{"id":248752,"date":"2023-04-03T05:46:10","date_gmt":"2023-04-02T21:46:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=248752"},"modified":"2023-03-31T15:46:22","modified_gmt":"2023-03-31T07:46:22","slug":"nature-catalysis%ef%bc%9a%e7%94%b5%e5%82%ac%e5%8c%96%e5%ae%9e%e7%8e%b0%e5%8f%8c%e6%9e%81%e5%8a%a0%e6%b0%a2%ef%bc%8c%e6%b3%95%e6%8b%89%e7%ac%ac%e6%95%88%e7%8e%87%e6%8e%a5%e8%bf%91200","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=248752","title":{"rendered":"Nature Catalysis\uff1a\u7535\u50ac\u5316\u5b9e\u73b0\u201c\u53cc\u6781\u52a0\u6c22\u201d\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u63a5\u8fd1200%"},"content":{"rendered":"<p>\u5f20\u7199\u7199<\/p>\n<p><strong>\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011\u00a0 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H<sup>*<\/sup>\u901a\u8fc7Pd\u819c\u9633\u6781\u6269\u6563\uff0c\u5728\u4e0e\u7535\u5316\u5b66\u7535\u6c60\u7a7a\u95f4\u5206\u79bb\u7684\u8154\u5ba4\u4e2d\u9a71\u52a8\u53e6\u4e00\u4fa7\u7684\u52a0\u6c22\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u5f53\u4e24\u4e2aPd\u819c\u7535\u6781\u5206\u522b\u4f5c\u4e3a\u9633\u6781\u548c\u9634\u6781\uff0c\u5728\u9633\u6781\u6db2\u548c\u9634\u6781\u6db2\u4e2d\u5206\u522b\u4ee5\u7532\u919b\u548c\u6c34\u4f5c\u4e3a\u8d28\u5b50\u6e90\u65f6\uff0c\u56db\u5ba4\u7ec4\u4ef6\u53ef\u5728\u7535\u5316\u5b66\u7535\u6c60\u5916\u7684\u8154\u5ba4\u4e2d\u5b9e\u73b0\u540c\u4e00\u6709\u673a\u5e95\u7269\u7684\u7535\u50ac\u5316\u53cc\u52a0\u6c22\uff0c\u7406\u8bba\u6700\u5927\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a200%(\u5373\u4e00\u4e2a\u7535\u5b50\u901a\u8fc7\u4ea7\u751f\u4e24\u4e2aH<sup>*<\/sup>)\u3002\u7531\u4e8e\u7532\u919b\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u53d1\u751f\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u540e\u5177\u6709\u826f\u597d\u7684\u6c27\u5316\u5f62\u6210\u70ed\u529b\u5b66\u52bf(E =-0.22 V\u76f8\u5bf9\u4e8e\u53ef\u9006\u6c22\u7535\u6781(RHE))\uff0c\u8fd9\u4e2a\u56db\u5ba4\u7ec4\u4ef6\u7684\u8bbe\u8ba1\u5728\u4f4e\u81f30.4V\u7684\u542f\u52a8\u8f93\u5165\u7535\u538b\u4e0b\u9a71\u52a8\u9a6c\u6765\u9178\u9150\u53cc\u91cd\u6c22\u5316\u4ee5\u4ea7\u751f\u6709\u4ef7\u503c\u7684\u5316\u5b66\u539f\u6599\u7425\u73c0\u9178\u3002<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201c<strong>Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<em>Nature<\/em> <em>Catalysis<\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248753\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-16.png\" alt=\"\" width=\"964\" height=\"575\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-16.png 964w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-16-300x179.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/1-16-768x458.png 768w\" sizes=\"(max-width: 964px) 100vw, 964px\" \/><\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u4f5c\u8005\u901a\u8fc7\u5229\u7528\u5c55\u793a\u7532\u919b\u5728Pt\u819c\u9633\u6781\u4e0a\u7684\u4f4e\u7535\u4f4d\u6c27\u5316\u4ea7\u751f\u7684H<sup>*<\/sup>\u6e17\u900f\u5230\u819c\u7535\u6781\u4e0a\uff0c\u8bc1\u660e\u4e86\u5f53\u53e6\u4e00\u4e2aPt\u819c\u7535\u6781\u88ab\u7528\u4f5c\u9634\u6781\u65f6\uff0c\u4e0d\u9971\u548c\u4e8c\u7fa7\u9178\u7684\u7535\u50ac\u5316\u53cc\u52a0\u6c22\u662f\u53ef\u80fd\u7684\u3002\u8fd9\u6837\u7684\u8bbe\u8ba1\u53ef\u4ee5\u5b9e\u73b0\u540c\u4e00\u5e95\u7269\u5728\u4e0e\u7535\u5316\u5b66\u7535\u6c60\u8154\u5206\u79bb\u7684\u4e24\u4e2a\u72ec\u7acb\u7684\u9633\u6781\u548c\u9634\u6781\u5ba4\u7684\u7535\u50ac\u5316\u52a0\u6c22\uff0c\u7406\u8bba\u6700\u5927\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a200%\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011 <\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248754\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-17.png\" alt=\"\" width=\"861\" height=\"765\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-17.png 861w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-17-300x267.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/2-17-768x682.png 768w\" sizes=\"(max-width: 861px) 100vw, 861px\" \/><\/strong><\/p>\n<p><strong>\u56fe1 \u4e09\u79cd\u4e0d\u540c\u7684\u7535\u50ac\u5316\u52a0\u6c22\u8bbe\u8ba1\u793a\u610f\u56fe\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248755\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-18.png\" alt=\"\" width=\"1012\" height=\"863\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-18.png 1012w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-18-300x256.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/3-18-768x655.png 768w\" sizes=\"(max-width: 1012px) 100vw, 1012px\" \/><\/strong><\/p>\n<p><strong>\u56fe2 Pd\u7535\u6781\u7535\u50ac\u5316\u4ea7\u6c22\u548c\u5438\u6536\u7684\u6bd4\u8f83\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248756\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-14.png\" alt=\"\" width=\"802\" height=\"831\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-14.png 802w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-14-290x300.png 290w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/4-14-768x796.png 768w\" sizes=\"(max-width: 802px) 100vw, 802px\" \/>\u56fe3 \u9a6c\u6765\u9178\u7535\u50ac\u5316\u53cc\u52a0\u6c22\u53cd\u5e94\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248757\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/5-6.png\" alt=\"\" width=\"653\" height=\"778\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/5-6.png 653w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/5-6-252x300.png 252w\" sizes=\"(max-width: 653px) 100vw, 653px\" \/><\/p>\n<p><strong>\u56fe4\u5404\u79cd\u6761\u4ef6\u4e0b\u7535\u50ac\u5316\u53cc\u52a0\u6c22\u53cd\u5e94\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248758\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/6-3.png\" alt=\"\" width=\"934\" height=\"787\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/6-3.png 934w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/6-3-300x253.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/6-3-768x647.png 768w\" sizes=\"(max-width: 934px) 100vw, 934px\" \/>\u56fe5 \u7535\u50ac\u5316\u53cc\u52a0\u6c22\u7684\u901a\u7528\u6027\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248759\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/7-1.png\" alt=\"\" width=\"779\" height=\"869\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/7-1.png 779w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/7-1-269x300.png 269w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/7-1-768x857.png 768w\" sizes=\"(max-width: 779px) 100vw, 779px\" \/>\u56fe6 \u6c22\u6e90\u7814\u7a76\u3002\u00a9 2023 Springer Nature Limited<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u8bc1\u660e\u4e86\u7532\u919b\u5728Pd\u819c\u9633\u6781\u4e0a\u7684\u4f4e\u7535\u4f4d\u6c27\u5316\u53ef\u4ee5\u4ea7\u751f\u6d3b\u6027\u6c22\u539f\u5b50\uff0c\u8fd9\u4e9b\u6c22\u539f\u5b50\u80fd\u591f\u901a\u8fc7\u819c\u7535\u6781\u6e17\u900f\u5230\u5bf9\u9762\u8fdb\u884c\u52a0\u6c22\u53cd\u5e94\u3002\u5f53\u4f7f\u7528\u4e24\u4e2aPd\u819c\u7535\u6781\u65f6\uff0c\u8be5\u7535\u50ac\u5316\u53cc\u52a0\u6c22\u7b56\u7565\u53ef\u4ee5\u5728\u7535\u5316\u5b66\u7535\u6c60\u5916\u7684\u8154\u5ba4\u4e2d\u5bf9\u76f8\u540c\u7684\u6709\u673a\u5e95\u7269\u540c\u65f6\u52a0\u6c22\u3002\u9634\u6781\u548c\u9633\u6781\u52a0\u6c22\u7684\u6c22\u6e90\u5206\u522b\u4e3a\u6c34\u548c\u7532\u919b\u3002\u4e0e\u4f20\u7edf\u7684\u5355\u4fa7\u7535\u50ac\u5316\u52a0\u6c22\u76f8\u6bd4\uff0c\u53cc\u52a0\u6c22\u7b56\u7565\u53ef\u4ee5\u8282\u7701\u81f3\u5c111v\u7684\u7535\u538b\u8f93\u5165\uff0c\u52a0\u6c22\u901f\u7387\u548c\u6cd5\u62c9\u7b2c\u6548\u7387\u63d0\u9ad8\u4e00\u500d\u3002\u6309\u7167\u8fd9\u79cd\u8bbe\u8ba1\u53ef\u4ee5\u6210\u529f\u5730\u4ece\u751f\u7269\u8d28\u884d\u751f\u7684\u9a6c\u6765\u9178\u3001\u5bcc\u9a6c\u9178\u6216\u9a6c\u6765\u9178\u9150\u4e2d\u751f\u4ea7\u7425\u73c0\u9178\u3002\u9274\u4e8e\u94af\u819c\u7535\u6781\u7684\u8f85\u50ac\u5316\u5242\u4fee\u9970\u7684\u4fbf\u5229\u6027\uff0c\u4f5c\u8005\u9884\u8ba1\u8fd9\u79cd\u7535\u50ac\u5316\u53cc\u52a0\u6c22\u7b56\u7565\u5c06\u9002\u7528\u4e8e\u8bb8\u591a\u6709\u673a\u52a0\u6c22\u53cd\u5e94\uff0c\u5177\u6709\u5de8\u5927\u7684\u5927\u89c4\u6a21\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/doi.org\/10.1038\/s41929-023-00923-6<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f20\u7199\u7199 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