{"id":244641,"date":"2022-12-06T08:04:45","date_gmt":"2022-12-06T00:04:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=244641"},"modified":"2022-12-05T21:26:47","modified_gmt":"2022-12-05T13:26:47","slug":"%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6mater-horiz-%e7%94%a8%e7%9c%9f%e6%ad%a3%e7%9a%84%e7%bb%bf%e8%89%b2%e6%ba%b6%e5%89%82%e5%88%b6%e5%a4%87%e9%ab%98%e6%95%88%e6%9c%89%e6%9c%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=244641","title":{"rendered":"\u534e\u5357\u7406\u5de5\u5927\u5b66Mater. Horiz. 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Horizons\u4e0a\u4e00\u9879\u5173\u4e8eB\u2212N\u5171\u4ef7\u952e\u805a\u5408\u7269\u6750\u6599\u5b9e\u73b0\u7eff\u8272\u6eb6\u5242\u5236\u5907\u9ad8\u6548OSCs\u5668\u4ef6\u7684\u5de5\u4f5c\u3002\u5728\u7eff\u8272\u6eb6\u5242\u82ef\u7532\u919a\u52a0\u5de5\u6761\u4ef6\u4e0b\uff0cOSCs\u5668\u4ef6\u5b9e\u73b0\u4e8615.65%\u7684PCE\uff0c\u540c\u65f6\u57fa\u4e8e1.10 cm2\u5927\u9762\u79ef\u5668\u4ef6\u7684PCE\u4e5f\u8d85\u8fc7\u4e8614%\uff0c\u5b9e\u73b0\u4e86\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u9886\u57df\u7684\u6548\u7387\u7a81\u7834\u3002\u8be5\u7814\u7a76\u4eceHansen\u6eb6\u5ea6\u53c2\u6570\u3001\u5206\u5b50\u5076\u6781\u7b49\u65b9\u9762\u8be6\u7ec6\u9610\u8ff0\u4e86B\u2212N\u5171\u4ef7\u952e\u805a\u5408\u7269\u53ef\u91c7\u7528\u82ef\u7532\u919a\u6eb6\u5242\u52a0\u5de5\u7684\u539f\u56e0\uff0c\u4e3a\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684\u9ad8\u6548\u5149\u4f0f\u6750\u6599\u4e0e\u5668\u4ef6\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244642\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72471-3.png\" alt=\"\" width=\"996\" height=\"487\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72471-3.png 996w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72471-3-300x147.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72471-3-768x376.png 768w\" sizes=\"(max-width: 996px) 100vw, 996px\" \/><\/p>\n<p><strong>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\u57fa\u4e8eB\u2212N\u5171\u4ef7\u952e\u5177\u6709\u6781\u6027\u7684\u7279\u70b9\uff0c\u63d0\u9ad8\u805a\u5408\u7269\u5171\u8f6d\u4e3b\u94fe\u6781\u6027\uff0c\u5b9e\u73b0\u6709\u673a\u592a\u9633\u7535\u6c60\u5668\u4ef6\u7684\u9ad8\u6548\u3001\u7eff\u8272\u52a0\u5de5\u3002<\/p>\n<p><strong>\u56db\u3001\u6570\u636e\u6982\u51b5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244643\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72472-2.png\" alt=\"\" width=\"1386\" height=\"725\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72472-2.png 1386w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72472-2-300x157.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72472-2-768x402.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72472-2-1024x536.png 1024w\" sizes=\"(max-width: 1386px) 100vw, 1386px\" \/><\/p>\n<p><strong><b>\u56fe1.<\/b><\/strong>\u00a0\u4ee3\u8868\u6027\u6eb6\u5242\u548c\u82ef\u7532\u919a\u7684GHS\u6807\u7b7e\u3002<\/p>\n<p>\u76ee\u524d\uff0c\u6709\u673a\u592a\u9633\u7535\u6c60\uff08OSCs\uff09\u7684\u5236\u5907\u4e25\u91cd\u4f9d\u8d56\u5267\u6bd2\u7684\u5364\u4ee3\u6eb6\u5242\uff0c\u5c3d\u7ba1\u8fd1\u5e74\u6765\u975e\u5364\u4ee3\u82b3\u9999\u70c3\u548c\u73af\u919a\u7b49\u6eb6\u5242\u88ab\u7528\u4f5c\u5364\u4ee3\u6eb6\u5242\u7684\u66ff\u4ee3\u6eb6\u5242\uff0c\u4f46\u6839\u636e\u8054\u5408\u56fd\u201c\u5168\u7403\u5316\u5b66\u54c1\u7edf\u4e00\u5206\u7c7b\u548c\u6807\u7b7e\u5236\u5ea6\u201d\uff08GHS\uff09\u7684\u6807\u51c6\uff0c\u6b64\u7c7b\u6eb6\u5242\u4ecd\u4e0d\u662f\u771f\u6b63\u7684\u201c\u7eff\u8272\u201d\u6eb6\u5242\uff0c\u8fd9\u5c06\u4e0d\u5229\u4e8eOSCs\u7684\u672a\u6765\u5de5\u4e1a\u5316\u5927\u9762\u79ef\u5236\u5907\u3002CHEM21\u3001Pfizer\u3001Sanofi\u3001GlaxoSmithKline\u7b49\u7ec4\u7ec7\u4e0e\u533b\u836f\u5de8\u5934\u5bf9\u6eb6\u5242\u7684\u6bd2\u6027\u7b49\u8fdb\u884c\u8fc7\u7cfb\u7edf\u8bc4\u4f30\uff0c\u5728\u6eb6\u5242\u9009\u62e9\u6307\u5357\u4e2d\u63a8\u8350\u4f7f\u7528\u6c34\u3001\u9187\u548c\u82ef\u7532\u919a\u7b49\u6eb6\u5242\u3002\u76f8\u6bd4\u6c34\u548c\u9187\u7b49\u6eb6\u5242\uff0c\u82ef\u7532\u919a\u66f4\u6709\u53ef\u80fd\u6210\u4e3a\u6709\u673a\u534a\u5bfc\u4f53\u7684\u826f\u6eb6\u5242\u3002\u540c\u65f6\uff0c\u6750\u6599\u5b89\u5168\u6570\u636e\u8868\uff08MSDS\uff09\u8868\u660e\uff0c\u82ef\u7532\u919a\u9664\u4e86GHS02\uff08\u6613\u71c3\uff09\u6807\u8bb0\u5916\uff0c\u6ca1\u6709GHS05\uff08\u8150\u8680\u6027\uff09\u3001GHS06\uff08\u6709\u6bd2\uff09\u3001GHS07\uff08\u6709\u5bb3\uff09\u3001GHS08\uff08\u5065\u5eb7\u5371\u5bb3\uff09\u6216GHS09\uff08\u73af\u5883\u5371\u5bb3\uff09\u7b49\u6807\u8bb0\u3002\u82ef\u7532\u919a\u53c8\u53eb\u8334\u9999\u919a\uff0c\u5728\u81ea\u7136\u754c\u5e7f\u6cdb\u5b58\u5728\u4e8e\u201c\u9f99\u84bf\uff08Tarragon\uff09\u201d\u7b49\u83ca\u79d1\u84bf\u5c5e\u690d\u7269\u4e2d\uff0c\u800c\u9f99\u84bf\u662f\u53ef\u98df\u7528\u7684\u690d\u7269\uff0c\u5e38\u7528\u4e8e\u70f9\u996a\u6cd5\u56fd\u83dc\uff08\u56fe2a\uff0cb\uff09\u3002\u6b64\u5916\uff0c\u82ef\u7532\u919a\u8fd8\u5e7f\u6cdb\u7528\u4e8e\u836f\u7269\u5236\u5242\uff0c\u5728\u5a74\u5e7c\u513f\u5e7f\u6cdb\u98df\u7528\u7684\u7ef4\u751f\u7d20\u6ef4\u5242\u4e2d\u82ef\u7532\u919a\u662f\u4e3b\u8981\u6210\u5206\u4e4b\u4e00\uff08\u56fe2c\uff0cd\uff09\u3002\u603b\u800c\u8a00\u4e4b\uff0c\u82ef\u7532\u919a\u662f\u4e00\u7c7b\u5bf9\u4eba\u4f53\u548c\u73af\u5883\u65e0\u5bb3\u7684\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u3002\u53e6\u5916\uff0c\u82ef\u7532\u919a\u5177\u6709\u76f8\u5bf9\u9ad8\u7684\u6cb8\u70b9\uff08155 \u00b0C\uff09\uff0c\u9002\u5408OSCs\u7684\u5927\u9762\u79ef\u5236\u5907\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244644\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72473.png\" alt=\"\" width=\"961\" height=\"611\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72473.png 961w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72473-300x191.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72473-768x488.png 768w\" sizes=\"(max-width: 961px) 100vw, 961px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>.<\/b><\/strong>\uff08a\uff09\u9f99\u84bf\uff0c\uff08b\uff09\u9f99\u84bf\u4f5c\u4e3a\u914d\u83dc\u7684\u6cd5\u56fd\u83dc\uff0c\uff08c\uff09\u548c\uff08d\uff09\u82ef\u7532\u919a\u7528\u4e8e\u5236\u5907\u5a74\u5e7c\u513f\u98df\u7528\u7684\u7ef4\u751f\u7d20\u6ef4\u5242\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244645\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72474.png\" alt=\"\" width=\"872\" height=\"392\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72474.png 872w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72474-300x135.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72474-768x345.png 768w\" sizes=\"(max-width: 872px) 100vw, 872px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244646\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72475.png\" alt=\"\" width=\"791\" height=\"262\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72475.png 791w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72475-300x99.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72475-768x254.png 768w\" sizes=\"(max-width: 791px) 100vw, 791px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>.<\/b><\/strong>\uff08a\uff09\u57fa\u4e8e\u7eff\u8272\u6807\u51c6\u5bf9OSCs\u52a0\u5de5\u5e38\u7528\u6eb6\u5242\u8fdb\u884c\u7684\u6392\u5e8f\uff0c\uff08b\uff09\u4ee3\u8868\u6027\u6eb6\u5242\u7684Hansen\u6eb6\u89e3\u5ea6\u53c2\u6570\uff0c\u4ee5\u53ca\uff08c\uff09\u4ee3\u8868\u6027\u9ad8\u6548\u5c0f\u5206\u5b50\u53d7\u4f53\u548c\u805a\u5408\u7269\u7ed9\u4f53\u5728\u82ef\u7532\u919a\u4e2d\u7684\u6eb6\u89e3\u72b6\u51b5\u3002<\/p>\n<p>\u9ad8\u6548OSCs\u5b9e\u73b0\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684\u5173\u952e\u5728\u4e8e\u80fd\u5426\u83b7\u5f97\u53ef\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684\u9ad8\u6027\u80fd\u5149\u4f0f\u6750\u6599\u3002\u521d\u6b65\u7684\u6eb6\u89e3\u5ea6\u6d4b\u8bd5\u8868\u660e\uff0c\u76ee\u524d\u9ad8\u6548\u7684\u975e\u5bcc\u52d2\u70ef\u5c0f\u5206\u5b50\u53d7\u4f53\uff08\u4f8b\u5982L8-BO\u3001Y6-BO\u548cY6\uff09\u5747\u53ef\u6eb6\u4e8e\u82ef\u7532\u919a\uff0c\u800c\u73b0\u6709\u7684\u9ad8\u6548\u805a\u5408\u7269\u7ed9\u4f53\u5219\u51e0\u4e4e\u5b8c\u5168\u4e0d\u6eb6\uff08\u56fe3c\uff09\u3002\u56e0\u6b64\uff0c\u5f53\u524d\u80fd\u5426\u4ee5\u82ef\u7532\u919a\u6210\u529f\u5236\u5907\u9ad8\u6548OSCs\u4e3b\u8981\u8fd8\u662f\u53d7\u9650\u4e8e\u805a\u5408\u7269\u7ed9\u4f53\u7684\u6eb6\u89e3\u6027\u3002\u6839\u636eHansen\u6eb6\u5ea6\u53c2\u6570\uff08HSPs\uff09\uff0c\u7eff\u8272\u6eb6\u5242\uff08\u6c34\u3001\u9187\u548c\u82ef\u7532\u919a\u7b49\uff09\u4e0e\u5e38\u7528\u7684\u5364\u4ee3\u6eb6\u5242\u3001\u975e\u5364\u6eb6\u5242\u76f8\u6bd4\uff0c\u5177\u6709\u66f4\u9ad8\u7684\u6781\u6027\u5206\u91cf\uff08<em><i>\u03b4<\/i><\/em><sub>P<\/sub>\uff09\uff08\u56fe3b\uff09\u3002\u56e0\u6b64\uff0c\u6839\u636e\u201c\u76f8\u4f3c\u76f8\u6eb6\u201d\u7684\u539f\u7406\uff0c\u8bbe\u8ba1\u7684\u805a\u5408\u7269\u7ed9\u4f53\u5e94\u5177\u6709\u8f83\u5927\u7684\u6781\u6027\uff0c\u4ee5\u5b9e\u73b0\u5728\u7eff\u8272\u6eb6\u5242\u4e2d\u8f83\u597d\u7684\u6eb6\u89e3\u6027\u3002\u6839\u636e\u6587\u732e\u62a5\u9053\uff0c\u5f15\u5165\u6781\u6027\u4fa7\u94fe\u662f\u589e\u52a0\u6709\u673a\u5171\u8f6d\u6750\u6599<em><i>\u03b4<\/i><\/em><sub>P<\/sub>\u7684\u5e38\u7528\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u6781\u6027\u4fa7\u94fe\u7684\u5f15\u5165\u5bf9\u6750\u6599\u7684\u7ed3\u6676\u5ea6\u3001\u7ed9\/\u53d7\u4f53\u7684\u76f8\u6eb6\u6027\u3001\u7535\u8377\u4f20\u8f93\u6027\u80fd\u7b49\u6027\u8d28\u4f1a\u4ea7\u751f\u8d1f\u9762\u5f71\u54cd\u3002\u4e3a\u4e86\u907f\u514d\u4e0a\u8ff0\u60c5\u51b5\uff0c\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u5728\u5171\u8f6d\u4e3b\u94fe\u4e0a\u5f15\u5165B\u2212N\u5171\u4ef7\u952e\u6765\u63d0\u9ad8\u6750\u6599\u6781\u6027\u7684\u7b56\u7565\u3002B\u2212N\u5171\u4ef7\u952e\u4e0eC=C\u952e\u662f\u7b49\u7535\u5b50\u4f53\uff0c\u4f46\u5f97\u76ca\u4e8eB\u539f\u5b50\u7684\u7f3a\u7535\u5b50\u6027\u8d28\u548cN\u539f\u5b50\u7684\u5bcc\u7535\u5b50\u6027\u8d28\uff0cB\u2212N\u5171\u4ef7\u952e\u662f\u6781\u6027\u952e\uff0c\u5177\u67091.84 Debye\u7684\u5076\u6781\u3002\u56e0\u6b64\uff0c\u5728\u5171\u8f6d\u4e3b\u94fe\u4e2d\u7528B\u2212N\u5171\u4ef7\u952e\u4ee3\u66ffC=C\u952e\u4e0d\u4ec5\u4e0d\u4f1a\u7834\u574f\u5206\u5b50\u7684\u5171\u8f6d\u548c\u7535\u5b50\u79bb\u57df\uff0c\u8fd8\u53ef\u4ee5\u6709\u6548\u589e\u52a0\u6750\u6599\u7684\u6781\u6027\u3002\u6545\u800c\u5728\u5171\u8f6d\u805a\u5408\u7269\u4e2d\u5f15\u5165B\u2212N\u5171\u4ef7\u952e\u662f\u5b9e\u73b0OSCs\u7eff\u8272\u52a0\u5de5\u7684\u53ef\u884c\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244647\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72476.png\" alt=\"\" width=\"1030\" height=\"503\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72476.png 1030w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72476-300x147.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72476-768x375.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72476-1024x500.png 1024w\" sizes=\"(max-width: 1030px) 100vw, 1030px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>.<\/b><\/strong>\uff08a\uff09\u6587\u732e\u62a5\u9053\u7684\u63d0\u9ad8\u6750\u6599\u6781\u6027\u7684\u65b9\u6cd5\uff0c\uff08b\uff09\u672c\u5de5\u4f5c\u63d0\u51fa\u7684\u589e\u52a0\u6750\u6599\u6781\u6027\u7684\u7b56\u7565\uff0c\uff08c\uff09\u672c\u5de5\u4f5c\u4e2d\u805a\u5408\u7269PBNT-TzTz\u7684\u5408\u6210\uff0c\u4ee5\u53ca\uff08d\uff09PBNT-TzTz\u5728\u82ef\u7532\u919a\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u60c5\u51b5\uff08c=8\u00a0mg\u00a0mL<sup>\u2212<\/sup><sup>1<\/sup>\uff09<\/p>\n<p>\u672c\u5de5\u4f5c\u5236\u5907\u7684\u805a\u5408\u7269PBNT-TzTz\u4e0d\u4ec5\u6613\u6eb6\u4e8e\u5e38\u89c1\u7684\u6709\u673a\u6eb6\u5242\uff0c\u5982\u6c2f\u4eff\u3001\u6c2f\u82ef\u548c\u7532\u82ef\u7b49\u3002\u800c\u4e14\uff0c\u901a\u8fc7\u5438\u6536\u548cBeer-Lambert\u5b9a\u5f8b\uff0c\u6d4b\u91cf\u5f97\u5230PBNT-TzTz\u5728\u82ef\u7532\u919a\u4e2d\u7684\u6eb6\u89e3\u5ea6\u9ad8\u8fbe11.2mg mL<sup>\u22121<\/sup>\u3002\u4e3a\u4e86\u9a8c\u8bc1PBNT-TzTz\u5728\u82ef\u7532\u919a\u4e2d\u826f\u597d\u7684\u6eb6\u89e3\u6027\u662f\u5f97\u76ca\u4e8e\u542bB\u2212N\u5171\u4ef7\u952e\u7684BNT\u5355\u5143\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u4e24\u79cd\u542bTzTz\u5355\u5143\u7684\u53c2\u6bd4\u805a\u5408\u7269\uff1aPBDT-TzTz\u548cPTTz-3HD\uff0c\u800c\u8fd9\u4e24\u4e2a\u6750\u6599\u5728\u82ef\u7532\u919a\u4e2d\u5b8c\u5168\u4e0d\u80fd\u6eb6\u89e3\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0cPBNT-TzTz\u5728\u82ef\u7532\u919a\u4e2d\u80fd\u83b7\u5f97\u826f\u597d\u6eb6\u89e3\u6027\u786e\u5b9e\u662f\u5f97\u76ca\u4e8e\u542bB\u2212N\u5171\u4ef7\u952e\u7684BNT\u5355\u5143\u3002\u5728\u7406\u8bba\u4e0a\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u4e86PBNT-TzTz\u548c\u53c2\u6bd4\u805a\u5408\u7269PBDT-TzTz\u7684\u5206\u5b50\u6781\u6027\u3002\u5982\u56fe5a\u6240\u793a\uff0cPBNT-TzTz\u7684\u5355\u4f53\u548c\u4e09\u805a\u4f53\u7684\u5076\u6781\u77e9\u5747\u9ad8\u4e8ePBDT-TzTz\u7684\u5076\u6781\u77e9\uff0c\u8fd9\u79cd\u5206\u5b50\u6781\u6027\u7684\u5dee\u5f02\u5f88\u597d\u5730\u89e3\u91ca\u4e86PBNT-TzTz\u548cPBDT-TzTz\u7684\u6eb6\u89e3\u5ea6\u5dee\u5f02\u3002\u7531\u4e8e\u6750\u6599\u5728\u6781\u6027\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u6027\u4e0e\u76f8\u5bf9\u4ecb\u7535\u5e38\u6570\u5927\u5c0f\u6b63\u76f8\u5173\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u901a\u8fc7\u7535\u5bb9\u2013\u7535\u538b\uff08<em><i>C\u2013V<\/i><\/em>\uff09\u8868\u5f81\u4e86\u6750\u6599\u7684\u76f8\u5bf9\u4ecb\u7535\u5e38\u6570\uff08<em><i>\u03b5<\/i><\/em><sub>r<\/sub>\uff09\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff08\u56fe5b\uff09\uff0c\u5f97\u76ca\u4e8e\u5177\u6709\u6781\u6027\u7684B\u2212N\u5171\u4ef7\u952e\uff0cPBNT-TzTz\u7684<em><i>\u03b5<\/i><\/em><sub>r<\/sub>\u503c\u66f4\u5927\u3002\u4ee5\u4e0a\u7406\u8bba\u548c\u5b9e\u9a8c\u7ed3\u679c\u8bc1\u660e\u4e86PBNT-TzTz\u5728\u82ef\u7532\u919a\u4e2d\u826f\u597d\u7684\u6eb6\u89e3\u6027\u6e90\u4e8e\u5177\u6709\u6781\u6027\u7684B\u2212N\u5171\u4ef7\u952e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244648\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72477.png\" alt=\"\" width=\"729\" height=\"534\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72477.png 729w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72477-300x220.png 300w\" sizes=\"(max-width: 729px) 100vw, 729px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong>\uff08a\uff09\u901a\u8fc7DFT\u8ba1\u7b97\u7684PBNT-TzTz\u548c\u53c2\u6bd4\u805a\u5408\u7269PBDT-TzTz\u7684\u5355\u4f53\u548c\u4e09\u805a\u4f53\u7684\u5076\u6781\u77e9\uff0c\uff08b\uff09PBNT-TzTz\u548cPBDT-TzTz\u5728\u4e0d\u540c\u9891\u7387\u4e0b\u7684\u76f8\u5bf9\u4ecb\u7535\u5e38\u6570\uff0c\uff08c\uff09\u5f52\u4e00\u5316\u7684\u8584\u819c\u5438\u6536\u5149\u8c31\uff0c\u4ee5\u53ca\uff08d\uff09PBNT-TzTz\u548c\u53d7\u4f53Y6-BO\u7684\u80fd\u7ea7\u3002<\/p>\n<p>\u5728\u5668\u4ef6\u4f18\u5316\u8fc7\u7a0b\u4e2d\uff0c\u4f5c\u8005\u9009\u62e9\u67e0\u6aac\u70ef\uff08LM\uff09\u4f5c\u4e3a\u6eb6\u5242\u6dfb\u52a0\u5242\u3002\u67e0\u6aac\u70ef\u5e7f\u6cdb\u5b58\u5728\u4e8e\u67d1\u6a58\u7c7b\u6c34\u679c\u4e2d\uff0c\u88ab\u8ba4\u4e3a\u662f\u5b89\u5168\u7684\u98df\u54c1\u548c\u9999\u6599\u6dfb\u52a0\u5242\u3002\u5b9e\u9a8c\u53d1\u73b0\u82ef\u7532\u919a:LM\u4f53\u79ef\u6bd4\u5bf9PBNT-TzTz:Y6-BO\u7684OSCs\u5668\u4ef6\u6027\u80fd\u6709\u663e\u8457\u5f71\u54cd\u3002\u5728\u82ef\u7532\u919a\u5728\u52a0\u5165\u9002\u91cf\uff0820%\uff09LM\u540e\uff0c\u83b7\u5f97\u4e8615.65%\u7684\u5668\u4ef6\u6548\u7387\uff0c\u662f\u76ee\u524d\u7531\u771f\u6b63\u7684\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684\u5668\u4ef6\u6548\u7387\u7684\u6700\u9ad8\u503c\uff08\u56fe6c\uff09\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u6700\u4f18\u52a0\u5de5\u6761\u4ef6\uff0c\u8fdb\u4e00\u6b65\u5236\u5907\u4e861.10\u00a0cm<sup>2<\/sup>\u7684\u5927\u9762\u79ef\u5668\u4ef6\uff0c\u5e76\u83b7\u5f9714.01%\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08\u56fe6d\u548c\u88681\uff09\uff0c\u8bc1\u5b9e\u4e86\u57fa\u4e8ePBNT-TzTz\u7eff\u8272\u5236\u5907\u5927\u9762\u79efOSCs\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-244649\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72478.png\" alt=\"\" width=\"1226\" height=\"959\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72478.png 1226w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72478-300x235.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72478-768x601.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u56fe\u72478-1024x801.png 1024w\" sizes=\"(max-width: 1226px) 100vw, 1226px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>6<\/b><\/strong><strong><b>.<\/b><\/strong>\uff08a\uff09AM 1.5G\uff08100 mW cm<sup>\u22122<\/sup>\uff09\u4e0b\u7684<em><i>J\u2212V<\/i><\/em>\u66f2\u7ebf\uff08b\uff09PBNT-TzTz:Y6-BO\u5668\u4ef6\u5728\u4e0d\u540c\u52a0\u5de5\u6761\u4ef6\u4e0b\u7684EQE\u8c31\uff0c\uff08c\uff09\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684OSCs\u7684\u6548\u7387\u7edf\u8ba1\u56fe\u548c\uff08d\uff09\u9762\u79ef\u4e3a1.10 cm<sup>2<\/sup>\u7684PBNT-TzTz:Y6-BO\u5668\u4ef6\u7684<em><i>J\u2013V<\/i><\/em>\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u8868<\/b><\/strong><strong><b>1<\/b><\/strong>.\u00a0AM 1.5G\uff08100 mW cm<sup>\u22122<\/sup>\uff09\u8f90\u7167\u4e0b\u7531\u82ef\u7532\u919a:LM\u6eb6\u5242\u6df7\u5408\u7269\u5236\u5907\u7684PBNT-TzTz:Y6-BO\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u53c2\u6570\u3002<\/p>\n<table style=\"width: 850px;\">\n<tbody>\n<tr>\n<td style=\"width: 147px;\">\n<p>Device<\/p>\n<\/td>\n<td style=\"width: 96.97px;\">\n<p>Area<\/p>\n<p>(cm<sup>2<\/sup>)<\/p>\n<\/td>\n<td style=\"width: 91.02px;\">\n<p><em><i>V<\/i><\/em><sub>oc<\/sub><\/p>\n<p>(V)<\/p>\n<\/td>\n<td style=\"width: 83px;\">\n<p><em><i>J<\/i><\/em><sub>sc<\/sub><\/p>\n<p>(mA cm<sup>\u22122<\/sup>)<\/p>\n<\/td>\n<td style=\"width: 106px;\">\n<p><em><i>J<\/i><\/em><sub>sc<\/sub><sup>[a]<\/sup><\/p>\n<p>(mA cm<sup>\u22122<\/sup>)<\/p>\n<\/td>\n<td style=\"width: 118px;\">\n<p>FF<\/p>\n<\/td>\n<td style=\"width: 173px;\">\n<p>PCE<\/p>\n<p>(%)<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 147px;\">\n<p>Anisole:LM=10:0<\/p>\n<\/td>\n<td style=\"width: 96.97px;\">\n<p>0.04<\/p>\n<\/td>\n<td style=\"width: 91.02px;\">\n<p>0.88<\/p>\n<\/td>\n<td style=\"width: 83px;\">\n<p>24.40<\/p>\n<\/td>\n<td style=\"width: 106px;\">\n<p>23.33<\/p>\n<\/td>\n<td style=\"width: 118px;\">\n<p>0.66<\/p>\n<\/td>\n<td style=\"width: 173px;\">\n<p>14.06<\/p>\n<p>(13.64\u00b10.41)<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 147px;\" rowspan=\"2\">\n<p>Anisole:LM=8:2<\/p>\n<\/td>\n<td style=\"width: 96.97px;\">\n<p>0.04<\/p>\n<\/td>\n<td style=\"width: 91.02px;\">\n<p>0.88<\/p>\n<\/td>\n<td style=\"width: 83px;\">\n<p>25.42<\/p>\n<\/td>\n<td style=\"width: 106px;\">\n<p>24.38<\/p>\n<\/td>\n<td style=\"width: 118px;\">\n<p>0.70<\/p>\n<\/td>\n<td style=\"width: 173px;\">\n<p>15.65<\/p>\n<p>(15.25\u00b10.40)<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 96.97px;\">\n<p>1.10<\/p>\n<\/td>\n<td style=\"width: 91.02px;\">\n<p>0.88<\/p>\n<\/td>\n<td style=\"width: 83px;\">\n<p>24.38<\/p>\n<\/td>\n<td style=\"width: 106px;\">\n<p>23.10<\/p>\n<\/td>\n<td style=\"width: 118px;\">\n<p>0.65<\/p>\n<\/td>\n<td style=\"width: 173px;\">\n<p>14.01<\/p>\n<p>(13.58\u00b10.43)<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 147px;\">\n<p>Anisole:LM=6:4<\/p>\n<\/td>\n<td style=\"width: 96.97px;\">\n<p>0.04<\/p>\n<\/td>\n<td style=\"width: 91.02px;\">\n<p>0.88<\/p>\n<\/td>\n<td style=\"width: 83px;\">\n<p>24.64<\/p>\n<\/td>\n<td style=\"width: 106px;\">\n<p>23.87<\/p>\n<\/td>\n<td style=\"width: 118px;\">\n<p>0.67<\/p>\n<\/td>\n<td style=\"width: 173px;\">\n<p>14.51<\/p>\n<p>(14.35\u00b10.16)<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong><b>\u4e94\u3001\u6210\u679c\u542f\u793a<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>1\u3001The <em><i>J<\/i><\/em><sub>sc<\/sub>\u00a0values are integrated from the EQE spectra.<\/p>\n<p><strong><b>2\u3001<\/b><\/strong><strong><b>\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong>S.\u00a0Pang, Z.\u00a0Chen, et al,<em>\u00a0Mater. Horiz., <\/em><strong>20<\/strong><strong>2<\/strong><strong>2<\/strong>, DOI: 10.1039\/D2MH01314B.<\/p>\n<p>3\u3001\u672c\u5de5\u4f5c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u4e2a\u542bB\u2212N\u5171\u4ef7\u952e\u7684\u805a\u5408\u7269PBNT-TzTz\uff0c\u5f97\u76ca\u4e8eB\u2212N\u5171\u4ef7\u952e\u5177\u6709\u6781\u6027\u7684\u7279\u70b9\uff0c\u805a\u5408\u7269\u5728\u771f\u6b63\u7684\u7eff\u8272\u6eb6\u5242\u82ef\u7532\u919a\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u52a0\u5de5\u6027\u3002\u57fa\u4e8e\u82ef\u7532\u919a\u5236\u5907\u7684OSCs\u5668\u4ef6\u5b9e\u73b0\u4e8615.65%\u7684PCE\uff0c\u5b9e\u73b0\u4e86\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u52a0\u5de5OSCs\u7684\u6548\u7387\u7a81\u7834\u3002\u91cd\u8981\u7684\u662f\uff0c\u5728\u5171\u8f6d\u805a\u5408\u7269\u4e2d\u5f15\u5165B\u2212N\u5171\u4ef7\u952e\u53ef\u5b9e\u73b0\u82ef\u7532\u919a\u52a0\u5de5\u7684\u7b56\u7565\u5177\u6709\u901a\u7528\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5f00\u53d1\u8bbe\u8ba1\u53ef\u771f\u6b63\u7eff\u8272\u6eb6\u5242\u52a0\u5de5\u7684\u9ad8\u6548\u5149\u4f0f\u6750\u6599\u548c\u5668\u4ef6\u63d0\u4f9b\u4e86\u5d2d\u65b0\u601d\u8def\u3002<\/p>\n<p>4\u3001\u6b64\u5916\uff0c\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u5728\u5171\u8f6d\u805a\u5408\u7269\u4e2d\u5f15\u5165B\u2212N\u5171\u4ef7\u952e\u53ef\u5b9e\u73b0\u82ef\u7532\u919a\u52a0\u5de5\u7684\u7b56\u7565\u5177\u6709\u901a\u7528\u6027\uff0c\u4f5c\u8005\u8fd8\u5408\u6210\u4e86\u5176\u4ed6\u56db\u4e2a\u542bBNT\u5355\u5143\u7684\u5171\u8f6d\u805a\u5408\u7269\uff08PBNT-T\u3001PBNT-2FT\u3001PBNT-T46\u548cPBNT-2FT46\uff09\u7528\u4e8e\u53c2\u6bd4\u7814\u7a76\u3002\u7ed3\u679c\u8868\u660e\uff0c\u867d\u7136\u8fd9\u4e9b\u5171\u805a\u7269\u5177\u6709\u4e0d\u540c\u7684\u5171\u805a\u5355\u4f53\uff08\u567b\u5429\u548c\u4e8c\u6c1f\u567b\u5429\uff09\u548c\u4e0d\u540c\u7684\u4fa7\u94fe\uff0c\u4f46\u5728\u82ef\u7532\u919a\u4e2d\u5747\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u8fdb\u800c\u8bc1\u5b9e\u4e86\u8be5\u7b56\u7565\u7684\u6709\u6548\u6027\u548c\u901a\u7528\u6027\u3002<\/p>\n<p><span style=\"text-align: justify; color: #333333; text-transform: none; text-indent: 0px; letter-spacing: normal; font-family: 'Helvetica Neue', Helvetica, 'Hiragino Sans GB', 'Apple Color Emoji', 'Emoji Symbols Font', 'Segoe UI Symbol', Arial, sans-serif; font-size: 15px; font-style: normal; font-weight: 400; word-spacing: 0px; float: none; display: inline !important; white-space: normal; orphans: 2; widows: 2; font-variant-ligatures: normal; font-variant-caps: normal; -webkit-text-stroke-width: 0px; text-decoration-style: initial; text-decoration-color: initial;\">\u539f\u6587\u94fe\u63a5\uff1a<\/span><span style=\"margin: 0px; padding: 0px; text-align: justify; color: #333333; text-transform: none; text-indent: 0px; letter-spacing: normal; font-family: 'Helvetica Neue', Helvetica, 'Hiragino Sans GB', 'Apple Color Emoji', 'Emoji Symbols Font', 'Segoe UI Symbol', Arial, sans-serif; font-size: 15px; font-style: normal; font-weight: 400; word-spacing: 0px; white-space: normal; orphans: 2; widows: 2; font-variant-ligatures: normal; font-variant-caps: normal; -webkit-text-stroke-width: 0px; text-decoration-style: initial; text-decoration-color: initial;\">ttps:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2022\/mh\/d2mh01314b<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0\u4e00\u3001\u5bfc\u8bfb \u5b9e\u73b0\u6709\u673a\u592a\u9633\u7535\u6c60\uff08OSCs\uff09\u7684\u7eff\u8272\u52a0\u5de5\u5bf9OSCs\u4ea7\u4e1a\u5316\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u76ee\u524d\uff0c\u6709\u673a\u592a\u9633\u7535\u6c60\uff08OSCs\uff09\u7684\u5236\u5907\u4e25\u91cd\u4f9d\u8d56\u5267\u6bd2\u7684\u5364\u4ee3\u6eb6\u5242\uff0c\u5c3d\u7ba1\u8fd1\u5e74\u6765\u975e\u5364\u4ee3\u82b3\u9999&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-244641","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/244641"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=244641"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/244641\/revisions"}],"predecessor-version":[{"id":244660,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/244641\/revisions\/244660"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=244641"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=244641"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=244641"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}