{"id":250167,"date":"2023-05-07T05:56:02","date_gmt":"2023-05-06T21:56:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=250167"},"modified":"2023-05-04T15:56:19","modified_gmt":"2023-05-04T07:56:19","slug":"nature-catalysis%ef%bc%9a%e7%83%af%e9%86%9b%e7%ab%8b%e4%bd%93%e9%80%89%e6%8b%a9%e6%80%a7%e5%85%b1%e8%bd%ad%e6%b0%b0%e5%9f%ba%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=250167","title":{"rendered":"Nature Catalysis\uff1a\u70ef\u919b\u7acb\u4f53\u9009\u62e9\u6027\u5171\u8f6d\u6c30\u57fa\u5316"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u7684\u9009\u62e9\u6027\u662f\u6709\u673a\u5316\u5b66\u7684\u76ee\u6807\u3002\u7ecf\u8fc7\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u52aa\u529b\uff0c\u76ee\u524d\u5728\u5b9e\u73b0\u7acb\u4f53\u63a7\u5236\u9886\u57df\u5df2\u7ecf\u53d6\u5f97\u4e86\u8f83\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u5bf9\u5e95\u7269\u5185\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u8f6c\u5316\uff08\u5316\u5b66\u9009\u62e9\u6027\uff09\u4ecd\u662f\u5de8\u5927\u7684\u6311\u6218\u3002\u919b\u7684\u6c30\u57fa\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7ecf\u5178\u7684\u5b9e\u4f8b\uff1a\u4eb2\u6838\u6027\u6c30\u5316\u7269\u4e0e\u919b\u57fa\u76841, 2-\u52a0\u6210\u53cd\u5e94\u662f\u9996\u4f8b\u7acb\u4f53\u9009\u62e9\u6027\u50ac\u5316\u8fc7\u7a0b\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7ebf\u6027\u03b1, \u03b2-\u4e0d\u9971\u548c\u919b\u7684\u5171\u8f6d\u52a0\u6210\u6c30\u57fa\u5316\u4ecd\u7136\u96be\u4ee5\u5b9e\u73b0\uff0c\u5373\u4f7f\u662f\u5916\u6d88\u65cb\u4f53\u4e5f\u662f\u5982\u6b64\u3002\u4e3b\u8981\u7684\u56f0\u96be\u5728\u4e8e\u5982\u4f55\u9ad8\u6548\u5b9e\u73b01,4-\u52a0\u6210\u6c30\u57fa\u5316\uff0c\u800c\u4e0d\u662f\u4f18\u5148\u7684\u6c30\u5316\u72691,2-\u52a0\u6210\u3002<strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u610f\u5927\u5229\u535a\u6d1b\u5c3c\u4e9a\u5927\u5b66<\/strong><strong>Paolo Melchiorre<\/strong><strong>\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u62a5\u544a\u4e86\u4e00\u79cd\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u548c\u6709\u673a\u50ac\u5316\u534f\u540c\u50ac\u5316\u7684\u03b1, \u03b2-\u4e0d\u9971\u548c\u919b\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5171\u8f6d\u52a0\u6210\u6c30\u57fa\u5316\u53cd\u5e94\u3002\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u4e0e\u53ef\u89c1\u5149\u6fc0\u6d3b\u7684\u5149\u6c27\u5316\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\u4fc3\u8fdb\u4e86\u70ef\u70c3\u7684\u5355\u7535\u5b50\u8fd8\u539f\uff0c\u8bf1\u5bfc\u4e86\u5f62\u5f0f\u4e0a\u7684\u6781\u6027\u53cd\u8f6c\u3002\u4ea7\u751f\u7684\u624b\u6027\u81ea\u7531\u57fa\u5177\u6709\u4eb2\u6838\u6027\uff0c\u7136\u540e\u4e0e\u6c30\u5316\u7269\u6e90\u7ed3\u5408\uff0c\u4ee51,4-\u5316\u5b66\u9009\u62e9\u6027\u5b9e\u73b0\u826f\u597d\u7684\u7acb\u4f53\u63a7\u5236\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Stereoselective conjugate cyanation of enals by combining photoredox and organocatalysis<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a<strong><em>Nature Catalysis<\/em><\/strong>\u4e0a\uff0c\u7b2c\u4e00\u5355\u4f4d\u4e3a\u897f\u73ed\u7259\u5df4\u585e\u7f57\u90a3\u79d1\u5b66\u6280\u672f\u7814\u7a76\u6240\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250168\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/0-14.png\" alt=\"\" width=\"600\" height=\"275\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/0-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/0-14-300x138.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u5229\u7528\u5149\u50ac\u5316\u4e0e\u6709\u673a\u50ac\u5316\u7ed3\u5408\uff0c\u901a\u8fc7\u5f62\u5f0f\u4e0a\u7684\u6781\u6027\u53cd\u8f6c\u7b56\u7565\uff0c\u9ad8\u6548\u5b9e\u73b0\u4e86\u03b1, \u03b2-\u4e0d\u9971\u548c\u919b\u7684\u7acb\u4f53\u9009\u62e9\u60271, 4-\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250169\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/1-17.png\" alt=\"\" width=\"600\" height=\"588\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/1-17.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/1-17-300x294.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>\u919b\u53ca\u5176\u4e0d\u9971\u548c\u5bf9\u5e94\u7269\u7684\u4e0d\u5bf9\u79f0\u50ac\u5316\u6c30\u57fa\u5316\u53cd\u5e94<\/strong><strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n<p>\uff08a-b\uff09\u4eb2\u6838\u6c30\u5316\u7269\u4e0e\u919b\u57fa\u76841, 2-\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<p>\uff08c\uff09\u624b\u6027\u6709\u673a\u50ac\u5316\u5242\u4e0e\u53ef\u89c1\u5149\u6d3b\u5316\u7684\u5149\u50ac\u5316\u5242\u4fc3\u8fdb\u4e86\u03b1, \u03b2-\u4e0d\u9971\u548c\u919b\u4e0e\u919b\u57fa\u76841, 4-\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250170\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/2-16.png\" alt=\"\" width=\"600\" height=\"347\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/2-16.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/2-16-300x174.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 \u00a0<\/strong><strong>\u521d\u6b65\u7814\u7a76\u53ca\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406<\/strong><strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n<p>\uff08a\uff09\u76ee\u6807\u6c30\u5316\u4ea7\u72692a\u548c\u526f\u4ea7\u72692a\u2032\u7684\u7814\u7a76\u4e0e\u9274\u5b9a\u3002<\/p>\n<p>\uff08b\uff09\u63d0\u51fa\u53cd\u5e94\u53ef\u80fd\u7684\u673a\u7406\u56fe\u793a\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250171\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/3-16.png\" alt=\"\" width=\"600\" height=\"516\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/3-16.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/3-16-300x258.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 <\/strong><strong>\u70ef\u919b\u7684\u6709\u673a\u50ac\u5316\u4e0d\u5bf9\u79f0\u5171\u8f6d\u6c30\u57fa\u5316<\/strong><strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n<p>\uff08a\uff09\u53cd\u5e94\u7684\u5e95\u7269\u62d3\u5c55\u3002<\/p>\n<p>\uff08b\uff09\u6c30\u57fa\u919b2a\u7684\u5408\u6210\u591a\u529f\u80fd\u6027\u53ca\u5176\u76f4\u63a5\u4fee\u9970\u5f97\u5230\u6c30\u91874a\uff08\u8def\u5f84i\uff09\u548c\u6c30\u91784b\uff08\u8def\u5f84ii\uff09\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250172\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/4-16.png\" alt=\"\" width=\"600\" height=\"610\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/4-16.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/04\/4-16-295x300.png 295w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4\u00a0 <\/strong><strong>\u70ef\u919b\u6781\u6027\u53cd\u8f6c\u7b56\u7565\u7684\u666e\u9002\u6027\u53ca\u673a\u7406\u7814\u7a76<\/strong><strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n<p>\uff08a\uff09\u6709\u673a\u50ac\u5316\u4eb2\u7535\u4ea4\u53c9\u5076\u8054\u5236\u5907\u624b\u60271,6-\u4e8c\u7fb0\u57fa\u5316\u5408\u7269<strong>6<\/strong>\u3002<\/p>\n<p>\uff08b\uff09\u4ee5\u4e8c\u9187\u5f62\u5f0f\u5206\u79bb\u975e\u5bf9\u6620\u5f02\u6784\u4f53\u3002<\/p>\n<p>\uff08c\uff09\u4ea7\u7269\u7a7a\u95f4\u7ed3\u6784\u7684\u786e\u5b9a\u3002<\/p>\n<p>\uff08d\uff09\u70ef\u919b\u7684\u4e0d\u5bf9\u79f0\u5171\u8f6d\u52a0\u6210\u70ef\u4e19\u57fa\u5316\u8fc7\u7a0b\u3002<\/p>\n<p>\uff08e\uff09\u673a\u5236\u5b9e\u9a8c\u8bc1\u5b9e\u4e865\u03c0-\u70ef\u80fa\u57fa\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53<strong>F<\/strong>\u7684\u77ac\u65f6\u5f62\u6210\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5c55\u793a\u4e86\u5c06\u6709\u673a\u50ac\u5316\u548c\u5149\u6c27\u5316\u50ac\u5316\u76f8\u7ed3\u5408\u6765\u89e3\u51b3\u624b\u6027\u5206\u5b50\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u4e00\u4e2a\u957f\u671f\u95ee\u9898\uff0c\u4e3a\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u919b\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5171\u8f6d\u6c30\u57fa\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u8fd9\u79cd\u6781\u6027\u53cd\u8f6c\u7b56\u7565\u4f7f\u03b1,\u03b2-\u4e0d\u9971\u548c\u919b\u7684\u56fa\u6709\u53cd\u5e94\u6027\u53d1\u751f\u53cd\u8f6c\uff0c\u5177\u6709\u4e00\u5b9a\u7684\u901a\u7528\u6027\uff0c\u5e76\u53ef\u4ee5\u5e94\u7528\u4e8e\u5176\u5b83\u975e\u5e38\u89c4\u7acb\u4f53\u63a7\u5236\u7684\u81ea\u7531\u57fa\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41929-023-00939-y\" target=\"_blank\" rel=\"noopener\">Stereoselective conjugate cyanation of enals by combining photoredox and organocatalysis<\/a> (<em>Nature Catalysis<\/em> <strong>2023<\/strong>, DOI: 10.1038\/s41929-023-00939-y)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u7684\u9009\u62e9\u6027\u662f\u6709\u673a\u5316\u5b66\u7684\u76ee\u6807\u3002\u7ecf\u8fc7\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u52aa\u529b\uff0c\u76ee\u524d\u5728\u5b9e\u73b0\u7acb\u4f53\u63a7\u5236\u9886\u57df\u5df2\u7ecf\u53d6\u5f97\u4e86\u8f83\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u5bf9\u5e95\u7269\u5185\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u8f6c\u5316\uff08\u5316\u5b66\u9009\u62e9\u6027\uff09&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-250167","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250167"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250167"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250167\/revisions"}],"predecessor-version":[{"id":250173,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250167\/revisions\/250173"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250167"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250167"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250167"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}