{"id":250964,"date":"2023-06-06T06:26:00","date_gmt":"2023-06-05T22:26:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=250964"},"modified":"2023-06-05T18:26:08","modified_gmt":"2023-06-05T10:26:08","slug":"angew%ef%bc%9a%e6%9d%a1%e4%bb%b6%e6%b8%a9%e5%92%8c%e3%80%81%e9%ab%98%e6%95%88%e3%80%81%e9%ab%98%e9%80%89%e6%8b%a9%e6%80%a7%ef%bc%81%e5%82%ac%e5%8c%96%e5%b0%bc%e9%be%99-6%e8%a7%a3%e8%81%9a%e6%96%b0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=250964","title":{"rendered":"Angew\uff1a\u6761\u4ef6\u6e29\u548c\u3001\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\uff01\u50ac\u5316\u5c3c\u9f99-6\u89e3\u805a\u65b0\u673a\u5236"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u73b0\u4ee3\u793e\u4f1a\u4e25\u91cd\u4f9d\u8d56\u4ee5\u5851\u6599\u4e3a\u57fa\u7840\u7684\u6750\u6599\uff0c\u5176\u4ea7\u91cf\u9010\u5e74\u9012\u589e\u3002\u4ece2002\u5e74\u52302018\u5e74\uff0c\u5851\u6599\u7684\u4ea7\u91cf\u7ffb\u4e86\u4e00\u756a\uff0c\u8fbe\u52303.95\u4ebf\u5428\uff0c\u9884\u8ba1\u52302050\u5e74\u5c06\u589e\u957f\u81f312\u4ebf\u5428\u3002\u7136\u800c\uff0c\u968f\u7740\u5851\u6599\u5236\u54c1\u7684\u4f7f\u7528\uff0c\u5e9f\u5f03\u5851\u6599\u5806\u79ef\u548c\u5316\u77f3\u539f\u6599\u7684\u5927\u91cf\u6d88\u8017\u5bf9\u5168\u7403\u73af\u5883\u548c\u80fd\u6e90\u9020\u6210\u4e86\u6781\u5927\u7684\u8d1f\u62c5\u3002\u5728\u627f\u53d7\u6076\u52a3\u7684\u673a\u68b0\u548c\u73af\u5883\u6761\u4ef6\u5e94\u7528\u7684\u6750\u6599\u4e2d\uff0c\u5de5\u7a0b\u5851\u6599\u5982\u805a\u9170\u80fa\u4f7f\u7528\u8f83\u4e3a\u5e7f\u6cdb\u3002\u5c3c\u9f99-6\u662f\u4e00\u79cd\u70ed\u5851\u6027\u805a\u9170\u80fa\uff0c\u7531\u025b-\u5df1\u5185\u9170\u80fa\u7684\u6c34\u8f85\u52a9\u5f00\u73af\u805a\u5408\uff08ROP\uff09\u751f\u4ea7\u3002\u7531\u4e8e\u5176\u7269\u7406\u548c\u5316\u5b66\u7279\u6027\uff0c\u5305\u62ec\u5f39\u6027\u3001\u9ad8\u62c9\u4f38\u5f3a\u5ea6\u3001\u9ad8\u5316\u5b66\u548c\u8010\u78e8\u6027\uff0c\u5c3c\u9f99-6\u662f\u8bb8\u591a\u5e94\u7528\u4e2d\u7684\u9996\u9009\u6750\u6599\uff0c\u5e02\u573a\u4ef7\u503c\u5de8\u5927\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u7279\u6027\u4e5f\u963b\u788d\u4e86\u5c3c\u9f99-6\u7684\u751f\u7269\u964d\u89e3\uff0c\u5bfc\u81f4\u5176\u5728\u5783\u573e\u586b\u57cb\u573a\u548c\u73af\u5883\u4e2d\u7684\u5927\u91cf\u5806\u79ef\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u7f8e\u56fd\u897f\u5317\u5927\u5b66<\/strong><strong>Yosi Kratish<\/strong><strong>\u6559\u6388\u4e0e<\/strong><strong>Tobin J. Marks<\/strong><strong>\u6559\u6388<\/strong>\u8054\u5408\uff0c\u901a\u8fc7\u5e02\u552e\u6613\u5f97\u7684\u9567\u7cfb\u5143\u7d20\u4e09\u9170\u80fa\u57fa\u50ac\u5316\u5242Ln(N(TMS)<sub>2<\/sub>)<sub>3<\/sub>\u9009\u62e9\u6027\u5c06\u5c3c\u9f99-6\u89e3\u805a\u4e3a\u5176\u6bcd\u4f53\u5355\u4f53\u025b-\u5df1\u5185\u9170\u80fa\u3002\u89e3\u805a\u8fc7\u7a0b\u65e0\u9700\u6eb6\u5242\u53c2\u4e0e\u3001\u53cd\u5e94\u8f83\u5b8c\u5168\u4e14\u5177\u6709\u9ad8\u5ea6\u9009\u62e9\u6027\uff0c\u540c\u65f6\u5177\u6709\u6700\u4f4e\u7684\u6587\u732e\u62a5\u9053\u6e29\u5ea6\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u4e0d\u540c\u9567\u7cfb\u5143\u7d20\u4e09\u9170\u80fa\u50ac\u5316\u5242\uff08Ln<sup>NTMS<\/sup>\uff09\u7684\u50ac\u5316\u6d3b\u6027\u968f\u7740Ln<sup>3+<\/sup>\u79bb\u5b50\u534a\u5f84\u7684\u589e\u52a0\u800c\u589e\u52a0\uff0c\u5e76\u4e14\u5bf9\u4f7f\u7528\u540e\u7684\u5c3c\u9f99-6\u4ee5\u53ca\u5c3c\u9f99-6+\u805a\u4e59\u70ef\u3001\u805a\u4e19\u70ef\u6216\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f\u6df7\u5408\u7269\u7684\u89e3\u805a\u90fd\u975e\u5e38\u6709\u6548\u3002\u5b9e\u9a8c\u52a8\u529b\u5b66\u6570\u636e\u548cDFT\u5206\u6790\u8868\u660e\uff0c\u9996\u5148\u5c3c\u9f99\u672b\u7aef\u9170\u80fa\u7684N-H\u952e\u53bb\u8d28\u5b50\u5316\uff0c\u7136\u540e\u5c06\u50ac\u5316\u5242\u5171\u4ef7\u7ed3\u5408\u5230\u805a\u5408\u7269\u4e0a\uff0c\u6700\u540e\u662f\u94fe\u7aef\u56de\u54ac\u5408\u8fc7\u7a0b\uff0c\u5728\u8be5\u8fc7\u7a0b\u4e2d\uff0c\u025b-\u5df1\u5185\u9170\u80fa\u5355\u5143\u4ece\u94fe\u7aef\u4f9d\u6b21\u8131\u843d\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Selective Lanthanide-Organic Catalyzed Depolymerization of Nylon- 6 to \u025b-Caprolactam<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a<strong><em>Angew. Chem. Int. Ed.<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250965\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/0-8.png\" alt=\"\" width=\"600\" height=\"182\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/0-8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/0-8-300x91.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u5e02\u552e\u6613\u5f97\u7684\u9567\u7cfb\u53ef\u4ee5\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\uff0c\u9ad8\u9009\u62e9\u9ad8\u6548\u50ac\u5316\u5c3c\u9f99-6\u89e3\u805a\u4e3a\u025b-\u5df1\u5185\u9170\u80fa\u5355\u4f53\uff0c\u968f\u540e\u63ed\u793a\u5176\u53cd\u5e94\u673a\u5236\u5e76\u9ad8\u6548\u5e94\u7528\u4e8e\u4f7f\u7528\u540e\u7684\u5c3c\u9f99-6\u548c\u6df7\u5408\u5851\u6599\uff08\u5982PP\u3001PE\u548cPET\uff09\u964d\u89e3\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250966\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/1-11.png\" alt=\"\" width=\"600\" height=\"755\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/1-11.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/1-11-238x300.png 238w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>\u5c3c\u9f99<\/strong><strong>-6<\/strong><strong>\u7684\u5316\u5b66\u964d\u89e3\u65b9\u6cd5<\/strong><strong> \u00a9 2022 Wiley-VCH GmbH<\/strong><\/p>\n<p>\u5c3c\u9f99-6\u5728\u79bb\u5b50\u6db2\u4f53\u4e2d\u89e3\u805a\u3001\u6c22\u5316\u89e3\u805a\u4e0e\u672c\u7814\u7a76\u7684\u5bf9\u6bd4\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250967\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/2-9.png\" alt=\"\" width=\"600\" height=\"471\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/2-9.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/2-9-300x236.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 \u00a0<\/strong><strong>\u4e0d\u540c<\/strong><strong>Ln<sup>NTMS<\/sup><\/strong><strong>\u50ac\u5316\u5242\u7684\u5df1\u5185\u9170\u80fa\u4ea7\u91cf\u4e0e\u5176\u79bb\u5b50\u534a\u5f84\u7684\u5173\u7cfb<\/strong><strong> \u00a9 2022 Wiley-VCH GmbH<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250968\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/3-11.png\" alt=\"\" width=\"600\" height=\"593\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/3-11.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/3-11-300x297.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>3 \u00a0<\/strong><strong>\u53cd\u5e94\u52a8\u529b\u5b66\u7814\u7a76<\/strong><strong> \u00a9 2022 Wiley-VCH GmbH<\/strong><\/p>\n<p>\uff08a\uff09\u53cd\u5e94\u65f6\u95f4\u5bf9\u025b-\u5df1\u5185\u9170\u80fa\u6536\u7387\u7684\u5f71\u54cd\u3002<\/p>\n<p>\uff08b\uff09\u5c3c\u9f99-6\u7684\u7ed3\u6784\u53ca\u4e0eLa<sup>NTMS<\/sup>\u50ac\u5316\u5242\u7684\u7ed3\u5408\u3002<\/p>\n<p>\uff08c\uff09\u50ac\u5316\u5242\u8d1f\u8f7d\u5bf9\u5df1\u5185\u9170\u80fa\u4ea7\u7387\u7684\u5f71\u54cd\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250969\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/4-10.png\" alt=\"\" width=\"600\" height=\"326\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/4-10.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/4-10-300x163.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 \u00a0<\/strong><strong>\u50ac\u5316\u5242\u7684<\/strong><strong>DFT<\/strong><strong>\u8ba1\u7b97\u6a21\u62df<\/strong><strong> \u00a9 2022 Wiley-VCH GmbH<\/strong><\/p>\n<p>(TMS<sub>2<\/sub>N)<sub>3<\/sub>La (La<sup>NTMS<\/sup>)\u7684\u6676\u4f53X\u5c04\u7ebf\u884d\u5c04\u4ee5\u53ca\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7684\u5173\u952e\u5316\u5b66\u952e\u7684\u952e\u957f\u548c\u952e\u89d2\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250970\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/5-6.png\" alt=\"\" width=\"600\" height=\"363\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/5-6.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/05\/5-6-300x182.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5 \u00a0<\/strong><strong>\u5c3c\u9f99<\/strong><strong>-6<\/strong><strong>\u89e3\u805a\u673a\u7406\u7684<\/strong><strong>DFT<\/strong><strong>\u5206\u6790<\/strong><strong> \u00a9 2022 Wiley-VCH GmbH<\/strong><\/p>\n<p>\uff08a\uff09\u8ba1\u7b97\u5c3c\u9f99-6\u6a21\u578b\u53cd\u5e94\u3002<\/p>\n<p>\uff08b\uff09\u5c3c\u9f99\u914d\u4f4d\u3002<\/p>\n<p>\uff08c\uff09\u53ef\u80fd\u7684\u89e3\u805a\u673a\u7406\u3002<\/p>\n<p>\uff08d\uff09\u8ba1\u7b97\u7684\u8fc7\u6e21\u6001\u7ed3\u6784\u3002<\/p>\n<p>\uff08e\uff09\u8ba1\u7b97\u7684\u6eb6\u6db2\u76f8\u7113\u503c\uff0c\u5355\u4f4d\u4e3akcal mol<sup>-1<\/sup>\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u5c55\u793a\u4e86\u4e00\u79cd\u57fa\u4e8e\u5e02\u552e\u6613\u5f97\u7684\u9567\u7cfb\u4e09\u9170\u80fa\u7684\u65b0\u50ac\u5316\u7cfb\u7edf\uff0c\u9ad8\u9009\u62e9\u5feb\u901f\u50ac\u5316\u5c3c\u9f99-6\u89e3\u805a\u6210\u5b83\u7684\u5de5\u4e1a\u524d\u4f53\uff0c\u025b-\u5df1\u5185\u9170\u80fa\u3002\u8fc7\u7a0b\u65e0\u9700\u6eb6\u5242\u53c2\u4e0e\u3001\u53cd\u5e94\u8f83\u5b8c\u5168\u4e14\u5177\u6709\u9ad8\u5ea6\u9009\u62e9\u6027\uff0c\u540c\u65f6\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u50ac\u5316\u6d3b\u6027\u4e0e\u9567\u7cfb\u79bb\u5b50\u7684\u79bb\u5b50\u534a\u5f84\u76f8\u5173\uff0c\u542b\u6709\u8f83\u5927\u534a\u5f84\u9567\u7cfb\u91d1\u5c5e\u79bb\u5b50\u7684\u590d\u5408\u7269\u663e\u793a\u51fa\u66f4\u9ad8\u7684\u6d3b\u6027\u3002\u8be5\u5de5\u827a\u8fd8\u4e0e\u4f7f\u7528\u540e\u7684\u5c3c\u9f99-6\u548c\u6df7\u5408\u5851\u6599\uff08\u5982PP\u3001PE\u548cPET\uff09\u517c\u5bb9\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u673a\u7406\u5206\u6790\u8868\u660e\uff0c\u8be5\u53cd\u5e94\u662f\u901a\u8fc7\u4e00\u79cd\u65b0\u7684\u673a\u5236\u8fdb\u884c\u7684\uff0c\u5176\u4e2d\u6d89\u53ca\u5c3c\u9f99\u9170\u80faN-H\u952e\u7684\u521d\u59cb\u53bb\u8d28\u5b50\u5316\u6b65\u9aa4\uff0c\u8be5\u6b65\u9aa4\u5c06\u50ac\u5316\u5242\u4e0e\u805a\u5408\u7269\u5171\u4ef7\u7ed3\u5408\uff0c\u968f\u540e\u662f\u4e3b\u8981\u7684\u94fe\u7aef\u56de\u54ac\u5408\u6b65\u9aa4\uff0c\u4f34\u968f\u7740\u025b-\u5df1\u5185\u9170\u80fa\u5355\u5143\u4f9d\u6b21\u4ece\u94fe\u7aef\u8131\u843d\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202212543\" target=\"_blank\" rel=\"noopener\">Selective Lanthanide-Organic Catalyzed Depolymerization of Nylon- 6 to \u025b-Caprolactam<\/a> (<em>Angew. Chem. Int. Ed.<\/em> <strong>2023<\/strong>, <em>62<\/em>, e202212543)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u73b0\u4ee3\u793e\u4f1a\u4e25\u91cd\u4f9d\u8d56\u4ee5\u5851\u6599\u4e3a\u57fa\u7840\u7684\u6750\u6599\uff0c\u5176\u4ea7\u91cf\u9010\u5e74\u9012\u589e\u3002\u4ece2002\u5e74\u52302018\u5e74\uff0c\u5851\u6599\u7684\u4ea7\u91cf\u7ffb\u4e86\u4e00\u756a\uff0c\u8fbe\u52303.95\u4ebf\u5428\uff0c\u9884\u8ba1\u52302050\u5e74\u5c06\u589e\u957f\u81f312\u4ebf&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-250964","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250964"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250964"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250964\/revisions"}],"predecessor-version":[{"id":250971,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/250964\/revisions\/250971"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250964"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250964"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250964"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}