{"id":246751,"date":"2023-02-05T06:00:25","date_gmt":"2023-02-04T22:00:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=246751"},"modified":"2023-02-03T15:28:07","modified_gmt":"2023-02-03T07:28:07","slug":"%e6%b1%87%e6%80%bb%ef%bc%9a%e8%87%aa%e6%97%8b%e5%82%ac%e5%8c%96%e5%89%82%e6%96%b0%e5%8a%a8%e5%90%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=246751","title":{"rendered":"\u6c47\u603b\uff1a\u81ea\u65cb\u50ac\u5316\u5242\u65b0\u52a8\u5411"},"content":{"rendered":"

\u201c\u81ea\u65cb\u201d\u88ab\u89c6\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u7535\u5b50\u81ea\u7531\u5ea6\uff0c\u53ef\u7528\u4e8e\u63d0\u9ad8\u7535\u50ac\u5316\u5242\u548c\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002\u4e0d\u96be\u53d1\u73b0\uff0c\u8fd1\u51e0\u5e74\u81ea\u65cb\u50ac\u5316\u5728OER\uff0cCO2<\/sub>RR\uff0c\u6c28\u5408\u6210\u4ee5\u53caLSB\u7b49\u591a\u4e2a\u50ac\u5316\u9886\u57df\u4e2d\u88ab\u63d0\u53ca\uff0c\u5c24\u5176\u662f\u5728\u8fc7\u53bb\u76842022\u5e74\uff0c\u66f4\u662f\u5728\u5404\u5927\u9876\u520a\u4e2d\u9891\u7e41\u51fa\u73b0\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u4e00\u4e2a\u5f02\u519b\u7a81\u8d77\u7684\u65b0\u578b\u50ac\u5316\u5242\u4f5c\u7528\u673a\u5236\uff0c\u5176\u5185\u5728\u673a\u7406\uff0c\u4f5c\u7528\u65b9\u5f0f\u7a76\u7adf\u662f\u600e\u4e48\u6837\uff0c\u5176\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u53c8\u5728\u4f55\u65b9\uff1f\u80fd\u5426\u53bb\u7e41\u5316\u7b80\uff0c\u5c06\u5916\u52a0\u78c1\u573a\u6539\u4e3a\u5185\u5728\u7980\u6027\uff1f\u901a\u8fc7\u672c\u4e13\u9898\uff0c\u8ba9\u6211\u4eec\u6765\u8fdb\u4e00\u6b65\u5c55\u671b\u81ea\u65cb\u50ac\u5316\u5242\u65b0\u52a8\u5411\u3002<\/p>\n

 <\/p>\n

1.\u00a0<\/b>\u65b0\u52a0\u5761\u56fd\u7acb&\u6e05\u534eACS Nano\uff1a\u8c03\u63a7\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u81ea\u65cb\u5bc6\u5ea6\u4ee5\u5b9e\u73b0\u9ad8\u6548OER<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/strong><\/p>\n

\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u5415\u70af\u6559\u6388\u548c\u6e05\u534e\u5927\u5b66\u8096\u6d77\u6559\u6388\u7b49\u4eba\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u5728\u91d1\u5c5e\u6001TaS2<\/sub>\u5355\u5206\u5b50\u5c42\u4e0a\u5408\u6210\u4e86\u94c1\u78c1\u6027\u5355\u539f\u5b50Co\u50ac\u5316\u5242\uff08Co1<\/sub>\/TaS2<\/sub>\uff09\uff0c\u4ee5\u6b64\u4f5c\u4e3a\u6a21\u578b\u7cfb\u7edf\u63a2\u7d22\u4e86OER\u4e2d\u53cd\u5e94\u4f4d\u70b9\u7684\u81ea\u65cb\u6001\u4e0e\u50ac\u5316\u6d3b\u6027\u7684\u76f8\u5173\u6027\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5438\u9644\u5728\u7a7a\u5fc3\u4f4d\u70b9\u7684\u5355\u4e2aCo\u539f\u5b50\uff08CoHS<\/sub>\uff09\u5177\u6709\u81ea\u65cb\u6781\u5316\u7535\u5b50\u6001\uff0c\u80fd\u591f\u4f5c\u4e3aOER\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u901a\u8fc7\u63a7\u5236Co\u7684\u8d1f\u8f7d\u91cf\u6765\u8c03\u63a7Co\u539f\u5b50\u95f4\u7684\u8ddd\u79bb\uff0c\u5b9e\u73b0Co\u4f4d\u70b9\u81ea\u65cb\u5bc6\u5ea6\u7684\u8c03\u63a7\u3002<\/p>\n

\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\u63ed\u793a\u4e86\u4e0e\u81ea\u65cb\u5bc6\u5ea6\u76f8\u5173\u7684OER\u6d3b\u6027\uff0c\u5373\u901a\u8fc7\u76f8\u90bb\u7684Co\u53d6\u4ee3Ta\u7684CoTa<\/sub>\u4f4d\u70b9\uff08\u76f8\u4e92\u4f5c\u7528\u53ef\u4ee5\u83b7\u5f97CoHS<\/sub>\u7684\u6700\u4f73\u81ea\u65cb\u5bc6\u5ea6\uff0c\u4ece\u800c\u83b7\u5f97\u4f18\u5f02\u7684OER\u6027\u80fd\uff0c\u800cCoHS<\/sub>\u4f4d\u70b9\u4f7f\u5f97\u90bb\u8fd1\u7684CoHS<\/sub>\u4e0a\u4ea7\u751f\u8fc7\u591a\u7684\u81ea\u65cb\u5bc6\u5ea6\uff0c\u5bfc\u81f4\u4e86OER\u6027\u80fd\u7684\u964d\u4f4e\u3002\u56e0\u6b64\uff0c\u8be5\u7ed3\u679c\u8868\u660e\u4e86\u4f18\u5316\u7684CoHS<\/sub>\u81ea\u65cb\u5bc6\u5ea6\u53ef\u4ee5\u5f97\u5230OER\u7684\u6700\u4f73\u6c27\u7ed3\u5408\u80fd\uff0c\u81ea\u65cb\u6001\u4e0e\u50ac\u5316\u4f4d\u70b9\u6d3b\u6027\u7684\u76f8\u5173\u6027\u53ef\u4ee5\u4e3a\u8bbe\u8ba1\u7528\u4e8e\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u6362\u7684\u9ad8\u6548\u78c1\u6027SACs\u63d0\u4f9b\u65b0\u601d\u8def\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cTuning the Spin Density of Cobalt Single\u00a0Atom Catalysts for Efficient Oxygen Evolution<\/i><\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728ACS Nano<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u65b0\u52a0\u5761\u56fd\u7acb&\u6e05\u534eACS Nano\uff1a\u8c03\u63a7\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u81ea\u65cb\u5bc6\u5ea6\u4ee5\u5b9e\u73b0\u9ad8\u6548OER<\/u><\/a><\/p>\n

 <\/p>\n

2.<\/b><\/strong>JACS\uff1aMn\u63ba\u6742\u9499\u949b\u77ff\u7eb3\u7c73\u7247\u7684\u81ea\u65cb\u6781\u5316\u5b9e\u73b0\u66f4\u9ad8\u6548\u5149\u50ac\u5316CO2\u8fd8\u539f\uff01<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u53f0\u6e7e\u5927\u5b66\u9648\u4fca\u7ef4\u548c\u53f0\u6e7e\u5e08\u8303\u5927\u5b66Chia-Chun Chen\u56e2\u961f\u901a\u8fc7\u63a7\u5236\u5364\u5316\u7269\u9499\u949b\u77ff\u7eb3\u7c73\u7247(NPLs)CsPbBr3<\/sub>\u4e2d\u81ea\u65cb\u6781\u5316\u7535\u5b50\uff0c\u663e\u8457\u63d0\u9ad8\u4e86CO2<\/sub>\u8fd8\u539f\u8f6c\u5316\u6548\u7387\u3002<\/p>\n

\u8be5\u9879\u5de5\u4f5c\u4e2d\uff0c\u4ee5\u63a7\u5236CsPbBr3<\/sub>\u4e2d\u63ba\u6742\u9530\u9633\u79bb\u5b50(Mn2+<\/sup>)\u5e76\u65bd\u52a0\u5916\u90e8\u78c1\u573a\u6765\u5c55\u5f00\u5b9e\u9a8c\u3002\u7ed3\u679c\u8868\u660e\u4e0e\u539f\u59cbCsPbBr3<\/sub>\u00a0NPLs\u76f8\u6bd4\uff0cMn\u63ba\u6742CsPbBr3<\/sub>\u00a0(Mn-CsPbBr3<\/sub>) NPLs\u7531\u4e8e\u63ba\u6742\u540e\u4ea7\u751f\u4e86\u81ea\u65cb\u6781\u5316\u7535\u5b50\uff0c\u5b9e\u73b0\u4e86\u66f4\u51fa\u8272\u7684\u5149\u50ac\u5316CO2<\/sub>RR\u3002\u5e76\u4e14\u5916\u52a0\u78c1\u573a\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8MnCsPbBr3<\/sub>\u00a0NPLs\u7684\u5149\u50ac\u5316CO2<\/sub>RR\u3002\u5728300 mT\u7684\u6c38\u78c1\u4f53\u4e0b\uff0cMnCsPbBr3<\/sub>\u00a0NPLs\u7684\u5149\u50ac\u5316CO2<\/sub>RR\u6027\u80fd\u63d0\u9ad8\u4e865.7\u500d\u3002\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cSpin-Polarized Photocatalytic CO2 Reduction of Mn-Doped<\/strong><\/p>\n

Perovskite Nanoplates<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aJournal of the American Chemical Society<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1aJACS\uff1aMn\u63ba\u6742\u9499\u949b\u77ff\u7eb3\u7c73\u7247\u7684\u81ea\u65cb\u6781\u5316\u5b9e\u73b0\u66f4\u9ad8\u6548\u5149\u50ac\u5316CO2\u8fd8\u539f<\/u><\/a><\/p>\n

 <\/p>\n

3.<\/b><\/strong>\u674e\u987a\u65b9&\u5f20\u632f\u5b87Nano Lett.\uff1a\u63ed\u793a\u5355\u539f\u5b50\u50ac\u5316\u5242\u201c\u7535\u8377-\u81ea\u65cb\u534f\u540c\u50ac\u5316\u201d\u673a\u5236<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/strong><\/p>\n

\u90d1\u5dde\u5927\u5b66\u674e\u987a\u65b9\u6559\u6388\u548c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5f20\u632f\u5b87\u6559\u6388<\/strong>\u8054\u5408\u4ee5O2<\/sub>\u5728\u4e8c\u7ef4\u94c1\u78c1\u6709\u673a\u91d1\u5c5e\u6846\u67b6Mn2<\/sub>C18<\/sub>H12<\/sub>-MSAC\u4f53\u7cfb\u4e0a\u7684\u6fc0\u53d1\u548cCO\u6c27\u5316\u4e3a\u4f8b\uff0c\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u6a21\u62df\uff0c\u9996\u6b21\u53d1\u73b0\u8be5MSAC\u4f53\u7cfb\u9ad8\u6548\u6fc0\u53d1O2<\/sub>\u7684\u7269\u7406\u673a\u5236\u4e3a\u4e00\u79cd\u65b0\u5947\u7684\u201c\u7535\u8377-\u81ea\u65cb\u7684\u53cc\u91cd\u534f\u540c\u673a\u5236\u201d\u3002\u5f53O2<\/sub>\u5206\u5b50\u5438\u9644\u5728\u8be5\u94c1\u78c1\u6027\u7684MSAC\u4f53\u7cfb\u4e0a\u7684\u67d0\u4e2aMn\u5355\u539f\u5b50\u6d3b\u6027\u4f4d\u65f6\uff08\u6807\u8bb0\u4e3aMn-I\uff09\uff0cO2<\/sub>\u5b9e\u73b0\u4e86\u4ece\u81ea\u65cb\u4e09\u91cd\u6001\u5230\u81ea\u65cb\u5355\u91cd\u6001\u7684\u8f6c\u53d8\uff1b\u66f4\u91cd\u8981\u7684\u662f\uff0c\u79d1\u7814\u56e2\u961f\u53d1\u73b0Mn-I\u6d3b\u6027\u4f4d\u70b9\u4e0e\u5176\u8fd1\u90bbMn-II\u5355\u539f\u5b50\u5728\u7535\u8377\u548c\u81ea\u65cb\u81ea\u7531\u5ea6\u4e0a\u5177\u6709\u8fe5\u7136\u4e0d\u540c\u7684\u5206\u5de5\u4e0e\u5408\u4f5c\uff1aO2<\/sub>\u5438\u9644\u65f6\uff0c\u7535\u8377\u8f6c\u79fb\u4e3b\u8981\u7531Mn-I\u63d0\u4f9b\u548c\u4e3b\u5bfc\uff0c\u7136\u800c\u6839\u636eWigner\u81ea\u65cb\u5b88\u6052\u9009\u62e9\u5b9a\u5219\uff0cMn-II\u5bb9\u7eb3\u4e86\u4eceO2<\/sub>\u5206\u5b50\u4e0a\u8f6c\u79fb\u6765\u7684\u5927\u90e8\u5206\u81ea\u65cb\u78c1\u77e9\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9O2<\/sub>\u4ece\u81ea\u65cb\u4e09\u91cd\u6001\u5230\u81ea\u65cb\u5355\u6001\u7684\u6709\u6548\u6fc0\u53d1\uff0c\u8be5\u91cf\u5b50\u534f\u540c\u673a\u5236\u6709\u6548\u964d\u4f4e\u4e86CO\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u51b3\u901f\u6b65\u52bf\u5792\u3002\u8fd9\u79cd\u65b0\u5947\u7684\u201c\u7535\u8377-\u81ea\u65cb\u534f\u540c\u50ac\u5316\u201d\u7684\u91cf\u5b50\u6548\u5e94\u8fd8\u88ab\u8fdb\u4e00\u6b65\u63a8\u5e7f\u5230\u591a\u79cd\u78c1\u6027X2<\/sub>C18<\/sub>H12<\/sub>(X=Mn\u3001Fe\u3001Co\u548cNi)\u4f53\u7cfb\uff0c\u5e76\u53d1\u73b0\u8fd9\u4e9bMSAC\u4f53\u7cfb\u5bf9O2<\/sub>\u6fc0\u53d1\u7684\u5316\u5b66\u6d3b\u6027\u7a0b\u5ea6\u4e0e\u81ea\u65cb\u6fc0\u53d1\u80fd\u4e4b\u95f4\u5b58\u5728\u660e\u786e\u7684\u7ebf\u6027\u6807\u5ea6\u5173\u7cfb\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cSynergetic Charge Transfer and Spin Selection in CO Oxidation at Neighboring Magnetic Single-Atom Catalyst Sites<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNano Letters<\/i><\/em>\u4e0a\uff0c\u90d1\u5dde\u5927\u5b66\u4e3a\u7b2c\u4e00\u4f5c\u8005\u5355\u4f4d\uff0c\u90d1\u5dde\u5927\u5b66\u7269\u7406\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u5f20\u4e3d\u83b9\u548c\u9752\u5e74\u6559\u5e08\u4efb\u6653\u71d5\u526f\u6559\u6388\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u674e\u987a\u65b9&\u5f20\u632f\u5b87Nano Lett.\uff1a\u63ed\u793a\u5355\u539f\u5b50\u50ac\u5316\u5242\u201c\u7535\u8377-\u81ea\u65cb\u534f\u540c\u50ac\u5316\u201d\u673a\u5236<\/u><\/a><\/p>\n

 <\/p>\n

4.<\/b><\/strong>\u4e13\u8bbf\u5170\u5dde\u5927\u5b66\u5468\u91d1\u5143\u6559\u6388\uff1a\u81ea\u65cb\u6548\u5e94\u5982\u4f55\u5b9e\u73b0\u9ad8\u6548\u9502\u786b\u50ac\u5316<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u5170\u5dde\u5927\u5b66\u5468\u91d1\u5143\u6559\u6388\u548cCatalonia\u80fd\u6e90\u7814\u7a76\u9662Andreu Cabot<\/b><\/strong>\u7b49\u4eba\u53d1\u73b0\u4ee5CoSx<\/sub>\u4f5c\u4e3a\u50ac\u5316\u6dfb\u52a0\u5242\u65f6\uff0c\u901a\u8fc7\u5916\u78c1\u94c1\u4ea7\u751f\u7684\u78c1\u573a\u53ef\u4ee5\u663e\u8457\u6539\u5584LiPS\u7684\u5438\u9644\u80fd\u529b\u548cLi-S\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u7814\u7a76\u7ed3\u679c\u4ece\u5b9e\u9a8c\u548c\u7406\u8bba\u4e0a\u663e\u793a\u4e86Co\u79bb\u5b50\u7684\u7535\u5b50\u81ea\u65cb\u6781\u5316\u662f\u5982\u4f55\u51cf\u5c11\u7535\u5b50\u6392\u65a5\u548c\u63d0\u9ad8\u8f68\u9053\u6742\u5316\u7a0b\u5ea6\u7684\uff0c\u4ece\u800c\u4f7fLSB\u5c55\u793a\u51fa\u524d\u6240\u672a\u6709\u7684\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u3002\u5728\u5916\u90e8\u78c1\u573a\u7684\u4f5c\u7528\u4e0b\uff0c\u7535\u6c60\u57282 C\u4e0b\u5faa\u73af8150\u540e\u4ecd\u80fd\u6b63\u5e38\u5de5\u4f5c\uff0c\u5355\u5708\u8870\u51cf\u7387\u4e3a0.0084%\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u8bc1\u660e\u4e86\u81ea\u65cb\u6548\u5e94\u662f\u4fc3\u8fdbLiPS\u5438\u9644\u548c\u7535\u5316\u5b66\u8f6c\u5316\u7684\u6709\u6548\u7b56\u7565\uff0c\u800c\u4e14\u8fd8\u4e30\u5bcc\u4e86\u81ea\u65cb\u6548\u5e94\u5728\u7535\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cSpin Effect to Promote Reaction Kinetics and Overall Performance of Lithium-Sulfur Batteries under External Magnetic Field\u201d\u53d1\u8868\u5728\u56fd\u9645\u671f\u520aAngew\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u4e13\u8bbf\u5170\u5dde\u5927\u5b66\u5468\u91d1\u5143\u6559\u6388\uff1a\u81ea\u65cb\u6548\u5e94\u5982\u4f55\u5b9e\u73b0\u9ad8\u6548\u9502\u786b\u50ac\u5316<\/u><\/a><\/p>\n

 <\/p>\n

5.<\/b><\/strong>\u5408\u6210\u6c28\u65b0\u673a\u5236Nat. Commun\uff1a\u5408\u6210\u6c28\u50ac\u5316\u4e2d\u7684\u81ea\u65cb\u4fc3\u8fdb\u6548\u5e94<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u4e39\u9ea6\u6280\u672f\u5927\u5b66\u7269\u7406\u7cfbIb Chorkendorff\u548cJens K. N\u00f8rskov\u6559\u6388\u53ca\u5176\u56e2\u961f\u6982\u8ff0\u4e86\u5408\u6210\u6c28\u50ac\u5316\u5242\u7814\u7a76\u7684\u6700\u65b0\u5b9e\u9a8c\u7ed3\u679c\uff0c\u5e76\u5f00\u53d1\u4e86\u4e00\u4e2a\u7efc\u5408\u6a21\u578b\u6765\u89e3\u91ca\u5b83\u4eec\u662f\u5982\u4f55\u5de5\u4f5c\u7684\u3002\u8be5\u6a21\u578b\u6709\u4e24\u4e2a\u7ec4\u6210\u90e8\u5206\u3002\u9996\u5148\uff0c\u7814\u7a76\u4eba\u5458\u786e\u5b9a\u4e86\u5728\u4e0d\u540c\u52a9\u50ac\u5316\u5242\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u6d3b\u6027\u4f4d\u70b9\u6700\u6709\u53ef\u80fd\u7684\u7ed3\u6784\uff0c\u7136\u540e\u8868\u660e\u6709\u4e24\u4e2a\u6548\u5e94\u51b3\u5b9a\u50ac\u5316\u6d3b\u6027\u3002\u4e00\u79cd\u662f\u5438\u9644\u52a9\u50ac\u5316\u5242\u4e0eN-N\u89e3\u79bb\u8fc7\u6e21\u6001\u4e4b\u95f4\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff08\u4e3b\u8981\u9488\u5bf9Ru\u548c\u5176\u4ed6\u975e\u78c1\u6027\u50ac\u5316\u5242\uff09\uff0c\u53e6\u4e00\u79cd\u662f\u5173\u4e8e\u78c1\u6027\u50ac\u5316\u5242\u7684\u4e00\u79cd\u65b0\u7684\u81ea\u65cb\u4fc3\u8fdb\u6548\u5e94\uff0c\u53ef\u4f7fN2<\/sub>\u89e3\u79bb\u7684\u8fc7\u6e21\u6001(TS)\u80fd\u5792\u5927\u5e45\u5ea6\u964d\u4f4e\uff0c\u8fd9\u4e3a\u53d1\u73b0\u65b0\u7684\u5408\u6210\u6c28\u50ac\u5316\u5242\u5f00\u8f9f\u4e86\u53ef\u80fd\u3002\u4e3a\u4e86\u5e2e\u52a9\u7406\u89e3\uff0c\u9996\u5148\u9700\u8981\u660e\u786e\u7684\u662f\uff0cCo\u901a\u5e38\u5bf9N2<\/sub>\u89e3\u79bb\u662f\u76f8\u5f53\u60f0\u6027\u7684\uff0c\u5373\u4f7f\u5728\u78b1\u91d1\u5c5e\u7684\u4fc3\u8fdb\u4e0b\u4e5f\u8868\u73b0\u51fa\u8f7b\u5fae\u7684\u5408\u6210\u6c28\u6d3b\u6027\u3002\u800c\u7531\u4e8e\u9759\u7535\u6548\u5e94\u5728\u89e3\u91caCs\u548cK\u7684\u4fc3\u8fdb\u4f5c\u7528\u65b9\u9762\u8d77\u5230\u4e86\u5f88\u5927\u7684\u4f5c\u7528\uff0c\u56e0\u6b64\uff0c\u8be5\u7814\u7a76\u56e2\u961f\u8ba4\u4e3a\u8fd9\u79cd\u9759\u7535\u6548\u5e94\u4e5f\u9002\u7528\u4e8e\u89e3\u91caLi\u3001Ba\u548cCa\u4ee5\u53caLa\u5bf9\u4e8eCo\u7684\u975e\u51e1\u4fc3\u8fdb\u6548\u679c\u3002\u7136\u800c\uff0c\u7814\u7a76\u53d1\u73b0Li\uff0cBa\uff0cCa\uff0cLa\u5bf9Co\u7684\u989d\u5916\u4fc3\u8fdb\u4f5c\u7528\u5374\u4e0eCo\u7684\u81ea\u65cb\u6781\u5316\u6709\u5173\uff0c\u975e\u4f20\u7edf\u7684\u52a9\u50ac\u5316\u5242\u964d\u4f4e\u4e86\u76f8\u90bbCo\u539f\u5b50\u7684\u81ea\u65cb\u6781\u5316\uff0c\u4ece\u800c\u4fc3\u8fdbN2<\/sub>\u89e3\u79bb\u3002\u8fd9\u79cd\u989d\u5916\u7684\u4fc3\u8fdb\u6548\u5e94\u4e0e\u78c1\u6027\u52a9\u50ac\u5316\u5242\u8bf1\u5bfc\u7684Co\u539f\u5b50\u81ea\u65cb\u78c1\u77e9\u7684\u964d\u4f4e\u6210\u6b63\u6bd4\u3002\u5f97\u76ca\u4e8e\u8fd9\u4e00\u53cd\u5e38\u81ea\u65cb\u4fc3\u8fdb\u6548\u5e94\uff0c\u8fd9\u4e9b\u52a9\u50ac\u5316\u5242\u80fd\u6700\u5927\u7a0b\u5ea6\u5730\u964d\u4f4e\u91d1\u5c5e\u539f\u5b50\u7684\u81ea\u65cb\u529b\u77e9\uff0c\u56e0\u6b64\u7531\u81ea\u65cb\u6781\u5316\u5f15\u8d77\u7684N-N\u89e3\u79bb\u7684TS\u80fd\u5792\u4e5f\u5f97\u5230\u964d\u4f4e\uff0c\u7531\u6b64\u4f7f\u50ac\u5316\u6548\u7387\u5f97\u5230\u4e86\u63d0\u5347\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA spin promotion effect in catalytic ammonia synthesis<\/i><\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Communications<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u5408\u6210\u6c28\u65b0\u673a\u5236Nat. Commun\uff1a\u5408\u6210\u6c28\u50ac\u5316\u4e2d\u7684\u81ea\u65cb\u4fc3\u8fdb\u6548\u5e94<\/u><\/a><\/p>\n

6.<\/b><\/strong>\u5317\u5e08\u5927\u5b59\u6839\u73ed\u6559\u6388JACS\uff1aCu2+\u8c03\u63a7Fe3+\u4f4d\u70b9\u201c\u81ea\u65cb\u78c1\u6548\u5e94\u201d\u5b9e\u73b0\u9ad8\u6548OER<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/strong><\/p>\n

\u5317\u4eac\u5e08\u8303\u5927\u5b66\u5b59\u6839\u73ed\u6559\u6388\u56e2\u961f<\/strong>\u4ee5NiFe\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269\uff08NiFe-LDHs\uff09\u4f5c\u4e3a\u78b1\u6027OER\u50ac\u5316\u5242\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u7684\u78c1\u6027Fe3+<\/sup>\u7684\u81ea\u65cb\u5206\u88c2\u63d0\u5347OER\u50ac\u5316\u6027\u80fd\u7b56\u7565\u2014\u901a\u8fc7Cu2+<\/sup>\u7684Jahn-Teller\u6548\u5e94\u6709\u6548\u5730\u8bf1\u5bfc\u548c\u4f18\u5316\u4e86Fe3+<\/sup>\u4f4d\u7684\u7535\u5b50\u7ed3\u6784\u548c\u81ea\u65cb\u6001\u3002\u7406\u8bba\u8ba1\u7b97\u7ed3\u5408\u539f\u4f4dATR FT-IR\u63ed\u793a\u4e86Cu2+<\/sup>\u7684\u5f15\u5165\u4fc3\u8fdbO-O\u952e\u7684\u5f62\u6210\uff0c\u63d0\u5347\u4e86OH–<\/sup>\u751f\u6210O2<\/sub>\u53cd\u5e94\u6548\u7387\u3002Cu1<\/sub>-Ni6<\/sub>Fe2<\/sub>-LDH\u50ac\u5316\u5242\u572810 mA cm-2<\/sup>\u65f6\u7684\u8fc7\u7535\u4f4d\u4e3a210 mV\u3002\u5728Cu2+<\/sup>\u7684\u8c03\u63a7\u4e0b\uff0c\u5b9e\u73b0\u4e86NiFe-LDHs\u4ece\u4e9a\u94c1\u78c1\u4f53\u5230\u94c1\u78c1\u4f53\u7684\u8f6c\u53d8\uff0c\u5e76\u9996\u6b21\u8bc1\u660e\u4e86\u5728\u78c1\u573a\u4f5c\u7528\u4e0b\uff0c\u4e0eNiFe-LDHs\u76f8\u6bd4\uff0c CuNiFe-LDHs\u7684OER\u6027\u80fd\u663e\u8457\u63d0\u9ad8\u3002\u78c1\u573a\u8f85\u52a9\u6761\u4ef6\u4e0bCu1<\/sub>-Ni6<\/sub>Fe2<\/sub>-LDHs\u572810 mA cm-2<\/sup>\u65f6\u5177\u6709180 mV\u7684\u8d85\u4f4e\u8fc7\u7535\u4f4d\uff0c\u662f\u76ee\u524dOER\u6027\u80fd\u6700\u597d\u7684\u6750\u6599\u4e4b\u4e00\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cRegulating the Spin State of Fe<\/strong>III<\/sup><\/strong>\u00a0Enhances the Magnetic Effect of the Molecular Catalysis Mechanism<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aJ. Am. Chem. Soc.<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u5317\u5e08\u5927\u5b59\u6839\u73ed\u6559\u6388JACS\uff1aCu2+\u8c03\u63a7Fe3+\u4f4d\u70b9\u201c\u81ea\u65cb\u78c1\u6548\u5e94\u201d\u5b9e\u73b0\u9ad8\u6548OER<\/u><\/a><\/p>\n

 <\/p>\n

7.<\/b><\/strong>\u4e2d\u79d1\u9662\u7269\u7406\u6240Nat. Commun.\uff1a\u78c1\u573a\u4e0b\u7684\u81ea\u65cb\u6781\u5316\u6790\u6c27\u53cd\u5e94<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\/\u5317\u4eac\u51dd\u805a\u6001\u7269\u7406\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3N04\u7ec4\u6768\u6d77\u6d9b\u526f\u7814\u7a76\u5458\u8054\u5408\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u7684\u5f90\u68bd\u5ddd\u6559\u6388\u62a5\u544a\uff0c\u5728\u6052\u5b9a\u78c1\u573a\u4e0b\u4f7f\u7528\u94c1\u78c1\u6709\u5e8f\u50ac\u5316\u5242\u4f5c\u4e3a\u81ea\u65cb\u6781\u5316\u5668\u8fdb\u884c\u81ea\u65cb\u9009\u62e9\uff0c\u53ef\u4ee5\u589e\u5f3aOER\u3002\u7136\u800c\uff0c\u5b83\u4e0d\u9002\u7528\u4e8e\u975e\u94c1\u78c1\u6027\u50ac\u5316\u5242\u3002\u63a5\u7740\u53d1\u73b0OER\u7684\u81ea\u65cb\u6781\u5316\u53d1\u751f\u5728\u7535\u5b50\u8f6c\u79fb\u7684\u7b2c\u4e00\u6b65\uff0c\u5728\u81ea\u65cb\u89d2\u52a8\u91cf\u5b88\u6052\u7684\u539f\u7406\u4e0b\uff0c\u94c1\u78c1\u50ac\u5316\u5242\u4e0e\u5438\u9644\u7684\u6c27\u539f\u5b50\u4e4b\u95f4\u53d1\u751f\u4e86\u5feb\u901f\u7684\u76f8\u5e72\u81ea\u65cb\u4ea4\u6362\u3002\u5728\u63a5\u4e0b\u6765\u7684\u4e09\u4e2a\u7535\u5b50\u8f6c\u79fb\u6b65\u9aa4\u4e2d\uff0c\u7531\u4e8e\u5438\u9644\u7684O\u79cd\u81ea\u65cb\u65b9\u5411\u56fa\u5b9a\uff0cOER\u7535\u5b50\u9700\u8981\u9075\u5faa\u6d2a\u5fb7\u89c4\u5219\u548c\u9c8d\u6797\u4e0d\u76f8\u5bb9\u539f\u7406\uff0c\u81ea\u53d1\u8fdb\u884c\u81ea\u65cb\u6781\u5316\uff0c\u6700\u7ec8\u5bfc\u81f4\u4e09\u6001O2<\/sub>\u7684\u751f\u6210\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSpin-polarized oxygen evolution reaction under magnetic field<\/strong>\u201d\u53d1\u8868\u5728Nature communications<\/i><\/em>\u4e0a\u3002\u4efb\u8096\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u6768\u6d77\u6d9b\u6559\u6388\u548c\u5f90\u68bd\u5ddd\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u4e2d\u79d1\u9662\u7269\u7406\u6240Nat. Commun.\uff1a\u78c1\u573a\u4e0b\u7684\u81ea\u65cb\u6781\u5316\u6790\u6c27\u53cd\u5e94<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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