{"id":247440,"date":"2023-02-19T06:28:51","date_gmt":"2023-02-18T22:28:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247440"},"modified":"2023-02-18T09:35:38","modified_gmt":"2023-02-18T01:35:38","slug":"%e5%8d%97%e4%ba%ac%e7%90%86%e5%b7%a5%e5%bc%a0%e8%83%9c%e5%88%a9%e6%9b%be%e6%b5%b7%e6%b3%a2%e6%9c%80%e6%96%b0%e7%ba%af%e8%ae%a1%e7%ae%97-nano-letters%ef%bc%9a%e9%80%9a%e8%bf%87%e5%bc%95%e5%85%a5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247440","title":{"rendered":"\u5357\u4eac\u7406\u5de5\u5f20\u80dc\u5229&#038;\u66fe\u6d77\u6ce2\u6700\u65b0\u7eaf\u8ba1\u7b97 Nano Letters\uff1a\u901a\u8fc7\u5f15\u5165\u4f9b\u7535\u5b50\u57fa\u56e2\u6291\u5236\u4e8c\u7ef4\u5171\u8f6d\u805a\u5408\u7269\u7684e-h\u975e\u8f90\u5c04\u590d\u5408"},"content":{"rendered":"<p><strong>01<\/strong><strong>\u5bfc\u8bfb<\/strong><\/p>\n<p>\u76ee\u524d\u62a5\u9053\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7684\u6548\u7387\u4e00\u76f4\u65e0\u6cd5\u7a81\u7834Shockley-Queisser\u6781\u9650\uff0c\u8fd9\u662f\u56e0\u4e3a\u5bf9\u5176\u5149\u7269\u7406\u8fc7\u7a0b\u4e86\u89e3\u7684\u4e0d\u591f\u6df1\u5165\u3002\u800c\u5728\u6b64\u8fc7\u7a0b\u626e\u6f14\u91cd\u8981\u89d2\u8272\u7684\u662f\u7535\u5b50-\u7a7a\u7a74\uff08e-h\uff09\u7684\u975e\u8f90\u5c04\u590d\u5408\uff0c\u8fd9\u662f\u6548\u7387\u635f\u5931\u7684\u6700\u4e3b\u8981\u6765\u6e90\u3002\u7136\u800c\uff0c\u975e\u8f90\u5c04\u590d\u5408\u7684\u8d77\u6e90\u5f88\u590d\u6742\uff0c\u5305\u62ec\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5e7f\u4e49\u590d\u5408\u52a8\u529b\u5b66\u548c\u754c\u9762\u8bf1\u5bfc\u7684\u590d\u5408\u3002\u56e0\u6b64\uff0c\u8bc6\u522b\u6548\u7387\u635f\u5931\u7684\u6765\u6e90\u5e76\u9488\u5bf9\u5176\u8fdb\u884c\u6291\u5236\u662f\u5b9e\u73b0\u9ad8\u6027\u80fd\u5668\u4ef6\u7684\u5173\u952e\u3002<\/p>\n<p>\u4e8c\u7ef4\u5171\u8f6d\u805a\u5408\u7269\u662f\u4e00\u7cfb\u5217\u5355\u4f53\u901a\u8fc7\u5171\u4ef7\u952e\u4ee5\u6b63\u4ea4\u65b9\u5411\u8fde\u63a5\u7684\u9ad8\u5ea6\u6709\u5e8f\u7f51\u7edc\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u9499\u949b\u77ff\u5149\u7535\u5668\u4ef6\u4e2d\u4f5c\u4e3a\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08HTL\uff09\uff0c\u4ee5\u63d0\u9ad8\u5668\u4ef6\u6027\u80fd\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u5982\u4f55\u6291\u5236\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u754c\u9762\u7535\u8377\u590d\u5408\u635f\u5931\u76ee\u524d\u5c1a\u4e0d\u6e05\u695a\uff0c\u9886\u57df\u5185\u4e5f\u9c9c\u6709\u62a5\u9053\u3002<\/p>\n<p><strong>02<\/strong><strong>\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u9488\u5bf9\u8fd9\u4e2a\u95ee\u9898\uff0c\u5357\u4eac\u7406\u5de5\u5927\u5b66<strong>\u5f20\u80dc\u5229\u3001\u66fe\u6d77\u6ce2\u3001\u5f90\u52c3<\/strong>\u7b49\u4eba\u5229\u7528\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8d75\u747e\u56e2\u961f\u81ea\u4e3b\u7814\u53d1\u7684\u7b2c\u4e00\u6027\u539f\u7406\u6fc0\u53d1\u6001\u52a8\u529b\u5b66\u7a0b\u5e8fHefei-NAMD\u6765\u7814\u7a76\u4e8c\u7ef4\u4e09\u82b3\u80fa\u805a\u5408\u7269\uff082D-triphenylamine polymer\uff09\u7684\u975e\u8f90\u5c04\u590d\u5408\u8fc7\u7a0b\u3002\u9996\u5148\uff0c\u4f5c\u8005\u901a\u8fc7DFT\u8ba1\u7b97\u53d1\u73b0\uff0c\u4e0e\u5438\u7535\u5b50\u57fa\u56e2\u76f8\u6bd4\uff0c\u5177\u6709\u4f9b\u7535\u5b50\u57fa\u56e2\u76842D-triphenylamine\u5177\u6709\u66f4\u5408\u9002\u7684\u5e26\u8fb9\u4f4d\u7f6e\uff0c\u66f4\u5c0f\u7684\u6709\u6548\u8d28\u91cf\u548c\u66f4\u5927\u7684\u5076\u6781\u77e9\uff0c\u8868\u660e\u5177\u6709\u4f9b\u7535\u5b50\u57fa\u56e2\u76842D-triphenylamine\u6709\u6210\u4e3aPSC\u4e2dHTL\u7684\u6f5c\u529b\u3002\u975e\u7edd\u70ed\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8fdb\u4e00\u6b65\u8868\u660e\u4e86\u5177\u6709\u4f9b\u7535\u5b50\u57fa\u56e2\u76842D-triphenylamine\u53ef\u4ee5\u6709\u6548\u7684\u6291\u5236e-h\u7684\u975e\u8f90\u5c04\u590d\u5408\u3002\u8fd9\u662f\u7531\u4e0b\u9762\u51e0\u4e2a\u56e0\u7d20\u5bfc\u81f4\u7684\uff1a1\uff09\u4f9b\u7535\u5b50\u57fa\u56e2\u4f7f\u7535\u5b50\u4e91\u504f\u79bb\u5b98\u80fd\u56e2\u7684\u90e8\u5206\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u672c\u5f81\u6750\u6599\u7684\u5171\u8f6d\u6548\u5e94\uff0c\u5bfc\u81f4\u80fd\u7ea7\u632f\u8361\u7684\u51cf\u5f31\uff0c\u4ece\u800c\u5bfc\u81f4\u7535\u5b50-\u58f0\u5b50\u8026\u5408\u7684\u964d\u4f4e\uff1b2\uff09\u5177\u6709\u4f9b\u7535\u5b50\u57fa\u56e2\u76842D\u805a\u5408\u7269\u7684\u5e26\u9699\u5927\u4e8e\u7531\u5438\u7535\u5b50\u57fa\u56e2\u7ec4\u6210\u76842D\u805a\u5408\u7269\uff0c\u8fd9\u51cf\u5c11\u4e86\u975e\u7edd\u70ed\u8026\u5408\uff08NAC\uff09\uff0c\u4ece\u800c\u6291\u5236\u4e86e-h\u975e\u8f90\u5c04\u590d\u5408\uff1b3\uff09\u4f4e\u9891\u58f0\u5b50\u7684\u5f15\u5165\u964d\u4f4e\u4e86\u6838\u901f\u5ea6\uff0c\u4ece\u800c\u964d\u4f4e\u4e86NAC\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cSuppressing Nonradiative Recombination by Electron-Donating Substituents in 2D Conjugated Triphenylamine Polymers toward Efficient Perovskite Optoelectronics\u201d\u4e3a\u9898\u4e8e2023\u5e742\u670815\u65e5\u53d1\u8868\u5728<em><strong>Nano Letters<\/strong><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone  wp-image-247441\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-1-1.png\" alt=\"\" width=\"434\" height=\"421\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-1-1.png 980w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-1-1-300x291.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-1-1-768x744.png 768w\" sizes=\"(max-width: 434px) 100vw, 434px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-247442\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-2-1.png\" alt=\"\" width=\"1287\" height=\"281\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-2-1.png 1287w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-2-1-300x66.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-2-1-768x168.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-2-1-1024x224.png 1024w\" sizes=\"(max-width: 1287px) 100vw, 1287px\" \/><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>03<\/strong><strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<ol>\n<li>\u9996\u6b21\u63d0\u51fa\u4e86\u901a\u8fc7\u6dfb\u52a0\u4f9b\u7535\u5b50\u57fa\u56e2\u6765\u6291\u52362D-triphenylamine\u805a\u5408\u7269\u4e2d\u7684e-h\u975e\u8f90\u5c04\u590d\u5408\u7684\u7b56\u7565\u3002<\/li>\n<li>\u5177\u6709\u9ad8\u5171\u8f6d\u6027\u7684\u4e8c\u7ef4\u805a\u5408\u7269\u53ef\u4ee5\u6709\u6548\u7684\u964d\u4f4e\u7535\u5b50-\u58f0\u5b50\u8026\u5408\uff0c\u5e76\u4e14\u5f15\u5165\u4e00\u4e9b\u4f4e\u9891\u58f0\u5b50\uff0c\u4ece\u800c\u964d\u4f4e\u4e86NAC\u3002<\/li>\n<\/ol>\n<p><strong>04<\/strong><strong>\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-247444\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-28.png\" alt=\"\" width=\"1369\" height=\"770\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-28.png 1369w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-28-300x169.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-28-768x432.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-28-1024x576.png 1024w\" sizes=\"(max-width: 1369px) 100vw, 1369px\" \/><\/p>\n<p>\u56fe1. \u4f9b\u7535\u5b50\u57fa\u56e2\uff08a\uff092D-HQAO\u548c\uff08b\uff092D-DQAO\u4ee5\u53ca\u5438\u7535\u5b50\u57fa\u56e2\uff08c\uff092D-OQAO\u548c\uff08d\uff092D-SQAO\u4e2d\u7684\u7ed3\u6784\u548c\u7535\u5b50\u5bc6\u5ea6\u56fe\u7684\u793a\u610f\u56fe\u3002\u5176\u4e2d\u7ea2\u8272\u6846\u8868\u793a\u5b98\u80fd\u56e2\u4e0a\u7684\u7535\u5b50\u4e0e\u82ef\u73af\u7684\u03c0\u7cfb\u7edf\u4e4b\u95f4\u7684\u91cd\u53e0\u7a0b\u5ea6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-247445\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-25.png\" alt=\"\" width=\"1969\" height=\"1108\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-25.png 1969w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-25-300x169.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-25-768x432.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-25-1024x576.png 1024w\" sizes=\"(max-width: 1969px) 100vw, 1969px\" \/><\/p>\n<p>\u56fe2.\uff08a\uff092D-HQAO\u3001\uff08b\uff092D-DQAO\u3001\uff08c\uff092D-OQAO\u548c\uff08d\uff092D-SQAO\u7684\u80fd\u5e26\u7ed3\u6784\uff08\u5de6\u9762\u677f\uff09\u548c\u76f8\u5e94\u7684\u90e8\u5206\u7535\u8377\u5bc6\u5ea6\uff08\u53f3\u9762\u677f\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-247446\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-23.png\" alt=\"\" width=\"1280\" height=\"720\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-23.png 1280w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-23-300x169.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-23-768x432.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-23-1024x576.png 1024w\" sizes=\"(max-width: 1280px) 100vw, 1280px\" \/><\/p>\n<p>\u56fe3.\uff08a\uff09\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u80fd\u7ea7\u6392\u5217\uff08\u4e0a\u56fe\uff09\u3001\u5076\u6781\u77e9\uff08\u5de6\u4e0b\u56fe\uff09\u548c\u6709\u6548\u8d28\u91cf\uff08\u53f3\u4e0b\u56fe\uff09\u3002\uff08b\uff092D-HQAO\u30012D-DQAO\u30012D-OQAO\u548c2D-SQAO\u4e2d\u7684e-h\u975e\u8f90\u5c04\u590d\u5408\u52a8\u529b\u5b66\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-247447\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-22.png\" alt=\"\" width=\"1379\" height=\"776\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-22.png 1379w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-22-300x169.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-22-768x432.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-22-1024x576.png 1024w\" sizes=\"(max-width: 1379px) 100vw, 1379px\" \/><\/p>\n<p>\u56fe4.\uff08a\uff092D-HQAO\u3001\uff08b\uff092D-DQAO\uff0c\uff08c\uff092D-OQAO\u548c\uff08d\uff092D-SQAO\u7684KS\u6001\uff08\u5de6\u9762\u677f\uff09\u548cFT\uff08\u53f3\u9762\u677f\uff09\u58f0\u5b50\u8bf1\u5bfc\u7684VBM\u548cCBM\u6ce2\u52a8\u7684\u80fd\u91cf\u6f14\u53d8\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>05<\/strong><strong>\u6210\u679c\u542f\u793a<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u79cd\u7b56\u7565\uff0c\u901a\u8fc7\u5f15\u5165\u4f9b\u7535\u5b50\u57fa\u56e2\u6765\u589e\u5f3a\u5171\u8f6d\u6548\u5e94\u548c\u7535\u5b50\u4e91\u5bc6\u5ea6\uff0c\u4ece\u800c\u6291\u52362D-triphenylamine\u805a\u5408\u7269\u7684\u975e\u8f90\u5c04\u590d\u5408\u3002NAMD\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u5177\u6709\u4f9b\u7535\u5b50\u57fa\u56e2\u7684\u5171\u8f6d\u7cfb\u7edf\u5448\u73b0\u51fa\u66f4\u5c0f\u7684\u80fd\u7ea7\u632f\u8361\u3002\u5e76\u4e14\uff0c\u5728\u4f9b\u7535\u5b50\u57fa\u56e2\u7cfb\u7edf\u4e2d\u5f15\u5165\u7684\u4f4e\u9891\u58f0\u5b50\u964d\u4f4e\u4e86\u975e\u7edd\u70ed\u8026\u5408\u91cf\uff0c\u8fdb\u800c\u6291\u5236\u4e86\u975e\u8f90\u5c04\u590d\u5408\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u6837\u7684\u4f9b\u7535\u5b50\u57fa\u56e2\u53ef\u4ee5\u964d\u4f4e2D\u805a\u5408\u7269\u7684\u4ef7\u5e26\u6700\u5927\u503c\u5e76\u4fc3\u8fdb\u7a7a\u7a74\u4f20\u8f93\u3002\u4f5c\u8005\u7684\u62a5\u544a\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u8bbe\u8ba1\u7b56\u7565\u6765\u6291\u5236HTL\u4e2d\u7684\u975e\u8f90\u5c04\u590d\u5408\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a\u201cSuppressing Nonradiative Recombination by Electron-Donating Substituents in 2D Conjugated Triphenylamine Polymers toward Efficient Perovskite Optoelectronics\u201d (Nano Letters\uff0c<a href=\"https:\/\/doi.org\/10.1021\/acs.nanolett.2c05106\">https:\/\/doi.org\/10.1021\/acs.nanolett.2c05106<\/a>)<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>01\u5bfc\u8bfb \u76ee\u524d\u62a5\u9053\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7684\u6548\u7387\u4e00\u76f4\u65e0\u6cd5\u7a81\u7834Shockley-Queisser\u6781\u9650\uff0c\u8fd9\u662f\u56e0\u4e3a\u5bf9\u5176\u5149\u7269\u7406\u8fc7\u7a0b\u4e86\u89e3\u7684\u4e0d\u591f\u6df1\u5165\u3002\u800c\u5728\u6b64\u8fc7\u7a0b\u626e\u6f14\u91cd\u8981&#8230;<\/p>\n","protected":false},"author":41672,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-247440","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/247440"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/41672"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=247440"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/247440\/revisions"}],"predecessor-version":[{"id":247448,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/247440\/revisions\/247448"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=247440"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=247440"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=247440"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}