{"id":245354,"date":"2023-01-07T06:00:37","date_gmt":"2023-01-06T22:00:37","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=245354"},"modified":"2023-01-04T21:11:39","modified_gmt":"2023-01-04T13:11:39","slug":"%e7%b1%b3%e5%85%b0%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6acs-catal-%ef%bc%9a%e9%ab%98%e6%b4%bb%e6%80%a7%e5%92%8c%e9%80%89%e6%8b%a9%e6%80%a7%e9%93%9c%e5%9f%ba%e5%8d%95%e5%8e%9f%e5%ad%90%e5%a4%9a%e7%9b%b8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=245354","title":{"rendered":"ACS Catal.\uff1a\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u94dc\u57fa\u5355\u539f\u5b50\u591a\u76f8\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u91d1\u5c5e\u5747\u76f8\u50ac\u5316\u5242\u5bf9\u4e8e\u5feb\u901f\u3001\u9ad8\u6548\u5730\u751f\u4ea7\u5316\u5b66\u54c1\u81f3\u5173\u91cd\u8981\u3002\u4e09\u5511\u662f\u5236\u5907\u836f\u7269\u3001\u519c\u836f\u3001\u5929\u7136\u5316\u5408\u7269\u548c\u529f\u80fd\u6750\u6599\u7684\u5173\u952e\u57fa\u5143\uff0c\u53e0\u6c2e\u5316\u7269\u2014\u7094\u70b9\u51fb\u73af\u52a0\u6210\u662f\u751f\u6210\u4e09\u5511\u7684\u91cd\u8981\u5747\u76f8\u53cd\u5e94\u7684\u4e00\u4e2a\u5b9e\u4f8b\u3002\u4e00\u9505\u4e09\u7ec4\u5206\u533a\u57df\u9009\u62e9\u6027\u53e0\u6c2e\u57fa\u73af\u52a0\u6210\u662f\u5408\u6210\u836f\u7269\u548c\u7cbe\u7ec6\u5316\u5b66\u54c1\u7684\u91cd\u8981\u53cd\u5e94\uff0c\u4e5f\u53ef\u5e94\u7528\u4e8e\u4f53\u5185\u4ee3\u8c22\u6807\u8bb0\u751f\u7269\u6280\u672f\u3002\u57fa\u4e8e\u4e0e\u8f85\u52a9\u914d\u4f53\u914d\u4f4d\u7684\u94dc\u7269\u79cd\u7684\u5747\u76f8\u50ac\u5316\u5242\u7ecf\u5e38\u7528\u4e8e\u8fdb\u884c\u8be5\u53cd\u5e94\uff0c\u4e0e\u57fa\u4e8e\u8d1f\u8f7d\u7684\u94dc\u7eb3\u7c73\u9897\u7c92\u7684\u5e38\u89c4\u975e\u5747\u76f8\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u50ac\u5316\u5242\u56de\u6536\u7684\u6311\u6218\u9650\u5236\u4e86\u8fd9\u4e9b\u5747\u76f8\u50ac\u5316\u5242\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u4e3a\u4e86\u89e3\u51b3\u4ee5\u4e0a\u96be\u9898\uff0c<strong>\u610f\u5927\u5229\u7c73\u5170\u7406\u5de5\u5927\u5b66<\/strong><strong>Gianvito Vil\u00e9<\/strong><strong>\u6559\u6388<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u591a\u76f8\u94dc\u57fa\u5355\u539f\u5b50\u50ac\u5316\u5242\u7528\u4e8e\u4e09\u5511\u5408\u6210\uff0c\u91cd\u70b9\u662f\u5bf9\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u529f\u80fd\u7684\u5168\u9762\u7406\u89e3\u3002\u901a\u8fc7\u4e09\u6c30\u57fa\u7532\u70f7\u805a\u5408\u5236\u5907\u4ee5\u521b\u9020\u4e00\u4e2a\u8054\u5408\u7535\u5b50\u7ed3\u6784\uff0c\u5176\u4e2d\u4ecb\u5b54\u77f3\u58a8\u6c2e\u5316\u7269\u8f7d\u4f53\u4f5c\u4e3a\u539f\u5b50\u5206\u6563\u7684\u94dc\u7269\u79cd\u7684\u914d\u4f53\u3002\u968f\u540e\u7ecf\u8fc7\u4e00\u7cfb\u5217\u5149\u8c31\u548c\u7406\u8bba\u65b9\u6cd5\u5bf9\u6750\u6599\u7279\u6027\u548c\u91d1\u5c5e\u7684\u7cbe\u786e\u4f4d\u7f6e\/\u914d\u4f4d\u8fdb\u884c\u4e86\u5206\u6790\u3002\u8fd9\u4e9b\u50ac\u5316\u5242\u88ab\u7528\u4e8e\u5728\u65e0\u78b1\u6761\u4ef6\u4e0b\u53e0\u6c2e\u2014\u7094\u70b9\u51fb\u53cd\u5e94\u5408\u62101,2,3-\u4e09\u5511\u5316\u5408\u7269\u3002\u4e0e\u5747\u76f8\u5bf9\u7167\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\u663e\u793a\u51fa\u66f4\u597d\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u5bc6\u5ea6\u51fd\u6570\u7406\u8bba\u8ba1\u7b97\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u7ed3\u679c\uff0c\u5e76\u8868\u660e\u53cd\u5e94\u901a\u8fc7Cu<sub>1<\/sub>\u4e0a\u7684\u4e59\u7094\u57fa\u7684\u6d3b\u5316\u6240\u4ea7\u751f\u7684\u80fd\u5792\u8fdb\u884c\uff0c\u8fd9\u4e00\u6b65\u9aa4\u7684\u6d3b\u6027\u4e3b\u8981\u53d7\u91d1\u5c5e\u4e0e\u8f7d\u4f53\u7684\u914d\u4f4d\u5f71\u54cd\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201c<strong>Azide-Alkyne Click Chemistry over a Heterogeneous Copper-Based Single-Atom Catalyst\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong><em>ACS Catalysis<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245355\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/0-14.png\" alt=\"\" width=\"600\" height=\"231\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/0-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/0-14-300x116.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u591a\u76f8\u94dc\u57fa\u5355\u539f\u5b50\u50ac\u5316\u5242\u7528\u4e8e\u65e0\u78b1\u6761\u4ef6\u4e0b\u4e09\u5511\u5408\u6210\uff0c\u4e0e\u5176\u4ed6\u62a5\u9053\u7684\u5747\u76f8\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u663e\u793a\u51fa\u66f4\u597d\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245356\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-22.png\" alt=\"\" width=\"600\" height=\"250\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-22.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/1-22-300x125.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e00\u3001\u50ac\u5316\u5242\u7684\u6210\u5206\u5206\u6790<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>\u591a\u76f8\u50ac\u5316\u5242\u7684\uff08a\uff09X\u5c04\u7ebf\u884d\u5c04\u56fe\u548c\uff08b\uff09N<sub>2<\/sub>\u7269\u7406\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245357\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-22.png\" alt=\"\" width=\"600\" height=\"600\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-22.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-22-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/2-22-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e8c\u3001\u50ac\u5316\u5242\u7684\u7ed3\u6784\u5206\u6790<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>saCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u7684\uff08a\uff09SEM\u3001\uff08b\uff09HR-TEM\u548c\uff08c\uff09AC HAADF-TEM\u8868\u5f81\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245358\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-22.png\" alt=\"\" width=\"600\" height=\"321\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-22.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/3-22-300x161.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e09\u3001\u50ac\u5316\u5242\u8868\u9762\u5206\u6790<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>\uff08a\uff09saCu-1@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u548c\uff08a\uff09saCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u7684Cu 2p XPS\u8868\u5f81\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245359\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-21.png\" alt=\"\" width=\"600\" height=\"693\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/4-21-260x300.png 260w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u56db\u3001\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u7cbe\u7ec6\u7ed3\u6784<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>\uff08a\uff09saCu-1@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u548csaCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u7684Cu XANES\u8868\u5f81\uff0c\u4ee5Cu<sub>2<\/sub>O\u548cCuO\u4f5c\u4e3a\u5bf9\u7167\u3002<\/p>\n<p>\uff08b\uff09saCu-1@mpgC<sub>3<\/sub>N<sub>4<\/sub>\uff08\u9876\u90e8\uff09\u548csaCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\uff08\u5e95\u90e8\uff09\u7684\u5e7f\u5ef6X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u3002<\/p>\n<p>\uff08c-g\uff09\u94dc\u57fa\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u53ef\u80fd\u6a21\u578b\u7ed3\u6784\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245360\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/5-14.png\" alt=\"\" width=\"600\" height=\"584\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/5-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/5-14-300x292.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e94\u3001\u50ac\u5316\u5242\u7684\u6027\u80fd\u8868\u5f81<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>\uff08a-b\uff09\u53cd\u5e94\u65f6\u95f4\u548c\u53cd\u5e94\u6e29\u5ea6\u5bf9\u4e0d\u540c\u50ac\u5316\u5242\uff08mpgC<sub>3<\/sub>N<sub>4<\/sub>\u3001CuCl<sub>2<\/sub>\u3001CuCl\u548csaCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\uff09\u7684\u5f71\u54cd\u3002<\/p>\n<p>\uff08c\uff09saCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u50ac\u5316\u5242\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\uff08d\uff09saCu-1@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u548csaCu-2@mpgC<sub>3<\/sub>N<sub>4<\/sub>\u7684\u50ac\u5316\u6d3b\u6027\u5bf9\u6bd4\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245361\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/6-8.png\" alt=\"\" width=\"600\" height=\"217\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/6-8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/12\/6-8-300x109.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u516d\u3001\u50ac\u5316\u673a\u7406\u7814\u7a76<\/strong><strong> \u00a9 2022 ACS publication<\/strong><\/p>\n<p>\uff08a\uff09\u63d0\u51fa\u7684\u8d1f\u8f7d\u578bCu<sub>1<\/sub>\u7269\u79cd\u4e0a\u4e09\u5511\u751f\u6210\u7684\u50ac\u5316\u5faa\u73af\u3002<\/p>\n<p>\uff08b\uff09130\u2103\u65f6\u7684\u53cd\u5e94\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86\u4e00\u79cd\u7528\u4e8e\u70b9\u51fb\u5316\u5b66\u7684\u7a33\u5b9a\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u4ec5\u7531\u5bcc\u542b\u7a00\u571f\u7684\u5143\u7d20\u5236\u6210\u3002\u8fd9\u79cd\u65b0\u578b\u50ac\u5316\u5242\u5229\u7528\u4ecb\u5b54\u77f3\u58a8\u78b3\u6c2e\u7ed3\u6784\u548c\u7535\u5b50\u6027\u8d28\u6765\u6355\u83b7\u94dc\u7269\u79cd\uff0c\u6a21\u62df\u5e76\u8d85\u8d8a\u4e86\u91d1\u5c5e\u7edc\u5408\u7269\u4e2d\u5747\u76f8\u914d\u4f53\u7684\u4f18\u52bf\u529f\u80fd\u3002\u5206\u5b50\u6c34\u5e73\u7684\u7814\u7a76\u663e\u793a\uff0c\u53cd\u5e94\u901a\u8fc7Cu<sub>1<\/sub>\u7269\u79cd\u4e0a\u7684\u7094\u57fa\u90e8\u5206\u7684\u6d3b\u5316\u6240\u63d0\u4f9b\u7684\u80fd\u5792\u8fdb\u884c\uff0c\u8fd9\u4e00\u6b65\u9aa4\u4e3b\u8981\u53d7\u91d1\u5c5e\u548c\u8f7d\u4f53\u4e4b\u95f4\u7684\u914d\u5408\u5f71\u54cd\u3002\u8fd9\u4e9b\u53d1\u73b0\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u901a\u8fc7\u7406\u89e3\u7cbe\u786e\u7684\u91d1\u5c5e\u914d\u4f4d\u6765\u4f18\u5316\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u91cd\u8981\u6027\uff0c\u5e76\u6709\u52a9\u4e8e\u4f18\u5316\u4e30\u5bcc\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u4ee5\u7528\u4e8e\u70b9\u51fb\u5316\u5b66\u548c\u5176\u4ed6\u7cbe\u7ec6\u5316\u5b66\u54c1\u4ee5\u53ca\u5236\u836f\u8fc7\u7a0b\u4e2d\u5177\u6709\u6311\u6218\u6027\u7684\u5316\u5b66\u53cd\u5e94\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.1c05610\" target=\"_blank\" rel=\"noopener\">Azide-Alkyne Click Chemistry over a Heterogeneous Copper-Based Single-Atom Catalyst<\/a> (<em>ACS Catal.,<\/em> <strong>2022<\/strong>, <em>12<\/em>, 2947\u22122958)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u91d1\u5c5e\u5747\u76f8\u50ac\u5316\u5242\u5bf9\u4e8e\u5feb\u901f\u3001\u9ad8\u6548\u5730\u751f\u4ea7\u5316\u5b66\u54c1\u81f3\u5173\u91cd\u8981\u3002\u4e09\u5511\u662f\u5236\u5907\u836f\u7269\u3001\u519c\u836f\u3001\u5929\u7136\u5316\u5408\u7269\u548c\u529f\u80fd\u6750\u6599\u7684\u5173\u952e\u57fa\u5143\uff0c\u53e0\u6c2e\u5316\u7269\u2014\u7094\u70b9\u51fb\u73af\u52a0\u6210\u662f\u751f\u6210\u4e09\u5511\u7684\u91cd\u8981\u5747\u76f8&#8230;<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4975],"class_list":["post-245354","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4975"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245354"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245354"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245354\/revisions"}],"predecessor-version":[{"id":245436,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245354\/revisions\/245436"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245354"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245354"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245354"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}