{"id":249568,"date":"2023-04-08T06:22:15","date_gmt":"2023-04-07T22:22:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=249568"},"modified":"2023-04-06T11:25:13","modified_gmt":"2023-04-06T03:25:13","slug":"%e9%b2%81%e9%9b%84-%e8%b0%a2%e8%b6%85%e9%b8%a3-%e5%a7%9c%e4%b8%bd%e4%b8%bd%e5%9b%a2%e9%98%9fmaterials-horizons%ef%bc%9a%e5%9f%ba%e4%ba%8e%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9fmofs%e7%b2%98%e9%99%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=249568","title":{"rendered":"\u9c81\u96c4\/\u8c22\u8d85\u9e23\/\u59dc\u4e3d\u4e3d\u56e2\u961fMaterials Horizons\uff1a\u57fa\u4e8e\u6c27\u5316\u8fd8\u539fMOFs\u7c98\u9644\u5bfc\u7535\u6c34\u51dd\u80f6\u751f\u7269\u7535\u5b50\u548c\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u7531\u4e8e\u5177\u6709\u591a\u5b54\u7ed3\u6784\u3001\u53ef\u8c03\u63a7\u7684\u5316\u5b66\u7ec4\u6210\u548c\u9ad8\u6bd4\u8868\u9762\u79ef\u7b49\u7279\u6027\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c14\u4f53\u50a8\u5b58\u3001\u50ac\u5316\u5242\u4ee5\u53ca\u751f\u7269\u533b\u5b66\u9886\u57df\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u53d1\u73b0MOFs\u80fd\u591f\u901a\u8fc7\u7535\u89e3\u8d28\u6269\u6563\u6548\u5e94\u5f62\u6210\u53cc\u7535\u5c42\u548c\u8d5d\u7535\u5bb9\u884c\u4e3a\uff0c\u8fd9\u4f7f\u5f97\u5176\u5728\u80fd\u6e90\u50a8\u5b58\u4e2d\u4e5f\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u5e94\u7528\u524d\u666f\u3002\u5c3d\u7ba1MOFs\u5177\u6709\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0cMOFs\u6750\u6599\u5bfc\u7535\u6027\u5dee\u7684\u7f3a\u70b9\u9650\u5236\u4e86\u5176\u5728\u751f\u7269\u7535\u6781\u4e2d\u7684\u5e94\u7528\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u5927\u90e8\u5206MOFs\u6750\u6599\u9700\u8981\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u5408\u6210\uff0c\u5176\u4eb2\u6c34\u6027\u548c\u6c34\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u5f88\u96be\u5728\u6c34\u51dd\u80f6\u57fa\u8d28\u4e2d\u7a33\u5b9a\u5206\u6563\u3002\u7528MOFs\u6750\u6599\u6765\u5236\u5907\u53ef\u7528\u4e8e\u751f\u7269\u7535\u6781\u548c\u529f\u80fd\u6027\u8d85\u7ea7\u7535\u5bb9\u7684\u7535\u6d3b\u6027\u6c34\u51dd\u80f6\u4ecd\u7136\u5b58\u5728\u7740\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n<p>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u897f\u5357\u4ea4\u901a\u5927\u5b66<\/strong>\u533b\u5b66\u9662\uff08\u751f\u7269\u533b\u5b66\u5de5\u7a0b\u7814\u7a76\u9662\uff09<strong>\u9c81\u96c4\u6559\u6388\u3001\u8c22\u8d85\u9e23\u7814\u7a76\u5458\u56e2\u961f\u548c\u897f\u534e\u5927\u5b66\u59dc\u4e3d\u4e3d\u526f\u6559\u6388<\/strong>\u57fa\u4e8e\u4eff\u8d3b\u8d1d\u673a\u7406\uff0c\u5229\u7528\u805a\u591a\u5df4\u80fa\uff08PDA\uff09\u4ecb\u5bfc\u5bfc\u7535\u9ad8\u5206\u5b50PEDOT\u5728ZIF-71\u8868\u9762\u81ea\u7ec4\u88c5\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u5177\u6709\u4eb2\u6c34\u6027\u3001\u5bfc\u7535\u6027\u548c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u6838\u58f3\u7ed3\u6784PEDOT@PZIF-71\u7eb3\u7c73\u9897\u7c92\u3002\u5e76\u5c06\u8be5\u7eb3\u7c73\u9897\u7c92\u4f5c\u4e3a\u586b\u6599\u63ba\u6742\u8fdb\u805a\u4e19\u70ef\u9170\u80fa\uff08PAM\uff09\u7f51\u7edc\u4e2d\uff0c\u5236\u5907\u4e86\u5177\u6709\u751f\u7269\u7c98\u9644\u6027\u3001\u67d4\u6027\u7684\u5bfc\u7535PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u3002\u4e00\u65b9\u9762\uff0cPDA\u4fee\u9970\u7684ZIF-71\uff08PZIF-71\uff09\u53ef\u4ee5\u4f5c\u4e3a\u6838\u5fc3\u6a21\u677f\u4e3aPEDOT\u7684\u7ec4\u88c5\u63d0\u4f9b\u5927\u91cf\u7684\u6d3b\u6027\u4f4d\u70b9\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5bfc\u7535\u5916\u58f3PEDOT\u53ef\u4ee5\u505a\u4e3a\u7535\u8377\u6536\u96c6\u5668\u63d0\u5347PEDOT@PZIF-71\u7684\u7535\u5b50\u8f6c\u79fb\u80fd\u529b\u3002PEDOT\u548cPZIF-71\u534f\u540c\u589e\u52a0\u7eb3\u7c73\u9897\u7c92\u7684\u5bfc\u7535\u6027\u548c\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0c\u7531\u4e8ePEDOT@PZIF-71\u7eb3\u7c73\u9897\u7c92\u4e2d\u513f\u8336\u915a\u57fa\u56e2\u7684\u5b58\u5728\uff0c\u5236\u5907\u7684\u6c34\u51dd\u80f6\u5177\u6709\u826f\u597d\u7684\u7c98\u9644\u6027\u548c\u751f\u7269\u76f8\u5bb9\u6027\u3002\u57fa\u4e8e\u4ee5\u4e0a\u4f18\u70b9\uff0c\u8be5\u6c34\u51dd\u80f6\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u7528\u4e8e\u7535\u751f\u7406\u4fe1\u53f7\u6d4b\u91cf\u7684\u751f\u7269\u7535\u6781\uff0c\u8fd8\u53ef\u4ee5\u7528\u6765\u7ec4\u88c5\u53ef\u63d0\u4f9b\u7535\u523a\u6fc0\u6cbb\u7597\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c<a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/MH\/D2MH01234K\"><strong><u><b>Bioadhesive and electroactive hydrogels for flexible bioelectronics and supercapacitors enabled by a redox-active core\u2013shell PEDOT@PZIF-71 system<\/b><\/u><\/strong><\/a>\u201d\u4e3a\u9898\u53d1\u8868\u4e8e<strong>\u300a<\/strong><strong>Materials<\/strong><strong>\u00a0<\/strong><strong>Horizons<\/strong><strong>\u300b<\/strong><strong>\uff08IF=<\/strong><strong>15.<\/strong><strong>7<\/strong><strong>17<\/strong><strong>\uff09<\/strong>\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a<strong>\u7518\u4e1c\u6797<\/strong><strong>\u535a\u58eb\uff08<\/strong>\u73b0\u4e3a\u5357\u4eac\u5e08\u8303\u5927\u5b66\u9752\u5e74\u6559\u5e08<strong>\uff09<\/strong>\u548c\u7855\u58eb\u7814\u7a76\u751f<strong><b>\u9ec4\u81ea\u5f3a<\/b><\/strong>\uff0c\u8bba\u6587\u7684\u901a\u8baf\u4f5c\u8005\u4e3a\u897f\u5357\u4ea4\u901a\u5927\u5b66\u533b\u5b66\u9662\uff08\u751f\u7269\u533b\u5b66\u5de5\u7a0b\u7814\u7a76\u9662\uff09<strong>\u9c81\u96c4\u6559\u6388<\/strong>\u548c<strong>\u8c22\u8d85\u9e23\u7814\u7a76\u5458<\/strong>\u4ee5\u53ca<strong>\u897f\u534e\u5927\u5b66\u7684\u59dc\u4e3d\u4e3d\u526f\u6559\u6388<\/strong>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249569\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-8.png\" alt=\"\" width=\"1072\" height=\"799\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-8.png 1072w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-8-300x224.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-8-768x572.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-8-1024x763.png 1024w\" sizes=\"(max-width: 1072px) 100vw, 1072px\" \/><\/p>\n<p>Fig. 1 (a) \u5177\u6709\u4eb2\u6c34\u6027\u548c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u6838\u58f3\u7ed3\u6784PEDOT@PZIF-71\u00a0NPs\u5236\u5907\u6b65\u9aa4\u3002(b)\u00a0PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u3002\u00a0(c)\u6c34\u51dd\u80f6\u7684\u6027\u80fd\u53ca\u5e94\u7528\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249570\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-6.png\" alt=\"\" width=\"893\" height=\"851\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-6.png 893w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-6-300x286.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-6-768x732.png 768w\" sizes=\"(max-width: 893px) 100vw, 893px\" \/><\/p>\n<p>Fig. 2\u00a0(a)\u00a0PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u5728\u4e0d\u540c\u57fa\u4f53\u8868\u9762\u7684\u7c98\u9644\uff0c\u5982\u5851\u6599\u3001\u9676\u74f7\u3001\u575a\u679c\u3001\u808c\u8089\u548c\u8f6f\u9aa8\u3002(b)\u00a0PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u5728\u4e0d\u540c\u57fa\u4f53\u4e0a\u7684\u7c98\u9644\u5f3a\u5ea6\u3002(c) PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u5728\u732a\u76ae\u4e0a\u7684\u53cd\u590d\u7c98\u9644\u5f3a\u5ea6\u3002(d)\u00a0PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u957f\u6548\u7c98\u9644\u6027\u80fd\u6d4b\u8bd5\u3002 (e) \u6c34\u51dd\u80f6\u548c\u4e0d\u540c\u57fa\u4f53\u7684\u7c98\u9644\u673a\u7406\uff1a\u00a0I. \u6c22\u952e\u3001\u00a0II. \u914d\u4f4d\u952e\u3001\u00a0III. \u9633\u79bb\u5b50\u2013\u03c0 \u76f8\u4e92\u4f5c\u7528\u548cIV. \u5171\u4ef7\u952e\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>PEDOT@PZIF-71\u00a0NPs\u4f5c\u4e3a\u4e00\u79cd\u901a\u7528\u7684\u5bfc\u7535\u7eb3\u7c73\u586b\u6599\uff0c\u53ef\u7528\u4e8e\u5236\u5907\u5177\u6709\u826f\u597d\u5bfc\u7535\u6027\u3001\u7c98\u9644\u6027\u548c\u53ef\u62c9\u4f38\u6027\u80fd\u7684\u6c34\u51dd\u80f6\u3002\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684 PEDOT@PZIF-71\u00a0NPs\u00a0\u80fd\u5728\u6c34\u51dd\u80f6\u5185\u90e8\u6784\u5efa\u7c7b\u4f3c\u8d3b\u8d1d\u7c98\u9644\u86cb\u767d\u7684\u52a8\u6001\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5e76\u4f7f\u6c34\u51dd\u80f6\u4fdd\u6301\u8db3\u591f\u7684\u591a\u7684\u513f\u8336\u915a\u57fa\u56e2\uff0c\u8d4b\u4e88\u6c34\u51dd\u80f6\u6301\u4e45\u53ef\u91cd\u590d\u7684\u7c98\u9644\u6027\u80fd\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249571\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-4.png\" alt=\"\" width=\"820\" height=\"909\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-4.png 820w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-4-271x300.png 271w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-4-768x851.png 768w\" sizes=\"(max-width: 820px) 100vw, 820px\" \/><\/p>\n<p>Fig. 3 PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u751f\u7269\u76f8\u5bb9\u6027\u3002\u5728300 mV\u7535\u523a\u6fc0\u4e0b(a)\u00a0\u4e0d\u540c\u6c34\u51dd\u80f6\u4e0a\u57f9\u517bC2C12\u7ec6\u80de\u7684\u6d3b\u7ec6\u80de\u67d3\u8272\uff08\u7eff\u8272\uff09\u3002(b)\u00a0\u5728\u4e0d\u540c\u6c34\u51dd\u80f6\u8868\u9762\u7c98\u7740\u6591\u7684\u5f62\u6210\uff08\u7eff\u8272\uff1a\u7c98\u7740\u6591\uff1b\u84dd\u8272\uff1a\u7ec6\u80de\u6838\uff09\u3002(c)\u6c34\u51dd\u80f6\u4f53\u5185\u751f\u7269\u76f8\u5bb9\u6027\u8bc4\u4ef7\u3002(d)\u00a0PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u4f5c\u4e3a\u690d\u5165\u7535\u6781\uff0c\u6d4b\u91cf\u65b0\u897f\u5170\u5927\u8033\u767d\u5154\u80cc\u90e8\u808c\u8089\u7684\u808c\u7535\u4fe1\u53f7\u3002<\/p>\n<p>\u4f53\u5185\u690d\u5165\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cPEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u7531\u4e8e\u513f\u8336\u915a\u57fa\u56e2\u7684\u5b58\u5728\uff0c\u5177\u6709\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u80fd\u591f\u4fc3\u8fdb\u7ec6\u80de\u5728\u6c34\u51dd\u80f6\u7684\u589e\u6b96\u548c\u7c98\u9644\uff0c\u80fd\u591f\u4f5c\u4e3a\u53ef\u690d\u5165\u7535\u6781\u7528\u4e8e\u4f53\u5185\u7535\u751f\u7406\u4fe1\u53f7\u7684\u68c0\u6d4b\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249572\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-4.png\" alt=\"\" width=\"957\" height=\"904\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-4.png 957w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-4-300x283.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-4-768x725.png 768w\" sizes=\"(max-width: 957px) 100vw, 957px\" \/><\/p>\n<p>Fig. 4 (a)\u4e0d\u540c\u6c34\u51dd\u80f6\u7684\u7535\u5bfc\u7387\u3002(b)\u00a0\u4e0d\u540cPEDOT\u548cPZIF-71\u6bd4\u4f8b\u7684\u6c34\u51dd\u80f6\u7535\u5bfc\u7387\u3002(c)\u00a0\u5c06PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u8fde\u5165\u7535\u8def\u5e76\u70b9\u4eaeLED\u706f\u3002\u6c34\u51dd\u80f6\u4f5c\u4e3a\u751f\u7269\u7535\u6781\u68c0\u6d4b (d) \u5fae\u7b11\u548c\u773c\u775b\u8fd0\u52a8\u65f6\u7684\u8111\u7535\u4fe1\u53f7\u3002(e)\u00a0\u5fc3\u7535\u4fe1\u53f7\u548c (f) \u808c\u7535\u4fe1\u53f7\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>PEDOT@PZIF-71\u63ba\u6742\u8d4b\u4e88\u4e86\u6c34\u51dd\u80f6\u826f\u597d\u7684\u5bfc\u7535\u6027\u3002\u4e0ePEDOT\/PAM\u548cZIF-71\/PAM\u6c34\u51dd\u80f6\u76f8\u6bd4\uff0c\u8be5\u6c34\u51dd\u80f6\u4e0d\u4ec5\u6709\u66f4\u597d\u7684\u5bfc\u7535\u6027\uff08\u7535\u5bfc\u7387\u53ef\u8fbe50.2 S\/m\uff09\uff0c\u8fd8\u80fd\u591f\u8fde\u5165\u7535\u8def\u5e76\u70b9\u4eaeLED\u706f\u3002\u7531\u4e8e PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u7684\u4f18\u826f\u7684\u7c98\u9644\u6027\u548c\u5bfc\u7535\u6027\uff0c\u6c34\u51dd\u80f6\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u81ea\u7c98\u9644\u7535\u6781\uff0c\u51c6\u786e\u7684\u68c0\u6d4bEEG\uff0cECG\u548cEMG\u4fe1\u53f7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249573\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-2.png\" alt=\"\" width=\"1214\" height=\"763\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-2.png 1214w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-2-300x189.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-2-768x483.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-2-1024x644.png 1024w\" sizes=\"(max-width: 1214px) 100vw, 1214px\" \/><\/p>\n<p>Fig. 5 PEDOT@PZIF-71\/PAM\u6c34\u51dd\u80f6\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002(a) \u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u6c34\u51dd\u80f6\u7684CV\u66f2\u7ebf\u3002(b) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6c34\u51dd\u80f6\u5145\u653e\u7535\u6027\u80fd\u3002(c) \u57281.6 mA\/g\u7684\u7535\u6d41\u4e0b\uff0c\u6c34\u51dd\u80f6\u7684\u5145\u653e\u7535\u5faa\u73af\u7a33\u5b9a\u6027\u3002(d) 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