{"id":245551,"date":"2023-01-13T06:00:17","date_gmt":"2023-01-12T22:00:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=245551"},"modified":"2023-01-12T19:44:38","modified_gmt":"2023-01-12T11:44:38","slug":"%e3%80%90%e5%b7%b2%e5%ae%a1%e3%80%91%e5%90%88%e6%88%90%e6%b0%a8%e6%96%b0%e6%9c%ba%e5%88%b6nat-commun%ef%bc%9a%e5%90%88%e6%88%90%e6%b0%a8%e5%82%ac%e5%8c%96%e4%b8%ad%e7%9a%84%e8%87%aa%e6%97%8b%e4%bf%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=245551","title":{"rendered":"\u5408\u6210\u6c28\u65b0\u673a\u5236Nat. 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spin promotion effect in catalytic ammonia synthesis<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong><em>Nature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-245553\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-5.png\" alt=\"\" width=\"692\" height=\"211\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-5.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72471-5-300x91.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>03<\/strong><strong>\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\u221a 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wp-image-245554\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72472-4.png\" alt=\"\" width=\"494\" height=\"372\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72472-4.png 494w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72472-4-300x226.png 300w\" sizes=\"(max-width: 494px) 100vw, 494px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u4e0d\u540c\u5408\u6210\u6c28\u50ac\u5316\u5242\u7684\u5b9e\u9a8c\u6d3b\u6027<\/strong> <strong>\u00a9 2022 The Author(s)<\/strong><\/p>\n<p>\u6ce8\uff1a\u7efc\u8ff0\u4e86\u4e00\u4e9b\u6700\u65b0\u7684\u548c\u6709\u524d\u9014\u7684\u5408\u6210\u6c28\u50ac\u5316\u5242\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-245555\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72473-5.png\" alt=\"\" width=\"706\" height=\"538\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72473-5.png 1150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72473-5-300x229.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72473-5-768x585.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72473-5-1024x780.png 1024w\" sizes=\"(max-width: 706px) 100vw, 706px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u8868\u9762\u76f8\u56fe<\/strong> <strong>\u00a9 2022 The Author(s)<\/strong><\/p>\n<p>\uff08a-d\uff09M*\/(MO)*\/(MOH)*\/(MN)*\u5728Ru(1015)\u8868\u9762\u7684\u5438\u9644\u7ed3\u6784\u7684\u9876\u90e8\u548c\u4fa7\u9762\u3002M\u4ee3\u8868\u91d1\u5c5e\u52a9\u50ac\u5316\u5242\u539f\u5b50\u3002\u7eff\u8272\u3001\u7d2b\u8272\u3001\u7ea2\u8272\u3001\u9ec4\u8272\u548c\u84dd\u8272\u7403\u4f53\u4ee3\u8868Ru\u3001\u52a9\u50ac\u5316\u5242M\u3001\u6c27\u3001\u6c22\u548c\u6c2e\u539f\u5b50\uff1b<\/p>\n<p>\uff08e-j\uff09\u5728\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0cCs\u3001K\u3001Li\u3001Ba\u3001Ca\u548cLa\u7684\u76f8\u56fe\u4fc3\u8fdbRu\u4e0e\u5b83\u4eec\u7684\u6c27\u5316\u7269\u3001\u6c22\u6c27\u5316\u7269\u3001\u6c2e\u5316\u7269\u6216\u78b1\u571f\u91d1\u5c5e\u5e73\u8861\u3002\u5927\u90e8\u5206\u7269\u79cd\u4ee5\u865a\u7ebf\u8868\u793a\uff0c\u800c\u5438\u9644\u7269\u79cd\u4ee5\u5b9e\u7ebf\u8868\u793a\uff0c\u5e76\u7528*\u6807\u8bc6\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-245556\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72474-4.png\" alt=\"\" width=\"735\" height=\"638\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72474-4.png 1198w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72474-4-300x260.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72474-4-768x667.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72474-4-1024x889.png 1024w\" sizes=\"(max-width: 735px) 100vw, 735px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u9759\u7535\u548c\u78c1\u6548\u5e94<\/strong><strong>\u00a9 2022 The Author(s)<\/strong><\/p>\n<p>\uff08a\uff09N-N\u8fc7\u6e21\u6001(TS)\u80fd\u91cf\u7a33\u5b9a(\u0394\u0394E<sub>TS<\/sub> = \u0394E<sub>TS<\/sub>(\u542b\u52a9\u50ac\u5316\u5242)- \u0394E<sub>TS<\/sub>(\u4e0d\u542b\u52a9\u50ac\u5316\u5242))\u5bf9\u4e8e\u4e0d\u540c\u52a9\u50ac\u5316\u5242\u7684\u9759\u7535\u4fc3\u8fdb\u4f5c\u7528(\u0394E<sub>\u52a9\u50ac\u5316\u5242<\/sub> = &#8211; \u03bc<sub>N-N<\/sub>\u2107<sub>\u52a9\u50ac\u5316\u5242<\/sub>)\u3002\u4e09\u89d2\u5f62\u548c\u6b63\u65b9\u5f62\u5206\u522b\u6307Ru\u548cCo\u66f2\u9762\uff1b<\/p>\n<p>\uff08b\uff09\u81ea\u65cb\u6781\u5316\u548c\u975e\u81ea\u65cb\u6781\u5316Co\u5bf9\u4e0d\u540c\u52a9\u50ac\u5316\u5242\u7684\u0394\u0394E<sub>TS<\/sub>\uff1b<\/p>\n<p>\uff08c\uff09\u81ea\u65cb\u6781\u5316\uff08b\u4e2d\u4e3a\u84dd\u8272\uff09\u548c\u975e\u81ea\u65cb\u6781\u5316\uff08b\u4e2d\u4e3a\u7eff\u8272\uff09Co\u7684TS\u80fd\u91cf\u4e4b\u95f4\u7684\u5dee\u503c\u0394\u0394E<sub>TS<\/sub>[diff]=\u0394\u0394E<sub>TS<\/sub>\uff08\u81ea\u65cb\u6781\u5316\uff09-\u0394\u0394E<sub>TS<\/sub>\uff1b<\/p>\n<p>\uff08d\uff09\u81ea\u65cb\u6781\u5316\u548c\u975e\u81ea\u65cb\u6781\u5316\u8868\u9762\u4e0a\u0394E<sub>TS<\/sub>\u548cd\u5e26\u9876\u90e8\u4e4b\u95f4\u5173\u7cfb\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter  wp-image-245557\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-5.png\" alt=\"\" width=\"747\" height=\"298\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-5.png 1297w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-5-300x120.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-5-768x307.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/01\/\u56fe\u72475-5-1024x409.png 1024w\" sizes=\"(max-width: 747px) 100vw, 747px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u81ea\u65cb\u6548\u5e94\u7684\u5e94\u7528<\/strong> <strong>\u00a9 2022 The Author(s)<\/strong><\/p>\n<p>\uff08a\uff09\u5b9e\u9a8c\u6d3b\u5ea6\u662f\u8ba1\u7b97\u8fc7\u6e21\u6001\u81ea\u7531\u80fd\u7684\u51fd\u6570\u3002\u8fd9\u4e9b\u50ac\u5316\u5242\u7684\u53c2\u8003\u6587\u732e\u7528\u4e0a\u6807\u6807\u8bb0\uff0c\u4e0a\u6807\u201ca\u201d\u4e3a\u672c\u5de5\u4f5c\u5236\u5907\u7684RuCs\/C\u50ac\u5316\u5242\uff1b<\/p>\n<p>\uff08b\uff09Co\u81ea\u65cb\u6781\u5316\u548c\u975e\u81ea\u65cb\u6781\u5316\u7684TS\u80fd\u91cf\u4e4b\u95f4\u7684\u5dee\u0394\u0394E<sub>TS<\/sub> [diff] = \u0394\u0394E<sub>TS<\/sub>(\u81ea\u65cb\u6781\u5316)- \u0394\u0394E<sub>TS<\/sub>(\u975e\u81ea\u65cb\u6781\u5316)\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u8bf1\u5bfcCo\u539f\u5b50\u5728\u6d3b\u6027\u9636\u8dc3\u70b9\u81ea\u65cb\u78c1\u77e9\u53d8\u5316\u7684\u51fd\u6570\uff1b<\/p>\n<p style=\"text-align: center;\"><strong>05<\/strong><strong>\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u5de5\u4f5c\u63d0\u51fa\u7684\u6a21\u578b\u89e3\u51b3\u4e86Ba\u548cCa\u5982\u4f55\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u5de5\u4f5c\u7684\u957f\u671f\u95ee\u9898\u3002\u5bf9\u4e8eRu\u548c\u5176\u4ed6\u975e\u78c1\u6027\u50ac\u5316\u5242\uff0c\u5176\u4fc3\u8fdb\u4f5c\u7528\u673a\u5236\u4e3b\u8981\u901a\u8fc7\u9759\u7535\u4f5c\u7528\u6765\u89e3\u91ca\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8be5\u6a21\u578b\u91cd\u70b9\u89e3\u91ca\u4e86\u78c1\u6027\u52a9\u50ac\u5316\u5242Li\u3001Ba\u3001Ca\u548cLa\u5bf9Co\u7684\u663e\u8457\u4fc3\u8fdb\u4f5c\u7528\uff0c\u8fd9\u6837\u4e00\u79cd\u65b0\u7684\u81ea\u65cb\u4fc3\u8fdb\u6548\u5e94\u4e0d\u4ec5\u9650\u4e8e\u8fc4\u4eca\u4e3a\u6b62\u6240\u8003\u8651\u7684\u52a9\u50ac\u5316\u5242\uff0c\u800c\u4e14\u4e3a\u78c1\u6027\u50ac\u5316\u5242\u7684\u65b0\u52a9\u50ac\u5316\u5242\u7cfb\u7edf\u63d0\u4f9b\u4e86\u7814\u7a76\u4e0a\u7684\u53ef\u80fd\u6027\u3002\u8be5\u7814\u7a76\u53ef\u4e3a\u540e\u7eed\u5408\u6210\u6c28\u50ac\u5316\u5242\u7684\u7814\u53d1\u63d0\u4f9b\u6709\u6548\u5e2e\u52a9\uff0c\u671f\u5f85\u540e\u7eed\u6709\u66f4\u8fdb\u4e00\u6b65\u7684\u6210\u679c\u8bde\u751f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><strong>A spin promotion effect in catalytic ammonia synthesis<\/strong><strong>\uff0c<\/strong><strong>2022<\/strong><strong>\uff0c<\/strong><strong>https:\/\/doi.org\/10.1038\/s41467-022-30034-y<\/strong><strong>\uff09<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531LWB\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0 01\u3001\u5bfc\u8bfb \u6c28\u5bf9\u4e8e\u6c2e\u80a5\u751f\u4ea7\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u4e5f\u88ab\u8ba4\u4e3a\u662f\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u6f5c\u5728\u80fd\u6e90\u8f7d\u4f53\u3002\u54c8\u4f2f-\u535a\u4e16 \uff08Haber-Bosch\uff09\u5de5\u827a\u662f\u7528\u6c22\u56fa\u5b9a\u6c2e\u4ee5\u4ea7\u751f\u6c28\u7684\u5de5\u827a\uff0c\u8fd9\u662f\u5f53\u4eca\u5408&#8230;<\/p>\n","protected":false},"author":38813,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-245551","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245551"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/38813"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245551"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245551\/revisions"}],"predecessor-version":[{"id":245878,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/245551\/revisions\/245878"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245551"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245551"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245551"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}