{"id":247835,"date":"2023-03-13T06:16:28","date_gmt":"2023-03-12T22:16:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=247835"},"modified":"2023-03-10T14:26:39","modified_gmt":"2023-03-10T06:26:39","slug":"%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6acs-energy-lett-%e6%88%90%e5%88%86%e5%8f%af%e8%b0%83%e7%9a%84co3-xfexmo3n%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e%e6%9e%90%e6%b0%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=247835","title":{"rendered":"\u534e\u5357\u7406\u5de5\u5927\u5b66ACS Energy Lett: \u6210\u5206\u53ef\u8c03\u7684Co3-xFexMo3N\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6790\u6c27\u53cd\u5e94"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

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\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u5d14\u5fd7\u660e\u6559\u6388\u56e2\u961f\u6210\u529f\u5f00\u53d1\u4e86\u4e00\u79cd\u5177\u6709\u03b7-\u78b3\u5316\u7269\u578b\u7ed3\u6784\u7684\u65b0\u578bCo3-x<\/sub>Fex<\/sub>Mo3<\/sub>N (0\u2264x\u22643)\u7535\u50ac\u5316\u5242\u3002\u8be5\u50ac\u5316\u5242\u5177\u6709\u826f\u597d\u7684\u7ec4\u6210\u7075\u6d3b\u53ef\u8c03\u6027\uff0c\u53ef\u4f5c\u4e3a\u9ad8\u6548\u3001\u8010\u7528\u7684OER\u7535\u50ac\u5316\u5242\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cComposition-Tunable Co3\u2013xFexMo3N Electrocatalysts for the Oxygen Evolution Reaction<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728ACS Energy Letters<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n

1<\/strong>\u3001\u4f5c\u8005\u5229\u7528\u7ec4\u5206\u53ef\u8c03\u63a7\u6027\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u3001\u8010\u7528\u7684Co3-x<\/sub>Fex<\/sub>Mo3<\/sub>N (0\u2264x\u22643)<\/strong>\u6c2e\u5316\u7269\u7535\u50ac\u5316\u5242\u3002<\/strong>\u4f18\u5316\u540e\u7684<\/strong>Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N<\/strong>\u5728<\/strong>10 mA cmgeo<\/sub>-2<\/sup><\/strong>\u4e0b\u7684\u8fc7\u7535\u4f4d\u4ec5\u4e3a<\/strong>218 mV<\/strong>\uff0c\u5728<\/strong>100 mA cmgeo<\/sub>-2<\/sup><\/strong>\u4e0b\u5177\u6709\u8d85\u8fc7<\/strong>90 h<\/strong>\u7684\u7a33\u5b9a\u8010\u7528\u6027\u3002<\/strong><\/p>\n

2<\/strong>\u3001\u7ed3\u5408<\/strong>XPS<\/strong>\u548c<\/strong>DFT<\/strong>\u8ba1\u7b97\u53d1\u73b0\uff0c<\/strong>Fe<\/strong>\u53d6\u4ee3\u90e8\u5206<\/strong>Co<\/strong>\u4f4d\u70b9\u4e0d\u4ec5\u589e\u52a0\u4e86<\/strong>Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N<\/strong>\u8868\u9762\u6d3b\u6027\u7ec4\u5206\u7684\u542b\u91cf\uff0c\u540c\u65f6\u5bfc\u81f4<\/strong>Co<\/strong>\u4f4d\u70b9\u7684<\/strong>d<\/strong>\u5e26\u4e2d\u5fc3\u5411\u8d39\u7c73\u80fd\u7ea7\u4e0a\u79fb\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u6c27\u4e2d\u95f4\u4f53\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u4e86\u901f\u7387\u51b3\u5b9a\u6b65\u9aa4\u7684\u80fd\u5792\u3002<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong> (a) Co3\u2013\u00a0x<\/sub>Fex<\/sub>Mo3<\/sub>N\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u3002(b) Co3\u2013\u00a0x<\/sub>Fex<\/sub>Mo3<\/sub>N (0 \u2264\u00a0x\u00a0\u2264 3)\u7684Co\u4f4d\u70b9\u7684\u90e8\u5206\u53d6\u4ee3\u65b9\u6848.\u00a0(c) Co3<\/sub>Mo3<\/sub>N\u3001Fe3<\/sub>Mo3<\/sub>N\u3001Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u548c\u76f8\u5e94\u7684\u6c27\u5316\u7269\u4e4b\u95f4\u7535\u5b50\u7535\u5bfc\u7387\u7684\u6bd4\u8f83\u3002(d, e) Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u7684TEM\u56fe\u50cf\u3002\u00a9\u00a0 2023 ACS publication<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong> (a) Co3\u2013\u00a0x<\/sub>Fex<\/sub>Mo3<\/sub>N\u548c\u5546\u4e1aIrO2<\/sub>\u5728O2<\/sub>\u9971\u548c1.0 M KOH\u6eb6\u6db2\u4e2d\u4ee51 mV s-1\u626b\u63cf\u901f\u7387\u6d4b\u91cf\u7684LSV\u548c(b) Tafel\u56fe\u3002(c) Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u3001Co3<\/sub>Mo3<\/sub>N\u548cIrO2<\/sub>\u572810 mA cm-2<\/sup>\u548c100 mA cm-2<\/sup>\u5904\u7684\u8fc7\u7535\u4f4d\u4ee5\u53caTafel\u659c\u7387\u7684\u6bd4\u8f83\u3002(d) Co3<\/sub>Mo3<\/sub>N\u548cCo2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u7ecfECSA\u5f52\u4e00\u5316\u540e\u7684LSV\u66f2\u7ebf\u3002(e) OER\u7535\u50ac\u5316\u5242\u7684\u6bd4\u8f83\u3002(f) Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u5728100mA cmgeo<\/sub>-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002 \u00a9 2023 ACS publication<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>(a)\u53cc\u7535\u6781\u7cfb\u7edf\u7684\u7167\u7247\uff0c\u5206\u522b\u5728\u9634\u6781\u548c\u9633\u6781\u4ea7\u751fH2<\/sub>\u548cO2<\/sub>\u6c14\u6ce1\u3002(b) Pt\/C\u2225Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u548cPt\/C\u2225IrO2<\/sub>\u6574\u4f53\u6c34\u5206\u89e3\u6781\u5316\u66f2\u7ebf\u3002(c)\u7535\u6d41\u5bc6\u5ea6\u4e3a100mA cmgeo<\/sub>-2<\/sup>\u65f6Pt\/C\u2225Co2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u548cPt\/C\u2225IrO2<\/sub>\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002\u00a9 2023 ACS publication<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> (a, b) OER\u540eCo2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u7684TEM\u56fe\u50cf\u3002(c) OER\u540eCo2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u7684Co 2p XPS \u5149\u8c31\u3002(d) OER\u540eCo2.5<\/sub>Fe0.5<\/sub>Mo3<\/sub>N\u7684O 1s XPS\u5149\u8c31\u3002(e, f)\u00a0OER\u540eCo3<\/sub>Mo3<\/sub>N\u7684TEM\u56fe\u50cf\u3002(g) OER\u540eCo3<\/sub>Mo3<\/sub>N\u7684Co 2p XPS \u5149\u8c31\u3002(h)\u00a0OER\u540eCo3<\/sub>Mo3<\/sub>N\u7684O 1s XPS\u5149\u8c31\u3002\u00a9 2023 ACS publication<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5<\/strong> (a) CoFeMoOOH\u8868\u9762\u7684OER \u673a\u5236\u793a\u610f\u56fe\u3002(b) CoFeMoOOH \u548c CoMoOOH \u8868\u9762Co\u4f4d\u70b9OER\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\u3002(c) CoFeMoOOH \u548c CoMoOOH \u8868\u9762\u4e0a Co\u4f4d\u70b9\u7684OH\u5438\u6536\u80fd\u3002(d) CoFeMoOOH \u548c CoMoOOH \u8868\u9762\u7684 Co 3d \u5e26\u7684 PDOS\u503c\u3002\u00a9 2023 ACS publication<\/strong><\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5145\u5206\u5229\u7528\u7ec4\u6210\u7075\u6d3b\u6027\uff0c\u5f00\u53d1\u4e00\u79cd\u5177\u6709\u03b7-\u78b3\u5316\u7269\u578b\u7684Co3-x<\/sub>Fex<\/sub>Mo3<\/sub>N (0\u2264x\u22643)\u7535\u50ac\u5316\u5242\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u79cd\u6784\u578b\u7684\u50ac\u5316\u5242\u5177\u6709\u9ad8\u6548OER\u6027\u80fd\u548c\u8010\u7528\u7a33\u5b9a\u6027\uff0c\u6709\u671b\u6210\u4e3a\u66ff\u4ee3\u76ee\u524d\u5546\u7528\u8d35\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u53e6\u5916\uff0c\u8fd9\u9879\u7814\u7a76\u4e3a\u901a\u8fc7\u8c03\u6574\u4e09\u5143\u91d1\u5c5e\u95f4\u6c2e\u5316\u7269\u7684\u7ec4\u6210\u6765\u4f18\u5316\u5176\u7535\u50ac\u5316\u6027\u80fd\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u6761\u6709\u6548\u7684\u7b56\u7565\u3002<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<\/strong>https:\/\/doi.org\/10.1021\/acsenergylett.3c00048<\/a><\/p>\n

\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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