{"id":247201,"date":"2023-02-23T11:21:44","date_gmt":"2023-02-23T03:21:44","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247201"},"modified":"2023-02-23T14:29:05","modified_gmt":"2023-02-23T06:29:05","slug":"%e3%80%90%e6%96%b0%e8%83%bd%e6%ba%90%e5%89%8d%e7%ba%bf%e3%80%91acs-energy-lett-%ef%bc%9a%e6%b0%b4%e7%b3%bb%e7%94%b5%e8%a7%a3%e6%b6%b2%e6%ba%b6%e5%89%82%e5%8c%96%e8%ae%be%e8%ae%a1%e4%b8%ad%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247201","title":{"rendered":"ACS Energy Lett.\uff1a\u6c34\u7cfb\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u8bbe\u8ba1\u4e2d\u7684\u5b9a\u91cf\u7814\u7a76"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u6c34\u7cfb\u4e8c\u6b21\u7535\u6c60\uff08ARBs\uff09\u4ee5\u6c34\u6eb6\u6db2\u4e3a\u7535\u89e3\u6db2\uff0c\u5177\u6709\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u3001\u6613\u89c4\u6a21\u5316\u751f\u4ea7\u53ca\u5e94\u7528\u7b49\u4f18\u70b9\uff0c\u662f\u4e00\u79cd\u7406\u60f3\u7684\u5927\u89c4\u6a21\u50a8\u80fd\u6280\u672f\u3002\u7136\u800c\uff0cARBs\u8f83\u7a84\uff08< 2.0 V\uff09\u7684\u7535\u5316\u5b66\u7a97\u53e3\uff08ESW\uff09\u9650\u5236\u4e86\u5176\u8f93\u51fa\u7535\u538b\u548c\u80fd\u91cf\u5bc6\u5ea6\uff0c\u540c\u65f6\u4e5f\u9650\u5236\u4e86\u90e8\u5206\u6b63\u6781\uff08LiNi0.5<\/sub>Mn1.5<\/sub>O4<\/sub>\u3001LiNi1-x-y<\/sub>MnxCoy<\/sub>O2<\/sub>\u7b49\uff09\u548c\u8d1f\u6781\u6750\u6599\uff08Li2<\/sub>Ti4<\/sub>O5<\/sub>\u3001TiO2<\/sub>\u7b49\uff09\u7684\u5e94\u7528\u3002\u6b64\u5916\uff0c\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cH2<\/sub>O\u5206\u5b50\u5728\u6b63\u6781\u3001\u8d1f\u6781\u8868\u9762\u6613\u53d1\u751f\u6790\u6c22\uff08HRE\uff09\u3001\u6790\u6c27\uff08OER\uff09\u526f\u53cd\u5e94\uff0c\u7834\u574f\u7535\u6781\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u964d\u4f4e\u5176\u5faa\u73af\u5bff\u547d\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u6216\u6539\u6027\u6c34\u7cfb\u7535\u89e3\u6db2\uff0c\u8c03\u63a7\u754c\u9762\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\uff0c\u4ee5\u62d3\u5bbd\u5176ESW\uff0c\u5e76\u6291\u5236\u7535\u6781\u754c\u9762\u526f\u53cd\u5e94\u53d1\u751f\uff0c\u5bf9\u63d0\u9ad8ARBs\u7684\u8f93\u51fa\u7535\u538b\u3001\u80fd\u91cf\u5bc6\u5ea6\u4ee5\u53ca\u5faa\u73af\u5bff\u547d\u81f3\u5173\u91cd\u8981\u3002\u76ee\u524d\u4e3b\u8981\u6709\u4e09\u79cd\u7684\u6c34\u7cfb\u7535\u89e3\u6db2\u6539\u6027\u7b56\u7565\uff0c\u5373\u8d85\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\uff08Water-in Salt Electrolytes, WiSEs\uff09\u3001\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u548c\u6dfb\u52a0\u5242\u6539\u6027\u7535\u89e3\u6db2\uff0c\u4ee5\u62d3\u5bbd\u5176ESW\uff0c\u5e76\u6709\u6548\u6291\u5236\u754c\u9762\u526f\u53cd\u5e94\u53d1\u751f\u3002\u7136\u800c\uff0c\u76ee\u524d\u4ecd\u7f3a\u4e4f\u4e00\u4e2a\u5177\u6709\u666e\u9002\u6027\u3001\u5b9a\u91cf\u5316\u7684\u6a21\u578b\u6765\u9610\u660e\u5176\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240\u660e\u519b\u7814\u7a76\u5458\u3001\u9a6c\u5f81\u7279\u522b\u7814\u7a76\u52a9\u7406\u8054\u5408\u5170\u5dde\u5927\u5b66\u5f20\u4fca\u4e3d\u6559\u6388\uff0c<\/strong>\u63d0\u51fa\u4e86\u6c34\u7cfb\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u7ed3\u6784\u548c\u91d1\u5c5e\u79bb\u5b50\uff08\u8131\uff09\u6eb6\u5242\u5316\u8fc7\u7a0b\u7684\u5b9a\u91cf\u548c\u56fe\u5f62\u6a21\u578b\uff08\u5373\u754c\u9762\u6a21\u578b\uff09\uff0c\u4ee5\u603b\u7ed3\u7535\u89e3\u6db2-\u7535\u6781\u754c\u9762\u5316\u5b66\u548c\u7535\u6781\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u672c\u7efc\u8ff0\u5c06\u6eb6\u5242\u5316\u7ed3\u6784\u548c\u754c\u9762\u6a21\u578b\u6269\u5c55\u5230\u6c34\u7cfb\u7535\u89e3\u6db2\u9886\u57df\uff0c\u4ece\u4e0d\u540c\u7684\u89c6\u89d2\u9610\u8ff0\u4e86\u4e0a\u8ff0\u4e09\u79cd\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u8fc7\u7a0b\u5dee\u5f02\uff0c\u5efa\u7acb\u4e86\u7535\u89e3\u6db2-\u7535\u6781\u754c\u9762\u5316\u5b66\u4e0e\u7535\u6781\u6027\u80fd\u4e4b\u95f4\u7684\u53ef\u89c6\u5316\u5173\u7cfb\u3002\u672c\u7efc\u8ff0\u4e3a\u7814\u7a76\u6c34\u7cfb\u7535\u89e3\u6db2\u7a33\u5b9a\u6027\u548c\u7535\u6781\u6027\u80fd\u5173\u7cfb\u63d0\u4f9b\u4e86\u65b0\u89c6\u89d2\uff0c\u8865\u5145\u4e86\u5bf9SEI\u4f5c\u7528\u7684\u8ba4\u77e5\uff0c\u63d0\u51fa\u4e86\uff08\u6c34\u7cfb\uff09\u7535\u89e3\u6db2\u7684\u5b9a\u91cf\u5316\u8bbe\u8ba1\u53ca\u7535\u6c60\u6027\u80fd\u7684\u5b9a\u91cf\u5316\u5206\u6790\u3002\u8be5\u7efc\u8ff0\u4ee5\u9898\u4e3a\u201cQuantitative Chemistry in Electrolyte Solvation Design for Aqueous Batteries\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aACS Energy Letters<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u63d0\u51fa\u4e86\u4e00\u4e2a\u5b9a\u91cf\u3001\u53ef\u89c6\u5316\u7684\u6a21\u578b\uff0c\u4ece\u4e0d\u540c\u7684\u89c6\u89d2\u9610\u8ff0\u4e86\u4e0a\u8ff0\u4e09\u79cd\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u8fc7\u7a0b\u5dee\u5f02\uff0c\u5efa\u7acb\u4e86\u7535\u89e3\u6db2-\u7535\u6781\u754c\u9762\u5316\u5b66\u4e0e\u7535\u6781\u6027\u80fd\u4e4b\u95f4\u7684\u53ef\u89c6\u5316\u6784\u6548\u5173\u7cfb\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e00\u3001\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u6539\u6027\u7b56\u7565\u53ca\u7814\u7a76\u8fdb\u5c55<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff09\u968fpH\u53d8\u5316\u7684\u6c34\u7684\u7406\u8bba\u7535\u5316\u5b66\u7a97\u53e3\u3002<\/p>\n

\uff08b\uff09\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u4e3b\u8981\u6539\u6027\u7b56\u7565\u3002<\/p>\n

\uff08c\uff09\u5177\u6709\u4ee3\u8868\u6027\u7684\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u6a21\u578b<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff09\u56fe\u50cf\u5316\/\u5b9a\u91cf\u5316\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u4ee5\u53ca\uff08b\uff09\u754c\u9762\u53bb\u6eb6\u5242\u5316\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e09\u3001\u8d85\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\uff08<\/strong>WiSEs<\/strong>\uff09\u7684\u5e94\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff09\u4f4e\u6d53\u5ea6\u7535\u89e3\u6db2\u548cWiSEs\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u4e0d\u540c\u6d53\u5ea6LiTFSI-H2<\/sub>O\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08c\uff09\u4eceMD\u6a21\u62df\u4e2d\u63d0\u53d6\u768421 m LiTFSI + 7 m LiOTf \uff08WiBSE\uff09\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff09WiBSE\u548cWiSE\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u53caC-TiO2<\/sub>\u8d1f\u6781\u548cLiMn2<\/sub>O4<\/sub>\u6b63\u6781\u7684\u5faa\u73af\u4f0f\u5b89\u6027\u80fd\u6d4b\u8bd5\u3002<\/p>\n

\uff08e\uff09\u4ece\u4f20\u7edf\u6c34\u6027\u7535\u89e3\u6db2\u5230\u8d85\u9ad8\u6d53\u5ea6\u7684\u6df7\u5408\u76d0\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u7684\u53d8\u5316\u3002<\/p>\n

\uff08f\uff09\u4ee55mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u7684\u4e0d\u540c\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u56db\u3001\u5b9a\u91cf\u5316\u7684<\/strong>Li+<\/sup><\/strong>\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u6a21\u578b<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

1 m LiTFSI\u300121 m LiTFSI (WiSEs)\u300121 m LiTFSI + 7 m LiOTf (WiBSE)\u548c42 m LiTFSI + 21 m Me3EtN\u00b7TFSI (63 m super-concentrated WiSE)\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e94\u3001<\/strong>DMC<\/strong>\u5728\u62d3\u5bbd\u6c34\u7cfb\u7535\u89e3\u6db2<\/strong>ESW<\/strong>\u7684\u4f5c\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a-b\uff0921 m LiTFSI-H2<\/sub>O\/9.25 m LiTFSI-DMC\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u548c\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08c\uff0921 m LiTFSI-H2<\/sub>O\/9.25 m LiTFSI-DMC\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u516d\u3001\u201c<\/strong>Water-in-Salt\u201d<\/strong>\u7b56\u7565\u5728\u6c34\u7cfb\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff099.26 m NaOTf\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08b-c\uff091 m NaOTf\u548c9.26 m NaOTf\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff099 m NaOTf + 22 m TEAOTF\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u4ee5\u53ca\u5176\u4e3b\u8981\u4f18\u70b9\u5206\u6790\u3002<\/p>\n

\uff08e-g\uff091 m NaOTf\u30019.26 m NaOTf\u30019 m NaOTf + 22 m TEAOTF \uff0831 m high concentrated WiSE\uff09\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e03\u3001\u201c<\/strong>Water-in-Salt\u201d<\/strong>\u7b56\u7565\u5728\u5176\u4ed6\u6c34\u7cfb\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff091 m\u300110 m\u548c30 m KFSI\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08b\uff094 m Mg(TFSI)2<\/sub>\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08c\uff095 m Al(OTf)3<\/sub> WiSE\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff091 M Al(NO3<\/sub>)3<\/sub>\u30010.5 M Al2<\/sub>(SO4<\/sub>)3<\/sub>\u548c5 m Al(CF3<\/sub>SO3<\/sub>)3<\/sub>\u7684\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08e-g\uff0930 m KFSI\u30014 m Mg(TFSI)2<\/sub>\u548c5 m Al(OTf)3<\/sub>\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u516b\u3001\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u7b56\u7565<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff097-LiTFSI\/3-LiBETI\/20-H2<\/sub>O\u5171\u6676\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u548c\uff08b\uff09\u7535\u5316\u5b66\u7a97\u53e3\u6d4b\u8bd5\u3002<\/p>\n

\uff08c\uff094.5 m LiTFSI-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u5171\u6676\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff09Zn(ClO4<\/sub>)2<\/sub>\u00b76H2<\/sub>O\/succinonitrile\u5171\u6676\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08e\uff09ZnCl2<\/sub>\u00b72.33H2<\/sub>O\u7194\u878d\u5171\u6676\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u4e5d\u3001\u57fa\u4e8e\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u7684\u5b9a\u91cf\u5316\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53cd\u5e94\u6a21\u578b<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff097-LiTFSI\/3-LiBETI\/20-H2<\/sub>O<\/p>\n

\uff08b\uff094.5 m LiTFSI-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O<\/p>\n

\uff08c\uff09Zn(ClO4<\/sub>)2<\/sub>\u00b76H2<\/sub>O\/succinonitrile<\/p>\n

\uff08d\uff09ZnCl2<\/sub>\u00b72.33H2<\/sub>O\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u3001\u6dfb\u52a0\u5242\u6539\u6027\u7684\u6c34\u7cfb\u7535\u89e3\u6db2<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\uff08a\uff0921 m LiFTFSI-H2<\/sub>O WiSE\u548c1.9 m [LiTFSI-H2<\/sub>O]-1,4-dioxane\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u5316\u5b66\u793a\u610f\u56fe<\/p>\n

\uff08b\uff09\u73af\u4e01\u781c\u6dfb\u52a0\u5242\u8bf1\u5bfcLiTFSI\u7535\u89e3\u6db2\u4e2dLi+<\/sup>\u6eb6\u5242\u5316\u7ed3\u6784\u53d8\u5316\u793a\u610f\u56fe\u3002<\/p>\n

\uff08c\uff09MU\u5206\u5b50\u8c03\u63a7\u7684\u5177\u6709\u7eb3\u7c73\u6838\u58f3\u72b6Li+<\/sup>\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff09\u52a0\u5165\u6469\u5c14\u5206\u6570\u4e3a0.3\u7684DMSO\u540e2 m NaClO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08e\uff09\u52a0\u5165\u6469\u5c14\u5206\u6570\u4e3a0.5\u7684DMSO\u6dfb\u52a0\u5242\u524d\u540e2 m NaClO4<\/sub>\u7535\u89e3\u6db2\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53cd\u5e94\u3002<\/p>\n

\uff08f\uff09DMSO\u6dfb\u52a0\u5242\u8c03\u63a7\u7684ZnCl2<\/sub>\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u5316\u5b66\u793a\u610f\u56fe\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u4e00\u3001\u4e0d\u540c\u6dfb\u52a0\u5242\u5206\u5b50\u7684\u8c03\u63a7\u4f5c\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

1.9 m [LiTFSI-H2<\/sub>O]-1,4-dioxane\u30013.6 m LiTFSI\/sulfolane-H2<\/sub>O\u300115.9 m LiTFSI\/methylurea-H2<\/sub>O\u30012 m NaClO4<\/sub>-0.5 DMSO\u548c1.3 m ZnCl2<\/sub>\/H2<\/sub>O-DMSO\u6dfb\u52a0\u5242\u6539\u6027\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u6a21\u578b\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u4e8c\u3001\u7535\u89e3\u6db2\u7684<\/strong>HER<\/strong>\u7535\u52bf\u53d8\u5316<\/strong>\u00a9 2023 ACS publication<\/strong><\/p>\n

\u91c7\u7528Butler-Volmer\u4e00\u6b65\u53cd\u5e94\u6a21\u578b\u548cTafel\u65b9\u7a0b\u6a21\u62df\u7684\u7535\u89e3\u6db2\u4e2d\u81ea\u7531H2<\/sub>O\u5206\u5b50\u6d53\u5ea6\u5bf9\u5176HER\u7535\u52bf\u53d8\u5316\u8d8b\u52bf\u7684\u5f71\u54cd\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u4e09\u3001\u4f4e\u6d53\u5ea6\u548c\u6539\u6027\u540e\u7535\u89e3\u6db2\u8c03\u63a7\u4f5c\u7528<\/strong> \u00a9 2023 ACS publication<\/strong><\/p>\n

\u4f20\u7edf\u4f4e\u6d53\u5ea6\u7535\u89e3\u6db2\u548c\u6539\u6027\u540e\u7535\u89e3\u6db2\uff08WiSEs\u3001\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u548c\u6dfb\u52a0\u5242\u6539\u6027\u7535\u89e3\u6db2\uff09\u7684\u5b9a\u91cf\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u6a21\u578b\u3002<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u672c\u6587\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u6c34\u7cfb\u7535\u89e3\u6db2\u5728\u62d3\u5bbd\u5176ESW\u548c\u6291\u5236\u526f\u53cd\u5e94\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u57fa\u4e8eWiSEs\u3001\u6c34\u7cfb\u5171\u6676\u7535\u89e3\u6db2\u548c\u6dfb\u52a0\u5242\u6539\u6027\u7535\u89e3\u6db2\u4e09\u7c7b\u6539\u6027\u540e\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u7814\u7a76\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u4e2a\u5b9a\u91cf\u5316\u3001\u53ef\u89c6\u5316\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u53ca\u754c\u9762\u53cd\u5e94\u6a21\u578b\uff0c\u5c1d\u8bd5\u9610\u660e\u7535\u89e3\u6db2\u7279\u6027\u4e0e\u7535\u6781\u6027\u80fd\u4e4b\u95f4\u7684\u5b9a\u91cf\u5316\u5173\u7cfb\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8ba4\u4e3a\u8981\u5b9e\u73b0ARBs\u7684\u5546\u4e1a\u5316\u5e94\u7528\uff0c\u4ecd\u6709\u8bb8\u591a\u79d1\u5b66\u95ee\u9898\u548c\u73b0\u5b9e\u95ee\u9898\u9700\u8981\u89e3\u51b3\uff1a\uff081\uff09\u91cf\u5316\u91d1\u5c5e\u79bb\u5b50\u6eb6\u5242\u5316\u7ed3\u6784\uff1b\uff082\uff09\u91cf\u5316\u7535\u6781\u754c\u9762\u53cd\u5e94\u884c\u4e3a\uff1b\uff083\uff09\u91cf\u5316\u6b63\u6781\u3001\u8d1f\u6781\u754c\u9762\u53bb\u6eb6\u5242\u5316\u53cd\u5e94\u6a21\u578b\u4e4b\u95f4\u7684\u4f5c\u7528\uff1b\uff084\uff09\u91cf\u5316\u6c34\u7cfb\u7535\u89e3\u6db2\u754c\u9762\u5316\u5b66\u4f5c\u7528\u548cSEI\u819c\u5bf9\u7535\u6781\u6027\u80fd\u7684\u5f71\u54cd\uff1b\uff085\uff09\u91cf\u5316ARBs\u7684\u6210\u672c\u548c\u53ef\u9760\u6027\u3002<\/p>\n

\u5b9a\u91cf\u5316\u5b66\u95ee\u9898\u5728\u7535\u6c60\u9886\u57df\u53d8\u5f97\u8d8a\u6765\u8d8a\u91cd\u8981\uff0c\u8fd9\u4e0d\u4ec5\u4f53\u73b0\u5728\u901a\u8fc7\u5b9a\u91cf\u3001\u53ef\u89c6\u5316\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u548c\u754c\u9762\u6a21\u578b\u80fd\u591f\u76f8\u5bf9\u76f4\u89c2\u5730\u89e3\u91ca\u8bf8\u591a\u5b9e\u9a8c\u73b0\u8c61\u3002\u540c\u65f6\uff0c\u7535\u6781\u6750\u6599\u7684\u8868\u5f81\u53ca\u7535\u6c60\u6027\u80fd\u7684\u5206\u6790\u4e5f\u9700\u8981\u91cf\u5316\uff0c\u4ee5\u63d0\u9ad8\u7535\u6c60\u4ea7\u54c1\u7684\u4e00\u81f4\u6027\uff0c\u4ece\u800c\u4fdd\u8bc1\u5176\u53ef\u9760\u6027\u548c\u5b89\u5168\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aQuantitative Chemistry in Electrolyte Solvation Design for Aqueous Batteries<\/a> ( ACS Energy Lett. <\/em>2023<\/strong>, 8, 1076-1095)<\/p>\n

\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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