{"id":247785,"date":"2023-03-07T06:07:44","date_gmt":"2023-03-06T22:07:44","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247785"},"modified":"2023-03-06T13:43:04","modified_gmt":"2023-03-06T05:43:04","slug":"%e5%8c%97%e5%a4%a7%e3%80%81%e6%9a%a8%e5%a4%a7acs-eenrgy-lett-%ef%bc%9a%e5%8e%9f%e4%bd%8d%e7%94%9f%e9%95%bf%e7%9a%84mof%e5%9f%ba%e4%ba%ba%e5%b7%a5sei%e5%8a%a9%e5%8a%9b%e9%ab%98%e5%8f%af%e9%80%86zn","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247785","title":{"rendered":"\u5317\u5927\u3001\u66a8\u5927ACS Energy Lett.\uff1a\u539f\u4f4d\u751f\u957f\u7684MOF\u57fa\u4eba\u5de5SEI\u52a9\u529b\u9ad8\u53ef\u9006Zn\u8d1f\u6781"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>\u4e00\u3001\u5bfc\u8bfb<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u5728\u53cc\u78b3\u5927\u80cc\u666f\u4e0b\uff0c\u793e\u4f1a\u66f4\u52a0\u8ffd\u6c42\u53ef\u518d\u751f\u80fd\u6e90\u7684\u8f6c\u5316\u548c\u5229\u7528\uff0c\u5c24\u5176\u5728\u7535\u6c60\u5e02\u573a\uff0c\u6210\u4e3a\u5404\u5927\u8d44\u672c\u529b\u91cf\u89d2\u9010\u7684\u9ad8\u5730\u3002\u76ee\u524d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u826f\u597d\u7684\u5faa\u73af\u5bff\u547d\u5df2\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u5230\u4e86\u7535\u52a8\u6c7d\u8f66\u4ee5\u53ca\u624b\u673a\u548c\u7535\u8111\u7b49\u4fbf\u643a\u7535\u5b50\u8bbe\u5907\u4e2d\u3002\u4f46\u662f\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u9502\u3001\u94b4\u7b49\u5143\u7d20\u50a8\u91cf\u4f4e\u3001\u6210\u672c\u9ad8\u6602\uff0c\u5e76\u4e14\u6709\u673a\u7535\u89e3\u6db2\u6613\u71c3\u70e7\u3001\u5b89\u5168\u6027\u4f4e\uff0c\u8fd9\u4e9b\u90fd\u9650\u5236\u4e86\u5176\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u7684\u5e94\u7528\u3002\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u91c7\u7528\u91d1\u5c5e\u950c\u4f5c\u4e3a\u8d1f\u6781\uff0c\u5176\u8d44\u6e90\u4e30\u5bcc\u3001\u4f4e\u6bd2\u6027\u3002\u56e0\u6b64\u4ef7\u683c\u4f4e\u5ec9\u3001\u5b89\u5168\u6027\u9ad8\u3001\u65e0\u73af\u5883\u6c61\u67d3\u7684\u4e8c\u6b21\u950c\u79bb\u5b50\u6c34\u7cfb\u7535\u6c60\u662f\u7406\u60f3\u7684\u7eff\u8272\u7535\u6c60\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5b58\u5728\u7740\u80fd\u91cf\u5bc6\u5ea6\u6709\u9650\u3001\u81ea\u653e\u7535\u548c\u950c\u8d1f\u6781\u4e0d\u53ef\u63a7\u7684\u679d\u6676\u751f\u957f\u3001\u6790\u6c22\u3001\u949d\u5316\u7b49\u95ee\u9898\u3002\u8fd9\u4e9b\u95ee\u9898\u5927\u5927\u964d\u4f4e\u8d1f\u6781\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u6d3b\u6027\u9020\u6210\u5bb9\u91cf\u8870\u51cf\u3001\u500d\u7387\u6027\u80fd\u964d\u4f4e\uff0c\u9650\u5236\u4e86\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u65b0\u578b\u8d1f\u6781\u7684\u7814\u7a76\u662f\u5b9e\u73b0\u950c\u79bb\u5b50\u7535\u6c60\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u53ca\u53ef\u7a7f\u6234\u8bbe\u5907\u7b49\u9886\u57df\u5b9e\u9645\u5e94\u7528\u7684\u5f53\u52a1\u4e4b\u6025\u3002<\/p>\n<p>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u5c3d\u7ba1\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u56e0\u5b89\u5168\u6027\u9ad8\u3001\u6210\u672c\u4f4e\u7b49\u4f18\u52bf\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u4f46\u950c\u91d1\u5c5e\u8d1f\u6781\u4f4e\u7684\u53ef\u9006\u6027\u4e25\u91cd\u9650\u5236\u4e86\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u3002\u5bf9\u6b64\uff0c\u672c\u5de5\u4f5c\u5728Zn\u8d1f\u6781\u8868\u9762\u539f\u4f4d\u5236\u5907\u4e86\u57fa\u4e8e\u9634\u79bb\u5b50\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6(MOF)\u7684\u4eba\u5de5\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u76f8(ASEI)\u3002\u8be5ASEI\u4fdd\u62a4\u8d1f\u6781\u514d\u53d7\u679d\u6676\u3001HER\u526f\u53cd\u5e94\u7684\u5f71\u54cd\uff0c\u80fd\u5728\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u5176\u5e93\u4ed1\u6548\u7387\u3002\u5e76\u4e14\uff0c\u8be5MOF\u5177\u6709\u9ad8\u7684Zn<sup>2+<\/sup>\u672c\u5f81\u7535\u5bfc\u7387\u548c\u4e30\u5bcc\u7684\u4eb2Zn\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u589e\u5f3aZn\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u3002MOF\u901a\u9053\u4e2d\u8fde\u7eed\u7684\u78fa\u9178\u57fa\u5f15\u5bfc\u4e86Zn<sup>2+<\/sup>\u7684\u5feb\u901f\u5b9a\u5411\u8fd0\u8f93\uff0c\u4ece\u800c\u4f7f\u7535\u6c60\u57282 mA cm<sup>\u2212<\/sup><sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5177\u67095700 h\u7684\u950c\u65e0\u679d\u6676\u6c89\u79ef\/\u5265\u79bb\u5faa\u73af\u5bff\u547d\u3002\u8fd9\u9879\u5de5\u4f5c\u7531\u5317\u4eac\u5927\u5b66\u6f58\u950b\u6559\u6388\u548c\u66a8\u5357\u5927\u5b66\u674e\u5b8f\u5ca9\u6559\u6388\u548c\u738b\u5b50\u5947\u6559\u6388\u5b8c\u6210\uff0c\u4ee5\u9898\u76ee\u4e3a\uff1a\u201cIn Situ Growth of a Metal\u2212Organic Framework-Based Solid Electrolyte Interphase for Highly Reversible Zn Anodes\u201d\uff0c\u53d1\u8868\u5728ACS Eenrgy Lett.\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247786\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-17.png\" alt=\"\" width=\"1592\" height=\"660\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-17.png 1592w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-17-300x124.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-17-768x318.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/0-17-1024x425.png 1024w\" sizes=\"(max-width: 1592px) 100vw, 1592px\" \/><\/p>\n<p>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n<ol>\n<li>\u4f7f\u7528\u590d\u5408\u6750\u6599\u4fee\u9970\uff0c\u540c\u65f6\u6784\u5efa\u8f83\u5c0f\u7684\u6269\u6563\u8def\u5f84\u548c\u5229\u7528\u5316\u5b66\u914d\u4f4d\u524a\u5f31\u950c\u79bb\u5b50\u6c34\u5408\u9798\u5c42\uff0c\u63d0\u9ad8\u4e86\u7535\u6c60\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u5e76\u4f7f\u679d\u6676\u548cHER\u5f97\u5230\u63a7\u5236\u3002<\/li>\n<\/ol>\n<p>\u00a0 \u00a0 \u00a0 2.\u5728\u950c\u8d1f\u6781\u8868\u9762\u5f62\u6210\u4eba\u5de5\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u5c42\u5176\u65b9\u6cd5\u7b80\u5355\u4e14\u6709\u6548\uff0c\u5176ASEI\u662f\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u5c06\u523b\u8680\u540e\u7684\u950c\u7247\u6d78\u6ce1\u5728\u542bMOF\u524d\u9a71\u4f53\u7684\u6eb6\u6db2\u4e2d\u5373\u53ef\u5728\u950c\u8868\u9762\u539f\u4f4d\u5f62\u6210\u3002<\/p>\n<ol start=\"3\">\n<li>ASEI\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u59cb\u7ec8\u4fdd\u6301\u5b8c\u6574\uff0c\u6301\u7eed\u4fdd\u62a4\u950c\u8d1f\u6781\u3002\u6b64\u5916\uff0c\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u6709\u5229\u4e8e\u63d0\u9ad8Zn\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u5e76\u4e14\uff0cASEI \u9634\u79bb\u5b50\u901a\u9053\u4e2d\u8fde\u7eed\u7684\u78fa\u9178\u57fa\u4e5f\u8c03\u8282\u4e86Zn\u7684\u5747\u5300\u6c89\u79ef\u907f\u514d\u4e86\u679d\u6676\u751f\u957f\u3002<\/li>\n<\/ol>\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247787\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-36.png\" alt=\"\" width=\"1413\" height=\"811\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-36.png 1413w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-36-300x172.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-36-768x441.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/1-36-1024x588.png 1024w\" sizes=\"(max-width: 1413px) 100vw, 1413px\" \/><\/p>\n<p>\u56fe1. (a)Zn\u3001E-Zn\u548cZSB@Zn\u7684\u5b9e\u7269\u56fe\u7247\u3002(b) E-Zn\u548c(c) ZSB@Zn\u7684SEM\u56fe\u50cf\u3002(d)\u6a21\u62dfZSB\u3001ZSB\u7c89\u672b\u3001E-Zn\u548cZSB@Zn\u7684XRD\u8c31\u56fe\u3002(e)\u5408\u6210\u7684ZSB\u3001E-Zn\u548cZSB@Zn\u7684FTIR\u3002(f) ZSB\u572830 ~ 100\u2103\u6e29\u5ea6\u4e0b\u7684EIS\u8c31\u56fe\u548c(g)\u76f8\u5e94\u7684\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\u3002\u00a92022 ACS Eenrgy Lett.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247788\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-31.png\" alt=\"\" width=\"1060\" height=\"782\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-31.png 1060w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-31-300x221.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-31-768x567.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/2-31-1024x755.png 1024w\" sizes=\"(max-width: 1060px) 100vw, 1060px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe2. (a)\u626b\u63cf\u901f\u7387\u4e3a0.5 mV s<sup>\u22121<\/sup>\u65f6Zn\u3001ZBB@Zn\u548cZSB@Zn\u8d1f\u6781\u7684CV\u66f2\u7ebf\u548c(b) Tafel\u56fe\u3002(c) \u572850 mV\u4e0b\uff0cZSB@Zn\u5bf9\u79f0\u7535\u6c60\u6781\u5316\u524d\u540e\u7684EIS\u8c31\u56fe\u3002\u63d2\u56fe:\u5bf9\u5e94\u7684\u8ba1\u65f6\u5b89\u57f9\u66f2\u7ebf\u3002(d)\u5bf9\u79f0\u7535\u6c60\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6c89\u79ef\/\u5265\u79bb\u6027\u80fd\u3002(e)\u6700\u8fd1\u62a5\u9053\u7684\u5177\u6709\u529f\u80fd\u754c\u9762\u76f8\u7684Zn\u8d1f\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u6bd4\u8f83\u3002(f)\u88f8\u9732Zn\u3001ZBB@Zn\u548cZSB@Zn\u8d1f\u6781\u7684\u4e0d\u5bf9\u79f0\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5 mA cm<sup>-2<\/sup>\u4e0b\u7684\u5e73\u5747\u5e93\u4ed1\u6548\u7387\u3002(g)\u5bf9\u79f0\u7535\u6c60\u57282mA cm<sup>\u22122<\/sup>\u4e0b\u7684\u950c\u6c89\u79ef\/\u5265\u79bb\u6027\u80fd\u3002\u00a92022 ACS Eenrgy Lett.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247789\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-29.png\" alt=\"\" width=\"811\" height=\"682\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-29.png 811w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-29-300x252.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/3-29-768x646.png 768w\" sizes=\"(max-width: 811px) 100vw, 811px\" \/><\/p>\n<p>\u56fe3. (a)\u572810 mA cm<sup>\u22122<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cZSB@Zn(\u4e0a)\u548c\u88f8\u950c(\u4e0b)\u8d1f\u6781\u4e0a\u950c\u6c89\u79ef\u7684\u5149\u5b66\u7167\u7247\u3002(b) ZSB@Zn\u548c(c)\u88f8Zn\u572810 mA cm<sup>\u22122<\/sup>\u6761\u4ef6\u4e0b\u6c89\u79ef10\u5206\u949f\u540e\u7684\u8d1f\u6781\u7684SEM\u622a\u9762\u56fe\u3002(d)\u3001(e)\u548c(f)\u5206\u522b\u4e3aZSB@Zn\u8d1f\u6781\u572810 mA cm<sup>-2<\/sup>\u6761\u4ef6\u4e0b\u6c89\u79ef5\u300110\u300115\u5206\u949f\u7684SEM\u56fe\u50cf\u3002(g)\u3001(h)\u548c(i)\u5206\u522b\u4e3a\u88f8Zn\u8d1f\u6781\u572810 mA cm<sup>-2<\/sup>\u6761\u4ef6\u4e0b\u6c89\u79ef5\u300110\u300115\u5206\u949f\u7684SEM\u56fe\u50cf\u3002\u00a92022 ACS Eenrgy Lett.<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247790\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-28.png\" alt=\"\" width=\"896\" height=\"766\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-28.png 896w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-28-300x256.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/4-28-768x657.png 768w\" sizes=\"(max-width: 896px) 100vw, 896px\" \/><\/p>\n<p>\u56fe4. (a)\u88f8Zn\u548cZSB@Zn\u8d1f\u6781\u5728\u6c89\u79ef\/\u5265\u79bb\u5faa\u73af\u524d\u540e\u7684Zn 2p<sub>3 \/2<\/sub>(\u5de6)\u548cO 1s(\u53f3)XPS\u5cf0\u3002c-Zn<sup>2+<\/sup>\u4e3aZSB\u4e2d\u7684Zn<sup>2+<\/sup>\u53cd\u79bb\u5b50;ad-O\u8868\u793a\u5438\u9644\u6c27\u3002(b)\u8ba1\u7b97\u5f97\u5230\u7684Zn<sup>2+<\/sup>\u6cbfZSB\u9634\u79bb\u5b50\u901a\u9053\u8fc1\u79fb\u8def\u5f84\u7684\u80fd\u91cf\u5206\u5e03\u3002(c) ZSB@Zn\u754c\u9762\u76f8\u7535\u8377\u5bc6\u5ea6\u5dee\u5206\u5e03(\u5de6)\u548c\u76f8\u5e94\u7684\u4e8c\u7ef4\u7b49\u9ad8\u7ebf\u5207\u9762\u56fe(\u53f3)\u3002\u5916\u6765Zn<sup>2+<\/sup>\u5728(d) ZSB ASEI\u548c(e) Zn(002)\u8868\u9762\u5438\u6536\u4f4d\u70b9\u7684\u7ed3\u5408\u80fd\u3002\u00a92022 ACS Eenrgy Lett.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247791\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/5-22.png\" alt=\"\" width=\"1170\" height=\"753\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/5-22.png 1170w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/5-22-300x193.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/5-22-768x494.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/02\/5-22-1024x659.png 1024w\" sizes=\"(max-width: 1170px) 100vw, 1170px\" \/><\/p>\n<p style=\"text-align: left;\">\u56fe5. (a)\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u88f8\u9732Zn(\u4e0a)\u3001ZBB@Zn(\u4e2d)\u548cZSB@Zn(\u4e0b)\u8d1f\u6781\u7684NVO\u5168\u7535\u6c60CV\u5206\u5e03\u56fe\u3002(b)\u88f8\u9732Zn\u3001ZBB@Zn\u548cZSB@Zn\u8d1f\u6781\u7684NVO\u5168\u7535\u6c60\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u80fd\u529b\u548c\u76f8\u5e94\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(d) 5 A g<sup>\u22121<\/sup>\u65f6\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002(e)\u9759\u7f6e10\u5c0f\u65f6\u540e\uff0cZSB@Zn|NVO\u7535\u6c60\u57285 A g<sup>\u22121<\/sup>\u7684\u81ea\u653e\u7535\u3002\u00a92022 ACS Eenrgy Lett.<\/p>\n<p>\u4e94\u3001\u6210\u679c\u542f\u793a<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u6210\u529f\u5730\u5728Zn\u7247\u8d1f\u6781\u4e0a\u539f\u4f4d\u6784\u5efa\u4e86\u9634\u79bb\u5b50MOF \u4eba\u5de5\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u76f8\uff08ASEI\uff09\u3002\u901a\u8fc7\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\uff0c\u575a\u56fa\u7684ASEI\u5c42\u7d27\u5bc6\u5730\u7c98\u9644\u5728Zn\u91d1\u5c5e\u8868\u9762\uff0c\u786e\u4fdd\u4e86\u7535\u6c60\u8fd0\u884c\u671f\u95f4\u7684\u826f\u597d\u53ef\u9760\u6027\u3002\u5b83\u5177\u6709\u8f83\u9ad8\u7684\u672c\u5f81Zn<sup>2+<\/sup>\u7535\u5bfc\u7387\uff0c\u901a\u9053\u4e2d\u4e30\u5bcc\u7684\u78fa\u9178\u57fa\u6709\u52a9\u4e8eZn<sup>2+<\/sup>\u5b9a\u5411\u5feb\u901f\u8f93\u8fd0\u3002\u6b64\u5916\uff0c\u5728ASEI\u7684\u4fdd\u62a4\u4e0b\uff0cZSB@Zn\u8d1f\u6781\u5bf9HER\u8868\u73b0\u51fa\u589e\u5f3a\u7684\u7a33\u5b9a\u6027\uff0c\u51cf\u8f7b\u4e86\u6574\u4e2a\u7535\u6c60\u7684\u81ea\u653e\u7535\uff0c\u964d\u4f4e\u7535\u6c60\u7684\u526f\u53cd\u5e94\u3002ZSB ASEI\u4e2d\u5bccZn<sup>2+<\/sup>\u73af\u5883\u53ca\u4eb2\u950c\u4f4d\u70b9\u4fc3\u8fdb\u4e86\u8d1f\u6781\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u6709\u6548\u5730\u63d0\u9ad8\u4e86\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u3002\u540c\u65f6\uff0cASEI\u9634\u79bb\u5b50\u901a\u9053\u4e2d\u8fde\u7eed\u7684\u78fa\u9178\u57fa\u4e5f\u8c03\u8282\u4e86Zn\u7684\u5747\u5300\u6c89\u79ef\u3002\u4ee5\u4e0a\u7ed3\u8bba\u901a\u8fc7\u5b9e\u9a8c\u8868\u5f81\u5e76\u7ed3\u5408DFT\u8ba1\u7b97\u5f97\u5230\u4e86\u9a8c\u8bc1\u3002\u53e6\u5916\uff0cZSB@Zn\u7535\u6c60\u5177\u6709\u8d85\u8fc75700\u5c0f\u65f6\u7684\u957f\u6c89\u79ef\/\u5265\u79bb\u5faa\u73af\u5bff\u547d\u3002\u5f00\u53d1\u7684ZSB@Zn\u8d1f\u6781\u8fdb\u4e00\u6b65\u4f7fNVO\u5168\u7535\u6c60\u5177\u6709\u9ad8\u5bb9\u91cf\uff0c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8fdc\u8fdc\u4f18\u4e8e\u88f8\u950c\u8d1f\u6781\u3002\u8fd9\u4e2a\u7b80\u5355\u800c\u6709\u6548\u7684\u7b56\u7565\u5728\u91d1\u5c5e\u8d1f\u6781\u4e0a\u6784\u9020\u4e00\u4e2aMOF ASEI\u5c42\uff0c\u6253\u5f00\u4e86\u4e00\u4e2a\u5411\u5b9e\u7528\u7684\u5148\u8fdb\u50a8\u80fd\u7cfb\u7edf\u8fc8\u8fdb\u7684\u65b0\u8def\u7ebf\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/acsenergylett.2c01958<\/p>\n<p>\u672c\u6587\u7531\u91d1\u7235\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; 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