{"id":246544,"date":"2023-02-10T06:01:59","date_gmt":"2023-02-09T22:01:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=246544"},"modified":"2023-02-07T16:41:54","modified_gmt":"2023-02-07T08:41:54","slug":"nano-energy%ef%bc%9a%e5%bc%82%e8%b4%a8%e5%8f%8c%e9%87%91%e5%b1%9e%e7%a1%ab%e5%8c%96%e7%89%a9%e5%b1%82%e7%8a%b6ti3c2tx-mxene%e4%bd%9c%e4%b8%ba%e5%8d%8f%e5%90%8c%e7%94%b5%e6%9e%81-%e5%ae%9e%e7%8e%b0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=246544","title":{"rendered":"Nano Energy\uff1a\u5f02\u8d28\u53cc\u91d1\u5c5e\u786b\u5316\u7269@\u5c42\u72b6Ti3C2TX-Mxene\u4f5c\u4e3a\u534f\u540c\u7535\u6781 \u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6c34\u57fa\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb<\/strong><\/p>\n

\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u667a\u80fd\u7535\u5b50\u4ea7\u54c1\u3001\u533b\u7597\u8bbe\u5907\u548c\u5176\u4ed6\u65e5\u5e38\u7535\u5668\uff0c\u5728\u6211\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\u53d1\u6325\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u8fd1\u5e74\u6765\uff0c\u5404\u79cd\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668(SCs)\u7b49\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u5df2\u6210\u4e3a\u6709\u524d\u9014\u7684\u5019\u9009\u5668\u4ef6\uff0c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u6781\u5927\u5174\u8da3\u3002\u7136\u800c\uff0c\u7535\u5316\u5b66\u7535\u6c60\u5b58\u5728\u4f7f\u7528\u6613\u71c3\u548c\u6709\u6bd2\u6709\u673a\u7535\u89e3\u8d28\u7684\u5b89\u5168\u95ee\u9898\u4ee5\u53ca\u529f\u7387\u5bc6\u5ea6\u6709\u9650\u7684\u95ee\u9898\u3002\u6709\u9650\u7684\u5bff\u547d\u548c\u5145\u7535\u901f\u5ea6\u4f7f\u5176\u5728\u8bb8\u591a\u9886\u57df\u4e0d\u9002\u7528\u3002\u5c3d\u7ba1\u7535\u5316\u5b66SCs\u5728\u529f\u7387\u5bc6\u5ea6\u3001\u5bff\u547d\u3001\u5145\u7535\u901f\u7387\u7b49\u65b9\u9762\u90fd\u80fd\u6ee1\u8db3\u8981\u6c42\uff0c\u4f46\u5176\u80fd\u91cf\u5bc6\u5ea6\u8fdc\u4e0d\u5982\u7535\u5316\u5b66\u7535\u6c60\u3002\u6c34\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668(AHSCs)\u662f\u89e3\u51b3\u6240\u6709\u8fd9\u4e9b\u95ee\u9898\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u66ff\u4ee3\u65b9\u6848\uff0c\u5b83\u4f7f\u7528\u7535\u6c60\u578b\u7535\u6781\u6765\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4f7f\u7528\u7535\u5bb9\u578b\u7535\u6781\u6765\u63d0\u9ad8\u529f\u7387\u5bc6\u5ea6\u548c\u5bff\u547d\uff0c\u4f7f\u7528\u6c34\u7535\u89e3\u8d28\u6765\u89e3\u51b3\u5b89\u5168\u95ee\u9898\u3002AHSCs\u6709\u671b\u63d0\u4f9b\u6bd4\u542b\u6c34SCs\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u6bd4\u7535\u6c60\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u5728\u5bfb\u627e\u5408\u9002\u7684\u7535\u6781\u6750\u6599\u548c\u5668\u4ef6\u914d\u7f6e\u65b9\u9762\u53d6\u5f97\u4e86\u8fdb\u5c55\uff0c\u4f46\u901a\u8fc7\u6750\u6599\u9009\u62e9\u3001\u7ed3\u6784\u6784\u5efa\u6216\u8868\u9762\/\u754c\u9762\u5de5\u7a0b\uff0c\u5f00\u53d1\u65b0\u7684\u590d\u5408\u7cfb\u7edf\uff0c\u4f7f\u4e24\u4e2a\u7535\u6781\u5b9e\u73b0\u5b8c\u7f8e\u7684\u5145\u653e\u7535\u52a8\u529b\u5b66\u8fd9\u4e00\u95ee\u9898\uff0c\u4ecd\u7136\u4e9f\u5f85\u89e3\u51b3\u3002<\/p>\n

\u5c06\u4e8c\u7ef4MXenes\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u7ed3\u5408\u662f\u89e3\u51b3\u8be5\u95ee\u9898\u6700\u6709\u6548\u7684\u7b56\u7565\u4e4b\u4e00\u3002MXenes\u72ec\u7279\u7684\u7ed3\u6784\uff0c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u4e2d\u5177\u6709\u76f8\u5f53\u5927\u7684\u4f18\u52bf\uff0c\u5305\u62ec\u5feb\u901f\u7684\u7535\u5b50\u4f20\u8f93\u3001\u5feb\u901f\u7684\u79bb\u5b50\u6269\u6563\u548c\u826f\u597d\u7684\u8d5d\u7535\u5bb9\u6027\u80fd\u3002\u4e0e\u8fc7\u6e21\u53cc\u91d1\u5c5e\u786b\u5316\u7269\u7ed3\u5408\u540e\uff0c\u5f02\u8d28\u7ed3\u6784(HS)\u590d\u5408\u6750\u6599\u2014\u954d\u94b4\u786b\u5316\u7269(NCS)@MXene\u5c06\u89e3\u51b3MXenes\u7684\u4f4e\u7535\u5bb9\u95ee\u9898\uff0c\u63d0\u9ad8\u539f\u59cbNCS\u6750\u6599\u7684\u901f\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8fd9\u79cd\u7ec4\u5408\u4e0d\u4ec5\u5145\u5206\u5229\u7528\u4e86\u9ad8\u5ea6\u66b4\u9732\u7684\u4e8c\u7ef4\u5c42\u72b6\u6d3b\u6027\u6750\u6599\uff0c\u800c\u4e14\u8fd8\u4ea7\u751f\u4e86\u4f18\u5316\u79bb\u5b50\u63d2\u5c42\u3001\u7269\u7406\/\u5316\u5b66\u5438\u9644\u3001\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u7b49\u534f\u540c\u6548\u5e94\u3002MXenes\u901a\u8fc7\u5176\u9ad8\u5bfc\u7535\u6027\u548c\u4e8c\u7ef4\u7ed3\u6784\u4e2d\u66f4\u591a\u7684\u7535\u6d3b\u6027\u4f4d\u70b9\u63d0\u9ad8\u4e86\u590d\u5408\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8fd9\u79cd\u590d\u5408\u6750\u6599\u8fd8\u6ca1\u6709\u7528\u4e8eAHSCs\u3002<\/p>\n

\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u5170\u5dde\u5927\u5b66\u97e9\u536b\u534e\u6559\u6388\uff0cMuhammad Sufyan Javed\uff0c\u6df1\u5733\u5927\u5b66Tayyaba Najam\u5c06NCS\u7eb3\u7c73\u82b1\u539f\u4f4d\u5d4c\u5165\u5230\u5206\u5c42\u4e2d\uff0c\u91c7\u7528\u6c34\u70ed\u6cd5\u5236\u5907\u4e86Ti3<\/sub>C2<\/sub>TX<\/sub>-MXene\uff0c\u5e76\u5bf9\u5176\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u4f18\u5316\u540e\u7684HS-NCS@MXene\u8868\u73b0\u51fa\u8d85\u9ad8\u7535\u5bb9\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cHeterostructured bimetallic\u2013sulfide@layered Ti<\/strong>3<\/sub>C2<\/sub>Tx<\/sub>\u2013MXene as a synergistic electrode to realize high-energy-density aqueous \u00a0hybrid-supercapacitor<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNano Energy<\/em>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cdNCS\u7eb3\u7c73\u82b1\u5747\u5300\u5206\u6563\u5728MXene\u5c42\u5185\uff0c\u5f62\u6210\u4e09\u660e\u6cbb\u72b6\u7ed3\u6784\u7684\u5f02\u8d28\u7ed3\u6784\u590d\u5408\u6750\u6599HS-NCS@MXene\uff0c\u8be5\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u8d85\u9ad8\u7535\u5bb9\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7ec4\u88c5\u7684HS-NCS@MXene\/\/AC-AHSC\u53ef\u4ee5\u5728\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u5de5\u4f5c\uff0c\u5e76\u63d0\u4f9b\u9ad8\u5bb9\u91cf\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u5206\u6790\u8868\u660e\uff0c\u590d\u5408\u6750\u6599\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236\u662f\u6cd5\u62c9\u548c\u7535\u5316\u5b66\u53cc\u5c42\u5b58\u50a8\u7684\u7ed3\u5408\uff0c\u56e0\u6b64NCS\u548cMXene\u7684\u534f\u540c\u4f5c\u7528\u4f7fHS-NCS@MXene\u590d\u5408\u6750\u6599\u80fd\u591f\u4e3aAHSC\u63d0\u4f9b\u51fa\u8272\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u56db\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe1 \u6c34\u70ed\u6cd5\u5408\u6210HS<\/strong>\u2212<\/strong>NCS@MXene<\/strong>\u590d\u5408\u6750\u6599\u7684\u5de5\u827a\u793a\u610f\u56fe\u548c\u6c34\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5236\u5907\u8fc7\u7a0b\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe2 \u5f62\u8c8c\u8868\u5f81\u3002\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

(a) MAX\u76f8Ti3<\/sub>AlC2<\/sub>\u7684SEM\u56fe\u50cf\uff0c(b)\u5265\u79bbTi3<\/sub>C2<\/sub>Tx<\/sub>\u7684SEM\u56fe\u50cf\uff0c(c) NCO\u7684SEM\u56fe\u50cf\uff0c(d) HS-NCO@Ti3<\/sub>C2<\/sub>Tx<\/sub>\uff0c(e) HS-NCS@Ti3<\/sub>C2<\/sub>Tx<\/sub>\u7684\u9ad8\u5206\u8fa8\u7387SEM\u56fe\u50cf\uff0c(f) HS-NCS@Ti3<\/sub>C2<\/sub>Tx<\/sub>\u7684\u4f4e\u5206\u8fa8\u7387TEM\u56fe\u50cf(\u63d2\u56fe\u4e3a\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf)(g) HS-NCS@Ti3<\/sub>C2<\/sub>Tx<\/sub>\u7684EDX\u5143\u7d20\u6620\u5c04\u3002<\/p>\n

\"\"<\/strong><\/p>\n

\u56fe3 \u7269\u7406\u8868\u5f81\u3002\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

Ti3<\/sub>C2<\/sub>Tx<\/sub>-MXene, NCO, HS-NCO@MXene, HS-NCS@MXene\u7684(a)XRD\u56fe\u8c31(b) FTIR\u5149\u8c31\uff0c(c)\u62c9\u66fc\u5149\u8c31\u3002(d) Ti3<\/sub>C2<\/sub>Tx<\/sub>-MXene\u548cNCS@MXene\u7684\u5168\u626b\u63cfXPS\u8c31\uff0c(e) Ni-2p\uff0c(f) Co-2p\uff0c(g) Ti-2p\uff0c(h) C-1s\uff0c(i) S-2p\u7684\u53cd\u5377\u79efXPS\u8c31\u3002<\/p>\n

\"\"<\/strong><\/p>\n

\u56fe4 \u4e09\u7535\u6781\u4f53\u7cfbTi3<\/sub>C2<\/sub>Tx<\/sub>-MXene\u3001NCO\u3001HS<\/strong>\u2212<\/strong>NCO@MXene<\/strong>\u3001HS<\/strong>\u2212<\/strong>NCS@MXene<\/strong>\u7535\u6781\u5728KOH\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u8868\u5f81\u3002<\/strong><\/p>\n

HS\u2212NCS@MXene\u7684(a) CV\u66f2\u7ebf\uff0c(b) HS\u2212NCS@MXene\u7684CV\u66f2\u7ebf\uff0c(c) GCD\u66f2\u7ebf\uff0c(d) GCD\u66f2\u7ebf\uff0c(e)\u7535\u5bb9\/\u5bb9\u91cf\u4e0e\u7535\u6d41\u5bc6\u5ea6\u7684\u5173\u7cfb\uff0c(f) EIS\u8c31\uff0c(g)\u9ad8\u8fbe10,000\u6b21\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\"\"<\/strong><\/p>\n

\u56fe5 HS<\/strong>\u2212<\/strong>NCS@MXene<\/strong>\u7535\u6781\u7684\u7535\u5316\u5b66\u7535\u8377\u5b58\u50a8\u52a8\u529b\u5b66\u3002\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

(a)\u9634\u6781\u548c\u9633\u6781\u5cf0\u503c\u7535\u6d41\u5bc6\u5ea6\u4f5c\u4e3a\u626b\u63cf\u901f\u7387\u7684\u51fd\u6570\u3002(b)\u5bf9\u6570(\u626b\u63cf\u901f\u7387)\u4e0e\u9633\u6781\u548c\u9634\u6781\u5cf0\u503c\u7535\u6d41\u7684\u5bf9\u6570\u56fe\u3002(c)\u57285 m Vs-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u7535\u5bb9\u6027\u548c\u6269\u6563\u63a7\u5236\u7684\u7535\u8377\u5b58\u50a8\u8d21\u732e\u3002(d)\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7535\u5bb9\u548c\u6269\u6563\u63a7\u5236\u7535\u8377\u5b58\u50a8\u7684\u8d21\u732e\u6bd4\u4f8b\u3002<\/p>\n

\"\"<\/strong><\/p>\n

\u56fe6 \u57fa\u4e8e\u539f\u4f4dXPS\u548cXRD\u5206\u6790HS<\/strong>\u2212<\/strong>NCS@MXene<\/strong>\u7535\u6781\u7684\u7535\u8377\u5b58\u50a8\u673a\u7406\u3002\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

(a)\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684GCD\u66f2\u7ebf\u3002(b-e) Ni-2p\u3001Co-2p\u3001Ti-2p\u548cC-1s\u5bf9\u5e94\u7684\u53cd\u5377\u79efXPS\u8c31\u3002(f)\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u7684XRD\u8c31\u56fe\u3002(g)HS\u2212NCS@MXene\u7535\u6781\u4e2d\u7535\u8377\u5b58\u50a8\u673a\u5236\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/strong><\/p>\n

\u56fe7 HS<\/strong>\u2212<\/strong>NCS@MXene\/\/ AC-AHSC<\/strong>\u5728KOH\u7535\u89e3\u8d28\u4e2d\u53cc\u7535\u6781\u4f53\u7cfb\u7684\u7535\u5316\u5b66\u8868\u5f81\u3002\u00a9 2022 Elsevier Ltd.<\/strong><\/p>\n

(a)\u5408\u6210HS-NCS@MXene\/\/AC-AHSC\u7684\u5de5\u4f5c\u529f\u80fd\u793a\u610f\u56fe\u3002(b)\u4e0d\u540c\u7535\u4f4d\u7a97\u53e3\u4e0b\u7684CV\u66f2\u7ebf\u3002(c) +Ve (HS-NCS@MXene)\u548c-Ve (AC)\u7535\u6781\u7684CV\u66f2\u7ebf\u3002(d)\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\u3002(e)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\u3002(f)\u7535\u5bb9\u4e0e\u7535\u6d41\u5bc6\u5ea6\u7684\u5173\u7cfb\u3002(g) Ragone\u56fe\u3002(h)\u5bf9\u4e24\u4e2aHS-NCS@MXene\/\/ AC-AHSC\u8bbe\u5907\u8fdb\u884c\u591a\u8fbe20,000\u6b21\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u4e94\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u4f5c\u8005\u6210\u529f\u5730\u901a\u8fc7\u6c34\u70ed\u5de5\u827a\u5c06NCS\u7eb3\u7c73\u82b1\u5d4c\u5165\u5230\u5265\u79bb\u7684Ti3<\/sub>C2<\/sub>TX<\/sub>-MXene\u7eb3\u7c73\u7247\u4e2d\uff0c\u6784\u5efa\u4e86\u5f02\u8d28\u7ed3\u6784\u7684NCS@MXene\u590d\u5408\u7535\u6781\u3002\u4f18\u5316HS-NCS@MXene\u6837\u54c1HS-NCS@Mxene\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u7684\u8d5d\u7535\u5bb9\u6027\u80fd\u3002\u57282.5 A g–<\/sup>1<\/sup>\u4e0b\uff0c\u5bb9\u91cf\u53ef\u8fbe2637 F g–<\/sup>1<\/sup>(1582 C g–<\/sup>1<\/sup>)\uff0c\u5faa\u73af\u5bff\u547d\u7a33\u5b9a\u572810000\u6b21\u4ee5\u4e0a\uff0c\u5bb9\u91cf\u4fdd\u6301\u4e3a\u521d\u59cb\u503c\u768496%\u3002\u7ec4\u88c5\u4e4b\u540e\u7684HS NCS@MXene\/\/AC\u2013AHSC\u53ef\u4ee5\u5728\u6700\u9ad81.6 V\u7684\u7535\u4f4d\u8303\u56f4\u5185\u5de5\u4f5c\uff0c\u5e76\u57281.5 A g-1<\/sup>\u4e0b\u63d0\u4f9b226 F g-1<\/sup>\u7684\u9ad8\u7535\u5bb9\uff0c\u7a33\u5b9a\u7684\u5faa\u73af\u5bff\u547d(92%)\u53ef\u8fbe20000\u6b21\u5faa\u73af\u3002\u6b64\u5916\uff0cHS NCS@MXene\/\/AC\u2013AHSC\u8fd8\u5177\u670980 Wh kg-1<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u529f\u7387\u5bc6\u5ea6\u4e3a1196 W kg-1<\/sup>\uff0c\u8d85\u8fc7\u4e86\u6700\u8fd1\u62a5\u9053\u7684\u6027\u80fd\u3002<\/p>\n

DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660eHS-NCS@MXene\u7684\u7535\u5bfc\u7387\u4f18\u4e8e\u539f\u59cbMXene\u548cNCS\u3002AHSC\u63d0\u4f9b\u51fa\u8272\u7684\u7535\u5316\u5b66\u6027\u80fd\u662f\u7531\u4e8eHS-NCS@MXene\u590d\u5408\u6750\u6599\u4e2dNCS\u548cMXene\u7684\u534f\u540c\u4f5c\u7528\u3002\u8fd9\u4e00\u7b56\u7565\u4e0d\u4ec5\u80fd\u8bc1\u660eHS-NCS@MXene\u53d1\u5c55\u7684\u53ef\u80fd\u6027\uff0c\u800c\u4e14\u8fd8\u80fd\u4e3a\u672a\u6765\u5236\u9020\u9ad8\u6027\u80fdAHSCs\u6df7\u5408\u7535\u6781\u7684\u7a33\u5b9a\u754c\u9762\u5f00\u8f9f\u4e86\u9053\u8def\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1ahttps:\/\/doi.org\/10.1016\/j.nanoen.2022.107624<\/p>\n

\u672c\u6587\u7531\u5f20\u7199\u7199\u4f9b\u7a3f\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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