{"id":250380,"date":"2023-05-14T05:58:41","date_gmt":"2023-05-13T21:58:41","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=250380"},"modified":"2023-05-11T12:00:06","modified_gmt":"2023-05-11T04:00:06","slug":"appl-catal-b-%ef%bc%9a%e9%92%99%e9%92%9b%e7%9f%bf%e5%9f%ba%e7%ba%b3%e7%b1%b3%e5%a4%8d%e5%90%88%e7%89%a9%e5%9c%a8%e5%8f%af%e9%80%86%e8%b4%a8%e5%ad%90%e9%99%b6%e7%93%b7%e7%94%b5%e6%b1%a0%e4%b8%ad","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=250380","title":{"rendered":"Appl. Catal. B.\uff1a\u9499\u949b\u77ff\u57fa\u7eb3\u7c73\u590d\u5408\u7269\u5728\u53ef\u9006\u8d28\u5b50\u9676\u74f7\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\u00a0<\/strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5f90\u73ab\u7470\u535a\u58eb\u3001\u9999\u6e2f\u79d1\u6280\u5927\u5b66<\/strong>Francesco Ciucci<\/strong>\u6559\u6388\u4ee5\u53ca\u6fb3\u5927\u5229\u4e9a\u79d1\u5ef7\u5927\u5b66\u90b5\u5b97\u5e73\u6559\u6388<\/strong>\u7b49\u4eba\u4ece\u5b9e\u9a8c\u548c\u7406\u8bba\u4e0a\u8bc1\u660e\u4e86\u4e3b\u8981\u7531\u8fc7\u6c27\u5316\u7269\u76f8\uff08D-BCFZYN\uff09\u548c\u4e00\u4e2a\u6b21\u8981\u7684NiO\u76f8\u7ec4\u6210\u7eb3\u7c73\u590d\u5408\u6750\u6599Ba0.95<\/sub>(Co0.4<\/sub>Fe0.4<\/sub>Zr0.1<\/sub>Y0.1<\/sub>)0.95<\/sub>Ni0.05<\/sub>O3-\u03b4<\/sub>\uff08BCFZYN\uff09\u5177\u6709\u4f18\u5f02\u7684OER\u6d3b\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cNiO\u7eb3\u7c73\u9897\u7c92\u589e\u5f3a\u4e86\u5bf9\u6c34\u6c7d\u7684\u5438\u9644\uff0c\u800cD-BCFZYN\u52a0\u901f\u4e86\u6c27\u7684\u89e3\u5438\u548c\u8d28\u5b50\u4f20\u5bfc\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86OER\u52a8\u529b\u5b66\u3002\u7531BCFZYN\u7a7a\u6c14\u7535\u6781\u7ec4\u88c5\u7684\u7535\u6c60\u57281.3V\u548c600\u2103\u4e0b\u5b9e\u73b0\u4e86-1267 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u540c\u65f6\u4fdd\u6301\u4e86372\u5c0f\u65f6\u7684\u9ad8\u8010\u4e45\u6027\u3002\u76f8\u5e94\u7684\u7535\u6c60\u5728\u71c3\u6599\u7535\u6c60\u548c\u7535\u89e3\u6a21\u5f0f\u4e4b\u95f4\u7684\u5faa\u73af\u6a21\u5f0f\u4e0b\u8fd0\u884c\u7a33\u5b9a\uff0c\u8fd9\u8868\u660e\u8be5\u590d\u5408\u6750\u6599\u4f5c\u4e3ar-PCCs\u7684\u7a7a\u6c14\u7535\u6781\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cHigh-temperature water oxidation activity of a perovskite-based nanocomposite towards application as air electrode in reversible protonic ceramic cells<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aApplied Catalysis B: Environmental<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u5408\u6210\u4e86\u7eb3\u7c73\u590d\u5408\u6750\u6599BCFZYN\uff0c\u5e76\u901a\u8fc7\u5b9e\u9a8c\u548c\u7406\u8bba\u8bc1\u5b9e\u5176\u4f18\u5f02\u7684OER\u6d3b\u6027\uff1b<\/p>\n

2\u3001\u7531BCFZYN\u7a7a\u6c14\u7535\u6781\u7ec4\u88c5\u7684\u7535\u6c60\u57281.3V\u548c600\u2103\u4e0b\u5b9e\u73b0\u4e86-1267 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u540c\u65f6\u4fdd\u6301\u4e86372\u5c0f\u65f6\u7684\u9ad8\u8010\u4e45\u6027\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0 <\/strong>\u76f8\u7ed3\u6784\u548c<\/strong>OER<\/strong>\u6d3b\u6027\u5206\u6790<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09\u4ee5BZCYYb\u4e3a\u57fa\u7840\uff0c\u4ee5BCFZY\u548cBCFZYN\u4e3a\u7535\u6781\uff0c\u572830 vol% H2<\/sub>O-N2<\/sub>\u6761\u4ef6\u4e0b\u7684\u5bf9\u79f0\u7535\u6c60\u7684Rp\u503c\u7684Arrhenius\u56fe\u3002<\/p>\n

\uff08b\uff09BCFZYN\u548cBCFZY\u7535\u6781\u5728550 o<\/sup>C\u7684DRT\u3002<\/p>\n

\uff08c\uff09\u4ee5BZCYYb\u4e3a\u57fa\u7840\uff0c\u4ee5BCFZY\u548cBCFZYN\u4e3a\u7535\u6781\uff0c\u572830 vol% H2<\/sub>O-Air\u4e0b\u7684\u5bf9\u79f0\u7535\u6c60\u7684Rp\u503c\u7684Arrhenius\u56fe\u3002<\/p>\n

\uff08d\uff09BCFZYN\u548cBCFZY\u7535\u6781\u5728550 o<\/sup>C\u4e0b\u7684DRT\u3002<\/p>\n

\uff08e\uff09\u4ee5BCFZYN\u548cBCFZY\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u7684\u7535\u6c60\u5728500\u548c600 o<\/sup>C\u7684\u7535\u89e3\u6a21\u5f0f\u4e0b\u7684I-V\u66f2\u7ebf\u3002<\/p>\n

\uff08f\uff09BCFZY\u3001BCFZYN\u548c\u5176\u4ed6\u7a7a\u6c14\u7535\u6781\u57281.3V\u4e0b\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

 <\/p>\n

\"\"\u00a0<\/strong><\/p>\n

\u56fe<\/strong>2 \u00a0DFT<\/strong>\u5206\u6790<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09\u8ba1\u7b97\u7684BCFZY-Co11\u3001\u539f\u59cbBCFZYN\u548cD-BCFZYN\u9499\u949b\u77ff\u7684\u6c27\u7a7a\u4f4d\u5f62\u6210\u80fdE<\/em>F<\/sup>Vo<\/sub>\u548c\u6c34\u5408\u80fdE<\/em>hydr<\/sub>\u3002<\/p>\n

\uff08b\uff09BCFZY-Co11\u3001\u539f\u59cbBCFZYN\u548cD-BCFZYN\u9499\u949b\u77ff\u7684\u7535\u5b50\u6001\u5bc6\u5ea6\u3002<\/p>\n

\uff08c\uff09BCFZY-Co11\u548cD-BCFZYN\u9499\u949b\u77ff\u7684OER\/ORR\u53cd\u5e94\u9014\u5f84\u548c\u81ea\u7531\u80fd\u3002<\/p>\n

\uff08d\uff09BCFZY-Co11\u3001D-BCFZYN\u9499\u949b\u77ff\u548cNiO\u8868\u9762\u7684H2<\/sub>O\u548cO2<\/sub>\u5438\u9644\u80fd\u3002<\/p>\n

\uff08e\uff09\u7eb3\u7c73\u590d\u5408\u6750\u6599BCFZYN\u7a7a\u6c14\u7535\u6781\u8868\u9762OER\/ORR\u8fc7\u7a0b\u7684\u53ef\u80fd\u53cd\u5e94\u673a\u7406\u56fe\u793a\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 \u00a0<\/strong>\u76f8\u7ed3\u6784\u548c\u8fd0\u884c\u7a33\u5b9a\u6027<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09BCFZYN\u572830% H2<\/sub>O-\u7a7a\u6c14\u5904\u7406\u524d\u540e\u7684XRD\u3002<\/p>\n

\uff08b\uff09BCFZYN\u66b4\u9732\u4e8e30% H2<\/sub>O-\u7a7a\u6c14\u4e2d100\u5c0f\u65f6\u7684Rietveld\u7ec6\u5316\u5206\u6790\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540c\u50ac\u5316\u5242\u4e2d\u7684OV<\/sub>\u6bd4\u4f8b\u3002<\/p>\n

\uff08d\uff09\u5177\u6709BCFZYN\u548cBCFZY\u7535\u6781\u7684\u5bf9\u79f0\u7535\u6c60\u5728550\u2103\u300130% H2<\/sub>O-\u7a7a\u6c14\u4e0b\u7684\u957f\u671f\u8fd0\u884c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 \u00a0ORR<\/strong>\u6d3b\u6027\u548c<\/strong>r-PCC<\/strong>\u5206\u6790<\/strong> \u00a9 2023 Elsevier<\/strong><\/p>\n

\uff08a\uff09Ni-BZCYYb|BZCYYb|BCFZYN\u7ebd\u6263\u7535\u6c60\u5728450-600 \u2103\u7684H2<\/sub>\/\u5e72\u71e5\u5408\u6c14\u4e2d\u3001\u71c3\u6599\u7535\u6c60\u6a21\u5f0f\u4e0b\u7684I-V\u548cI-P\u66f2\u7ebf\u3002<\/p>\n

\uff08b\uff09\u4ee5BCFZYN\u4e3a\u7a7a\u6c14\u7535\u6781\u7684\u7535\u6c60\u5728450-600 \u2103\u53ef\u9006\u6a21\u5f0f\u4e0b\u7684I-V\u66f2\u7ebf\uff0c\u7eaf\u6c22\u6c14\u4f5c\u4e3a\u71c3\u6599\u7535\u6781\uff0c\u5408\u6210\u6c14\uff085 % H2<\/sub>O-\u7a7a\u6c14\uff09\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u3002<\/p>\n

\uff08c\uff09\u5177\u6709BCFZYN\u7a7a\u6c14\u7535\u6781\u7684r-PCC\u5728550 \u2103\u4e0b\u71c3\u6599\u7535\u6c60\u548c\u7535\u89e3\u6a21\u5f0f\u4e4b\u95f4\u7684\u5faa\u73af\u8fd0\u884c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u00a0<\/strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u4ece\u5b9e\u9a8c\u548c\u7406\u8bba\u8bc1\u660e\uff0cBCFZYN\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5728\u9ad8\u6e29\u4e0b\u8d28\u5b50\u7535\u89e3\u8d28\u4e2d\u5177\u6709\u4f18\u5f02\u7684OER\u50ac\u5316\u6d3b\u6027\uff0c\u6ee1\u8db3\u4e86PCEC\u7a7a\u6c14\u7535\u6781\u7684\u53cc\u529f\u80fd\u8981\u6c42\u3002\u91c7\u7528BCFZYN\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u7684PCEC\u5728600 \u2103\u4e0b1.3 V\u7684\u7535\u89e3\u6a21\u5f0f\u4e0b\u663e\u793a\u51fa-1267 mA cm-2<\/sup>\u7684\u9ad8\u7535\u89e3\u7535\u6d41\u5bc6\u5ea6\uff0c\u540c\u65f6\u5728550 \u2103\u4e0b\u4fdd\u6301372\u5c0f\u65f6\u7684\u4f18\u5f02\u8010\u4e45\u6027\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u4f18\u5f02\u7684OER\u6d3b\u6027\u5f52\u56e0\u4e8eNiO\u7eb3\u7c73\u9897\u7c92\u4e0a\u7684\u5feb\u901f\u6c34\u6c7d\u5438\u9644\uff0c\u4ee5\u53caD-BCFZYN\u4e3b\u76f8\u7684\u5feb\u901fO2<\/sub>\u89e3\u5438\u548c\u8d28\u5b50\u4f20\u5bfc\u3002\u6b64\u5916\uff0c\u5177\u6709BCFZYN\u7a7a\u6c14\u7535\u6781\u7684r-PCC\u5728\u71c3\u6599\u7535\u6c60\u548c\u7535\u89e3\u6a21\u5f0f\u4e4b\u95f4\u7684194\u5c0f\u65f6\u5faa\u73af\u6a21\u5f0f\u4e2d\u5b9e\u73b0\u4e86\u5353\u8d8a\u7684\u8010\u4e45\u6027\uff0c\u8bc1\u660e\u4e86BCFZYN\u5728r-PCCs\u6280\u672f\u4e2d\u7528\u4f5c\u7a7a\u6c14\u7535\u6781\u7684\u9ad8\u6f5c\u529b\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aHigh-temperature water oxidation activity of a perovskite-based nanocomposite towards application as air electrode in reversible protonic ceramic cells<\/a> (Applied Catalysis B: Environmental<\/em> 2023<\/strong>, 331<\/em>, 122682)<\/p>\n

\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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