{"id":246079,"date":"2023-01-26T06:00:14","date_gmt":"2023-01-25T22:00:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=246079"},"modified":"2023-01-24T20:22:32","modified_gmt":"2023-01-24T12:22:32","slug":"%e3%80%90%e5%b7%b2%e5%ae%a1%e3%80%91%e5%b1%b1%e4%b8%9c%e5%a4%a7%e5%ad%a6acs-catal-%ef%bc%9a%e5%b8%b8%e6%b8%a9%e5%b8%b8%e5%8e%8b%e4%b8%8bph%e8%b0%83%e6%8e%a7%e7%9a%84%e9%ab%98%e6%95%88co2%e5%82%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=246079","title":{"rendered":"\u5c71\u4e1c\u5927\u5b66ACS Catal.\uff1a\u5e38\u6e29\u5e38\u538b\u4e0bpH\u8c03\u63a7\u7684\u9ad8\u6548CO2\u50a8\u6c22\u6280\u672f"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u78b3\u4e2d\u548c\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u4e24\u79cd\u65b9\u5f0f\u5b9e\u73b0\uff1a1\u3001\u4ece\u4f20\u7edf\u77f3\u6cb9\u80fd\u6e90\u8f6c\u5411\u6e05\u6d01\u80fd\u6e90\u4ee5\u51cf\u5c11\u78b3\u6392\u653e\uff1b2\u3001\u901a\u8fc7\u78b3\u6355\u83b7\u53ca\u5229\u7528\u6765\u5e73\u8861\u78b3\u6392\u653e\u3002\u57fa\u4e8e\u8fd9\u4e00\u80cc\u666f\uff0c\u6c22\u6c14\u4f5c\u4e3a\u4e00\u79cd\u6e05\u6d01\u80fd\u6e90\u8f7d\u4f53\u5438\u5f15\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u56e0\u5176\u53ef\u4ee5\u901a\u8fc7\u53ef\u518d\u751f\u8d44\u6e90\u5236\u5907\uff0c\u4f8b\u5982\uff0c\u901a\u8fc7\u7535\u50ac\u5316\u6c34\u88c2\u89e3\uff0c\u5e76\u4e14\u5176\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u53ea\u4ea7\u751f\u80fd\u91cf\u548c\u526f\u4ea7\u7269\u6c34\u3002\u56e0\u6b64\u5927\u529b\u53d1\u5c55\u5316\u5b66\u50a8\u6c22\u6750\u6599\u5c06\u6709\u5229\u4e8e\u5bf9\u6c22\u6c14\u7b49\u6e05\u6d01\u80fd\u6e90\u7684\u9ad8\u6548\u5229\u7528\u5e76\u52a9\u529b\u56fd\u5bb6\u201c\u53cc\u78b3\u201d\u8ba1\u5212\u3002\u6c22\u6c14\u4f5c\u4e3a\u4e00\u79cd\u6e05\u6d01\u7684\u80fd\u6e90\u8f7d\u4f53\uff0c\u5bf9\u4e8e\u5176\u9ad8\u6548\u5316\u5b66\u5b58\u50a8\u4e0e\u91ca\u653e\u81f3\u5173\u91cd\u8981\u3002\u7532\u9178\u4f5c\u4e3a\u4e00\u79cd\u4fbf\u6377\u7684\u5316\u5b66\u50a8\u6c22\u4ecb\u8d28\uff0c\u539f\u5219\u4e0a\uff0c\u53ef\u4ee5\u901a\u8fc7\u53ef\u9006\u7684CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u5b9e\u73b0\u6c22\u6c14\u5316\u5b66\u5b58\u50a8\u4e0e\u91ca\u653e\u3002\u7136\u800c\uff0c\u76ee\u524d\u5927\u591a\u6570\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u7cfb\u7edf\u4ecd\u7136\u9700\u8981\u5927\u91cf\u5916\u90e8\u80fd\u91cf\u6ce8\u5165\u7528\u4e8eCO2<\/sub>\u6c22\u5316\u548c\u91ca\u653e\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u6761\u4ef6\u4e0b\u64cd\u4f5c\u7684\u9ad8\u6548\u50a8\u6c22\u548c\u91ca\u653e\u5de5\u827a\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5c71\u4e1c\u5927\u5b66\u4efb\u56fd\u5e86\u52a9\u7406\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u5236\u5907\u4e86L-\u7cbe\u6c28\u9178\uff08LA\uff09\u529f\u80fd\u5316\u7684\u6d3b\u6027\u78b3\u8d1f\u8f7d\u7684PdAu\u5408\u91d1\u50ac\u5316\u5242\uff08PdAu\/AC-LA\uff09\uff0c\u7528\u4e8epH\u8c03\u63a7\u7684\u7532\u9178\u57fa\u50a8\u653e\u6c22\u8fc7\u7a0b\u3002\u901a\u8fc7\u8c03\u8282LA\u8d1f\u8f7d\u548cPd\/Au\u6bd4\u4f8b\u83b7\u5f97\u4e86\u6700\u4f73\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7532\u9178\uff08FA\uff09\u91ca\u653e\u7684TOF\u4e3a1760 h-1<\/sup>\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0bCO2<\/sub>\u6c22\u5316\u7684TOF\u4e3a138 h-1<\/sup>\u3002XPS\u3001CO2<\/sub>-TPD\u548cHCOO–<\/sup>\u5438\u9644\u5b9e\u9a8c\u7b49\u63ed\u793a\u4e86PdAu\u5408\u91d1\u548cLA\u5f3a\u78b1\u6027\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u7269\u7684\u5438\u9644\u800c\u589e\u5f3a\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u672c\u7814\u7a76\u4f5c\u4e3a\u5728\u5e38\u6e29\u5e38\u538b\u6761\u4ef6\u4e0b\u57fa\u4e8eFA\/\u7532\u9178\u76d0\u7684\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u7684\u6210\u529f\u5b9e\u4f8b\uff0c\u5c06\u6709\u52a9\u4e8e\u63a8\u52a8\u6c22\u80fd\u6e90\u5e7f\u6cdb\u7684\u5546\u4e1a\u5316\u5e94\u7528\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cAmbient Hydrogen Storage and Release Using CO2<\/sub> and an L-Arginine-Functionalized PdAu Catalyst via pH Control<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aACS Catalysis<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u529f\u80fd\u5316\u50ac\u5316\u5242PdAu\/AC-LA\u4e3aFA\u8131\u6c22\u548cCO2<\/sub>\u6c22\u5316\u5e26\u6765\u4e86\u521b\u7eaa\u5f55\u7684TOF\uff0c\u572825\u2103\u548c0.1 MPa\u4e0b\u5206\u522b\u8fbe\u52301760 h-1<\/sup>\u548c138 h-1<\/sup>\uff0c\u968f\u540e\u901a\u8fc7\u5b9e\u9a8c\u63ed\u793a\u4e86\u5176\u589e\u5f3a\u7684\u50ac\u5316\u6d3b\u6027\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u56db\u3001\u3010\u8bba\u6587\u63a0\u5f71\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong>\u3001\u50ac\u5316\u5242\u5408\u6210\u53ca\u5fae\u89c2\u7ed3\u6784<\/strong> \u00a92022 ACS Publications<\/strong><\/p>\n

\uff08a\uff09PdAu\/AC-LA\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b-g\uff09Pd1<\/sub>Au2<\/sub>\/AC-LA\u7684HAADF-STEM\u56fe\u50cf\u4ee5\u53caC\u3001N\u3001Au\u3001Pd\u3001Pd+Au\u7684\u5143\u7d20mapping\u56fe\u50cf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001\u50ac\u5316\u5242\u7406\u5316\u6027\u8d28\u8868\u5f81<\/strong> \u00a92022 ACS Publications<\/strong><\/p>\n

\uff08a\uff09Pd1<\/sub>Au2<\/sub>\/AC\u548cPd1<\/sub>Au2<\/sub>\/AC-LA\u7684N2<\/sub>\u5438\u9644\u548c\u89e3\u5438\u7b49\u6e29\u7ebf\u3002<\/p>\n

\uff08b\uff09AC\u3001Pd1<\/sub>Au2<\/sub>\/AC-LA\u548cPd1<\/sub>Au2<\/sub>\/AC\u7684XRD\u56fe\u6848\u3002<\/p>\n

\uff08c-d\uff09\u4e0d\u540c\u50ac\u5316\u5242\u4e2d\u7684Pd\u548cAu\u7684XPS\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e09\u3001\u50ac\u5316<\/strong>CO2<\/sub><\/strong>\u52a0\u6c22\u53cd\u5e94\u6027\u80fd<\/strong> \u00a92022 ACS Publications<\/strong><\/p>\n

\uff08a\uff09\u5e38\u6e29\u5e38\u538b\u4e0b\u57fa\u4e8eFA\/\u7532\u9178\u76d0\u7684\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u4e0d\u540c\u50ac\u5316\u5242\u5bf9CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\uff08c\uff09PdAu\/AC-LA\u7684\u50ac\u5316\u6d3b\u6027\u4e0eAu\u542b\u91cf\u7684\u5173\u7cfb\u3002<\/p>\n

\uff08d\uff09LA\u542b\u91cf\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u5f71\u54cd\u3002<\/p>\n

\uff08e\uff09Pd1<\/sub>Au2<\/sub>\/AC\u548cPd1<\/sub>Au2<\/sub>\/AC-LA\u7684CO2<\/sub>-TPD\u4fe1\u53f7\u3002<\/p>\n

\uff08f\uff09\u4e0d\u540c\u6c28\u57fa\u9178\uff08AA\uff09\u7684Pd1<\/sub>Au2<\/sub>\/AC-AA\u50ac\u5316\u5242\u7684TON\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u56db\u3001\u50ac\u5316\u6c22\u6c14\u91ca\u653e\u6027\u80fd<\/strong> \u00a92022 ACS Publications<\/strong><\/p>\n

\uff08a\uff09Pd1<\/sub>Au2<\/sub>\/AC-LA\u548cPd1<\/sub>Au2<\/sub>\/AC\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u7684\u8131\u6c22\u6027\u80fd\u3002<\/p>\n

\uff08b\uff09Pd1<\/sub>Au2<\/sub>\/AC-LA\u548cPd1<\/sub>Au2<\/sub>\/AC\u7684HCOO–<\/sup>\u5438\u9644\u80fd\u529b\u5bf9\u6bd4\u3002<\/p>\n

\uff08c\uff09\u4f7f\u7528Pd1<\/sub>Au2<\/sub>\/AC-LA\u50ac\u5316\u5242\u5728\u4e00\u6bb5\u65f6\u95f4\u5185\u7684\u6c14\u76f8\u4ea7\u7269\u5206\u6790\u3002<\/p>\n

\uff08d\uff09Pd1<\/sub>Au2<\/sub>\/AC-LA\u50ac\u5316\u5242\u7684\u5faa\u73af\u53cd\u5e94\u6d3b\u6027\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e94\u3001\u53cd\u5e94\u673a\u7406<\/strong> \u00a92022 ACS Publications<\/strong><\/p>\n

\u63a8\u6d4bPd1<\/sub>Au2<\/sub>\/AC-LA\u4e0aCO2<\/sub>\u52a0\u6c22\u548cFA\u8131\u6c22\u7684\u53cd\u5e94\u673a\u7406\u56fe\u793a\u3002<\/p>\n

\u4e94\u3001\u3010\u603b\u7ed3\u5c55\u671b\u3011<\/strong><\/p>\n

\u901a\u8fc7LA\u529f\u80fd\u5316AC\u8d1f\u8f7d\u7684PdAu\u7eb3\u7c73\u50ac\u5316\u5242\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u57fa\u4e8eFA\/\u7532\u9178\u76d0\u7684\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u50ac\u5316\u6d3b\u6027\u3002\u901a\u8fc7\u4f18\u5316LA\u8d1f\u8f7d\u91cf\u548cAu\/Pd\u6bd4\u4f8b\uff0cPd1<\/sub>Au2<\/sub>\/AC-LA\u53cc\u50ac\u5316\u5242\u4e3aFA\u8131\u6c22\u548cCO2<\/sub>\u6c22\u5316\u5e26\u6765\u4e86\u521b\u7eaa\u5f55\u7684TOF\uff0c\u572825\u2103\u548c0.1 MPa\u4e0b\u5206\u522b\u8fbe\u52301760 h-1<\/sup>\u548c138 h-1<\/sup>\u3002\u4f18\u5f02\u7684\u6d3b\u6027\u6e90\u4e8e\u9178\u6027\u53cd\u5e94\u7269\uff08CO2<\/sub>\u548cHCOOH\uff09\u7684\u589e\u5f3a\u5438\u9644\u548cLA\u6539\u6027\u5f15\u8d77\u7684\u4eb2\u6c34\u6027\u4ee5\u53caPdAu\u5408\u91d1\u5316\u6548\u5e94\u5f15\u8d77\u7684\u7535\u5b50\u5bcc\u96c6\u3002\u672c\u7814\u7a76\u4e3a\u5e38\u6e29\u5e38\u538b\u6761\u4ef6\u4e0b\u7684\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6848\u4f8b\uff0c\u4e3a\u672a\u6765\u5927\u89c4\u6a21\u7684\u6c22\u6c14\u4f9b\u5e94\u5960\u5b9a\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAmbient Hydrogen Storage and Release Using CO2<\/sub> and an L-Arginine-Functionalized PdAu Catalyst via pH Control<\/a> ( ACS Catal. <\/em>2022<\/strong>, 12<\/em>, 14113\u201314122)<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u78b3\u4e2d\u548c\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u4e24\u79cd\u65b9\u5f0f\u5b9e\u73b0\uff1a1\u3001\u4ece\u4f20\u7edf\u77f3\u6cb9\u80fd\u6e90\u8f6c\u5411\u6e05\u6d01\u80fd\u6e90\u4ee5\u51cf\u5c11\u78b3\u6392\u653e\uff1b2\u3001\u901a\u8fc7\u78b3\u6355\u83b7\u53ca\u5229\u7528\u6765\u5e73\u8861\u78b3\u6392\u653e\u3002\u57fa\u4e8e\u8fd9\u4e00\u80cc\u666f\uff0c\u6c22\u6c14\u4f5c\u4e3a\u4e00…<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-246079","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246079"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=246079"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246079\/revisions"}],"predecessor-version":[{"id":246273,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/246079\/revisions\/246273"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=246079"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=246079"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=246079"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}