{"id":245544,"date":"2023-01-14T06:00:38","date_gmt":"2023-01-13T22:00:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=245544"},"modified":"2023-01-13T20:09:43","modified_gmt":"2023-01-13T12:09:43","slug":"%e5%88%86%e5%ad%90%e5%a2%9e%e5%bc%ba%e7%94%b5%e5%82%ac%e5%8c%96%ef%bc%9a%e6%9c%89%e6%9c%ba%e7%a1%92%e5%88%86%e5%ad%90%e7%9a%84%e6%96%b0%e5%a6%99%e7%94%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=245544","title":{"rendered":"\u5206\u5b50\u589e\u5f3a\u7535\u50ac\u5316\uff1a\u6709\u673a\u7852\u5206\u5b50\u7684\u65b0\u5999\u7528"},"content":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb<\/strong><\/p>\n

\u6790\u6c27\u53cd\u5e94\uff08OER\uff09<\/strong><\/span>\u4f5c\u4e3a\u6c34\u5206\u89e3\u53cd\u5e94\u7684\u534a\u53cd\u5e94\uff0c\u5177\u6709\u590d\u6742\u7684\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u6210\u4e3a\u9650\u5236\u7535\u89e3\u6c34\u7eff\u8272\u5236\u6c22\u6574\u4f53\u80fd\u91cf\u6548\u7387\u63d0\u5347\u7684\u74f6\u9888\u3002\u52a0\u901f\u6790\u6c27\u53cd\u5e94\u8fdb\u7a0b\uff0c\u53ef\u4ee5\u8003\u8651\u5982\u4f55\u589e\u52a0\u50ac\u5316\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u6570\u91cf\u548c\u964d\u4f4e\u53cd\u5e94\u52bf\u5792\uff0c\u4e3b\u8981\u7684\u65b9\u6cd5\u5305\u62ec\u63ba\u6742\u6742\u539f\u5b50\u3001\u6784\u7b51\u7a7a\u4f4d\u7f3a\u9677\u7b49\u65b9\u5f0f\u3002\u5176\u4e2d\u5728\u91d1\u5c5e\u6676\u683c\u4e2d\u63ba\u6742\u6742\u539f\u5b50\uff0c\u80fd\u591f\u91cd\u5851\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u7684\u53cd\u5e94\u6027\uff0c\u4fc3\u8fdb\u6790\u6c27\u53cd\u5e94\u3002\u4f8b\u5982:\u63ba\u6742\u7852\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u3002\u4f46\u5728\u82db\u523b\u7684\u7535\u50ac\u5316\u6761\u4ef6\u4e0b\uff0c\u901a\u5e38\u4f1a\u964d\u89e3\u6d41\u5931\u6742\u539f\u5b50\u5e76\u635f\u5931\u5176\u5177\u5907\u7684\u529f\u80fd\uff0c\u4ece\u800c\u5bfc\u81f4\u50ac\u5316\u5242\u7684\u9010\u6e10\u5931\u6d3b\u3002\u56e0\u6b64\uff0c\u5bfb\u6c42\u4e00\u79cd\u65b0\u7684\u589e\u5f3a\u7b56\u7565\uff0c\u5f15\u5165\u542b\u6742\u539f\u5b50\u7684\u6709\u673a\u5206\u5b50\u4f5c\u4e3a\u65b0\u7684\u8f85\u52a9\u4f4d\u70b9\u4ee5\u589e\u5f3a\u50ac\u5316\u4f53\u7cfb\uff0c\u4ee5\u5b9e\u73b0\u7a33\u5b9a\u7684\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u5728\u8d85\u8584\u91d1\u5c5e\u6709\u673a\u7eb3\u7c73\u7247Co-SeMON\u9884\u50ac\u5316\u5242\u4e2d\uff0c\u53d1\u73b0\u4e86\u4e00\u79cd\u542b\u6709\u7a33\u5b9aC\u2212Se\u2212C\u5171\u4ef7\u952e\u7684\u6709\u673a\u7852\u914d\u4f53\u53cc(3,5-\u4e8c\u7532\u57fa- 1H -\u5421\u5511-4-\u57fa)\u7852\u5316\u7269\uff0c\u53ef\u4ee5\u663e\u8457\u5c06\u94b4\u4f4d\u70b9\u7684\u50ac\u5316\u8d28\u91cf\u6d3b\u6027\u63d0\u9ad825\u500d\uff0c\u5e76\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5c06\u50ac\u5316\u5242\u7684\u64cd\u4f5c\u65f6\u95f4\u76f8\u5bf9\u4e8e\u5e38\u89c4\u7684\u65e0\u673a\u7852\u5316\u7269\u5ef6\u957f1\u62162\u4e2a\u6570\u91cf\u7ea7\u3002\u591a\u79cd\u539f\u4f4d\u548c\u975e\u539f\u4f4d\u5149\u8c31\u6280\u672f\u3001\u7b2c\u4e00\u539f\u7406\u5206\u5b50\u52a8\u529b\u5b66\uff08AIMD\uff09\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u7684\u7ed3\u5408\u63ed\u793a\u4e86\u6709\u673a\u7852\u5f3a\u5316\u673a\u5236\uff0c\u5176\u4e2d\u7852\u4e0e\u542b\u6c27\u4e2d\u95f4\u4f53\u7684\u975e\u7ecf\u5178\u952e\u5408\u4f5c\u7528\u8d4b\u4e88\u4e86\u8be5\u50ac\u5316\u5242\u8d85\u8d8a\u5e38\u89c4\u6bd4\u4f8b\u5173\u7cfb\u7684\u4e2d\u95f4\u4f53\u5438\u9644\u80fd\u8c03\u8282\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u5c55\u793a\u4e86\u5206\u5b50\u589e\u5f3a\u50ac\u5316\u5242\u5728\u9ad8\u6548\u3001\u7ecf\u6d4e\u7684\u6c34\u6c27\u5316\u65b9\u9762\u7684\u5de8\u5927\u6f5c\u529b\u3002\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u4f55\u7eaf\u633a\u56e2\u961f\u548c\u4e2d\u5c71\u5927\u5b66\u9648\u5c0f\u660e\u9662\u58eb\u5408\u4f5c\u5c06\u76f8\u5173\u5185\u5bb9\u4ee5\u9898\u4e3a\u201cMolecule-Enhanced Electrocatalysis of Sustainable Oxygen Evolution Using Organoselenium Functionalized Metal\u2212Organic Nanosheets<\/strong>\u201d\u53d1\u8868\u5728 J . Am. Chem. SOC<\/i><\/b>
\n \u4e0a\uff0c\u5e76\u88ab\u9074\u9009\u4e3a\u8865\u5145\u5c01\u9762\u8bba\u6587\u3002\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u4e3a\u4f55\u7eaf\u633a\u6559\u6388\uff1b\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9752\u5e74\u6559\u5e08\u66f9\u9ece\u660e\u535a\u58eb\u548c\u7855\u58eb\u751f\u80e1\u957f\u56fd\uff1b\u8bba\u6587\u901a\u8baf\u5355\u4f4d\uff1a\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

\u221a\u5f15\u5165\u4e00\u79cd\u542b\u6709\u7a33\u5b9aC\u2212Se\u2212C\u5171\u4ef7\u952e<\/strong><\/span>\u7684\u6709\u673a\u7852\u914d\u4f53\u53cc(3,5-\u4e8c\u7532\u57fa- 1H -\u5421\u5511-4-\u57fa)\u7852\u5316\u7269<\/p>\n

\u221a\u4e0e\u4f20\u7edf\u7684\u6676\u683c\u7852\u63ba\u6742\u8c03\u63a7\u76f8\u6bd4\uff0c\u5f15\u5165\u6709\u673a\u7852<\/strong><\/span>\uff0c\u589e\u5f3aOER\u50ac\u5316\u53cd\u5e94\u7a33\u5b9a\u6027<\/p>\n

\u56db\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/strong>\u00a0Co-SeMON\u7684\u7ed3\u6784\u7279\u5f81\u3002(a)\u6709\u673a\u7852\u914d\u4f53\u5408\u6210Co-SeMON\u53ca\u5176\u5728OER\u8fc7\u7a0b\u4e2d\u7684\u81ea\u91cd\u6784\u793a\u610f\u56fe\u3002(b) SEM\u56fe\u50cf\uff0c(c) TEM\u56fe\u50cf\uff0c(d) HRTEM\u56fe\u50cf\uff0c(e) \u6c2e\u6c14\u5438\u9644\u7b49\u6e29\u7ebf\uff0c(f) AFM\u56fe\u50cf\uff0c(g) Co-SeMON\u5bf9\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u00a0\u00a9 2022 ACS<\/span><\/p>\n

\"\"<\/p>\n

\u56fe2<\/strong> \u00a0Co-SeMON\u7684\u539f\u4f4d\u7ed3\u6784\u91cd\u7ec4\u4e0e\u6709\u673a\u7852\u7a33\u5b9a\u6027\u3002(a) HRTEM\uff0c(b) STEM-HAADF(\u63d2\u5165\u56fe\uff1aCoOOH\u6676\u683c\u7684\u91d1\u5c5e\u9635\u5217)\uff0c(c) OER\u540eCo-SeMON\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff0c(d) Co-SeMON\u57281.0 M KOH\u4e2dOER\u7684\u62c9\u66fc\u5149\u8c31(\u5728476\u548c578 cm\u22121<\/sup>\u5904\u6807\u8bb0\u4e3aCoOOH\u7684\u4e24\u4e2a\u7279\u5f81\u5cf0)\u3002(e) Co-SeMON OER\u524d\u540e\u7684FT-IR\u5149\u8c31(\u6807\u8bb01100 cm\u22121<\/sup>\u5904C\u2212Se\u952e\u7684\u7279\u5f81\u5cf0)\uff0c(f) Co-SeMON OER\u540e\u3001Co-MON OER\u540e\u3001Co\u7b94\u3001Co3<\/sub>O4<\/sub>\u548cCoO\u7684Co k<\/em>\u8fb9XANES\u8c31\uff0c(g) OER\u540eCo SeMON\u548cOER\u540eCo MON\u7684Co 2p<\/em>\u9ad8\u5206\u8fa8\u7387XPS\u8c31\uff0c(h) Co-SeMON OER\u540e\u3001Co-MON OER\u540e\u3001Co\u7b94\u3001Co3<\/sub>O4<\/sub>\u548cCoO\u7684FT-EXAFS\u8c31\u3002k<\/em>2<\/sup>\u52a0\u6743\u62d3\u5c55X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u7684\u6ce2\u53d8\u6362 (i) Co-SeMON OER\u540e\uff0c(j) Co-MON OER\u540e\uff0c(k) Co3<\/sub>O4<\/sub>\uff0c(l) CoO \u00a0\u00a9 2022 ACS<\/span><\/p>\n

\"\"<\/p>\n

\u56fe3<\/strong> \u00a0OER\u6027\u80fd\u8bc4\u4f30\u3002(a) 1.0 M KOH\u6761\u4ef6\u4e0b\u626b\u63cf\u901f\u7387\u4e3a5 mV\u00b7s\u22121<\/sup>\u65f6GCE\u7684Co-SeMON\u3001Co-MON\u3001RuO2<\/sub>\u548cH2<\/sub>SeBPz\u7684LSV\u6781\u5316\u66f2\u7ebf\u3002\u63d2\u56fe\uff1aCo-SeMON\u4ece1\u52306\u6b21\u7684\u8fde\u7eedLSV\u66f2\u7ebf\u3002(b) Co-SeMON\u3001Co-MON\u548cRuO2<\/sub>\u572810 mA\u00b7cm\u22122<\/sup>\u5904\u7684\u8fc7\u7535\u4f4d\u548cTafel\u659c\u7387\u3002(c) Co-SeMON\u548cCo-MON OER\u5728\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684Arrhenius\u56fe\u3002(d) \u572810 mA\u00b7cm\u22122<\/sup>\u4e0b\u7684\u8fc7\u7535\u4f4d\u548c\u4f7f\u7528\u5bff\u547d\u6216\u8fd0\u884c\u65f6\u95f4\u5185\u7684\u603b\u7535\u8377\u8f6c\u79fb\u91cf\u4e0e\u50ac\u5316\u5242\u7684\u6027\u80fd\u5bf9\u6bd4(\u4e09\u89d2\u5f62\uff1a\u591a\u91d1\u5c5e\u7852\u5316\u7269\uff1b\u5706\u5f62\uff1a\u5355\u91d1\u5c5e\u7852\u5316\u7269)\u3002(e) Co-SeMON@CC\u3001Co-MON@CC\u548cRuO2<\/sub>@CC\u5728500 mA\u00b7cm\u22122<\/sup>\u548c1000 mA\u00b7cm\u22122<\/sup>\u5904\u7684\u8fc7\u7535\u4f4d\u3002(f) \u0394\u03b7\/\u0394log|j|\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u533a\u95f4\u7684\u6bd4\u503c\u3002(g) \u57281.0 M KOH\u6eb6\u6db2\u4e2d\u5bf9Co-SeMON@CC\u8fdb\u884c\u6052\u7535\u4f4d\u7535\u89e3\u3002(h) Co-SeMON@CC\u548cCoSe2<\/sub>@CC\u5728100 mA\u00b7cm\u22122<\/sup>\u4e0b\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u6bd4\u8f83\u3002(i) \u5728Co-SeMON\u548cCoSe2<\/sub>\u7684\u4e0d\u540cOER\u626b\u63cf\u6bb5\u4e0b\uff0cSe\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u60c5\u51b5 \u00a9 2022 ACS<\/span><\/p>\n

\"\"<\/p>\n

\u56fe4<\/strong> \u6709\u673a\u7852\u5f3a\u5316\u673a\u5236\u3002(a) \u5728\u6a21\u62df\u76841.0 M KOH\u6c34\u6eb6\u6db2\u73af\u5883\u4e2d\uff0c\u7ecf\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u5f1b\u8c6b\u4e4b\u540e\u6709\u673aH2<\/sub>SeBPz\u4e2dSe\u2212C\u952e\u4e0e\u65e0\u673aCoSe2<\/sub>\u4e2dSe\u2212Co\u952e\u7684\u8ddd\u79bb\u5206\u5e03\u3002(b) H2<\/sub>SeBPz\u57281.0 M KOH\u6c34\u6eb6\u6db2\u4e2d\u7ecf\u8fc75 ps AIMD\u6a21\u62df\u540e\u7684\u5e73\u8861\u7ed3\u6784\u3002(c) H2<\/sub>SeBPz\u6216CoSe2<\/sub>\u4e2dO\u56f4\u7ed5Se\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u3002(d) CoOOH\/H2<\/sub>SeBPz\u4e0a\u7684\u56db\u7535\u5b50OER\u673a\u5236\u548c\u4f18\u5316\u7684\u4e2d\u95f4\u6784\u578b\u3002(e) \u4e0d\u540c\u50ac\u5316\u5242\u6a21\u578bOER\u8def\u5f84\u7684\u81ea\u7531\u80fd\u56fe\u3002CoOOH\/H2<\/sub>SeBPz\u542b(f) O*\u548c(g) OH*\u7684\u7535\u5b50\u5dee\u5206\u5bc6\u5ea6\u56fe\u3002(h) Se\u5728CoOOH\/H2<\/sub>SeBPz\u4e2d\uff0cO\u3001Se\u5728\u4e2d\u95f4\u4f53O\u914d\u4f4d\u7684CoOOH\/ SeH2<\/sub>SeBPz\u4e2d\u7684p<\/em>\u8f68\u9053PDOS\u56fe \u00a9 2022 \u00a0ACS<\/span><\/p>\n

 <\/p>\n

\u4e94\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u6587\u7ae0\u6210\u529f\u5408\u6210\u5e76\u8868\u5f81\u4e86\u65b0\u578b\u8d85\u8584\u91d1\u5c5e\u6709\u673a\u7eb3\u7c73\u7247Co-SeMON\u4f5c\u4e3a\u9ad8\u6548OER\u7684\u9884\u50ac\u5316\u5242\uff0c\u5176\u4e2d\u542b\u6709C\u2212Se\u2212C\u5171\u4ef7\u952e\u7684\u6709\u673a\u7852\u914d\u4f53\u3002\u901a\u8fc7\u5404\u79cd\u8868\u5f81\u6280\u672f\u3001\u7535\u5316\u5b66\u6d4b\u91cf\u3001AIMD\u6a21\u62df\u548cDFT\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86\u539f\u4f4d\u7ed3\u6784\u91cd\u7ec4\u548c\u6709\u673a\u7852\u5206\u5b50\u589e\u5f3a\u673a\u5236\u3002\u4e0e\u4f20\u7edf\u7684\u6676\u683c\u7852\u8c03\u63a7\u76f8\u6bd4\uff0c\u6709\u673a\u7852\u5728\u6574\u4e2aOER\u50ac\u5316\u8fc7\u7a0b\u4e2d\u975e\u5e38\u7a33\u5b9a\uff0c\u907f\u514d\u6eb6\u89e3\u5728\u7535\u89e3\u8d28\u4e2d\uff0c\u56e0\u6b64Se\u5bf9\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u548c\u6d3b\u6027\u4e2d\u95f4\u4f53\u7684\u589e\u5f3a\u4f5c\u7528\u4e0d\u4f1a\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\u800c\u51cf\u5f31\u3002\u6b64\u5916,\u6709\u673a\u7852\u901a\u8fc7Se\u4e0eO*\u7684\u5f31\u952e\u7ed3\u5408\uff0c\u589e\u5f3a\u4e86Co\u4f4d\u4e0eO\u4e2d\u95f4\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u529b\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002\u56e0\u6b64\uff0cCo-SeMON\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u53ef\u6301\u7eedOER\u6027\u80fd\uff0c\u662f\u6700\u5148\u8fdb\u7684\u975e\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u8bc1\u660eCo-SeMON\u50ac\u5316\u5242\u7684\u9ad8\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\uff0c\u540c\u65f6\u4e5f\u89c2\u5bdf\u5230\u6709\u673a\u7852\u7684\u5176\u4ed6\u5316\u5b66\u529f\u80fd\u3002\u7814\u7a76\u4e0d\u4ec5\u8be6\u7ec6\u9610\u8ff0\u4e86\u6709\u673a\u7852\u8c03\u63a7\u4e0eOER\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u800c\u4e14\u8fd8\u8bc1\u660e\u4e86\u5206\u5b50\u589e\u5f3a\u50ac\u5316\u7684\u6982\u5ff5\u5bf9\u9ad8\u9644\u52a0\u503c\u5de5\u4e1a\u5316\u5b66\u54c1\u7684\u9ad8\u6548\u7ecf\u6d4e\u751f\u4ea7\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aCao L-M, Hu C-G, Li H-H, et al. Molecule-Enhanced Electrocatalysis of Sustainable Oxygen Evolution Using Organoselenium Functionalized Metal\u2013Organic Nanosheets [J]. Journal of the American Chemical Society<\/em>, 2022.<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c10823<\/p>\n

 <\/p>\n

\u4f55\u7eaf\u633a\u6559\u6388\u7b80\u4ecb<\/strong><\/p>\n

\"\"<\/p>\n

\u4f55\u7eaf\u633a<\/strong>\uff08Chun-Ting He<\/strong>\uff09\uff0c\u6c5f\u897f\u5e08\u8303\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30022011\u548c2016\u5e74\u5206\u522b\u83b7\u4e2d\u5c71\u5927\u5b66\u7406\u5b66\u5b66\u58eb\u548c\u6750\u6599\u7269\u7406\u4e0e\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff08\u5bfc\u5e08\uff1a\u9648\u5c0f\u660e\u9662\u58eb\uff09\u3002\u66fe\u5148\u540e\u5230\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u53ca\u6fb3\u5927\u5229\u4e9aGriffith\u5927\u5b66\u8fdb\u884c\u8bbf\u5b66\u7814\u7a76\u3002\u5165\u9009\u56fd\u5bb6\u7ea7\u9ad8\u5c42\u6b21\u9752\u5e74\u4eba\u624d\uff0c\u4e2d\u56fd\u79d1\u534f\u201c\u9752\u5e74\u4eba\u624d\u6258\u4e3e\u5de5\u7a0b\u201d\uff0c\u4e2d\u56fd\u201c\u535a\u58eb\u540e\u521b\u65b0\u4eba\u624d\u652f\u6301\u8ba1\u5212\u201d\u548c\u6c5f\u897f\u7701\u201c\u53cc\u5343\u8ba1\u5212\u201d\u521b\u65b0\u9886\u519b\u4eba\u624d\u9879\u76ee\u3002\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u6c5f\u897f\u7701\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u7b49\u9879\u76ee\u3002\u66fe\u83b7\u9996\u5c4a\u6c5f\u897f\u9752\u5e74\u79d1\u6280\u5956\u3001\u6c5f\u897f\u9752\u5e74\u4e94\u56db\u5956\u7ae0\u3001\u6c5f\u897f\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\uff082\/4\uff09\u548c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\uff084\/7\uff09\u3002\u81f3\u4eca\u5df2\u5728Nat. Energy, Nat. Commun., J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater.\u7b49\u56fd\u9645\u8457\u540d\u671f\u520a\u53d1\u8868SCI\u8bba\u6587100\u4f59\u7bc7\uff0c\u5176\u4e2d17\u7bc7\u5148\u540e\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c\u8bba\u6587\u4ed6\u5f158500\u4f59\u6b21\uff0cH\u6307\u6570\u4e3a45\uff0c\u5165\u90092019\u5e74\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u671f\u520aTop1%\u9ad8\u88ab\u5f15\u4f5c\u8005\u3002\u517c\u4efb\u4e2d\u56fd\u6676\u4f53\u5b66\u4f1a\u9752\u5e74\u5de5\u4f5c\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u5168\u56fd\u50ac\u5316\u6750\u6599\u4e13\u5bb6\u59d4\u5458\u4f1a\u59d4\u5458\u548c\u6c5f\u897f\u7701\u6750\u6599\u5b66\u4f1a\u7406\u4e8b\u4f1a\u6210\u5458\u7b49\u3002<\/p>\n

 <\/p>\n

\u672c\u6587\u7531\u91d1\u7235\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb \u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u4f5c\u4e3a\u6c34\u5206\u89e3\u53cd\u5e94\u7684\u534a\u53cd\u5e94\uff0c\u5177\u6709\u590d\u6742\u7684\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u6210\u4e3a\u9650\u5236\u7535\u89e3\u6c34\u7eff\u8272\u5236\u6c22\u6574\u4f53\u80fd\u91cf\u6548\u7387\u63d0\u5347\u7684\u74f6\u9888\u3002\u52a0\u901f\u6790\u6c27\u53cd\u5e94\u8fdb\u7a0b\uff0c\u53ef\u4ee5\u8003…<\/p>\n","protected":false},"author":35611,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-245544","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245544"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35611"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245544"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245544\/revisions"}],"predecessor-version":[{"id":245920,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245544\/revisions\/245920"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245544"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245544"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245544"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}