{"id":248732,"date":"2023-04-04T05:56:17","date_gmt":"2023-04-03T21:56:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=248732"},"modified":"2023-04-03T10:56:44","modified_gmt":"2023-04-03T02:56:44","slug":"nat-chem-%ef%bc%9a%e6%94%b9%e5%8f%98%e6%9c%89%e6%9c%ba%e9%94%82%e5%91%bd%e8%bf%90%e7%9a%84%e5%87%9d%e8%83%b6%e8%bd%bd%e4%bd%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=248732","title":{"rendered":"Nat. Chem.\uff1a\u6539\u53d8\u6709\u673a\u9502\u201c\u547d\u8fd0\u201d\u7684\u51dd\u80f6\u8f7d\u4f53"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><b>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>\u6709\u673a\u9502\u8bd5\u5242\uff08Organolithium reagents\uff09\u662f\u91d1\u5c5e\u6709\u673a\u5316\u5408\u7269\u4e2d\u8f83\u4e3a\u91cd\u8981\u7684\u4e00\u7c7b\u5316\u5408\u7269\uff0c\u4e00\u822c\u5177\u6709\u53cd\u5e94\u6d3b\u6027\u66f4\u5f3a\u3001\u4ea7\u7387\u9ad8\u3001\u8fd8\u539f\u503e\u5411\u8f83\u5c0f\u3001\u4ea7\u7269\u5bb9\u6613\u5206\u79bb\u3001\u80fd\u591f\u6eb6\u4e8e\u591a\u79cd\u975e\u6781\u6027\u6eb6\u5242\u7b49\u7279\u70b9\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u5f53\u4e2d\u3002\u7136\u800c\uff0c\u6709\u673a\u9502\u8bd5\u5242\u9700\u8981\u5728\u4f4e\u6e29\u53ca\u60f0\u6027\u6761\u4ef6\u4e0b\u50a8\u5b58\u548c\u53d6\u7528\uff0c\u5e76\u4e14\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u6613\u71c3\uff0c\u8fd9\u4e9b\u95ee\u9898\u4e3a\u6709\u673a\u9502\u5316\u5b66\u5728\u5de5\u4e1a\u4e2d\u7684\u4f7f\u7528\u5e26\u6765\u4e86\u989d\u5916\u7684\u6210\u672c\u548c\u5b89\u5168\u9690\u60a3\uff0c\u4e5f\u9650\u5236\u4e86\u975e\u4e13\u4e1a\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u4e2a\u7a33\u5b9a\u3001\u6613\u4f7f\u7528\u7684\u9502\u8bd5\u5242\u5c31\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n<p style=\"text-align: center;\"><strong><b>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u82f1\u56fd\u7ea6\u514b\u5927\u5b66David K. Smith\/Peter O\u2019Brien\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5728\u4f4e\u6210\u672c\u4e09\u5341\u516d\u78b3\u70f7\uff08C<sub>36<\/sub>H<sub>74<\/sub>\uff09\u6709\u673a\u51dd\u80f6\u4e2d\u5c01\u88c5\u7a33\u5b9a\u654f\u611f\u6709\u673a\u9502\u8bd5\u5242\u7684\u65b9\u6cd5\u3002\u8be5\u51dd\u80f6\u7684\u6709\u673a\u9502\u5728\u7a7a\u6c14\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4eb2\u6838\u52a0\u6210\u53cd\u5e94\u3001\u4f4e\u6e29\u6eb4-\u9502\u4ea4\u6362\u3001\u90bb\u4f4d\u9502\u5316\u548cC-H\u5b98\u80fd\u5316\u53cd\u5e94\u3002\u8be5\u51dd\u80f6\u663e\u8457\u589e\u5f3a\u4e86\u6709\u673a\u9502\u7684\u7a33\u5b9a\u6027\uff0c\u65b9\u4fbf\u6709\u673a\u9502\u7684\u50a8\u5b58\u3001\u5904\u7406\u548c\u9012\u9001\uff0c\u5e76\u4e14\u80fd\u591f\u8fdb\u884c\u53ef\u91cd\u590d\u7684\u8bd5\u5242\u5206\u914d\uff0c\u5f7b\u5e95\u6539\u53d8\u4e86\u6709\u673a\u9502\u8bd5\u5242\u7684\u201c\u547d\u8fd0\u201d\u3002\u8be5\u6587\u7ae0\u4ee5\u201cOrganogel delivery vehicles for the stabilization of organolithium 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wp-image-248736 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-14.png\" alt=\"\" width=\"1026\" height=\"454\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-14.png 1026w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-14-300x133.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-14-768x340.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-14-1024x453.png 1024w\" sizes=\"(max-width: 1026px) 100vw, 1026px\" 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http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-15-768x375.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-15-1024x500.png 1024w\" sizes=\"(max-width: 1040px) 100vw, 1040px\" 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-248738 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-16.png\" alt=\"\" width=\"1036\" height=\"545\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-16.png 1036w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-16-300x158.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-16-768x404.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-16-1024x539.png 1024w\" sizes=\"(max-width: 1036px) 100vw, 1036px\" \/><\/p>\n<p>\u56fe3\uff1a\u542bPhLi\u548cn-BuLi\u51dd\u80f6\u5757\u7684\u5f62\u6210\u3001\u7a33\u5b9a\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u3002a\uff0cPhLi\u51dd\u80f6\u5757\u7684\u5f62\u6210\uff1a(i)\u4e00\u4e2a\u70e4\u7bb1\u5e72\u71e5\u7684\u5c0f\u74f6\uff0c\u542b\u6709PhLi\uff0cBu<sub>2<\/sub>O\uff0cC<sub>36<\/sub>H<sub>74<\/sub>(16.7% 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wt\/vol\u7684C<sub>36<\/sub>H<sub>74<\/sub>\u51dd\u80f6\u5242\u5f62\u6210PhLi\u51dd\u80f6\u5757\u3002<sup>e<\/sup>\u8272\u8c31\u7eaf\u5316\u540e\u7684\u4ea7\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-248739 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-12.png\" alt=\"\" width=\"1033\" height=\"729\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-12.png 1033w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-12-300x212.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-12-768x542.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-12-1024x723.png 1024w\" sizes=\"(max-width: 1033px) 100vw, 1033px\" 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g\u90bb\u7532\u82ef\u6d77\u660e<strong><b>14<\/b><\/strong>\u3002c\uff0c\u4f7f\u7528n-BuLi\u51dd\u80f6\u5757\u8fdb\u884c\u6eb4-\u9502\u4ea4\u6362\uff0c\u5e76\u5c06\u6709\u673a\u9502\u6dfb\u52a0\u5230\u919b\u4e2d\u751f\u6210<strong><b>17<\/b><\/strong>\u3002d\uff0cWittig\u53cd\u5e94\u751f\u6210<strong><b>19<\/b><\/strong>\uff0c\u4f7f\u7528n-BuLi\u51dd\u80f6\u5757\u751f\u6210\u5185\u9393\u76d0\uff08ylid\uff09\u3002e\uff0c\u7528n-BuLi\u51dd\u80f6\u5757\u5236\u5907LDA<strong><b>21<\/b><\/strong>\u53ca\u5176\u5728\u70ef\u9178\u916f\u03b1-\u70f7\u57fa\u5316\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u3002f\uff0c\u03b1-C-H\u952e\u4e8c\u529f\u80fd\u5316\u5421\u54af\u70f7\u7684PhLi\u51dd\u80f6\u548cn-BuLi\u51dd\u80f6\u5757\u5f97\u5230<strong><b>28<\/b><\/strong>\u3002g\uff0cs-BuLi\u51dd\u80f6\u4e0e\u916e\u548c\u4e9a\u80fa\u7684\u4eb2\u6838\u52a0\u6210\u53cd\u5e94\u5206\u522b\u5f97\u5230<strong><b>29<\/b><\/strong>\u548c<strong><b>30<\/b><\/strong>\u3002h\uff0c\u7528n-BuLi\/TMEDA\u51dd\u80f6\u5bf9\u7532\u6c27\u57fa\u82ef\u8fdb\u884c\u6b63\u4f4d\u9502\u5316\uff0c\u7136\u540e\u7528\u4e09\u7532\u57fa\u7845\u9170\u6c2f\u6355\u83b7\uff0c\u5f97\u5230<strong><b>32<\/b><\/strong>\u3002i\uff0c\u4e59\u70ef\u57faMgBr\u51dd\u80f6\u4e0e\u916e\u7684\u4eb2\u6838\u52a0\u6210\u53cd\u5e94\uff0c\u5f97\u5230<strong><b>33<\/b><\/strong>\u3002<sup>a<\/sup>\u4ee5\u4e8c\u7532\u57fa\u7532\u9170\u80fa(DMF)\u4e3a\u5916\u90e8\u6807\u51c6\uff0c\u8f6c\u6362\u7531<sup>1<\/sup>H NMR\u6ce2\u8c31\u786e\u5b9a\u3002<sup>b<\/sup>\u5c42\u6790\u7eaf\u5316\u540e\u4ea7\u7387\u3002<sup>c<\/sup>\u00a0VinylMgBr\u51dd\u80f6\u5728\u53cd\u5e94\u524d\u4e8e\u7a7a\u6c14\u4e2d\u66b4\u97325\u5206\u949f\uff1b\u8f6c\u6362\u7528<sup>1<\/sup>H NMR\u6ce2\u8c31\u4f7f\u7528\u4ea7\u7269\u548c\u8d77\u59cb\u6750\u6599\u4e2d\u5173\u952e\u4fe1\u53f7\u7684\u76f8\u5bf9\u79ef\u5206\u786e\u5b9a\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/b><\/strong><\/p>\n<p>\u672c\u7814\u7a76\u6210\u529f\u5c06\u654f\u611f\u7684\u6709\u673a\u9502\u8bd5\u5242\u5982PhLi\uff0cn-BuLi\u548cs-BuLi\u53ef\u4ee5\u6210\u529f\u5730\u5c01\u88c5\u5165\u4f4e\u6210\u672cC<sub>36<\/sub>H<sub>74<\/sub>\u6709\u673a\u51dd\u80f6\u8f7d\u4f53\u4e2d\u3002\u8fd9\u4e9b\u6709\u673a\u9502\u51dd\u80f6\u7f51\u7edc\u5177\u6709\u76f8\u5bf9\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u4f7f\u7528\uff0c\u5177\u6709\u6eb6\u5242\u76f8\u5bb9\u6027\u3001\u5236\u9020\u7b80\u5355\u548c\u80fd\u901a\u8fc7\u51dd\u80f6\u5747\u5300\u5206\u5e03\u8bd5\u5242\u4ee5\u5b9e\u73b0\u6709\u6548\u7684\u7ec6\u5206\u548c\u51c6\u786e\u7684\u53cd\u5e94\u5242\u91cf\u7b49\u4f18\u70b9\u3002\u4f7f\u7528\u51dd\u80f6\u4f5c\u4e3a\u5371\u9669\u6709\u673a\u91d1\u5c5e\u7684\u8fd0\u8f7d\u5de5\u5177\uff0c\u80fd\u4f7f\u5176\u66f4\u5bb9\u6613\u83b7\u5f97\u5e76\u4e14\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u66f4\u4e3a\u5b89\u5168\uff0c\u9884\u8ba1\u8fd9\u79cd\u7b80\u5355\u7684\u51dd\u80f6\u4ecb\u5bfc\u7684\u8bd5\u5242\u7a33\u5b9a\u65b9\u6cd5\u53ef\u4ee5\u5e94\u7528\u4e8e\u5176\u4ed6\u5bf9\u6c34\u5206\u548c\u7a7a\u6c14\u654f\u611f\u7684\u8bd5\u5242\uff0c\u4e3a\u5b89\u5168\u4f7f\u7528\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1aSlav\u00edk, P., Trowse, B.R., O\u2019Brien, P. et al. Organogel delivery vehicles for the stabilization of organolithium reagents. <em><i>Nat. Chem.<\/i><\/em>\u00a015, 319\u2013325 (2023). https:\/\/doi.org\/10.1038\/s41557-023-01136-x<\/p>\n<p>\u672c\u6587\u7531\u714e\u86cb\u767d\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u6709\u673a\u9502\u8bd5\u5242\uff08Organolithium reagents\uff09\u662f\u91d1\u5c5e\u6709\u673a\u5316\u5408\u7269\u4e2d\u8f83\u4e3a\u91cd\u8981\u7684\u4e00\u7c7b\u5316\u5408\u7269\uff0c\u4e00\u822c\u5177\u6709\u53cd\u5e94\u6d3b\u6027\u66f4\u5f3a\u3001\u4ea7\u7387\u9ad8\u3001\u8fd8\u539f\u503e\u5411\u8f83\u5c0f\u3001\u4ea7\u7269&#8230;<\/p>\n","protected":false},"author":39059,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2,67],"tags":[4128,5023],"class_list":["post-248732","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","category-zhoubao","tag-4128","tag-5023"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/248732"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/39059"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=248732"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/248732\/revisions"}],"predecessor-version":[{"id":249455,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/248732\/revisions\/249455"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=248732"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=248732"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=248732"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}