{"id":249135,"date":"2023-03-24T06:20:17","date_gmt":"2023-03-23T22:20:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=249135"},"modified":"2023-03-23T14:27:44","modified_gmt":"2023-03-23T06:27:44","slug":"%e5%ae%89%e5%be%bd%e5%a4%a7%e5%ad%a6%e9%ad%8f%e5%9f%b9%e5%8f%91%e5%8d%8e%e4%b8%ad%e5%b8%88%e8%8c%83%e5%a4%a7%e5%ad%a6%e5%bc%a0%e4%b9%8b%e6%b6%b5acs-materials-lett%ef%bc%9a%e9%80%9a%e8%bf%87%e5%a4%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=249135","title":{"rendered":"\u5b89\u5fbd\u5927\u5b66\u9b4f\u57f9\u53d1&#038;\u534e\u4e2d\u5e08\u8303\u5927\u5b66\u5f20\u4e4b\u6db5ACS Materials Lett\uff1a\u901a\u8fc7\u5927\u73af\u7a7a\u8154\u548c\u6846\u67b6\u901a\u9053\u7684\u534f\u540c\u5b9e\u73b0\u56fa\u6001\u4e0b\u539f\u4f4d\u52a8\u6001\u8367\u5149"},"content":{"rendered":"<p><strong>\u5bfc\u8bfb<\/strong><\/p>\n<p>\u7531\u4e8e\u591a\u8272\u6709\u673a\u53d1\u5149\u6750\u6599\u5728\u663e\u793a\u5668\u3001\u751f\u7269\u6210\u50cf\u3001\u4fe1\u606f\u52a0\u5bc6\u5b58\u50a8\u548c\u9632\u4f2a\u6280\u672f\u4e2d\u7684\u91cd\u8981\u5e94\u7528\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u4e13\u6ce8\u4e8e\u5177\u6709\u52a8\u6001\u6027\u8d28\u7684\u667a\u80fd\u5149\u5b66\u6750\u6599\u7684\u5f00\u53d1\u3002\u5316\u5b66\u5bb6\u5df2\u7ecf\u5f00\u53d1\u4e86\u5404\u79cd\u7b56\u7565\u8c03\u8282\u8367\u5149\uff0c\u5982\u5316\u5b66\u4fee\u9970\u662f\u5176\u4e2d\u7684\u4e00\u79cd\u7ecf\u5178\u7b56\u7565\uff0c\u4f46\u5176\u8017\u65f6\u4e14\u6548\u7387\u8f83\u4f4e\u3002\u4e00\u79cd\u53ef\u66ff\u4ee3\u4e14\u66f4\u4e3a\u901a\u7528\u7684\u7b56\u7565\u662f\u5229\u7528\u975e\u5171\u4ef7\u952e\u4f5c\u7528\u7684\u672c\u5f81\u52a8\u6001\u548c\u53ef\u9006\u7279\u6027\u8d4b\u4e88\u4f53\u7cfb\u523a\u6fc0\u54cd\u5e94\u6027\u5e76\u4ee5\u5149\u5b66\u53d8\u5316\u7684\u65b9\u5f0f\u5448\u73b0\u3002\u4e0e\u6eb6\u6db2\u6001\u76f8\u6bd4\uff0c\u8c03\u8282\u6750\u6599\u7684\u56fa\u6001\u5149\u7269\u7406\u6027\u8d28\u66f4\u5177\u6709\u5b9e\u9645\u4ef7\u503c\uff0c\u4e5f\u66f4\u5177\u6311\u6218\u3002\u7136\u800c\uff0c\u56fa\u6001\u4e0b\u7d27\u5bc6\u7684\u5206\u5b50\u5806\u79ef\u9650\u5236\u4e86\u975e\u5171\u4ef7\u952e\u4f5c\u7528\u7684\u52a8\u6001\u6027\uff0c\u4e5f\u5c31\u9020\u6210\u4e86\u5149\u5b66\u8c03\u63a7\u53ef\u64cd\u4f5c\u6027\u5dee\u7684\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5408\u7406\u8bbe\u8ba1\u4f53\u7cfb\uff0c\u5b9e\u73b0\u5728\u56fa\u6001\u4e0b\u5bf9\u53d1\u5149\u7684\u4fbf\u6377\u8c03\u8282\u662f\u5341\u5206\u6709\u610f\u4e49\u5177\u6709\u6311\u6218\u7684\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5b89\u5fbd\u5927\u5b66\u9b4f\u57f9\u53d1\u6559\u6388\u4e0e\u534e\u4e2d\u5e08\u8303\u5927\u5b66\u5f20\u4e4b\u6db5\u7814\u7a76\u5458\u5408\u4f5c\u62a5\u9053\u5229\u7528\u53d1\u5149\u73af\u8543\u7684\u56fa\u6709\u7a7a\u8154\u5728\u56fa\u6001\u4e0b\u5f62\u6210\u901a\u9053\u7ed3\u6784\uff0c\u5e76\u8fdb\u4e00\u6b65\u5229\u7528\u4e3b\u4f53\u4e0e\u5ba2\u4f53\u4e4b\u95f4\u9010\u7ea7\u589e\u5f3a\u7684\u03c0-\u03c0\u5806\u79ef\u4f5c\u7528\uff0c\u5b9e\u73b0\u4e86\u201c\u591a\u7c73\u8bfa\u201d\u5f0f\u56fa\u6001\u53d1\u5149\u7684\u52a8\u6001\u8c03\u8282\u3002\u5177\u4f53\u5730\uff0c\u57fa\u4e8e\u7533\u8bf7\u4eba\u65e9\u671f\u5f00\u53d1\u7684\u53cc\u6c30\u57fa\u4e8c\u82ef\u4e59\u70ef\u5355\u5143\uff08<em><i>Angew. Chem. Int. Ed. <\/i><\/em><strong><b>2021<\/b><\/strong>, <em><i>60<\/i><\/em>, 7148\uff09\u8fdb\u884c\u62d3\u6251\u73af\u5316\u884d\u751f\uff0c\u5f97\u5230\u521a\u6027\u7f3a\u7535\u53d1\u5149\u73af\u8543\u3002\u5176\u5728\u6676\u6001\u4e0b\u53ef\u4ee5\u5f62\u6210\u4ee5\u73af\u8543\u4e3a\u4e00\u7ef4\u901a\u9053\u7684\u6846\u67b6\u7ed3\u6784\u3002\u901a\u8fc7\u9009\u53d6\u5177\u6709\u9010\u7ea7\u589e\u5f3a\u7ed9\u7535\u5b50\u80fd\u529b\u7684\u5ba2\u4f53\uff08\u82ef\u3001\u7532\u82ef\u3001\u567b\u5429\u3001\u8418\u548c\u8298\uff09\uff0c\u5728\u56fa\u6db2\u4e24\u76f8\u901a\u8fc7\u7a7a\u8154\u7684\u9009\u62e9\u6027\u5438\u9644\u5b9e\u73b0\u4e86\u901a\u9053\u4e2d\u5ba2\u4f53\u7684\u201c\u591a\u7c73\u8bfa\u201d\u5f0f\u66ff\u6362\uff0c\u6574\u4e2a\u8fc7\u7a0b\u5b54\u9053\u7ed3\u6784\u4fdd\u6301\uff0c\u56fa\u4f53\u53d1\u5149\u4e5f\u7531\u4e8e\u9010\u6e10\u589e\u5f3a\u7684\u03c0-\u03c0\u5806\u79ef\u4f5c\u7528\u800c\u9010\u6e10\u7ea2\u79fb\uff0c\u8367\u5149\u6ce2\u957f\u5b9e\u73b0\u4ece\u84dd\u8272\u5230\u6df1\u7ea2\u8272\u8d85\u8fc7200 nm\u7684\u8de8\u8d8a\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cAchieving <em><i>in situ<\/i><\/em>\u00a0Dynamic Fluorescence in the\u00a0Solid State Through Synergizing Cavities of Macrocycle and Channels of Framework\u201d\u4e3a\u9898\u53d1\u8868\u5728<em><i>A<\/i><\/em><em><i>CS M<\/i><\/em><em><i>a<\/i><\/em><em><i>terials Letters<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249136\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72470-17.png\" alt=\"\" width=\"1773\" height=\"758\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72470-17.png 1773w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72470-17-300x128.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72470-17-768x328.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72470-17-1024x438.png 1024w\" sizes=\"(max-width: 1773px) 100vw, 1773px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\uff081\uff09\u672c\u5de5\u4f5c\u5229\u7528\u5927\u73af\u5b9a\u5236\u7684\u7a7a\u8154\u5e73\u8861\u4e86\u4e3b\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u548c\u8367\u5149\u53d1\u5c04\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u6676\u6001\u4e0b\u5f62\u6210\u7684\u72ec\u7279\u4e00\u7ef4\u5b54\u9053\u7ed3\u6784\u6709\u5229\u4e8e\u5ba2\u4f53\u7684\u9009\u62e9\u6027\u5438\u9644\u4e0e\u4f20\u8f93\uff0c\u4e8c\u8005\u7684\u534f\u540c\u4f7f\u5927\u73af\u53ef\u4ee5\u63d0\u4f9b\u8f83\u4e3a\u901a\u7528\u7684\u53d1\u5149\u8c03\u63a7\u5e73\u53f0\u3002<\/p>\n<p>\uff082\uff09\u672c\u5de5\u4f5c\u901a\u8fc7\u5ba2\u4f53\u4ea4\u6362\u5b9e\u73b0\u8367\u5149\u7684\u52a8\u6001\u8c03\u8282\uff0c\u5177\u6709\u53ef\u64cd\u4f5c\u6027\u5f3a\u3001\u53d1\u5149\u8c03\u63a7\u6548\u7387\u9ad8\u3001\u4e3b\u4f53\u53ef\u56de\u6536\u6027\u5f3a\u7684\u4f18\u70b9\uff0c\u4e3a\u4fbf\u6377\u8c03\u8282\u56fa\u6001\u53d1\u5149\u63d0\u4f9b\u4e86\u65b0\u7b56\u7565\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249137\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-48.png\" alt=\"\" width=\"1205\" height=\"816\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-48.png 1205w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-48-300x203.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-48-768x520.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-48-1024x693.png 1024w\" sizes=\"(max-width: 1205px) 100vw, 1205px\" \/><\/p>\n<p><strong><b>\u56fe1 <\/b><\/strong>a) \u901a\u8fc7\u57fa\u4e8e\u5927\u73af\u7684\u7edc\u5408\u548c\u57fa\u4e8e\u6846\u67b6\u7684\u5438\u9644\u7b56\u7565\u5b9e\u73b0\u56fa\u6001\u53ef\u8c03\u8282\u8367\u5149\u3002b) \u5229\u7528\u5927\u73af\u548c\u8fde\u7eed\u5ba2\u4f53\u4ea4\u6362\u8c03\u63a7\u56fa\u6001\u8367\u5149\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249144\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe2-5.jpg\" alt=\"\" width=\"4128\" height=\"4352\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe2-5.jpg 4128w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe2-5-285x300.jpg 285w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe2-5-768x810.jpg 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe2-5-971x1024.jpg 971w\" sizes=\"(max-width: 4128px) 100vw, 4128px\" \/><\/p>\n<p><strong>\u56fe2 <\/strong>a)<strong><b>1<\/b><\/strong>\u00c9<strong><b>Ben<\/b><\/strong><strong><sup><b>c<\/b><\/sup><\/strong>\u4e2d\u7531\u5927\u73af\u5c42\u72b6\u5806\u79ef\u6784\u7b51\u7684\u4e00\u7ef4\u901a\u9053\u3002b) \u5229\u7528\u03c0-\u7535\u5b50\u5ba2\u4f53\u589e\u5f3a\u7684\u7ed9\u7535\u5b50\u6027\u5b9e\u73b0\u8fde\u7eed\u7684\u5ba2\u4f53\u4ea4\u6362\uff0c\u4ece\u800c\u5728\u56fa\u6001\u4e0b\u7cbe\u786e\u8c03\u63a7\u53d1\u5c04\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249140\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-45.png\" alt=\"\" width=\"514\" height=\"307\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-45.png 514w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-45-300x179.png 300w\" sizes=\"(max-width: 514px) 100vw, 514px\" \/><\/p>\n<p><strong>\u56fe3 <\/strong>a) (i) <strong><b>1<\/b><\/strong>\u00c9<strong>Ben<\/strong><strong><sup>c<\/sup><\/strong>\u6676\u4f53\u548c(ii-v)<strong>\u00a01<\/strong>\u00c9\u5ba2\u4f53\u5728\u8fde\u7eed\u4ea4\u6362\u8fc7\u7a0b\u4e2d\u7684\u6838\u78c1\u5171\u632f\u6c22\u8c31\u3002b) (i) <strong><b>1<\/b><\/strong>\u00c9<strong>Ben<\/strong><strong><sup>c<\/sup><\/strong>\u6676\u4f53\u548c(ii-v)<strong>\u00a01<\/strong>\u00c9\u5ba2\u4f53\u5728\u8fde\u7eed\u4ea4\u6362\u8fc7\u7a0b\u4e2d\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u8c31\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249141\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-38.png\" alt=\"\" width=\"2045\" height=\"1971\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-38.png 2045w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-38-300x289.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-38-768x740.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-38-1024x987.png 1024w\" sizes=\"(max-width: 2045px) 100vw, 2045px\" \/><\/p>\n<p><strong>\u56fe4 <\/strong><strong><b>1<\/b><\/strong>\u00c9\u5ba2\u4f53\u6676\u4f53\u5728\u65e5\u5149\u706f\u4e0b\u7684\u6676\u4f53\u7167\u7247\uff08\u5de6\uff09\u4ee5\u53ca<strong><b>1<\/b><\/strong>\u00c9\u5ba2\u4f53\u7684\u56fa\u6001\u7ed3\u6784\u7684\u4fa7\u89c6\uff08\u4e2d\uff09\u548c\u5e73\u9762\uff08\u53f3\uff09\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249142\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-28.png\" alt=\"\" width=\"1144\" height=\"702\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-28.png 1144w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-28-300x184.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-28-768x471.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-28-1024x628.png 1024w\" sizes=\"(max-width: 1144px) 100vw, 1144px\" \/><\/p>\n<p><strong>\u56fe5<\/strong>\u00a0a) \u4e0d\u540c\u6676\u4f53\u5728365 nm\u7d2b\u5916\u706f\u4e0b\u7684\u7167\u7247\u3002b) <strong>1<\/strong>\u00c9\u5ba2\u4f53\u6676\u4f53\u7684\u8367\u5149\u5149\u8c31\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249145\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe6-2.jpg\" alt=\"\" width=\"7328\" height=\"2949\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe6-2.jpg 7328w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe6-2-300x121.jpg 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe6-2-768x309.jpg 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/03\/\u56fe6-2-1024x412.jpg 1024w\" sizes=\"(max-width: 7328px) 100vw, 7328px\" \/><\/p>\n<p><strong>\u56fe6 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