{"id":243398,"date":"2022-10-18T06:09:17","date_gmt":"2022-10-17T22:09:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=243398"},"modified":"2022-10-17T21:11:18","modified_gmt":"2022-10-17T13:11:18","slug":"%e5%8c%97%e5%a4%a7nat-commun-%ef%bc%9a%e5%ae%9e%e7%8e%b0%e9%ab%98%e6%80%a7%e8%83%bdn%e5%9e%8b%e6%9c%89%e6%9c%ba%e7%94%b5%e5%8c%96%e5%ad%a6%e6%99%b6%e4%bd%93%e7%ae%a1%e8%bd%ac%e6%8d%a2%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=243398","title":{"rendered":"\u5317\u5927Nat. Commun.\uff1a\u5b9e\u73b0\u9ad8\u6027\u80fdn\u578b\u6709\u673a\u7535\u5316\u5b66\u6676\u4f53\u7ba1\u8f6c\u6362\uff01"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u6709\u673a\u7535\u5316\u5b66\u6676\u4f53\u7ba1\uff08OECTs\uff09\u5728\u795e\u7ecf\u63a5\u53e3\u5668\u4ef6\u3001\u751f\u7269\u5316\u5b66\u4f20\u611f\u5668\u548c\u795e\u7ecf\u5f62\u6001\u8ba1\u7b97\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5404\u79cdp\u578b\u805a\u5408\u7269\u5df2\u88ab\u5f00\u53d1\u7528\u4e8e\u9ad8\u6027\u80fdOECTs\uff0c\u5176\u6027\u80fd\u6307\u6807\u03bcC*\u8d85\u8fc7\u4e86200 F cm-1<\/sup> V-1<\/sup> s-1<\/sup>\u3002p\u578b\u805a\u5408\u7269\u54cd\u5e94\u901f\u5ea6\u5feb\uff0c\u03c4on<\/sub>\/\u03c4off<\/sub>\u5c0f\u4e8e1\/0.1 ms\uff0c\u6709\u5229\u4e8e\u5b9e\u65f6\u9ad8\u901f\u4f20\u611f\u5e94\u7528\u3002\u4e3a\u4e86\u6784\u5efa\u4e92\u8865\u7684\u903b\u8f91\u7535\u8def\uff0c\u5b9e\u73b0\u9ad8\u7075\u654f\u5ea6\u548c\u591a\u5668\u4ef6\u529f\u80fd\uff0c\u9700\u8981\u5177\u6709\u76f8\u5f53\u6027\u80fd\u7684n\u578bOECTs\u3002\u9057\u61be\u7684\u662f\uff0c\u4e0ep\u578bOECTs\u6750\u6599\u76f8\u6bd4\uff0cn\u578bOECTs\u6750\u6599\u5728\u6570\u91cf\u548c\u5668\u4ef6\u6027\u80fd\u4e0a\u90fd\u8fdc\u8fdc\u843d\u540e\uff0c\u03bcC*\u901a\u5e38\u5c0f\u4e8e1 F cm-1<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u03c4on<\/sub>\/\u03c4off<\/sub>\u4e5f\u8d85\u8fc7\u4e8610 ms\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u96f7\u9706\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u7814\u7a76\u8868\u660e\uff0c\u8bbe\u8ba1\u63ba\u6742\u6001\u5bf9n\u578bOECT\u805a\u5408\u7269\u66f4\u4e3a\u5173\u952e\u3002\u901a\u8fc7\u5e73\u8861\u4f9b\u4f53\u90e8\u5206\u7684\u66f4\u591a\u7535\u8377\uff0c\u7814\u7a76\u4eba\u5458\u53ef\u4ee5\u6709\u6548\u5730\u5c06p\u578b\u805a\u5408\u7269\u8f6c\u6362\u4e3a\u9ad8\u6027\u80fdn\u578b\u6750\u6599\u3002\u57fa\u4e8e\u8fd9\u4e00\u539f\u7406\uff0c\u805a\u5408\u7269P(gTDPP2FT)\u8868\u73b0\u51fa\u521b\u7eaa\u5f55\u7684\u9ad8n\u578bOECT\u6027\u80fd\uff0c\u03bcC*\u4e3a54.8\u2009 F cm-1<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u8fc1\u79fb\u7387\u4e3a0.35 cm2<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u54cd\u5e94\u901f\u5ea6\u03c4on<\/sub>\/\u03c4off<\/sub>\u4e3a1.75\/0.15\u2009ms\u3002\u8ba1\u7b97\u548c\u6bd4\u8f83\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u79cd\u8f6c\u5316\u4e3b\u8981\u662f\u7531\u4e8e\u7535\u8377\u66f4\u5747\u5300\u3001\u8d1f\u6781\u5316\u5b50\u7a33\u5b9a\u3001\u6784\u8c61\u589e\u5f3a\u4ee5\u53ca\u8d1f\u7535\u8377\u72b6\u6001\u4e0b\u7684\u4e3b\u94fe\u5e73\u9762\u6027\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f3a\u8c03\u4e86\u805a\u5408\u7269\u201c\u63ba\u6742\u6001\u5de5\u7a0b\u201d\u7406\u89e3\u548c\u5173\u952e\u4f5c\u7528\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201cSwitching p-type to high-performance n-type organic electrochemical transistors via doped state engineering\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n

\u901a\u8fc7\u805a\u5408\u7269\u201c\u63ba\u6742\u6001\u5de5\u7a0b\u201d\uff0c\u6210\u529f\u5730\u5c06p\u578b\u805a\u5408\u7269\u8f6c\u6362\u4e3a\u9ad8\u6027\u80fdn\u578b\u6750\u6599\uff0c\u5f97\u5230\u7684\u805a\u5408\u7269P(gTDPP2FT)\u8868\u73b0\u51fa\u521b\u7eaa\u5f55\u7684\u9ad8n\u578bOECT\u6027\u80fd\uff0c\u03bcC*\u4e3a54.8\u2009 F cm-1<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u8fc1\u79fb\u7387\u4e3a0.35 cm2<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u54cd\u5e94\u901f\u5ea6\u03c4on<\/sub>\/\u03c4off<\/sub>\u4e3a1.75\/0.15\u2009ms\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u805a\u5408\u7269<\/strong>P(gTDPPT) and P(gTDPP2FT)<\/strong>\u7684\u5408\u6210\u8def\u7ebf\u56fe<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe\u4e8c\u3001\u4e24\u79cd\u805a\u5408\u7269\u7684\u5149\u7535\u6027\u80fd<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u5728\u6c2f\u82ef\u6eb6\u6db2\u3001\u8584\u819c\u548c\u73bb\u7483\u4e0a\u9000\u706b\u819c\uff0880\u2103\uff0c10\u5206\u949f\uff09\u7684\u5f52\u4e00\u5316\u7d2b\u5916-\u53ef\u89c1\u5149-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\uff08c\uff09\u4e2d\u6027\u548c\u8d1f\u7535\u8377\u72b6\u6001\u4e0bP(gTDPPT)\u548cP(gTDPP2FT)\u5355\u4f53\u4e8c\u9762\u89d2\u7684PES\u626b\u63cf\u5bf9\u6bd4\u3002<\/p>\n

\uff08d\uff09\u4f18\u5316\u4e86\u5355\u4f53\u7684\u4e3b\u94fe\u7ed3\u6784\u3001\u952e\u957f\u548c\u4e8c\u9762\u89d2\u3002<\/p>\n

\uff08e-f\uff09P(gTDPPT)\u548cP(TDPP2FT)\u57280.1 M NaCl\u6c34\u6eb6\u6db2\u4e2d\u5728ITO\u73bb\u7483\u4e0a\u7684\u7535\u5316\u5b66\u5438\u6536\u5149\u8c31<\/p>\n

\u56fe\u4e09\u3001<\/strong>P(gTDPPT)<\/strong>\u548c<\/strong>P(gTDPP2FT)<\/strong>\u7684<\/strong>OECT<\/strong>\u5668\u4ef6\u8868\u5f81<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-d\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u7684\u4f20\u8f93\u6027\u80fd\uff08a,b\uff09\u4ee5\u53ca\u8f93\u51fa\u6027\u80fd\uff08c,d\uff09\u3002<\/p>\n

\uff08e-f\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u7684\u77ac\u6001\u5f00\/\u5173\u66f2\u7ebf\u3002<\/p>\n

\uff08g\uff09\u57fa\u4e8eP(gTDPPT)\u548cP(gTDPP2FT)\u4e92\u8865\u9006\u53d8\u5668\u7684\u7535\u538b\u4f20\u8f93\u7279\u6027\u548c\u589e\u76ca\u3002<\/p>\n

\uff08h-i\uff09P(gTDPP2FT)\u7684\u03bcC*\u548c\u03bc\u3001\u03c4on<\/sub>\u548c\u03bc\u503c\u4e0e\u5176\u4ed6n\u578bOECT\u6750\u6599\u7684\u5bf9\u6bd4\u3002<\/p>\n

\u56fe\u56db\u3001<\/strong>\u5206\u5b50\u5806\u79ef\u548c\u5f62\u6001\u8868\u5f81<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u7684\u4e8c\u7ef4GIWAXS\u56fe\u6848\u3002<\/p>\n

\uff08c-d\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u7684GIWAXS\u56fe\u6848\u7684\u76f8\u5e94\u7ebf\u5207\u5272\u3002<\/p>\n

\uff08e-f\uff09P(gTDPPT)\u548cP(gTDPP2FT)\u7684AFM\u9ad8\u5ea6\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e94\u3001\u63ba\u6742\u6001\u5de5\u7a0b<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u901a\u8fc7P(gTDPP2FT)\u7684CV\u548c\u03bcC*\u6d4b\u91cf\u7684LUMO\u80fd\u7ea7\u4e0e\u51e0\u4e2a\u62a5\u9053\u7684n\u578bOECT\u6750\u6599\u7684LUMO\u80fd\u7ea7\u7684\u6bd4\u8f83\u3002<\/p>\n

\uff08b\uff09\u53c2\u8003\u805a\u5408\u7269P(gPyDPPT)\u7684\u5316\u5b66\u7ed3\u6784\u5f0f\u3002<\/p>\n

\uff08c\uff09\u6bd4\u8f83\u7531CV\u6d4b\u91cf\u7684HOMO\/LUMO\u80fd\u7ea7\u4ee5\u53ca\u4e2d\u6027\u6001\u548c\u8d1f\u7535\u8377\u6001\u4e4b\u95f4\u7684\u80fd\u91cf\u5dee\u3002<\/p>\n

\uff08d-f\uff09\u4e09\u79cd\u805a\u5408\u7269\u6b63\u8d1f\u7535\u8377\u4e09\u805a\u4f53\u7684\u7535\u8377\u5206\u5e03\u6bd4\u8f83\u3002<\/p>\n

\uff08g-i\uff09T\/D\u788e\u7247\u548c\u4e8c\u9762\u4f53\u6570\u4e4b\u95f4\u7684\u4e8c\u9762\u89d2\u5206\u5e03\u3002<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u201c\u63ba\u6742\u6001\u5de5\u7a0b\u201d\u7b56\u7565\u6765\u8bbe\u8ba1n\u578bOECT\u805a\u5408\u7269\uff0c\u5e76\u6709\u6548\u5730\u5c06\u5178\u578b\u7684p\u578bOECT\u805a\u5408\u7269\u8f6c\u6362\u4e3a\u9ad8\u6027\u80fd\u7684n\u578bOECT\u805a\u5408\u7269\u3002\u7814\u7a76\u8868\u660e\uff0c\u9664\u4e86\u8f83\u4f4e\u7684LUMO\u80fd\u7ea7\u5916\uff0c\u7535\u8377\u4f20\u8f93\u7c7b\u578b\u7684\u5f00\u5173\u673a\u5236\u4e3b\u8981\u662f\u7531\u4e8en\u63ba\u6742\u540e\u8d1f\u7535\u8377\u5206\u5e03\u66f4\u52a0\u5747\u5300\u3001\u9aa8\u67b6\u5e73\u9762\u5ea6\u589e\u5f3a\u3001\u6784\u8c61\u7a33\u5b9a\u6027\u66f4\u597d\u4ee5\u53ca\u8d1f\u6781\u5316\u5b50\u66f4\u52a0\u7a33\u5b9a\u3002\u8fd9\u4e9b\u7279\u5f81\u4f7f\u805a\u5408\u7269P(gTDPP2FT) \u8868\u73b0\u51fa\u7eafn\u578b\u7535\u8377\u4f20\u8f93\u884c\u4e3a\uff0c\u5177\u6709\u6700\u9ad8\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u4e3a0.35 cm2<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u6700\u9ad8\u7684\u03bcC*\u503c\u4e3a54.8 F cm-1<\/sup> V-1<\/sup> s-1<\/sup>\uff0c\u54cd\u5e94\u901f\u5ea6\u4e3a\u03c4on<\/sub>\/\u03c4off<\/sub> = 1.75\/0.15 ms\u3002\u672c\u7814\u7a76\u63ed\u793a\u4e86\u5e26\u7535\u6001\u548c\u4e2d\u6027\u6001\u4e4b\u95f4\u7535\u5b50\u6027\u8d28\u7684\u663e\u8457\u5dee\u5f02\uff0c\u5e76\u5f3a\u8c03\u4e86\u672a\u6765\u9ad8\u6027\u80fdOECT\u6750\u6599\u8bbe\u8ba1\u7684\u201c\u63ba\u6742\u6001\u5de5\u7a0b\u201d\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSwitching p-type to high-performance n-type organic electrochemical transistors via doped state engineering<\/a> ( Nat. Commun. <\/em>2022<\/strong>, DOI: 10.1038\/s41467-022-33553-w)<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u6709\u673a\u7535\u5316\u5b66\u6676\u4f53\u7ba1\uff08OECTs\uff09\u5728\u795e\u7ecf\u63a5\u53e3\u5668\u4ef6\u3001\u751f\u7269\u5316\u5b66\u4f20\u611f\u5668\u548c\u795e\u7ecf\u5f62\u6001\u8ba1\u7b97\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5404\u79cdp\u578b\u805a\u5408\u7269\u5df2\u88ab\u5f00\u53d1\u7528\u4e8e\u9ad8…<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4951],"class_list":["post-243398","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4951"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/243398"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=243398"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/243398\/revisions"}],"predecessor-version":[{"id":243408,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/243398\/revisions\/243408"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=243398"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=243398"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=243398"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}