{"id":245330,"date":"2023-01-02T09:43:42","date_gmt":"2023-01-02T01:43:42","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=245330"},"modified":"2023-01-02T09:43:42","modified_gmt":"2023-01-02T01:43:42","slug":"%e9%ba%bb%e7%9c%81%e7%90%86%e5%b7%a5%e5%ad%a6%e9%99%a2nature-materials%ef%bc%9a%e8%87%aa%e7%84%b6%e6%b7%b7%e5%90%88%e5%8e%9f%e5%88%99%e8%ae%be%e8%ae%a1%e5%87%ba%e9%ab%98%e5%a1%91%e6%80%a7%e9%93%b8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=245330","title":{"rendered":"\u9ebb\u7701\u7406\u5de5\u5b66\u9662Nature Materials\uff1a\u81ea\u7136\u6df7\u5408\u539f\u5219\u8bbe\u8ba1\u51fa\u9ad8\u5851\u6027\u94f8\u9020\u96be\u7194\u9ad8\u71b5\u5408\u91d1"},"content":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb<\/p>\n<p>\u9ad8\u71b5\u5408\u91d1\u7684\u4e0d\u65ad\u53d1\u5c55\u4e3a\u7ed3\u6784\u548c\u529f\u80fd\u6750\u6599\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002\u8010\u706b\u96be\u7194\u9ad8\u71b5\u5408\u91d1(RHEAs)\u662f\u9ad8\u71b5\u5408\u91d1\u5bb6\u65cf\u7684\u4e00\u4e2a\u91cd\u8981\u5b50\u96c6\uff0c\u81ea\u9996\u6b21\u5355\u76f8\u4f53\u5fc3\u7acb\u65b9(bcc)\u7ed3\u6784\u7684\u7b2c\u4e00\u4e2a\u5b9e\u4f8b\u88ab\u53d1\u73b0\u4ee5\u540e\uff0c\u5f15\u8d77\u4e86\u79d1\u5b66\u5bb6\u8d8a\u6765\u8d8a\u591a\u7684\u5174\u8da3\u3002\u9ad8\u71b5\u96be\u7194\u5408\u91d1(RHEA)\u7684\u9ad8\u6e29\u5c48\u670d\u5f3a\u5ea6\u53ef\u4ee5\u5f88\u597d\u7684\u4fdd\u5b58\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\u3002\u4f46\u662f\u76ee\u524d\uff0c\u96be\u7194\u9ad8\u71b5\u5408\u91d1\u7684\u5f00\u53d1\u9047\u5230\u4e86\u4e00\u4e9b\u74f6\u9888\uff1a\uff081\uff09\u5927\u591a\u6570\u62a5\u9053\u7684\u96be\u7194\u9ad8\u71b5\u5408\u91d1\u5728\u73af\u5883\u6e29\u5ea6\u4e0b\u8868\u73b0\u51fa\u6781\u4f4e\u7684\u62c9\u4f38\u5ef6\u5c55\u6027\uff1b\uff082\uff09\u7531\u4e8e\u96be\u7194\u5143\u7d20\u6269\u6563\u52a8\u529b\u5b66\u7684\u8fdf\u6ede\uff0c\u5fae\u89c2\u7ed3\u6784\u7684\u5747\u5300\u5316\u5f88\u53d7\u6311\u6218\uff1b\uff083\uff09\u5728\u4e2d\u95f4\u6e29\u5ea6\u4e0b\u6297\u6c27\u5316\u6027\u80fd\u4e0d\u8db3\u4e25\u91cd\u963b\u788d\u4e86\u70ed\u52a0\u5de5\u5904\u7406\u7684\u5e94\u7528\u3002\u7531\u4e8e\u8fd9\u4e9b\u6311\u6218\u548c\u7f3a\u4e4f\u8db3\u591f\u590d\u6742\u7684\u70ed\u529b\u5b66-\u52a8\u529b\u5b66\u7814\u7a76\u57fa\u7840\uff0cRHEA\u7684\u5e94\u7528\u6f5c\u80fd\u8fd8\u6ca1\u6709\u88ab\u5b8c\u5168\u5f00\u53d1\u3002\u672c\u5de5\u4f5c\u901a\u8fc7\u5e94\u7528cantor\u7684\u65b9\u6cd5\uff0c\u5229\u7528\u8010\u706b\u5143\u7d20\u4e4b\u95f4\u7684\u81ea\u7136\u6df7\u5408\u7279\u6027\u6765\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u94f8\u4ef6\u504f\u6790\uff0c\u4ece\u800c\u5f00\u53d1\u51fa\u4e00\u79cdRHEA\uff0c\u5177\u6709\u9ad8\u6e29\u5f3a\u5ea6\u4ee5\u53ca\u5851\u6027\u548c\u5f3a\u5ea6\u7684\u7406\u60f3\u7ec4\u5408\u3002<\/p>\n<p>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u7684Cemal Cem Tasan\u6559\u6388\u5229\u7528\u96be\u7194\u5143\u7d20\u4e4b\u95f4\u7684\u81ea\u7136\u6df7\u5408\u7279\u6027\uff0c\u8bbe\u8ba1\u4e86\u4e00\u79cdTi<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub>\u96be\u7194\u9ad8\u71b5\u5408\u91d1\uff0c\u8be5\u5408\u91d1\u5728\u94f8\u6001\u4e0b\u5177\u6709&gt;20%\u7684\u62c9\u4f38\u5ef6\u5c55\u6027\uff0c\u5728\u9ad8\u6e29\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7269\u7406\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u5728\u591a\u4e2a\u957f\u5ea6\u5c3a\u5ea6\u4e0a\u5bf9\u6f5c\u5728\u53d8\u5f62\u673a\u5236\u7684\u7814\u7a76\u8868\u660e\uff0c\u4e00\u79cd\u7f55\u89c1\u7684\u03b2\u2032\u76f8\u5728\u8fd9\u79cd\u5408\u91d1\u7684\u529b\u5b66\u54cd\u5e94\u4e2d\u8d77\u7740\u4e3b\u5bfc\u6027\u7684\u4f5c\u7528\uff0c\u5176\u6781\u5927\u7684\u63d0\u9ad8\u4e86\u5408\u91d1\u7684\u52a0\u5de5\u786c\u5316\u80fd\u529b\uff0c\u8fd8\u5177\u6709\u9632\u6b62\u5143\u7d20\u5feb\u901f\u6269\u6563\u7684\u80fd\u529b\u3002\u8fd9\u4e9b\u7ed3\u679c\u63ed\u793a\u4e86\u81ea\u7136\u6df7\u5408\u503e\u5411\u5728\u52a0\u901f\u9ad8\u71b5\u5408\u91d1\u53d1\u73b0\u65b9\u9762\u7684\u6709\u6548\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<em>Natural-mixing guided design of refractory high-entropy alloys with as-cast tensile ductility<\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u6750\u6599\u9876\u520a<strong><em>Nature Materilas<\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245332\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u5c01\u9762-3.png\" alt=\"\" width=\"948\" height=\"558\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u5c01\u9762-3.png 948w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u5c01\u9762-3-300x177.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/\u5c01\u9762-3-768x452.png 768w\" sizes=\"(max-width: 948px) 100vw, 948px\" \/><\/p>\n<p>\u4e09\u3001 \u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n<p>\uff081\uff09\u5de7\u5999\u7684\u5229\u7528\u96be\u7194\u5143\u7d20\u4e4b\u95f4\u7684\u81ea\u7136\u6df7\u5408\u7279\u6027\uff0c\u8bbe\u8ba1\u51fa\u4e00\u79cdTi<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub>\u96be\u7194\u9ad8\u71b5\u5408\u91d1\uff1b<\/p>\n<p>\uff082\uff09\u53d1\u73b0\u4e00\u79cd\u7f55\u89c1\u7684\u03b2\u2032\u76f8\uff0c\u5177\u6709\u4f18\u5f02\u7684\u9ad8\u6e29\u7269\u7406-\u5316\u5b66\u7a33\u5b9a\u6027\uff1b<\/p>\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245333\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-20.png\" alt=\"\" width=\"872\" height=\"473\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-20.png 872w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-20-300x163.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-20-768x417.png 768w\" sizes=\"(max-width: 872px) 100vw, 872px\" \/><\/p>\n<p>\u56fe1 \u8010\u706b\u5143\u7d20\u6210\u5206\u641c\u7d22\u7b56\u7565\uff1ba) RHEA\u7684\u94f8\u6001\u5fae\u89c2\u7ec4\u7ec7\uff0c\u7531\u4e5d\u79cd\u76f8\u540c\u539f\u5b50\u6bd4\u4f8b\u96be\u7194\u5143\u7d20\u7ec4\u6210\u3002EDS\u7ed3\u679c\u663e\u793a\u4e86\u56db\u4e2a\u76f8\u504f\u6790\u533a\u57df\u7684\u5b58\u5728\uff0c\u5206\u522b\u5bcc\u96c6Ti\u3001Mo\u3001Cr\u548cHf\uff1bb) \u56db\u79cd\u5408\u91d1\u7684\u94f8\u6001\u663e\u5fae\u7ec4\u7ec7\uff1bc) \u518d\u7ed3\u6676Ti<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub> RHEA\u7684\u5fae\u89c2\u7ed3\u6784\u8868\u5f81\uff0c\u5176\u7ec4\u6210\u7ee7\u627f\u81eaa\u4e2d\u6700\u5927\u7684\u5355\u76f8\u533a(\u8bb0\u4e3aTi-V-Nb-Hf) \uff1b<strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245334\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-20.png\" alt=\"\" width=\"871\" height=\"407\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-20.png 871w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-20-300x140.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-20-768x359.png 768w\" sizes=\"(max-width: 871px) 100vw, 871px\" \/><\/p>\n<p>\u56fe2 \u8bbe\u8ba1\u7684Ti<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub> RHEA\u7684\u529b\u5b66\u884c\u4e3a\uff1ba)\u5ba4\u6e29\u4e0b\u5355\u8f74\u62c9\u4f38\u6027\u80fd\u3002Ti<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub> RHEA\u5728\u94f8\u6001\u548c\u5747\u8d28-\u518d\u7ed3\u6676\u5904\u7406\u540e\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u5f3a\u5ea6-\u5851\u6027\u7ec4\u5408\uff1b\u63d2\u56fe\u663e\u793a\u4e86\u4e0e\u6587\u732e\u76f8\u6bd4\uff0c\u76ee\u524d\u4e24\u4e2aRHEA\u7684\u6bd4\u5c48\u670d\u5f3a\u5ea6(\u03c3ys\/\u03c1)\u548c\u65ad\u88c2\u4f38\u957f\u7387(\u03b5f)\u4e4b\u95f4\u7684\u7406\u60f3\u534f\u540c\u4f5c\u7528\u7684Ashby\u56fe\uff1bb)\u5e94\u53d8\u786c\u5316\u7387\u4e0e\u5c40\u90e8\u5e94\u53d8\u5256\u9762\u56fe\u3002\u63d2\u56fe\u663e\u793a\u4e86\u4e24\u4e2aRHEA\u5728\u7f29\u9888\u8d77\u59cb\u70b9(\u5149\u73af\u5708)\u548c\u65ad\u88c2\u524d\u7684\u5c40\u90e8\u5e94\u53d8\u5256\u9762\u3002<strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245335\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-20.png\" alt=\"\" width=\"907\" height=\"782\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-20.png 907w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-20-300x259.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-20-768x662.png 768w\" sizes=\"(max-width: 907px) 100vw, 907px\" \/><\/p>\n<p>\u56fe3 Ti<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub> RHEA\u7684\u53d8\u5f62\u673a\u5236\u7814\u7a76\uff1ba)\u5c40\u90e8\u5e94\u53d8\u6c34\u5e73\u4e3a~10%\u65f6\u8868\u9762\u53f0\u9636\u7684\u5f62\u6001(\u89c1\u9ec4\u8272\u7bad\u5934)\uff1bb) ECCI\u548cTEM\u8868\u5f81\u4f4d\u9519\u6784\u578b\u3002\u5de6\u56fe:\u4f4e\u500d\u7387ECCI\u663e\u5fae\u7167\u7247\uff0c\u663e\u793a\u5728\u5c40\u90e8\u5e94\u53d8\u6c34\u5e73\u4e3a~3.0%\u65f6\u5b58\u5728\u6c9f\u9053\u5e26\u3002\u53f3\u56fe:\u6700\u4e0a\u9762\u4e00\u6392\u7684\u9ad8\u500dECCI\u663e\u5fae\u7167\u7247\u663e\u793a\u4e86\u5f2f\u66f2\u4f4d\u9519\u7ed3\u6784(\u9ec4\u8272\u7bad\u5934\u7a81\u51fa\u663e\u793a)\uff0c\u8868\u660e\u7eb3\u7c73\u5c3a\u5ea6\u5f02\u8d28\u6027\u7684\u5b58\u5728\uff0c\u5e95\u90e8\u7684TEM BF\u56fe\u50cf\u9a8c\u8bc1\u4e86ECCI\u89c2\u6d4b\u7ed3\u679c\uff1bc)\u5b9a\u91cf\u8bc4\u4f30\u7531\u4e8e\u6c9f\u9053\u5e26\u5f62\u6210\u7684\u5bf9\u6bd4\u548c\u5c40\u90e8\u53d6\u5411\u5dee\u3002d)EBSD IPF\u56fe\u3001\u76f8\u56fe\u548cGROD\u56fe\u8868\u660e\uff0c\u4f4d\u9519\u5851\u6027\u53d8\u5f62\u53d1\u751f\u5728\u6c9f\u9053\u5e26\u5185\uff0c\u4f46\u6ca1\u6709\u673a\u68b0\u5b6a\u751f\u6216\u76f8\u53d8\u7684\u7279\u5f81\u3002<strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245336\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-19.png\" alt=\"\" width=\"872\" height=\"466\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-19.png 872w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-19-300x160.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-19-768x410.png 768w\" sizes=\"(max-width: 872px) 100vw, 872px\" \/><\/p>\n<p>\u56fe4 Ti<sub>38<\/sub>V<sub>15<\/sub>Nb<sub>23<\/sub>Hf<sub>24<\/sub> RHEA\u7ed3\u6784\u5f02\u8d28\u6027\u7684\u539f\u5b50\u5c3a\u5ea6\u8868\u5f81\u3002a) HRTEM\u663e\u5fae\u7167\u7247\u4e0e\u76f8\u5e94\u7684FFT\u6a21\u5f0f\u8868\u660e\u5b58\u5728bct\u7ed3\u6784\u7684\u7eb3\u7c73\u7ea7\u6c89\u6dc0\u7269\uff1b\u4ece\u5b9e\u6d4b\u7684FFT\u56fe\u5f62\u548c\u6a21\u62df\u7684FFT\u56fe\u5f62\u6027\u7279\u5f81\u8868\u660e\uff0c\u7eb3\u7c73\u6c89\u6dc0\u7269\u7684\u6676\u4f53\u7ed3\u6784\u4e3ac\u8f74\u6536\u7f29\u7684bct\u7ed3\u6784\uff0c\u5176\u6676\u683c\u5e38\u6570a<sub>\u03b20<\/sub>&#8216;\u4e0e\u57fa\u4f53bcc\u6676\u683c\u76f8\u540c\uff1bb) APT\u56fe\u3002\u7b49\u6210\u5206\u9762\u8bc1\u660e\u4e86\u6210\u5206\u7684\u975e\u5747\u8d28\u6027\u3002c)\u6cbf\u7740b\u4e2d\u9009\u5b9a\u7684\u7c92\u5b50\u83b7\u5f97\u7684\u8fd1\u4f3c\u503c\uff0c\u663e\u793abcc\u77e9\u9635\u548cbct\u6c89\u6dc0\u7269\u4e4b\u95f4\u7684\u5143\u7d20\u5206\u914d\u7279\u5f81\u3002d)\u5de6\u8fb9\u4e3a\u7eb3\u7c73\u6c89\u6dc0\u7269\u7ed3\u6784\u53d8\u5f62\u673a\u7406\u7684\u5b9a\u6027\u8bf4\u660e\u3002\u53f3\u8fb9\u663e\u793a\u7684\u662f\u4e00\u7cfb\u5217\u626d\u66f2\u533a\u57df\u7684HRTEM\u663e\u5fae\u7167\u7247\u3002\u968f\u7740\u7535\u5b50\u675f\u9000\u706b\u65f6\u95f4\u7684\u5ef6\u957f\uff0c\u8be5\u533a\u57df\u7ecf\u5386\u4e86\u7ed3\u6784\u6062\u590d\uff0c\u9010\u6e10\u6539\u5584\u4e86\u5c40\u90e8\u6676\u683c\u5468\u671f\u6027\uff0c\u652f\u6301\u4e86\u6240\u63d0\u51fa\u7684\u6790\u51fa-\u7ed3\u6784\u7578\u53d8\u673a\u5236\u3002e) TEM 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