{"id":247315,"date":"2023-02-20T06:20:40","date_gmt":"2023-02-19T22:20:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247315"},"modified":"2023-02-16T14:29:05","modified_gmt":"2023-02-16T06:29:05","slug":"%e4%b8%93%e9%a2%98%e6%b1%87%e6%80%bb-%e6%9c%89%e6%9c%ba%e6%b6%b2%e4%bd%93%e5%82%a8%e6%b0%a2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247315","title":{"rendered":"\u4e13\u9898\u6c47\u603b:\u00a0\u00a0\u6709\u673a\u6db2\u4f53\u50a8\u6c22"},"content":{"rendered":"

\u4e0a\u4e16\u7eaa70\u5e74\u4ee3\uff0cSultan\u548cShaw\u7b49\u4eba\u63d0\u51fa\u4e86\u91c7\u7528\u6db2\u4f53\u5316\u5b66\u50a8\u6c22\u7684\u601d\u8def\uff0c\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u6280\u672f\u91c7\u7528\u5316\u5b66\u50ac\u5316\u5c06\u6c22\u6c14\u5b58\u50a8\u5728\u6db2\u4f53\u5316\u5b66\u6eb6\u5242\u4e2d\uff0c\u518d\u901a\u8fc7\u5316\u5b66\u8131\u6c22\u53cd\u5e94\u5b9e\u73b0\u653e\u6c22\u3002\u540c\u4f20\u7edf\u7684\u538b\u7f29\u6cd5\u50a8\u6c22\u76f8\u6bd4\uff0c\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u5177\u6709\u66f4\u9ad8\u7684\u5b89\u5168\u7cfb\u6570\uff0c\u66f4\u5927\u7684\u50a8\u6c22\u5bc6\u5ea6\uff0c\u6210\u672c\u4e5f\u66f4\u4f4e\u3002\u76ee\u524d\uff0c\u56fd\u5185\u5df2\u7ecf\u6709\u591a\u5bb6\u521d\u521b\u516c\u53f8\u5f00\u5c55\u8fd9\u4e00\u9886\u57df\u7684\u4ea7\u4e1a\u5316\u5e94\u7528\uff0c\u6709\u7684\u5df2\u7ecf\u5b9e\u73b0\u4e86\u89c4\u6a21\u5316\u91cf\u4ea7\uff0c\u5df2\u521d\u6b65\u5b9e\u73b0\u4e86\u5728\u6c22\u71c3\u6599\u7535\u6c60\u6c7d\u8f66\u4e0a\u7684\u5e94\u7528\u3002\u672c\u4e13\u9898\u9074\u9009\u8be5\u9886\u57df\u6700\u65b0\u7684\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4e86\u89e3\u57fa\u7840\u7814\u7a76\u5728\u8fd9\u4e00\u6781\u5177\u524d\u666f\u9886\u57df\u7684\u65b0\u98de\u8dc3\u3002<\/p>\n

 <\/p>\n

1.\u00a0<\/b>Sci. Adv\uff1a\u57fa\u4e8e\u6db2\u76f8\u6709\u673a\u6c22\u8f7d\u4f53\u7684\u4e3b\u65cf\u50ac\u5316\u7eaf\u5316H2<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u5927\u962a\u5927\u5b66Yoichi Hoshimoto\u526f\u6559\u6388\u548cSensuke Ogoshi\u6559\u6388\u56e2\u961f\u5c55\u793a\u5404\u79cd\u6df7\u5408\u6c14\u4f53\uff0c\u5305\u62ecH2<\/sub>\u3001CO\u3001CO2<\/sub>\u3001CH4<\/sub>\uff0c\u901a\u8fc7Bn<\/sup>\u50ac\u5316\u52a0\u6c22\u7684Qin\u548cLut\uff0c\u76f4\u63a5\u5b58\u50a8\u5728\u6c2e\u6742\u73af\u5316\u5408\u7269\uff08\u5982H4<\/sub>-Qin\u548cH6<\/sub>-Lut\uff09\u4e2d\u3002\u6b64\u5916\uff0cBn<\/sup>\u8fd8\u50ac\u5316H4<\/sub>-Qin\u8131\u6c22\u751f\u6210H2<\/sub>\u548cQin\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cMain group catalysis for H<\/strong>2<\/sub><\/strong>\u00a0purification based on liquid organic hydrogen carriers<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aScience Advances<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1aSci. Adv\uff1a\u57fa\u4e8e\u6db2\u76f8\u6709\u673a\u6c22\u8f7d\u4f53\u7684\u4e3b\u65cf\u50ac\u5316\u7eaf\u5316H2<\/u><\/a><\/p>\n

 <\/p>\n

2.\u00a0<\/b>\u897f\u5b89\u4ea4\u5927Fuel\uff1a\u901a\u8fc7\u7f3a\u9677\u5de5\u7a0b\u589e\u5f3aSMSI\u6548\u5e94\u5b9e\u73b0\u9ad8\u6548\u8131\u6c22<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/strong><\/p>\n

\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u59dc\u53ec\u526f\u6559\u6388\u56e2\u961f<\/strong>\u901a\u8fc7\u5c06\u91d1\u5c5ePt\u548cSiO2<\/sub>-TiO(OH)2<\/sub>\u8f7d\u4f53\u7ed3\u5408\u5236\u5907\u4e86Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u50ac\u5316\u5242\u7528\u4e8e12H-NECZ\u8131\u6c22\u3002\u901a\u8fc7\u7814\u7a76\u8f7d\u4f53\u7684\u5236\u5907\u5de5\u827a\u548cPt\u7684\u8d1f\u8f7d\u91cf\u7b5b\u9009\u51fa\u4e86\u6700\u4f73\u50ac\u5316\u5242\u3002\u7ed3\u679c\u8868\u660e\uff0c2.5wt%Pt\/SiO2<\/sub>-TiO(OH)2<\/sub>\u5177\u6709\u6700\u4f73\u7684\u8131\u6c22\u6027\u80fd\u3002\u7ed3\u5408XRD\u3001HRTEM\u3001ATR-FTIR\u3001XPS\u548cEPR\u5206\u6790\uff0c\u8be6\u7ec6\u8ba8\u8bba\u4e86\u50ac\u5316\u5242\u7684\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u548c\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u5bf9\u50ac\u5316\u8131\u6c22\u6027\u80fd\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5bf9\u5176\u52a8\u529b\u5b66\u5206\u6790\u548c\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u53d1\u73b0Pt\u548cSiO2-TiO(OH)2<\/sub>\u4e4b\u95f4\u7684\u9002\u5f53\u91d1\u5c5e-\u8f7d\u4f53\u5f3a\u76f8\u4e92\u4f5c\u7528\uff08SMSI\uff09\u6548\u5e94\u53ef\u4ee5\u8c03\u828212H-NECZ\u7684\u50ac\u5316\u8131\u6c22\u6027\u80fd\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cStrengthening the metal-support interaction over Pt\/SiO<\/strong>2<\/sub><\/strong>-TiO(OH)<\/strong>2<\/sub><\/strong>\u00a0by defect engineering for efficient dehydrogenation of dodecahydro-N-ethylcarbazole<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aFuel<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u897f\u5b89\u4ea4\u5927Fuel\uff1a\u901a\u8fc7\u7f3a\u9677\u5de5\u7a0b\u589e\u5f3aSMSI\u6548\u5e94\u5b9e\u73b0\u9ad8\u6548\u8131\u6c22<\/u><\/a><\/p>\n

 <\/p>\n

 <\/p>\n

3.\u00a0<\/b>Appl. Catal. B.\uff1a\u9ad8\u6548Pd\/C\u50ac\u5316\u5242\u7528\u4e8e\u7532\u9178\u94f5\u8131\u6c22\u4e2d\u8868\u9762\u6c27\u5b98\u80fd\u56e2\u7684\u5f71\u54cd<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u534e\u76db\u987f\u5dde\u7acb\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u751f\u7269\u5de5\u7a0b\u5b66\u9662\u6797\u9e3f\u98de\u6559\u6388\u56e2\u961f\u8054\u5408\u52b3\u4f26\u65af\u5229\u5f17\u83ab\u5c14\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u6750\u6599\u79d1\u5b66\u90e8Sneha A. Akhade\u6559\u6388\u56e2\u961f\u7814\u7a76\u4e86\u78b3\u8f7d\u8868\u9762\u529f\u80fd\u5316\u94af\u50ac\u5316\u5242\u7528\u4e8e\u7532\u9178\u916f\u8131\u6c22\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u53caO\u5b98\u80fd\u56e2\u7684\u5f71\u54cd\u3002\u8be5\u9879\u7814\u7a76\u8868\u660e\uff0c O\u5b98\u80fd\u56e2\u5728\u5206\u6563Pd\u7eb3\u7c73\u9897\u7c92\u548c\u964d\u4f4e\u8131\u6c22\u6d3b\u5316\u80fd\u65b9\u9762\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u5927\u591a\u6570O \u5b98\u80fd\u56e2\u589e\u5f3a\u4e86Pd\u6d3b\u6027\u4f4d\u70b9\u4e0a\u7532\u9178\u916f\u7684\u5438\u9644\u3002\u4f46C=O\u57fa\u56e2\u7684\u5b58\u5728\u6d88\u8017\u4e86\u8fd8\u539f\u5242\uff0c\u963b\u788d\u4e86\u91d1\u5c5ePd\u7684\u5f62\u6210\u3002Pd\u5411O\u5b98\u80fd\u56e2\u7684\u7535\u5b50\u8f6c\u79fb\u4e0d\u5229\u4e8e\u8131\u6c22\u3002\u5236\u5907\u7684Pd5\/re-ACA(\u7ecf\u9178\u6d17\u6da4\u7684\u8fd8\u539f\u6d3b\u6027\u78b3)\u8868\u73b0\u51fa\u663e\u8457\u7684\u6d3b\u6027\uff0c\u5176TOF\u503c\u4e3a13511 h\u22121<\/sup>\uff0c\u9ad8\u4e8e\u5546\u7528Pd\/C\u50ac\u5316\u5242\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cEfficient Pd on carbon catalyst for ammonium formate dehydrogenation: Effect of surface oxygen functional groups\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aApplied Catalysis B: Environmental<\/i><\/em>\u4e0a\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/b><\/strong>Appl. Catal. B.\uff1a\u9ad8\u6548Pd\/C\u50ac\u5316\u5242\u7528\u4e8e\u7532\u9178\u94f5\u8131\u6c22\u4e2d\u8868\u9762\u6c27\u5b98\u80fd\u56e2\u7684\u5f71\u54cd<\/u><\/a><\/h1>\n

 <\/p>\n

4.\u00a0<\/b>\u5c71\u4e1c\u5927\u5b66ACS Catal.\uff1a\u5e38\u6e29\u5e38\u538b\u4e0bpH\u8c03\u63a7\u7684\u9ad8\u6548CO2\u50a8\u6c22\u6280\u672f<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/strong><\/p>\n

\u5c71\u4e1c\u5927\u5b66\u4efb\u56fd\u5e86\u52a9\u7406\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u5236\u5907\u4e86L-\u7cbe\u6c28\u9178\uff08LA\uff09\u529f\u80fd\u5316\u7684\u6d3b\u6027\u78b3\u8d1f\u8f7d\u7684PdAu\u5408\u91d1\u50ac\u5316\u5242\uff08PdAu\/AC-LA\uff09\uff0c\u7528\u4e8epH\u8c03\u63a7\u7684\u7532\u9178\u57fa\u50a8\u653e\u6c22\u8fc7\u7a0b\u3002\u901a\u8fc7\u8c03\u8282LA\u8d1f\u8f7d\u548cPd\/Au\u6bd4\u4f8b\u83b7\u5f97\u4e86\u6700\u4f73\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7532\u9178\uff08FA\uff09\u91ca\u653e\u7684TOF\u4e3a1760 h-1<\/sup>\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0bCO2<\/sub>\u6c22\u5316\u7684TOF\u4e3a138 h-1<\/sup>\u3002XPS\u3001CO2<\/sub>-TPD\u548cHCOO–<\/sup>\u5438\u9644\u5b9e\u9a8c\u7b49\u63ed\u793a\u4e86PdAu\u5408\u91d1\u548cLA\u5f3a\u78b1\u6027\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u7269\u7684\u5438\u9644\u800c\u589e\u5f3a\u4e86\u50ac\u5316\u6d3b\u6027\u3002\u672c\u7814\u7a76\u4f5c\u4e3a\u5728\u5e38\u6e29\u5e38\u538b\u6761\u4ef6\u4e0b\u57fa\u4e8eFA\/\u7532\u9178\u76d0\u7684\u6c22\u6c14\u50a8\u5b58\u548c\u91ca\u653e\u7684\u6210\u529f\u5b9e\u4f8b\uff0c\u5c06\u6709\u52a9\u4e8e\u63a8\u52a8\u6c22\u80fd\u6e90\u5e7f\u6cdb\u7684\u5546\u4e1a\u5316\u5e94\u7528\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cAmbient Hydrogen Storage and Release Using CO<\/strong>2<\/sub><\/strong>\u00a0and an L-Arginine-Functionalized PdAu Catalyst via pH Control<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aACS Catalysis<\/i><\/em>\u4e0a\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a\u5c71\u4e1c\u5927\u5b66ACS Catal.\uff1a\u5e38\u6e29\u5e38\u538b\u4e0bpH\u8c03\u63a7\u7684\u9ad8\u6548CO2\u50a8\u6c22\u6280\u672f<\/u><\/a><\/p>\n

 <\/p>\n

5.\u00a0<\/b>Journal of Energy Chemistry\uff1aRu\/MgO\u50ac\u5316\u5242\u4e2d\u6dfb\u52a0K\uff0c\u52a0\u901f\u82b3\u9999\u82c4\u57fa\u7532\u82ef\u7684\u50a8\u6c22\uff01<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u97e9\u56fd\u6c49\u9633\u5927\u5b66Young-Woong Suh\u548c\u97e9\u56fd\u4e9a\u6d32\u5927\u5b66Seok Ki Kim\u56e2\u961f\u4ee5\u524d\u9a71\u4f53Ru3<\/sub>(CO)12<\/sub>\u5236\u5907Ru\/MgO\u7684\u65b9\u6cd5\u4e3a\u57fa\u7840\uff0c\u627e\u5230\u4e86\u6700\u9002\u5408\u5728Ru\/MgO\u4e2d\u8d1f\u8f7dK\u7684\u65b9\u6cd5\u3002\u7136\u540e\uff0c\u4f5c\u8005\u8003\u5bdf\u4e86\u4e0d\u540cK\u7684\u6d53\u5ea6\u4e0b\uff0c\u5236\u5907\u7684Ru\/K\/MgO\u50ac\u5316\u5242\u7684\u52a0\u6c22\u6d3b\u6027\u548c\u7279\u6027\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u4e00\u7cfb\u5217DFT\u8ba1\u7b97\uff0c\u4e0d\u4ec5\u5f97\u5230\u4e86K\u5bf9Ru\/MgO\u6700\u7a33\u5b9a\u7684\u6784\u578b\uff0c\u800c\u4e14\u5f97\u5230\u4e86\u5728\u6dfb\u52a0K\u7684Ru -MgO\u754c\u9762H\u5438\u9644\u80fd\u548c\u7535\u8377\u8f6c\u79fb\u76f8\u5bf9K\u5bc6\u5ea6\u7684\u53d8\u5316\u3002K\u7684\u52a0\u5165\u53ef\u4fc3\u8fdbRu\/MgO\u5bf9H2<\/sub>\u7684\u5f02\u88c2\u5438\u9644\uff0c\u4f7fH2<\/sub>\u57281000<\/sup>C\u4f4e\u6e29\u9644\u8fd1\u50a8\u5b58\u4e8eH0<\/sub>-MBT\u548cH0<\/sub>-DBT\u4e2d\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/b><\/strong>Journal of Energy Chemistry\uff1aRu\/MgO\u50ac\u5316\u5242\u4e2d\u6dfb\u52a0K\uff0c\u52a0\u901f\u82b3\u9999\u82c4\u57fa\u7532\u82ef\u7684\u50a8\u6c22\uff01<\/u><\/a><\/h1>\n

 <\/p>\n

6.\u00a0<\/b>\u7814\u7a76\u6db2\u6001\u6709\u673a\u6c22\u8f7d\u4f53\u53d1Joule\uff1a\u7ec6\u83cc\u63a7\u5236\u6c22\u6c14\u7684\u50a8\u5b58\u548c\u91ca\u653e\uff1f<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u5fb7\u56fd\u6b4c\u5fb7\u5927\u5b66\u5206\u5b50\u751f\u7269\u79d1\u5b66\u7814\u7a76\u6240\u5206\u5b50\u5fae\u751f\u7269\u5b66\u548c\u751f\u7269\u80fd\u91cf\u5b66\u7cfbVolker M\u00fcller\u6559\u6388\u56e2\u961f\u9996\u6b21\u5c55\u793a\u4e86\u4e00\u4e2a\u751f\u7269\u57fa\u7cfb\u7edf\uff0c\u5c06\u4f0d\u6c0f\u918b\u9178\u6746\u83cc\uff08Acetobacterium woodii\uff09\u4f5c\u4e3a\u751f\u7269\u50ac\u5316\u5242\uff0c\u5141\u8bb8\u5728\u4e00\u4e2a\u751f\u7269\u53cd\u5e94\u5668\u4e2d\u591a\u6b21\u53cc\u5411\u52a0\u6c22\u751f\u6210\u7532\u9178\u3002\u7531\u4e8eHDCR\u5168\u7ec6\u80de\u7cfb\u7edf\u7684\u5347\u7ea7\u53ef\u884c\u6027\u5df2\u5728\u6405\u62cc\u69fd\u751f\u7269\u53cd\u5e94\u5668\uff08STRs\uff09\u4e2d\u5f97\u5230\u8bc1\u5b9e\uff0c\u56e0\u6b64\u8be5\u7814\u7a76\u9009\u62e9\u4e86\u7c7b\u4f3c\u7684\u751f\u7269\u53cd\u5e94\u5668\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u4f0d\u6c0f\u918b\u9178\u6746\u83cc\u5168\u7ec6\u80de\u7cfb\u7edf\uff0c\u5728\u5b9e\u9a8c\u4e2d\u5047\u8bbeH2<\/sub>\u8d2e\u85cf\u671f\uff08\u767d\u5929\uff09\u4e3a8 h\uff0cH2<\/sub>\u751f\u4ea7\u671f\uff08\u591c\u95f4\uff09\u4e3a16 h\uff0c\u8fd9\u4e00\u6bd4\u4f8b\u662f\u57fa\u4e8e\u8fd9\u6837\u4e00\u4e2a\u4e8b\u5b9e\uff1a\u5728\u5fb7\u56fd\u5357\u90e8\uff0c\u590f\u5b63\u7684\u5e73\u5747\u65e5\u7167\u65f6\u7ea6\u4e3a7-8\u5c0f\u65f6\uff0c\u4ece\u800c\u5bfc\u81f4\u57288\u5c0f\u65f6\u7684\u65f6\u95f4\u5185\uff0c\u8feb\u4f7f\u4f9d\u8d56\u6c22\u7684\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u7532\u9178\uff0c\u5728\u5269\u4f59\u7684\u65f6\u95f4\u5185\uff0816\u5c0f\u65f6\uff09\uff0c\u6240\u4ea7\u751f\u7684\u7532\u9178\u88ab\u91cd\u65b0\u6c27\u5316\u4ee5\u91ca\u653e\u50a8\u5b58\u7684H2<\/sub>\u3002\u8be5\u7814\u7a76\u56e2\u961f\u5728\u5355\u4e2a\u751f\u7269\u53cd\u5e94\u5668\u4e2d\u7814\u7a76CO2<\/sub>\u53cc\u5411\u52a0\u6c22\u5236\u7532\u9178\u7684\u8fc7\u7a0b\uff0c\u7ed3\u679c\u53d1\u73b0\u4f7f\u7528\u8be5\u5de5\u827a\u80fd\u591f\u6301\u7eed\u8fd0\u884c2\u5468\u4ee5\u4e0a\uff0c\u5171\u751f\u4ea7\u548c\u6c27\u5316\u7532\u9178\u53ef\u8fbe330 mM\u3002\u901a\u8fc7\u751f\u7269\u4ee3\u8c22\u5de5\u7a0b\uff0c\u8fd8\u9632\u6b62\u4e86\u4e0d\u5fc5\u8981\u7684\u918b\u9178\u526f\u4ea7\u7269\u7684\u5f62\u6210\u3002\u8be5\u7814\u7a76\u6240\u5c55\u793a\u7684\u5de5\u827a\u8bbe\u8ba1\u53ef\u4ee5\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u7684\u201c\u751f\u7269\u7535\u6c60\u201d\uff0c\u7528\u4e8e\u4ee5H2<\/sub>\u5f62\u5f0f\u5728\u7532\u9178\uff08\u4e00\u79cd\u591a\u529f\u80fd\u5316\u5408\u7269\uff09\u4e2d\u53ef\u9006\u5b58\u50a8\u201c\u7535\u5b50\u201d\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cBiological hydrogen storage and release through multiple cycles of bi-directional hydrogenation of CO<\/i><\/em>2<\/i><\/sub><\/em>\u00a0to formic acid in a single process unit<\/i><\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aJoule<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/b><\/strong>\u7814\u7a76\u6db2\u6001\u6709\u673a\u6c22\u8f7d\u4f53\u53d1Joule\uff1a\u7ec6\u83cc\u63a7\u5236\u6c22\u6c14\u7684\u50a8\u5b58\u548c\u91ca\u653e\uff1f<\/u><\/a><\/h1>\n

 <\/p>\n

7.\u00a0<\/b>Green Chemistry\uff1a\u4e00\u79cd\u201c\u65e0\u9ad8\u538b\u6c14\u4f53\u201d\u52a0\u6c22\u7684\u7b80\u5355\u3001\u5b89\u5168\u3001\u53ef\u9760\u7684\u7cfb\u7edf<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u897f\u73ed\u7259\u6d77\u6885\u4e00\u4e16\u5927\u5b66Jose A. Mata\u6559\u6388\u548cEduardo Garc\u00eda-Verdugo\u6559\u6388\u62a5\u9053\u4e86\u4e00\u79cd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u8fde\u7eed\u3001\u5c31\u5730\u548c\u6309\u9700\u751f\u6210\u6c22\u6c14\u7684\u7b80\u5355\u3001\u5b89\u5168\u3001\u53ef\u9760\u7684\u7cfb\u7edf\u3002\u8be5\u88c5\u7f6e\u7531\u5305\u542b\u8d1f\u8f7d\u5728\u77f3\u58a8\u70ef(NHC-Ru-rGO)\u4e0a\u7684\u948cN-\u6742\u73af\u5361\u5bbe\u7edc\u5408\u7269[Ru(\u82b3\u70c3)(Cl)2<\/sub>(NHC)]\u7684\u586b\u5145\u5e8a\u53cd\u5e94\u5668\u548c\u6db2-\u6c14\u5206\u79bb\u5668\u7ec4\u6210\uff0c\u5141\u8bb8\u7845\u70f7\u548c\u9187\u5728\u6e29\u548c\u4e14\u5b89\u5168\u7684\u6761\u4ef6\u4e0b\u8131\u6c22\u5076\u8054\u4ea7\u751f\u6c22\u6c14\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cA simple, safe and robust system for\u00a0 hydrogenation \u201cwithout high-pressure gases\u201d under batch and flow conditions using a liquid\u00a0 organic hydrogen carrier<\/strong>\u201d\u53d1\u8868\u5728Green Chemistry<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1aGreen Chemistry\uff1a\u4e00\u79cd\u201c\u65e0\u9ad8\u538b\u6c14\u4f53\u201d\u52a0\u6c22\u7684\u7b80\u5355\u3001\u5b89\u5168\u3001\u53ef\u9760\u7684\u7cfb\u7edf<\/u><\/a><\/p>\n

 <\/p>\n

 <\/p>\n

8.\u00a0<\/b>\u4e2d\u79d1\u9662\u4e0a\u6d77\u9ad8\u7b49\u7814\u7a76\u9662\u9648\u65b0\u5e86ACB\uff1a\u948c\u5355\u539f\u5b50\u548c\u5206\u5b50\u7b5b\u534f\u540c\u50ac\u5316\u7528\u4e8e\u9ad8\u6548\u50a8\u6c22<\/b><\/strong><\/h1>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u9ad8\u7b49\u7814\u7a76\u9662\u9648\u65b0\u5e86\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u62a5\u9053\u4e86\u5728*BEA\u5206\u5b50\u7b5b\u4e0a\u8d1f\u8f7d\u948c\uff08Ru\uff09\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Ru(Na)\/Beta\uff09\uff0c\u5728\u6c22\u6ea2\u6d41\u7684\u534f\u52a9\u4e0b\uff0c\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u663e\u8457\u63d0\u9ad8\u4e86N-\u4e59\u57fa\u5494\u5511\uff08NEC\uff09\u3001N-\u4e19\u57fa\u5494\u5511\uff08NPC\uff09\u30012-\u7532\u57fa\u5432\u54da\uff082-MID\uff09\u7684\u52a0\u6c22\u6027\u80fd\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u672c\u6587\u5236\u5907\u7684Ru(Na)\/Beta\u50ac\u5316\u5242\u5bf9NEC\u52a0\u6c22\u5177\u6709\u826f\u597d\u7684\u6d3b\u6027\uff0c\u5728100\u00a0\u2103\u6761\u4ef6\u4e0b\uff0c6 MPa H2<\/sub>\u57281.5 h\u5185\u7684\u5438\u6c22\u7387\u4e3a5.69 wt%\uff0c\u8f6c\u5316\u7387\u4e3a> 99%\uff0c\u800c\u4f20\u7edfRu\/Al2<\/sub>O3<\/sub>\u53ea\u67092.97 wt%\uff0c\u5176\u8f6c\u5316\u7387\u4e3a67 %\u3002\u7ed3\u679c\u8868\u660e\uff0c\u9ad8\u5ea6\u5206\u6563\u7684Ru\u5355\u539f\u5b50\u4fc3\u8fdb\u4e86\u6c22\u6d3b\u5316\uff0c\u4e14\u5206\u5b50\u7b5b\u7684\u5f3a\u9178\u4f4d\u70b9\uff08Br\u00f8nsted\u548cLewis\uff09\u4fc3\u8fdb\u4e86\u6c22\u6ea2\u6d41\u548cLOHCs\u7684\u6c22\u5316\u3002\u6b64\u5916\uff0c\u4e0e\u4f20\u7edf\u7684Ru\u57fa\u50ac\u5316\u5242\u76f8\u6bd4\uff0cRu\u5355\u539f\u5b50\u548c*BEA\u5206\u5b50\u7b5b\u7684\u534f\u540c\u50ac\u5316\u6548\u5e94\u663e\u8457\u63d0\u9ad8\u4e86\u52a0\u6c22\u901f\u7387\u548c\u964d\u4f4e\u6d3b\u5316\u80fd\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cSynergistic catalysis of Ru single-atoms and zeolite boosts high-efficiency hydrogen storage<\/i><\/b><\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Applied Catalysis B: Environmental<\/b><\/strong>\u4e0a\u3002<\/p>\n

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