{"id":249858,"date":"2023-04-23T08:44:17","date_gmt":"2023-04-23T00:44:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=249858"},"modified":"2023-04-23T08:44:17","modified_gmt":"2023-04-23T00:44:17","slug":"nat-commun-%ef%bc%9a%e9%94%82%e7%94%b5%e6%b1%a0%e7%94%a8%e9%ab%98%e7%86%b5%e6%b6%b2%e4%bd%93%e7%94%b5%e8%a7%a3%e6%b6%b2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=249858","title":{"rendered":"Nat. Commun.\uff1a\u9502\u7535\u6c60\u7528\u9ad8\u71b5\u6db2\u4f53\u7535\u89e3\u6db2"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u9ad8\u71b5(HE)\u5408\u91d1\u901a\u5e38\u7531\u4e94\u79cd\u6216\u4e94\u79cd\u4ee5\u4e0a\u7684\u4e3b\u5143\u7d20\u7ec4\u6210\uff0c\u6709\u5229\u4e8e\u5f62\u6210\u5177\u6709\u7b80\u5355\u7ed3\u6784\u7684\u56fa\u6eb6\u76f8\u3002\u5bf9\u4e8e\u7ed9\u5b9a\u7684\u7cfb\u7edf\uff0c\u6784\u578b\u71b5\u4f1a\u968f\u7740\u4e3b\u6210\u5206\u7684\u5f15\u5165\u800c\u589e\u52a0\uff0c\u4ece\u800c\u964d\u4f4e\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002\u7136\u800c\uff0c\u71b5\u7684\u589e\u52a0\u5982\u4f55\u5f71\u54cd\u6db2\u4f53\u7684\u70ed\u529b\u5b66\/\u52a8\u529b\u5b66\u6027\u8d28\u662f\u4e0d\u660e\u786e\u7684\u3002HE\u7c7b\u6750\u6599\u4e2d\u7684\u4e00\u4e2a\u65b0\u7684\u7814\u7a76\u65b9\u5411\u662f\u6db2\u4f53\u7535\u89e3\u6db2\uff0c\u5b83\u5728\u7535\u6c60\u7535\u6781\u4e4b\u95f4\u8d77\u79bb\u5b50\u5bfc\u7535\u819c\u7684\u4f5c\u7528\u3002\u7136\u800c\uff0c\u8fc4\u4eca\u4e3a\u6b62\uff0cHE\u7535\u89e3\u6db2\u7684\u57fa\u672c\u6027\u8d28\u5c1a\u672a\u88ab\u7814\u7a76\u3002\u71b5\u7684\u589e\u52a0\u662f\u5982\u4f55\u5f71\u54cd\u5305\u62ec\u6c27\u5316\u8fd8\u539f\u7a33\u5b9a\u6027\u3001\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u7535\u8377\u8f6c\u79fb\u548c\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u76f8(SEI)\u5f62\u6210\u5728\u5185\u7684\u4e3b\u8981\u7535\u89e3\u6db2\u529f\u80fd\u7279\u6027\uff0c\u8fd9\u4e9b\u7814\u7a76\u5f88\u6709\u610f\u4e49\u3002\u7531\u4e8e\u6709\u53ef\u80fd\u901a\u8fc7\u71b5\u6765\u8c03\u8282\u7535\u89e3\u6db2\u7684\u6027\u8d28\uff0c\u5e76\u4e14\u7f3a\u4e4f\u8fd9\u65b9\u9762\u7684\u77e5\u8bc6\uff0c\u7cfb\u7edf\u5730\u7814\u7a76HE\u7535\u89e3\u6db2\u7684\u6027\u8d28\u53ca\u5176\u5bf9\u9502\u7535\u6c60\u4e2d\u76f8\u5173\u5de5\u827a\u7684\u5f71\u54cd\u5f88\u6709\u5fc5\u8981\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u4ee3\u5c14\u592b\u7279\u7406\u5de5\u5927\u5b66\u8f90\u5c04\u79d1\u5b66\u4e0e\u6280\u672f\u7cfbMarnix Wagemaker\u7814\u7a76\u56e2\u961f\u5728\u53ef\u5145\u7535\u9502\u7535\u6c60\u7684\u7535\u89e3\u6db2\u4e2d\u5c55\u793a\u4e86\u901a\u8fc7\u5f15\u5165\u591a\u79cd\u76d0\u6765\u63d0\u9ad8\u7535\u89e3\u6db2\u71b5\u7684\u6709\u6548\u7b56\u7565\u3002\u4e0e\u76ee\u524d\u62a5\u9053\u7684\u6240\u6709\u7535\u89e3\u6db2\u4e0d\u540c\uff0c\u8be5\u7535\u89e3\u6db2\u4e2d\u591a\u4e2a\u9634\u79bb\u5b50\u57fa\u56e2\u7684\u53c2\u4e0e\u5bfc\u81f4\u4e86\u66f4\u5927\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u591a\u6837\u6027\uff0c\u51fa\u4eba\u610f\u6599\u5730\u964d\u4f4e\u4e86\u9502\u79bb\u5b50\u4e0e\u6eb6\u5242\/\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u6eb6\u5242\u5316\u5f3a\u5ea6\uff0c\u4fc3\u8fdb\u4e86\u9502\u79bb\u5b50\u7684\u6269\u6563\u548c\u7a33\u5b9a\u7684\u76f8\u95f4\u949d\u5316\u5c42\u7684\u5f62\u6210\u3002\u4e0e\u5355\u76d0\u7535\u89e3\u6db2\u76f8\u6bd4\uff0c\u542b\u6709\u56db\u79cd\u76d0\u7684\u4f4e\u6d53\u5ea6\u4e8c\u7532\u919a\u7535\u89e3\u6db2\u663e\u793a\u51fa\u66f4\u9ad8\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u8fd9\u4e9b\u53d1\u73b0\u53ef\u4ee5\u901a\u8fc7\u88ab\u71b5\u4e3b\u5bfc\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u548c\u79bb\u5b50\u4f20\u8f93\u4e4b\u95f4\u7684\u57fa\u672c\u5173\u7cfb\u5408\u7406\u89e3\u91ca\u3002\u6b64\u5916\uff0c\u6587\u4e2d\u63d0\u51fa\u4e86\u9ad8\u71b5\u7535\u89e3\u6db2\u4f5c\u4e3a\u9502\u7535\u6c60\u7684\u4e30\u5bcc\u6210\u5206\u548c\u4e00\u4e9b\u672a\u5f00\u53d1\u7684\u7a7a\u95f4\uff0c\u4e3a\u672a\u6765\u7535\u89e3\u6db2\u4f53\u7cfb\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u53c2\u8003\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cHigh entropy liquid electrolytes for lithium batteries\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong><em>Nature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249860\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/00-1.png\" alt=\"\" width=\"1061\" height=\"475\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/00-1.png 1061w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/00-1-300x134.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/00-1-768x344.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/00-1-1024x458.png 1024w\" sizes=\"(max-width: 1061px) 100vw, 1061px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>1\u3001\u901a\u8fc7\u5f15\u5165\u591a\u79cd\u76d0\u83b7\u5f97\u4e86\u9ad8\u71b5\u7535\u89e3\u6db2\uff0c\u7814\u7a76\u4e86\u71b5\u5728\u591a\u79cd\u76d0\u7684\u7535\u89e3\u6db2\u4e2d\u7684\u4f5c\u7528\u548c\u5f71\u54cd\u3002<\/p>\n<p>2\u3001\u591a\u4e2a\u9634\u79bb\u5b50\u57fa\u56e2\u7684\u53c2\u4e0e\u5bfc\u81f4\u4e86\u66f4\u5927\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u591a\u6837\u6027\uff0c\u964d\u4f4e\u4e86\u9502\u79bb\u5b50\u4e0e\u6eb6\u5242\/\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u6eb6\u5242\u5316\u5f3a\u5ea6\uff0c\u6539\u5584\u4e86\u754c\u9762\u76f8\u6027\u80fd\uff0c\u4ece\u800c\u5927\u5e45\u6539\u5584\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6027\u80fd\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249861\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/001.png\" alt=\"\" width=\"1268\" height=\"677\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/001.png 1268w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/001-300x160.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/001-768x410.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/001-1024x547.png 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1 HE\u6db2\u4f53\u7535\u89e3\u6db2\u7684\u6027\u8d28<\/p>\n<p>a HE\u7535\u89e3\u6db2\u7535\u6c60\u7cfb\u7edf\u793a\u610f\u56fe\u3002b\u5355\u76d0\u7535\u89e3\u6db2\u548c\u5236\u5907\u7684HE\u7535\u89e3\u6db2\u7684<sup>7<\/sup>Li\u6838\u78c1\u5171\u632f\u8c31\u3002\u7531\u4e8eLiNO<sub>3<\/sub>\u5728\u4e8c\u7532\u919a\u4e2d\u7684\u76d0\u6eb6\u6027\u8f83\u4f4e\uff0c\u5236\u5907\u4e860.36 M LiNO<sub>3<\/sub>-DME\u7535\u89e3\u6db2\u8fdb\u884c\u6bd4\u8f83\u3002c\u5177\u6709\u4e0d\u540c\u7535\u89e3\u6db2\u7684Li||LiFePO<sub>4<\/sub>\u7535\u6c60\u57280.02 C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u7535\u8377\u5206\u5e03\u3002d\u4f7f\u75280.6 M LiFSI-DME\u548c0.6 M HE-DME\u7535\u89e3\u6db2\u5728Li||Cu\u7535\u89e3\u69fd\u4e2d\u9502\u7535\u9540\/\u5265\u79bb\u5e93\u4f26\u6548\u7387\uff08CE\uff09\u3002e 0.6 M HE-DME\u7535\u89e3\u6db2\u7684\u6052\u6d41\u9502\u7535\u9540\/\u5265\u79bb\u5256\u9762\u3002f\u4e0d\u540c\u7535\u89e3\u6db2\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6bd4\u8f83\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249862\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/002.png\" alt=\"\" width=\"1269\" height=\"915\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/002.png 1269w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/002-300x216.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/002-768x554.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/002-1024x738.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p>LiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>(NCM811)\u7535\u6c60\u5728(a)0.6 M LiFSI-DME\u548c(b)0.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u4ee50.1 C (1 C=180 mA g<sup>\u22121<\/sup>)\u7684\u500d\u7387\u57282.8-4.3 V\u7535\u538b\u8303\u56f4\u5185\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002\u5bf9NCM811\u548c50 \u03bcm\u9502\u91d1\u5c5e\u7b94\u8fdb\u884c\u5bb9\u91cf\u4e3a2 mAh cm<sup>\u22122<\/sup>\u7684\u7535\u6c60\u6d4b\u8bd5\uff0c\u5f97\u5230\u8d1f\/\u6b63\u5bb9\u91cf\u6bd4(N\/P)\u4e3a5\u3002c NCM811\u7535\u6c60\u57280.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u4e0d\u540c\u500d\u7387\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002d NCM811\u57280.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u500d\u7387\u6027\u80fd\u3002e NCM811\u57280.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u4ee50.1 C\u7684\u500d\u7387\u5faa\u73af\u4e09\u6b21\uff0c\u7136\u540e\u4ee50.333 C\u7684\u500d\u7387\u5728\u4e0d\u540c\u7535\u538b\u8303\u56f4\u5185\u5faa\u73af\u3002f LiFePO<sub>4<\/sub> (LFP)\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u5728\u4ee51.0 C\u7684\u500d\u7387\u5faa\u73af\u4e4b\u524d\uff0c\u4ee50.2 C\u7684\u500d\u7387\u5faa\u73af3\u4e2a\u5468\u671f\u3002g NCM811\u7535\u6c60\u57280.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u4ee56.0 C\u7684\u500d\u7387\u5faa\u73af\u7684\u957f\u671f\u5faa\u73af\u80fd\u529b\u4fdd\u6301\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249863\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/003.png\" alt=\"\" width=\"1268\" height=\"849\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/003.png 1268w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/003-300x201.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/003-768x514.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/003-1024x686.png 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3\u9502\u6c89\u79ef\u7269\u7684\u5f62\u8c8c\u548c\u5fae\u89c2\u7ed3\u6784<\/p>\n<p>\u7535\u9540\u540e\u7684\u9502\u91d1\u5c5e\u5f62\u6001\uff1aa\uff0cb \u4e3a0.6 M HE-DME\u7535\u89e3\u6db2\uff1bc, d\u4e3a0.6 M LiFSI-DME\u7535\u89e3\u6db2\u3002a, c\u4fef\u89c6\u56fe\uff1bb\u548cd\u6a2a\u622a\u9762\u89c6\u56fe\u3002\u4f4e\u6e29\u900f\u5c04\u7535\u955c\u56fe\u50cf\u4e2d\u7535\u89e3\u6db2\u4e2d\u6c89\u79ef\u7684\u9502\u91d1\u5c5e\u548c\u754c\u9762\u76f8\u7684\u663e\u5fae\u7ed3\u6784\uff1ae\uff0cf\u4e3a0.6 M HE-DME\u7535\u89e3\u6db2\uff1bg, h\u4e3a0.6 M LiFSI-DME\u7535\u89e3\u6db2\u3002Operando <sup>7<\/sup>Li\u56fa\u76f8\u6838\u78c1\u5171\u632f\u8c31\u548c\u9502\u79bb\u5b50\u7684\u5b9a\u91cf\uff1ai, j\u4e3a0.6 M HE-DME\u7535\u89e3\u6db2\uff1bk, l\u4e3a0.6 M LiFSI-DME\u7535\u89e3\u6db2\u3002\u56fa\u4f53\u7535\u89e3\u6db2\u95f4\u76f8\u4e2d\u7684\u9502(\u84dd\u8272\u6761)\u3001\u53ef\u9006\u91d1\u5c5e\u9502(\u7070\u8272\u6761)\u548c\u201c\u6b7b\u9502\u201d\u6b8b\u7559\u7269\u79cd(\u7ea2\u8272\u6761)\u4e2d\u7684\u9502\u79cd\u7c7b\u6765\u81ea\u9502\u91d1\u5c5e\u79ef\u5206\u5f3a\u5ea6\u6bd4I(\u5265\u79bb)\/I(\u7535\u9540)\u548cCE\u3002\u8bef\u5dee\u6761\u662f\u901a\u8fc7\u4e0d\u540c\u7684\u8bd5\u9a8c\u5f97\u5230\u7684\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249864\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/004.png\" alt=\"\" width=\"1269\" height=\"936\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/004.png 1269w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/004-300x221.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/004-768x566.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/004-1024x755.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4\u9634\u6781\u7535\u89e3\u6db2\u754c\u9762\u76f8(CEI)\u7684\u5f62\u8c8c\u3001\u5fae\u89c2\u7ed3\u6784\u548c\u7ec4\u6210<\/p>\n<p>a, b\u57280.6 M HE-DME\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u540eCEI\u7684\u4f4e\u6e29\u900f\u5c04\u7535\u955c\u56fe\u50cf\u3002c\u5ba4\u6e29\u4e0b\u539f\u5b50\u5206\u8fa8\u7387\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a(HAADF)\u548cd\u73af\u5f62\u4eae\u573a(ABF)\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(STEM)\u56fe\u50cf\u3002HAADF\u548cABF\u56fe\u50cf\u5747\u5728\u9897\u7c92\u8868\u9762\u9644\u8fd1\u53d1\u73b0\u4e86\u4e00\u5c42\u539a\u5ea6\u7ea6\u4e3a2 nm\u7684Li\/TM (TM\uff1a\u8fc7\u6e21\u91d1\u5c5e)\u6df7\u5408\u5c42\uff0c\u6b64\u5916\uff0c\u5229\u7528ABF\u56fe\u50cf\u68c0\u6d4b\u8f7b\u5143\u7d20\u7684\u80fd\u529b\uff0c\u5728ABF\u56fe\u50cf\u4e0a\u53d1\u73b0\u4e86\u4e00\u5c42\u7ea6\u4e3a1.7 nm\u7684\u6df7\u5408\u5c42\u3002e NCM811 CEI\u7684\u4f4e\u6e29\u900f\u5c04\u7535\u955c\u7535\u5b50\u80fd\u91cf\u635f\u5931\u80fd\u8c31(EELS)\u6620\u5c04\uff0c\u5305\u62ec\u4f4e\u6e29\u900f\u5c04\u7535\u955cADF\u56fe\u50cf\uff0c\u4ee5\u53caO, C, F, N, Ni, Co\u548cMn\u5143\u7d20\u56fe\u3002\u6bd4\u4f8b\u5c3a\u4e3a20 nm\u3002f\u4ee5\u542b\u6709Fe<sub>2<\/sub>O<sub>3<\/sub>\u7684CEI\u4e3a\u53c2\u8003\uff0c\u8bd5\u6837\u4e2dO\u00a0K-edge\u7684EELS\u7cbe\u7ec6\u7ed3\u6784\uff1bg\u4ee5\u542b\u6709C\u7684CEI\u4f5c\u4e3a\u53c2\u8003\uff0c\u8bd5\u6837\u4e2dC\u00a0<em>K<\/em>-edge\u7684EELS\u7cbe\u7ec6\u7ed3\u6784\uff1bh\u4ee5\u542b\u6709LiF\u7684CEI\u4f5c\u4e3a\u53c2\u8003\uff0c\u8bd5\u6837\u4e2dF\u00a0<em>K<\/em>-edge\u7684EELS\u7cbe\u7ec6\u7ed3\u6784\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249865\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/005.png\" alt=\"\" width=\"1268\" height=\"1034\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/005.png 1268w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/005-300x245.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/005-768x626.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/005-1024x835.png 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5 HE\u7535\u89e3\u6db2\u7684\u6eb6\u5242\u5316\u7ed3\u6784<\/p>\n<p>a\u5355\u4e00\u76d0\u548cHE\u7535\u89e3\u6db2\u7684\u62c9\u66fc\u5149\u8c31\u3002b\u4e0d\u540cLiFSI\u6d53\u5ea6DME\u7535\u89e3\u6db2\u7684\u62c9\u66fc\u5149\u8c31\u3002c HE-DME\u7535\u89e3\u6db2\u548cDME\u7535\u89e3\u6db2\u4e2d\u7684LiFSI\u7684<sup>7<\/sup>Li NMR\u8c31\uff0c\u53c2\u8003\u5728D<sub>2<\/sub>O\u6eb6\u6db2\u4e2d\u76841 M LiCl\u3002d 0.6 M LiFSI-DME\u7535\u89e3\u6db2\u548ce 0.6 M HE-DME\u7535\u89e3\u6db2\u7684\u9502\u79bb\u5b50\u914d\u4f4d\u73af\u5883\u3002f 0.6 M LiFSI-DME\u7535\u89e3\u6db2(\u84dd\u7ebf)\u548c0.6 M HE-DME\u7535\u89e3\u6db2(\u6a59\u7ebf)\u7684\u9502\u79bb\u5b50\u81ea\u6269\u6563\u7cfb\u6570(D<em><sub>Li<\/sub><\/em>)\uff0c\u7531MD\u6a21\u62df\u7684\u5747\u65b9\u4f4d\u79fb\u5f97\u51fa\u3002\u5728g\u5e38\u89c4\u7535\u89e3\u6db2\u548ch 0.6 M HE\u7535\u89e3\u6db2\u4e2d\uff0c\u7535\u6781\u548c\u7535\u89e3\u6db2\u4e4b\u95f4\u79bb\u5b50\u4f20\u8f93\u7684\u793a\u610f\u56fe\u3002i\u4e0e\u5e38\u89c4\u7a00\u7535\u89e3\u6db2\u548c\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u76f8\u6bd4\uff0cHE\u7535\u89e3\u6db2\u7684\u6027\u80fd\u3002\u00a92023 The Author(s)<\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\u63d0\u51fa\u4e86\u591a\u79cd\u76d0\u7684\u7535\u89e3\u6db2\uff0c\u5e76\u7814\u7a76\u4e86\u71b5\u5728\u8fd9\u7c7b\u6750\u6599\u4e2d\u7684\u4f5c\u7528\u548c\u5f71\u54cd\u3002\u901a\u8fc7\u5728\u919a\u6eb6\u5242\u4e2d\u5f15\u5165\u591a\u79cd\u76d0(\u5982LiFSI\u3001LiTFSI\u3001LiDFOB\u548cLiNO<sub>3<\/sub>)\uff0c\u5236\u5907\u4e86\u7528\u4e8e\u6982\u5ff5\u9a8c\u8bc1\u7684HE\u7535\u89e3\u6db2\uff0c\u8be5\u7535\u89e3\u6db2\u5bf9\u9502\u91d1\u5c5e\u7535\u9540\/\u5265\u79bb\u5177\u6709\u66f4\u9ad8\u7684\u53ef\u9006\u6027\uff0c\u5bf9\u5bcc\u954d\u9634\u6781\u5145\u7535\u5230\u9ad8\u7ec8\u6b62\u7535\u538b\u5177\u6709\u66f4\u9ad8\u7684\u6c27\u5316\u7a33\u5b9a\u6027\uff0c\u5e76\u63d0\u9ad8\u4e86\u500d\u7387\u6027\u80fd\u3002\u5c3d\u7ba1DME\u7684\u76d0\u6d53\u5ea6\u8f83\u4f4e(0.6 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