{"id":246041,"date":"2023-01-25T06:00:36","date_gmt":"2023-01-24T22:00:36","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=246041"},"modified":"2023-01-24T20:21:59","modified_gmt":"2023-01-24T12:21:59","slug":"%e3%80%90%e5%b7%b2%e5%ae%a1%e3%80%91%e8%a5%bf%e5%ae%89%e4%ba%a4%e5%a4%a7fuel%ef%bc%9a%e9%80%9a%e8%bf%87%e7%bc%ba%e9%99%b7%e5%b7%a5%e7%a8%8b%e5%a2%9e%e5%bc%basmsi%e6%95%88%e5%ba%94%e5%ae%9e%e7%8e%b0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=246041","title":{"rendered":"\u897f\u5b89\u4ea4\u5927Fuel\uff1a\u901a\u8fc7\u7f3a\u9677\u5de5\u7a0b\u589e\u5f3aSMSI\u6548\u5e94\u5b9e\u73b0\u9ad8\u6548\u8131\u6c22"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u968f\u7740\u7ecf\u6d4e\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u5316\u77f3\u71c3\u6599\u7684\u6d88\u8017\u91cf\u9010\u6e10\u589e\u52a0\uff0c\u73af\u5883\u548c\u80fd\u6e90\u95ee\u9898\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\u3002\u4f5c\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u6c22\u80fd\u5728\u80fd\u6e90\u6d88\u8017\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u96f6\u78b3\u6392\u653e\uff0c\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\u3002\u7136\u800c\uff0c\u50a8\u6c22\u6280\u672f\u662f\u6c22\u80fd\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u74f6\u9888\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u9ad8\u6548\u50a8\u6c22\u6280\u672f\u4ee5\u6ee1\u8db3\u6c22\u80fd\u7684\u5927\u89c4\u6a21\u5229\u7528\u81f3\u5173\u91cd\u8981\u3002\u76ee\u524d\uff0c\u73b0\u6709\u7684\u50a8\u6c22\u6280\u672f\u7531\u4e8e\u50a8\u6c22\u5bc6\u5ea6\u4f4e\u3001\u80fd\u8017\u9ad8\u3001\u50a8\u6c22\u6750\u6599\u5bb9\u6613\u5931\u6d3b\u548c\u6210\u672c\u9ad8\u7b49\u7f3a\u70b9\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e94\u7528\u3002\u6709\u673a\u6db2\u6001\u50a8\u6c22\u8f7d\u4f53\uff08LOHC\uff09\u88ab\u8ba4\u4e3a\u662f\u5927\u89c4\u6a21\u50a8\u6c22\u7684\u7406\u60f3\u9009\u62e9\u3002\u5176\u4e2dNECZ\/12H-NECZ\u4f53\u7cfb\u7531\u4e8e\u5177\u67095.79 wt%\u7684\u9ad8\u50a8\u6c22\u5bb9\u91cf\u548c50.6 kJ\/mol H2<\/sub>\u7684\u4f4e\u8131\u6c22\u7113\u7684\u4f18\u5f02\u6027\u80fd\u800c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800cNECZ\u7684\u4f4e\u8131\u6c22\u901f\u7387\u548c\u9009\u62e9\u6027\u4f7f12H-NECZ\u7684\u8131\u6c22\u8fc7\u7a0b\u5145\u6ee1\u6311\u6218\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u4ee5\u4e0a\u96be\u9898\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u59dc\u53ec\u526f\u6559\u6388\u56e2\u961f<\/strong>\u901a\u8fc7\u5c06\u91d1\u5c5ePt\u548cSiO2<\/sub>-TiO(OH)2<\/sub>\u8f7d\u4f53\u7ed3\u5408\u5236\u5907\u4e86Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u50ac\u5316\u5242\u7528\u4e8e12H-NECZ\u8131\u6c22\u3002\u901a\u8fc7\u7814\u7a76\u8f7d\u4f53\u7684\u5236\u5907\u5de5\u827a\u548cPt\u7684\u8d1f\u8f7d\u91cf\u7b5b\u9009\u51fa\u4e86\u6700\u4f73\u50ac\u5316\u5242\u3002\u7ed3\u679c\u8868\u660e\uff0c2.5wt%Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u5177\u6709\u6700\u4f73\u7684\u8131\u6c22\u6027\u80fd\u3002\u7ed3\u5408XRD\u3001HRTEM\u3001ATR-FTIR\u3001XPS\u548cEPR\u5206\u6790\uff0c\u8be6\u7ec6\u8ba8\u8bba\u4e86\u50ac\u5316\u5242\u7684\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u548c\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u5bf9\u50ac\u5316\u8131\u6c22\u6027\u80fd\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5bf9\u5176\u52a8\u529b\u5b66\u5206\u6790\u548c\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u53d1\u73b0Pt\u548cSiO2-TiO(OH)2<\/sub>\u4e4b\u95f4\u7684\u9002\u5f53\u91d1\u5c5e-\u8f7d\u4f53\u5f3a\u76f8\u4e92\u4f5c\u7528\uff08SMSI\uff09\u6548\u5e94\u53ef\u4ee5\u8c03\u828212H-NECZ\u7684\u50ac\u5316\u8131\u6c22\u6027\u80fd\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cStrengthening the metal-support interaction over Pt\/SiO2<\/sub>-TiO(OH)2<\/sub> by defect engineering for efficient dehydrogenation of dodecahydro-N-ethylcarbazole<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aFuel<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u5236\u5907\u76842.5wt% Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u50ac\u5316\u5242\u663e\u793a\u51fa\u9ad8\u6548\u768412H-NECZ\u8131\u6c22\u6027\u80fd\uff0c\u5f52\u56e0\u4e8e\u63d0\u9ad8\u7684\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u589e\u5f3a\u4e86Pt\u548cSiO2<\/sub>-TiO(OH)2<\/sub>\u4e4b\u95f4\u7684SMSI\u6548\u5e94\uff0c\u6539\u53d8\u4e86Pt\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4f18\u5316\u4e86d\u5e26\u4e2d\u5fc3\u4ee5\u52a0\u901f\u53cd\u5e94\u3002<\/p>\n

\u56db\u3001\u3010\u8bba\u6587\u63a0\u5f71\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong>\u3001<\/strong>XRD<\/strong>\u5206\u6790<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff092.5PS\u30012.5PT\u30012.5PST\u30012.5PAT\u548c2.5PCT\u50ac\u5316\u5242\u7684XRD\u56fe\u6848\u3002<\/p>\n

\uff08b-c\uff09\u4e0d\u540cST\u8f7d\u4f53\u5408\u6210\u76842.5PST\u50ac\u5316\u5242\u7684XRD\u56fe\u6848\u3002<\/p>\n

\uff08d\uff09\u5236\u5907\u7684TiO(OH)2<\/sub>\u3001SiO2<\/sub>-TiO(OH)2<\/sub>\u3001SiO2<\/sub>-TiO2<\/sub>\u548cTiO2<\/sub>\u8f7d\u4f53\u7684XRD\u56fe\u6848\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001<\/strong>ATR-FTIR<\/strong>\u5149\u8c31<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a-b\uff092.5PT\u30012.5PS\u30012.5PST\u30012.5PAT\u548c2.5PCT\u5728650-4000 cm-1<\/sup>\u533a\u57df\u7684ATR-FTIR\u5149\u8c31\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540cST\u8f7d\u4f53\u5408\u6210\u76842.5PST\u50ac\u5316\u5242\u5728650-2000 cm-1<\/sup>\u533a\u57df\u7684ATR-FTIR\u5149\u8c31\u3002<\/p>\n

\uff08d\uff09ST\u4e0e2.5PST\u7684ATR-FTIR\u5149\u8c31\u5bf9\u6bd4\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e09\u3001<\/strong>EPR<\/strong>\u8868\u5f81<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

2.5PT\u30012.5PS\u548c2.5PST\u50ac\u5316\u5242\u7684EPR\u8c31\u56fe\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u56db\u3001<\/strong>XPS<\/strong>\u8868\u5f81<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

2.5PS\u30012.5PT\u548c2.5PST\u7684Si 2p\u3001Ti 2p\u3001Pt 4f\u4ee5\u53caO 1s XPS\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e94\u3001\u5b54\u5f84\u7ed3\u6784\u7814\u7a76<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09\u6c2e\u6c14\uff08N2<\/sub>\uff09\u5438\u9644-\u89e3\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\uff08b\uff092.5PT\u30012.5PS\u548c2.5PST\u50ac\u5316\u5242\u7684\u76f8\u5e94DFT\u4ecb\u5b54\u5c3a\u5bf8\u5206\u5e03\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u516d\u3001<\/strong>TEM<\/strong>\u8868\u5f81<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a-b\uff09\u4e0d\u540c\u653e\u5927\u500d\u6570\u76842.5PST\u50ac\u5316\u5242\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\uff08c-e\uff09\u56feb\u4e2d\u4e0d\u540c\u533a\u57df\u76f8\u5e94\u5c40\u90e8\u653e\u5927\u56fe\u50cf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e03\u3001\u5143\u7d20\u5206\u5e03<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09HRTEM\u56fe\u50cf\u548c2.5PST\u4e2dPt\u7684\u5e73\u5747\u5c3a\u5bf8\u5206\u5e03\u3002<\/p>\n

\uff08b-f\uff09O\u3001Si\u3001Pt\u548cTi\u7684mapping\u56fe\u50cf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u516b\u3001\u5b54\u5f84\u7ed3\u6784\u7814\u7a76<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09\u50ac\u5316\u5242\u5728453K\u4e0b\u7684\u65f6\u95f4\u5206\u8fa8\u8131\u6c22\u6027\u80fd\u3002<\/p>\n

\uff08b-i\uff0912H-NECZ\u8131\u6c22\u7684\u76f8\u5e94\u4ea7\u7269\u5206\u5e03\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e5d\u3001\u8131\u6c22\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u7814\u7a76<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\u4e09\u79cd\u57fa\u672c\u53cd\u5e94\u5728\u4e0d\u540c\u50ac\u5316\u5242\u4e0a\u7684\u901f\u7387\u5e38\u6570\u5bf9\u6bd4\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u3001\u672c\u5f81\u7535\u5b50\u7ed3\u6784\u4e0e\u50ac\u5316\u6027\u80fd\u7684\u5173\u7cfb<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff092.5PS\u30012.5PT\u548c2.5PST\u5230VBM\u7684\u9ad8\u5206\u8fa8\u7387\u4ef7\u5e26\u3002<\/p>\n

\uff08b\uff09\u50ac\u5316\u5242\u7684\u8131\u6c22\u6d3b\u6027\u4e0ed\u5e26\u4e2d\u5fc3\u7684\u5173\u7cfb\u3002<\/p>\n

\u4e94\u3001\u3010\u603b\u7ed3\u5c55\u671b\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u7528\u6eb6\u5242\u70ed\u6cd5\u5408\u6210\u4e86Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u50ac\u5316\u5242\uff0c\u5e76\u5bf9\u5176\u8131\u6c22\u6027\u80fd\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u7ed3\u679c\u8868\u660e\uff0c2.5wt% Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u50ac\u5316\u5242\u8868\u73b0\u51fa\u6700\u4f73\u7684\u8131\u6c22\u6027\u80fd\uff0c\u91ca\u653e\u91cf\u4e3a5.75wt%\uff0cNECZ\u7684\u9009\u62e9\u6027\u4e3a98%\u3002\u7ed3\u5408XRD\u3001HRTEM\u3001ATR-FTIR\u548cEPR\u5206\u6790\u8868\u660e\uff0c\u589e\u5f3a\u7684\u6027\u80fd\u53ef\u4ee5\u5f52\u56e0\u4e8e\u57282.5PST\u4e2dSiO2\u548cTiO(OH)2<\/sub>\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u4e86\u6c27\u7a7a\u4f4d\u7684\u751f\u6210\uff0c\u8fd9\u63d0\u4f9b\u4e86Pt\u7eb3\u7c73\u9897\u7c92\u7684\u66f4\u591a\u951a\u5b9a\u4f4d\u70b9\u3002\u672c\u7814\u7a76\u4e3a\u4f7f\u7528\u7f3a\u9677\u5de5\u7a0b\u65b9\u6cd5\u8bbe\u8ba1LOHC\u7cfb\u7edf\u7684\u9ad8\u6548\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aStrengthening the metal-support interaction over Pt\/SiO2<\/sub>-TiO(OH)2<\/sub> by defect engineering for efficient dehydrogenation of dodecahydro-N-ethylcarbazole<\/a> (Fuel<\/em> 2023<\/strong>, 334<\/em>, 126733)<\/p>\n

\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u968f\u7740\u7ecf\u6d4e\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u5316\u77f3\u71c3\u6599\u7684\u6d88\u8017\u91cf\u9010\u6e10\u589e\u52a0\uff0c\u73af\u5883\u548c\u80fd\u6e90\u95ee\u9898\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\u3002\u4f5c\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u6c22\u80fd\u5728\u80fd\u6e90\u6d88\u8017\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u96f6\u78b3\u6392\u653e\uff0c\u8d8a\u6765\u8d8a\u53d7…<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-246041","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246041"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=246041"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246041\/revisions"}],"predecessor-version":[{"id":246271,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246041\/revisions\/246271"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=246041"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=246041"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=246041"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}