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    \"\"\u56fe<\/strong>4.<\/strong> Cux<\/sub>Co1-x<\/sub>P\/MXene\u4e0e\u5bf9\u7167\u6837\u54c1\u7684\u50ac\u5316\u6027\u80fd\u548c\u6d3b\u5316\u80fd\u6bd4\u8f83\u3002\u00a9 2022 The Authors<\/strong><\/p>\n

    \u56fe<\/strong>4.<\/strong>b-c\u8fdb\u4e00\u6b65\u901a\u8fc7XPS\u5149\u8c31\u5206\u6790\u4e86Cux<\/sub>Co1-x<\/sub>P\/MXene\u548cCoP\/MXene\u4e0eLi2<\/sub>S6<\/sub>\u76f8\u4e92\u4f5c\u7528\u524d\u540e\u7684\u8868\u9762\u5316\u5b66\u6027\u8d28\uff0c\u7ed3\u679c\u8868\u660eCu0.1<\/sub>Co0.9<\/sub>P\/MXene-Li2<\/sub>S6<\/sub>\u4e2d\u7684Co-S\u952e\u66f4\u5f3a\uff0c\u8fd9\u8bf4\u660eCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u4e2d\u6709\u66f4\u591a\u7684Co\u951a\u5b9aLi2<\/sub>S6<\/sub>\uff0c\u8fd9\u53ef\u80fd\u662f\u56e0\u4e3aCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u4e2d\u5b58\u5728\u66f4\u591a\u7684\u7a7a\u4f4d\u548c\u7f3a\u9677\u3002\u6b64\u5916\uff0cCo\u539f\u5b50\u4e0eS\u539f\u5b50\u76f8\u4e92\u4f5c\u7528\u540e\uff0cCo\u7684\u5cf0\u5411\u8f83\u4f4e\u7684\u7ed3\u5408\u80fd\u8f6c\u79fb\uff0c\u8fd9\u8868\u660e\u7535\u5b50\u4eceLi2<\/sub>Sn<\/sub>\u8f6c\u79fb\u5230CoP\u8868\u9762\u3002\u4e0a\u8ff0\u7ed3\u679c\u8868\u660eCux<\/sub>Co1-x<\/sub>P\/MXene\u7535\u50ac\u5316\u5242\u5bf9Li2<\/sub>S6<\/sub>\u5177\u6709\u826f\u597d\u7684\u5438\u9644\u80fd\u529b\u3002\u56fe<\/strong>4.<\/strong>d\u901a\u8fc7\u4e0d\u540c\u901f\u7387\u4e0b\u7684\u5bf9\u79f0\u7535\u6c60\u8bc4\u4f30\u4e86Cux<\/sub>Co1-x<\/sub>P\/MXene\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u5faa\u73af\u4f0f\u5b89\uff08CV\uff09\u66f2\u7ebf\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u5cf0\u53ef\u5f52\u56e0\u4e8eLi2<\/sub>Sn<\/sub>\u7684\u9010\u6b65\u8f6c\u5316\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7684CV\u66f2\u7ebf\u51fa\u73b0\u4e86\u4e09\u5bf9\u6c27\u5316\u8fd8\u539f\u5cf0\uff0c\u8868\u660eLi2<\/sub>Sn<\/sub>\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u6700\u5feb\u3002\u56fe<\/strong>4.<\/strong>f\u901a\u8fc7\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5\uff08LSV\uff09\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86Cux<\/sub>Co1-x<\/sub>P\/MXene\u548cMXene\u5bf9\u591a\u786b\u5316\u7269\u8f6c\u5316\u7684\u5f71\u54cd\u3002LSV\u66f2\u7ebf\u6e05\u695a\u5730\u8868\u660e\uff0cCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7535\u6781\u7684\u8d77\u59cb\u7535\u4f4d\u6700\u4f4e\uff0c\u8868\u660eCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u6781\u5927\u5730\u4fc3\u8fdb\u4e86Li2<\/sub>S\u5411\u591a\u786b\u5316\u7269\u7684\u8f6c\u5316\u52a8\u529b\u5b66\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660eCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7535\u50ac\u5316\u5242\u5bf9\u591a\u786b\u5316\u7269\u7684\u53cc\u5411\u50ac\u5316\u4f5c\u7528\uff0c\u4f5c\u8005\u901a\u8fc7Li2<\/sub>S\u6210\u6838\u548c\u6eb6\u89e3\u5b9e\u9a8c\u7814\u7a76\u4e86Li2<\/sub>S\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u4e00\u7cfb\u5217\u6570\u636e\u8868\u660e\uff0cCu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7535\u6781\u5bf9Li2<\/sub>Sn<\/sub>\u8f6c\u5316\u4e3aLi2<\/sub>S\u548cLi2<\/sub>S\u8f6c\u5316\u4e3aLi2<\/sub>Sn<\/sub>\u7684\u50ac\u5316\u6548\u7387\u6700\u9ad8\uff0c\u53ef\u4ee5\u5927\u5927\u7f29\u77ed\u8f6c\u5316\u53cd\u5e94\u65f6\u95f4\uff0c\u51cf\u5c11\u591a\u786b\u5316\u7269\u7684\u79ef\u7d2f\uff0c\u52a0\u5febLi2S\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002<\/p>\n

    \"\"\u56fe<\/strong>5. <\/strong>\u4e0d\u540c\u57fa\u5e95\u53cd\u5e94\u673a\u7406\u7684\u7406\u8bba\u8ba1\u7b97\u3002\u00a9 2022 The Authors<\/strong><\/p>\n

    \u4f5c\u8005\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8fdb\u4e00\u6b65\u4ece\u673a\u7406\u4e0a\u63a2\u7a76\u50ac\u5316\u5242\u5bf9\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u56fe<\/strong>5.<\/strong>a\u663e\u793a\u4e86Cux<\/sub>Co1-x<\/sub>P\u5438\u6536Li2<\/sub>S6<\/sub>\u4e4b\u540e\u6a21\u578b\u7684\u4fa7\u89c6\u56fe\u548c\u4fef\u89c6\u56fe\u3002\u56fe<\/strong>5.<\/strong>b\u8868\u660eCux<\/sub>Co1-x<\/sub>P-Li2<\/sub>S6<\/sub>\u7684\u7535\u8377\u5bc6\u5ea6\u5728\u7535\u5b50\u7ed9\u4f53Cu\u63ba\u6742\u540e\u7535\u8377\u8f6c\u79fb\u660e\u663e\u589e\u52a0\u3002\u56fe<\/strong>5.<\/strong>c\u663e\u793a\u4e86Cux<\/sub>Co1-x<\/sub>P-Li2<\/sub>S\u7684\u7535\u8377\u5bc6\u5ea6\u3002\u968f\u7740Cu\u63ba\u6742\u542b\u91cf\u7684\u589e\u52a0\uff0cCo-S\u952e\u7684\u957f\u5ea6\u53d8\u957f\u3002\u76f4\u5230Cu\u63ba\u6742\u91cf\u8fbe\u523015%\u65f6\uff0cCu0.15<\/sub>Co0.85<\/sub>P-Li2<\/sub>S\u4e2d\u7684S\u952e\u6bd4Cu0.1<\/sub>Co0.9<\/sub>P-Li2<\/sub>S\u4e2d\u7684\u77ed\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8eCux<\/sub>Co1-x<\/sub>P\/MXene\u4e2d\u7684Co2+<\/sup>\u589e\u52a0\uff0c\u7535\u8d1f\u6027\u6bd4Co3+<\/sup>\u5f31\u3002\u56fe<\/strong>5.<\/strong>e\u901a\u8fc7DFT\u8ba1\u7b97\u5bf9Li2<\/sub>S\u7684\u5206\u89e3\u52bf\u5792\u548cCux<\/sub>Co1-x<\/sub>P\u8868\u9762\u4e0aLi2<\/sub>S6<\/sub>\u7684\u7ed3\u5408\u80fd\u8fdb\u884c\u5206\u6790\uff0c\u53d1\u73b0Cu0.1<\/sub>Co0.9<\/sub>P\u8868\u9762\u4e0a\u7684Li2<\/sub>S\u8868\u73b0\u66f4\u4f4e\u7684\u6269\u6563\u80fd\u91cf\u52bf\u5792\uff08\u56fe<\/strong>5.<\/strong>f\uff09\u3002<\/p>\n

    \"\"\u56fe<\/strong>6. <\/strong>Cux<\/sub>Co1-x<\/sub>P\/MXene\/S\u6b63\u6781\u5728LSB\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u3002\u00a9 2022 The Authors<\/strong><\/p>\n

    \u4f5c\u8005\u901a\u8fc7\u7194\u878d\u704c\u6ce8\u6cd5\u8d1f\u8f7d\u786b\u3002\u56fe<\/strong>6.<\/strong>a\u663e\u793a\u4e86S\/Cux<\/sub>Co1-x<\/sub>P\/MXene\u7684\u548cS\/MXenes\u6b63\u6781\u7684CV\u66f2\u7ebf\uff0c\u7ed3\u679c\u8868\u660eS\/Cu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u6700\u5feb\uff0c\u8fd9\u6709\u5229\u4e8e\u591a\u786b\u5316\u7269\u7684\u8f6c\u5316\u3002\u56fe<\/strong>6.<\/strong>b\u663e\u793a\u4e86S\/Cux<\/sub>Co1\u2212x<\/sub>P\/MXene\u548cS\/MXene\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\uff08GDC\uff09\u66f2\u7ebf\u3002S\/Cu0.1<\/sub>Co0.9<\/sub>P\/MXene\u6b63\u6781\u7684\u521d\u59cb\u5bb9\u91cf\u4e3a1475 mAh g-1<\/sup>\u3002S\/Cu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\u663e\u793a\u51fa\u66f4\u5c0f\u7684\u534a\u5706\u76f4\u5f84\uff08\u56fe<\/strong>6.<\/strong>c\uff09\uff0c\u8fd9\u8868\u660e\u7535\u8377\u8f6c\u79fb\u66f4\u5feb\u3002\u56fe<\/strong>6.<\/strong>d\u663e\u793a\u4e86Cux<\/sub>Co1-x<\/sub>P\/MXene\u548cMXenes\u786b\u6b63\u6781\u57280.2 C\u4e0b\u5faa\u73af500\u6b21\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0cS\/Cu0.1<\/sub>Co0.9<\/sub>P\/MXene\u7535\u6781\u7684\u5bb9\u91cf\u4fdd\u6301\u738748.6%\u3002S\/Cu0.1<\/sub>Co0.9<\/sub>P\/MXene\u4f18\u5f02\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u610f\u5473\u7740\u5176\u5bf9\u591a\u786b\u5316\u7269\u6c27\u5316\u8fd8\u539f\u8f6c\u5316\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u80fd\u529b\u3002<\/p>\n

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    \u6587\u732e\u94fe\u63a5: Shan, J., Wang, W., Zhang, B., Wang, X., Zhou, W., Yue, L., Li, Y., Unraveling the Atomic-Level Manipulation Mechanism of Li2<\/sub>S Redox Kinetics via Electron-Donor Doping for Designing High-Volumetric-Energy-Density, Lean-Electrolyte Lithium\u2013Sulfur Batteries. Adv. Sci. 2022, 2204192. https:\/\/doi.org\/10.1002\/advs.202204192<\/p>\n

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