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-768x389.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u72477-1024x519.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6 <\/strong><strong>\u7acb\u4f53\u5316\u5b66\u7684\u8003\u8651\u548c\u5efa\u8bae<\/strong><strong> \u00a9 2022 The Author(s)<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong>05<\/strong><strong>\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u7814\u7a76\u8bbe\u8ba1\u4e86\u4e00\u79cd\u901a\u8fc7\u4e19\u4e8c\u9178\u916f\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u03b1-\u56db\u53d6\u4ee3\u80fa\u548c\u9187\u7684\u65b9\u6cd5\u3002\u8be5\u65b9\u6cd5\u5229\u7528\u4e86\u6742\u539f\u5b50\u53d6\u4ee3\u7684\u4e19\u4e8c\u9178\u916f\u7684\u7b80\u4fbf\u5236\u5907\uff0c\u5e76\u5c06\u5176\u4e0e\u591a\u5b98\u80fd\u5316\u7845\u6c22\u5316\u4ea7\u7269\u7684\u9ad8\u884d\u751f\u6f5c\u529b\u8fde\u63a5\u8d77\u6765\u3002\u4f7f\u7528\u4e86\u5177\u6709\u4e00\u5bf9\u4e8c\u53d4\u4e01\u57fa\u82ef\u57fa\u7684\u54cc\u5576\u9187\u884d\u751f\u548c\u56db\u9f7f\u914d\u4f53\u652f\u67b6\u5141\u8bb8\u5305\u542b\u5177\u6709\u591a\u79cd\u6c28\u57fa\u548c\u6c27\u5b98\u80fd\u56e2\u7684\u5e95\u7269\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u4e19\u4e8c\u9178\u916f\u7684\u5408\u6210\u80fd\u591f\u4ee5\u5feb\u901f\u548c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u65b9\u5f0f\u83b7\u5f97\u5929\u7136\u4ee3\u8c22\u7269\u548c\u751f\u7269\u6d3b\u6027\u5206\u5b50\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1aDiverse synthesis of \u03b1-tertiary amines and tertiary alcohols via desymmetric reduction of malonic esters\uff08<em>Nature Communications<\/em>\uff0c2022\uff0chttps:\/\/doi.org\/10.1038\/s41467-022-32560-1\uff09<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e0d\u5bf9\u79f0\u5408\u6210\uff01Nature communications\uff1a\u4e19\u4e8c\u9178\u916f\u4e0d\u5bf9\u79f0\u8fd8\u539f\u6cd5\u5408\u6210\u03b1-\u53d4\u80fa\u548c\u53d4\u9187\u7684\u591a\u79cd\u65b9\u6cd5 lwbsyf 01\u3001\u5bfc\u8bfb 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