{"id":247603,"date":"2023-03-03T15:45:27","date_gmt":"2023-03-03T07:45:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247603"},"modified":"2023-03-03T15:14:30","modified_gmt":"2023-03-03T07:14:30","slug":"%e3%80%90%e6%96%b0%e8%83%bd%e6%ba%90%e5%89%8d%e7%ba%bf%e3%80%91%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e7%89%9b%e5%bf%97%e5%bc%bap-natl-acad-sci-usa%ef%bc%9a%e8%80%a6%e5%90%88%e5%8f%8c%e9%87%91%e5%b1%9e","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247603","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u725b\u5fd7\u5f3aP Natl Acad Sci Usa\uff1a\u8026\u5408\u53cc\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u548c\u4f4e\u6eb6\u5242\u5316\u4f53\u7cfb\u5b9e\u73b0\u9ad8\u6027\u80fd\u7684\u6c34\u6eb6\u6db2\u94f5\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"

\u5357\u5f00\u5927\u5b66\u725b\u5fd7\u5f3a\u56e2\u961f<\/strong> P Natl Acad Sci Usa<\/strong>\uff1a\u8026\u5408\u53cc\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u548c\u4f4e\u6eb6\u5242\u5316\u4f53\u7cfb\u5b9e\u73b0\u9ad8\u6027\u80fd\u7684\u6c34\u6eb6\u6db2\u94f5\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n

01<\/strong>\u3001\u5bfc\u8bfb<\/strong><\/p>\n

\u6c34\u6027\u53ef\u5145\u7535\u7535\u6c60\u5177\u6709\u4f4e\u6210\u672c\u3001\u5b89\u5168\u6027\u9ad8\u3001\u5bf9\u73af\u5883\u53cb\u597d\u7b49\u7279\u70b9\uff0c\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u5e94\u7528\u4e2d\u6f5c\u529b\u5341\u8db3\u3002\u8f7d\u6d41\u5b50\u5bf9\u4e8e\u8c03\u63a7\u6c34\u6027\u53ef\u5145\u7535\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u5341\u5206\u91cd\u8981\u3002\u901a\u5e38\uff0c\u91d1\u5c5e\u9633\u79bb\u5b50\u5728\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u88ab\u7528\u4f5c\u7535\u8377\u8f7d\u4f53\uff0c\u4f46\u8fd1\u5e74\u6765\uff0c\u975e\u91d1\u5c5e\u79bb\u5b50\u4e5f\u88ab\u79d1\u5b66\u5bb6\u5145\u5f53\u8f7d\u6d41\u5b50\u4f7f\u7528\u3002\u5728\u5404\u79cd\u975e\u91d1\u5c5e\u8f7d\u6d41\u5b50\u4e2d\uff0cNH4+<\/sup>\u79bb\u5b50\u7684\u6469\u5c14\u8d28\u91cf\u76f8\u5bf9\u8f83\u4f4e\uff0c\u6c34\u5408\u79bb\u5b50\u534a\u5f84\u8f83\u5c0f\uff0c\u8fd9\u5c06\u6709\u5229\u4e8e\u79bb\u5b50\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u5feb\u901f\u8fc1\u79fb\u3002\u6b64\u5916\uff0c\u4e0e\u9178\u6027\u6216\u78b1\u6027\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cNH4+<\/sup>\u57fa\u6c34\u7535\u89e3\u8d28\u5177\u6709\u66f4\u6e29\u548c\u7684\u6027\u8d28\uff0c\u5bf9\u5404\u79cd\u7535\u6781\u6750\u6599\u90fd\u5f88\u53cb\u597d\u3002\u6b64\u5916\uff0cNH4+<\/sup>\u57fa\u6c34\u7535\u89e3\u8d28\u7684\u9ad8\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u53ef\u4ee5\u907f\u514d\u7535\u89e3\u8d28\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u526f\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9ad8\u6027\u80fd\u7684\u6c34\u6001\u94f5\u79bb\u5b50\u7535\u6c60\uff08AIBs\uff09\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\uff08PBAs\uff09\u662f\u5e38\u89c1\u7684\u6c34\u6027AIBs\u6b63\u6781\u6d3b\u6027\u6750\u6599\uff0c\u76f8\u6bd4\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff0cPBAs\u53ef\u4ee5\u63d0\u4f9b\u66f4\u9ad8\u7684NH4+<\/sup>\u79bb\u5b50\u5b58\u50a8\u6f5c\u529b\uff0c\u7136\u800c\uff0c\u5b83\u4eec\u7684NH4+<\/sup>\u79bb\u5b50\u5b58\u50a8\u7535\u4f4d\u90fd\u5f80\u5f80\u8f83\u4f4e\uff0c\u8fd9\u5bfc\u81f4\u6c34\u6001AIBs\u7684\u8f93\u51fa\u7535\u538b\u4e0d\u80fd\u6ee1\u8db3\u8981\u6c42\u3002\u4f46\u7814\u7a76\u53d1\u73b0\uff0c\u5982\u679c\u5c06N\u914d\u4f4d\u7684Mn\u6d3b\u6027\u7269\u79cd\u5f15\u5165PBAs\u4e2d\uff0c\u5c06\u663e\u8457\u63d0\u9ad8PBAs\u7684NH4+<\/sup>\u79bb\u5b50\u5b58\u50a8\u80fd\u529b\uff0c\u589e\u5f3aPBAs\u7684\u5b58\u50a8\u6f5c\u529b\u3002\u6b64\u5916\uff0cFe\u53d6\u4ee3Mn\u57faPBAs\u53ef\u4ee5\u63d0\u9ad8\u7535\u6c60\u5145\u653e\u7535\u7a33\u5b9a\u6027\u3002<\/p>\n

02<\/strong>\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u53d7\u4e0a\u8ff0\u542f\u53d1\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u7279\u8058\u7814\u7a76\u5458\u725b\u5fd7\u5f3a\u56e2\u961f\u5236\u5907\u4e86Fe\u53d6\u4ee3Mn-\u57faPBAs\uff08FeMnHCF\uff09\uff0c\u8be5PBAs\u5728\u9aa8\u67b6\u4e2d\u5177\u6709Mn\u548cFe\u7684\u53cc\u91cd\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\uff0c\u53ef\u4f5c\u4e3a\u6c34\u6027AIBs\u7684\u6b63\u6781\u6d3b\u6027\u6750\u6599\u3002\u540c\u65f6\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u4e00\u6b65\u5f00\u53d1\u4e86\u9ad8\u6d53\u5ea6\u4e09\u6c1f\u7532\u57fa\u78fa\u9178\u94f5\uff08NH4<\/sub>CF3<\/sub>SO3<\/sub>\uff09\u7535\u89e3\u6db2\uff0c\u4ee5\u5339\u914d\u8fd9\u79cd\u9ad8\u7535\u4f4d\u7684FeMnHCF\u9634\u6781\u3002\u5728\u6d53\u7535\u89e3\u8d28\u4e2d\uff0cCF3<\/sub>SO3-<\/sup>\u9634\u79bb\u5b50\u53c2\u4e0eNH4+<\/sup>\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u8fd9\u6709\u5229\u4e8eNH4+<\/sup>\u79bb\u5b50\u5728FeMnHCF\u4e2d\u7684\u63d2\u5c42\u52a8\u529b\u5b66\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6c34\u5206\u5b50\u4e0eNH4+<\/sup>\/CF3<\/sub>SO3\u2212<\/sup>\u79bb\u5b50\u4e4b\u95f4\u7684\u6c22\u952e\u7f51\u7edc\u5728\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u4e2d\u88ab\u91cd\u6784\uff0c\u6c34\u5206\u5b50\u7684\u6d3b\u6027\u88ab\u6709\u6548\u6291\u5236\u3002\u56e0\u6b64\uff0c\u9ad8\u6d53\u5ea6NH4<\/sub>CF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u7684\u7535\u538b\u7a97\u53e3\u663e\u8457\u6269\u5927\uff0c\u8fd9\u4fdd\u8bc1\u4e86FeMnHCF\u4e2d\u53d1\u751f\u9ad8\u7535\u4f4d\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u8fd9\u79cd\u6d53\u7f29\u7535\u89e3\u8d28\u4e2d\u6e38\u79bb\u6c34\u5206\u5b50\u8f83\u5c11\uff0c\u4e5f\u6709\u6548\u5730\u6291\u5236\u6d3b\u6027\u7269\u8d28\u7684\u6eb6\u89e3\u3002\u7ed3\u679c\u8868\u660e\uff0c\u7ec4\u88c5\u540e\u7684\u6c34\u6027AIBs\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u4f18\u5f02\u7684\u901f\u7387\u80fd\u529b\u548c\u7a33\u5b9a\u7684\u5faa\u73af\u884c\u4e3a\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u6784\u5efa\u9ad8\u6027\u80fd\u6c34\u6027AIBs\u63d0\u4f9b\u4e86\u4e00\u6761\u521b\u9020\u6027\u7684\u9014\u5f84\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cCoupling dual metal active sites and low-solvation architecture toward high-performance aqueous ammonium-ion batteries<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aPROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

03<\/strong>\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

1\u3001\u8be5\u7814\u7a76\u5c06FeMnHCF\u9634\u6781\u4e0e\u9ad8\u6d53\u5ea6NH4<\/sub>CF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u76f8\u7ed3\u5408\uff0c\u5236\u5907\u4e86\u9ad8\u80fd\u91cf\u6c34\u76f8AIBs\u3002<\/p>\n

2\u3001\u5728\u9ad8\u6d53\u5ea6NH4<\/sub>CF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u4e2d\uff0cFeMnHCF\u7684\u6eb6\u89e3\u5f97\u5230\u4e86\u6709\u6548\u7684\u9650\u5236\uff0c\u4ece\u800c\u83b7\u5f97\u4e86\u7a33\u5b9a\u7684NH4+<\/sup>\u5b58\u50a8\u6027\u80fd\uff08\u57283.0 ag\u22121<\/sup>\u6761\u4ef6\u4e0b\uff0c1\u4e07\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u7559\u7387\u4e3a68.5%\uff09\u3002<\/p>\n

3\u3001\u6c34\u76f8AIBs\u7535\u6c60\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u80fd\u91cf\u5bc6\u5ea6~71 Wh kg-1<\/sup>\uff0c\u800c\u4e14\u8fd8\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u901f\u7387\u80fd\u529b\u548c\u957f\u5468\u671f\u5bff\u547d\u3002<\/p>\n

04<\/strong>\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>\uff08<\/strong>A<\/strong>\uff09\u6c34\u6eb6\u6db2<\/strong>AIBs SHE<\/strong>\uff1a\u6807\u51c6\u6c22\u7535\u6781\u4e2d\u5404\u79cd\u6d3b\u6027\u6750\u6599\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u4e0d\u540c\u6c34\u6eb6\u6db2\u7535\u89e3\u8d28\u7684\u7535\u538b\u7a97\u53e3\u3002\uff08<\/strong>B<\/strong>\uff09\u4f4e\u3001\u9ad8\u6d53\u5ea6<\/strong>NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u6c34\u6eb6\u6db2\u7535\u89e3\u8d28\u4e2d<\/strong>AIBs<\/strong>\u7684\u793a\u610f\u56fe\uff1b<\/strong>Copyright \u00a9 2023 National Academy of Science.<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u7535\u89e3\u6db2\u8868\u5f81<\/strong>Copyright \u00a9 2023 National Academy of Science.<\/strong><\/p>\n

\uff08<\/strong>A<\/strong>\uff09<\/strong>NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u7535\u89e3\u6db2\u7684\u5149\u5b66\u56fe\u50cf\uff1b<\/strong><\/p>\n

\uff08<\/strong>B<\/strong>\uff09\u4e0d\u540c\u6d53\u5ea6<\/strong>NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u7535\u89e3\u6db2\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u542b\u6c34\u91cf\u548c\uff08<\/strong>C<\/strong>\uff09<\/strong>FTIR<\/strong>\u5149\u8c31\uff1b<\/strong><\/p>\n

\uff08<\/strong>D<\/strong>\uff09<\/strong>MD<\/strong>\u6a21\u62df\u5feb\u7167\uff1b<\/strong><\/p>\n

\uff08<\/strong>E<\/strong>\uff09<\/strong>N (NH4+<\/sup>) -O (H2<\/sub>O)<\/strong>\u548c<\/strong>N (NH4+<\/sup>) -O (CF3<\/sub>SO3\u2212<\/sup>)<\/strong>\u7684<\/strong>RDF<\/strong>\u56fe\uff0c\u4ee5\u53ca\u5bf9\u5e94\u7684<\/strong>1 m<\/strong>\u548c<\/strong>24 m NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u7535\u89e3\u6db2\u7684\u5e73\u5747\u914d\u4f4d\u6570\u3002<\/strong><\/p>\n

\uff08<\/strong>F<\/strong>\u3001<\/strong>G<\/strong>\uff09<\/strong>H(H2<\/sub>O)-N(NH4+<\/sup>)<\/strong>\u3001<\/strong>H (H2<\/sub>O)-O(CF3<\/sub>SO3\u2212<\/sup>)<\/strong>\u3001<\/strong>O(H2<\/sub>O)-O(H2<\/sub>O)<\/strong>\u548c<\/strong>O(H2<\/sub>O)-H(NH4+<\/sup>)<\/strong>\u5728<\/strong>1m<\/strong>\u548c<\/strong>24 m<\/strong>\u7535\u89e3\u6db2\u4e2d\u7684<\/strong>RDF<\/strong>\u56fe\u53ca\u5bf9\u5e94\u7684\u5e73\u5747\u914d\u4f4d\u6570\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 FeMnHCF<\/strong>\u7535\u6781\u5728<\/strong>1 m<\/strong>\u548c<\/strong>24 m NH4<\/sub>CF3<\/sub>SO3<\/sub><\/strong>\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>Copyright \u00a9 2023 National Academy of Science.<\/strong><\/p>\n

\uff08<\/strong>A<\/strong>\uff09<\/strong>5.0 mV s\u22121<\/sup><\/strong>\u65f6<\/strong>LSV<\/strong>\u66f2\u7ebf\uff1b<\/strong><\/p>\n

\uff08<\/strong>B<\/strong>\uff09<\/strong>0.5 A g\u22121<\/sup><\/strong>\u5904\u7684<\/strong>GCD<\/strong>\u66f2\u7ebf\uff1b<\/strong><\/p>\n

\uff08<\/strong>C<\/strong>\uff09\u5404\u79cd<\/strong>NH4+<\/sup><\/strong>\u79bb\u5b50\u5b58\u50a8\u6750\u6599\u7684\u7535\u4f4d\u6bd4\u8f83\uff1b<\/strong><\/p>\n

\uff08<\/strong>D<\/strong>\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5e93\u4ed1\u6548\u7387\uff1b<\/strong><\/p>\n

\uff08<\/strong>E<\/strong>\uff09<\/strong>3.0 A g\u22121<\/sup><\/strong>\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/strong><\/p>\n

\uff08<\/strong>F<\/strong>\uff09\u5faa\u73af\u540e\u6ee4\u5149\u5206\u79bb\u5668\u7684<\/strong>FTIR<\/strong>\u5149\u8c31\u548c\u5149\u5b66\u56fe\u50cf\uff1b<\/strong><\/p>\n

\uff08<\/strong>G<\/strong>\u3001<\/strong>H<\/strong>\uff09\u4e0d\u540c\u5468\u671f\u7684\u5c3c\u594e\u65af\u7279\u56fe\uff1b<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u5168<\/strong>AIBs<\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>Copyright \u00a9 2023 National Academy of Science.<\/strong><\/p>\n

\uff08<\/strong>A<\/strong>\uff09<\/strong>10.0 mV s\u22121<\/sup><\/strong>\u65f6\u7684<\/strong>CV<\/strong>\u66f2\u7ebf\uff1b<\/strong><\/p>\n

\uff08<\/strong>B<\/strong>\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684<\/strong>GCD<\/strong>\u66f2\u7ebf\uff1b<\/strong><\/p>\n

\uff08<\/strong>C<\/strong>\uff09\u6bd4\u8f83\u5168\u7535\u6c60\u4e0e\u5176\u4ed6\u62a5\u9053\u7684\u542b\u6c34\u5168<\/strong>AIBs<\/strong>\u7684\u5e73\u5747\u653e\u7535\u7535\u538b\u3001\u5bb9\u91cf\uff08\u57fa\u4e8e\u4e24\u4e2a\u7535\u6781\u7684\u603b\u6d3b\u6027\u8d28\u91cf\uff09\u4ee5\u53ca\u80fd\u91cf\u5bc6\u5ea6\uff1b<\/strong><\/p>\n

\uff08<\/strong>D<\/strong>\uff09<\/strong>FeMnHCF<\/strong>\u4e0e\u5176\u4ed6\u62a5\u9053\u7684\u57fa\u4e8e<\/strong>PBAs<\/strong>\u7684\u6c34\u6027<\/strong>AIBs<\/strong>\u6b63\u6781\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u6bd4\u8f83\uff1b\uff08<\/strong>E<\/strong>\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684<\/strong>CV<\/strong>\u66f2\u7ebf\uff1b<\/strong><\/p>\n

\uff08<\/strong>F<\/strong>\uff09\u6c27\u5316\u8fd8\u539f\u5cf0\u7684<\/strong>log(<\/strong>\u5cf0\u503c\u7535\u6d41<\/strong>)<\/strong>\u4e0e<\/strong>log(<\/strong>\u626b\u63cf\u901f\u7387<\/strong>)<\/strong>\u5bf9\u5e94\u56fe\uff1b<\/strong><\/p>\n

\uff08<\/strong>G<\/strong>\uff09\u653e\u7535\u8fc7\u7a0b\u4e2d\u8ba1\u7b97\u7684<\/strong>NH4+<\/sup><\/strong>\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u53ca\u4e0e\u5176\u4ed6\u7535\u6c60\u7cfb\u7edf\u7684\u6bd4\u8f83\uff1b<\/strong><\/p>\n

\uff08<\/strong>H<\/strong>\uff09<\/strong>9.0 A g\u22121<\/sup><\/strong>\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 FeMnHCF<\/strong>\u9634\u6781\u5728\u6c34\u6027<\/strong>AIBs<\/strong>\u4e2d\u7684\u50a8\u80fd\u673a\u7406<\/strong> Copyright \u00a9 2023 National Academy of Science.<\/strong><\/p>\n

\uff08<\/strong>A<\/strong>\uff09<\/strong> 0.2 A g\u22121<\/sup><\/strong>\u5904\u7684\u7b2c\u4e09\u6761<\/strong>GCD<\/strong>\u66f2\u7ebf\uff0c\u5176\u4e2d\u5728<\/strong>GCD<\/strong>\u66f2\u7ebf\u7684\u6807\u8bb0\u70b9\u4e0a\u5bf9<\/strong>FeMnHCF<\/strong>\u7535\u6781\u8fdb\u884c\u5404\u79cd\u539f\u4f4d\u8868\u5f81\uff1b<\/strong><\/p>\n

\uff08<\/strong>B<\/strong>\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684<\/strong>FTIR<\/strong>\u5149\u8c31\uff1b<\/strong><\/p>\n

\uff08<\/strong>C<\/strong>\uff09<\/strong>N 1s XPS<\/strong>\u5149\u8c31\uff1b<\/strong><\/p>\n

\uff08<\/strong>D<\/strong>\uff09<\/strong>XRD<\/strong>\u56fe\u8c31\uff1b<\/strong><\/p>\n

\uff08<\/strong>E<\/strong>\uff09<\/strong>Mn 2p<\/strong>\u548c\uff08<\/strong>F<\/strong>\uff09<\/strong>Fe 2p XPS<\/strong>\u56fe\u8c31\uff1b<\/strong><\/p>\n

\uff08<\/strong>G<\/strong>\uff09<\/strong>FeMnHCF<\/strong>\u9634\u6781\u4e2d<\/strong>NH4+<\/sup><\/strong>\u79bb\u5b50\u5b58\u50a8\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/strong><\/p>\n

05<\/strong>\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u7814\u7a76\u5c06FeMnHCF\u9634\u6781\u4e0e\u9ad8\u6d53\u5ea6NH4<\/sub>CF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u76f8\u7ed3\u5408\uff0c\u5236\u5907\u4e86\u9ad8\u80fd\u91cf\u6c34\u76f8AIBs\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728\u6b64\u6d53\u7f29\u7535\u89e3\u6db2\u4e2d\uff0c\u5177\u6709\u4e24\u79cd\u6d3b\u6027\u7ec4\u5206\u7684FeMnHCF\u9634\u6781\u5177\u6709\u8f83\u597d\u7684NH4+<\/sup>\u79bb\u5b50\u5b58\u50a8\u5bb9\u91cf\u548c\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\u3002\u6b64\u5916\uff0c\u5728\u9ad8\u6d53\u5ea6NH4<\/sub>CF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u4e2d\uff0cFeMnHCF\u7684\u6eb6\u89e3\u4e5f\u5f97\u5230\u4e86\u6709\u6548\u7684\u9650\u5236\uff0c\u4ece\u800c\u83b7\u5f97\u4e86\u7a33\u5b9a\u7684NH4+<\/sup>\u5b58\u50a8\u6027\u80fd\uff08\u57283.0 ag\u22121<\/sup>\u6761\u4ef6\u4e0b\uff0c1\u4e07\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u7559\u7387\u4e3a68.5%\uff09\u3002\u4f5c\u4e3a\u6982\u5ff5\u9a8c\u8bc1\uff0c\u7814\u7a76\u4eba\u5458\u7ec4\u88c5\u4e86\u6c34\u76f8AIBs\uff0c\u7531\u6b64\u4ea7\u751f\u7684\u7535\u6c60\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u80fd\u91cf\u5bc6\u5ea6~71 Wh kg-1<\/sup>\uff0c\u800c\u4e14\u8fd8\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u901f\u7387\u80fd\u529b\u548c\u957f\u5468\u671f\u5bff\u547d\u3002\u8be5\u7814\u7a76\u4e3a\u7ed3\u5408\u591a\u79cd\u6d3b\u6027\u7ec4\u5206\u548c\u4f18\u5316\u6eb6\u5242\u5316\u7ed3\u6784\u6784\u5efa\u9ad8\u6027\u80fd\u6c34\u6027AIBs\u63d0\u4f9b\u4e86\u4e00\u6761\u53ef\u884c\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Coupling dual metal active sites and low-solvation architecture toward high-performance aqueous ammonium-ion batteries<\/strong>\uff0c<\/strong>2022<\/strong>\uff0c<\/strong>https:\/\/doi.org\/10.1073\/pnas.2214545119<\/strong>\uff09<\/strong><\/p>\n

 <\/p>\n

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