{"id":252092,"date":"2023-06-16T06:00:02","date_gmt":"2023-06-15T22:00:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=252092"},"modified":"2023-06-15T16:12:22","modified_gmt":"2023-06-15T08:12:22","slug":"%e4%b8%87%e4%bd%b3%e9%9b%a8%e8%af%be%e9%a2%98%e7%bb%84acs-energy-lett-%e8%b6%85%e5%bf%ab%e5%9b%9e%e6%94%b6%e5%ba%9f%e6%97%a7%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%ad%a3%e6%9e%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=252092","title":{"rendered":"\u4e07\u4f73\u96e8\u8bfe\u9898\u7ec4ACS Energy Lett.: \u8d85\u5feb\u56de\u6536\u5e9f\u65e7\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781"},"content":{"rendered":"<p><strong>\u3010\u5168\u6587\u901f\u89c8\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea\u4e8e\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u4e07\u4f73\u96e8\u526f\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u5728\u9502\u79bb\u5b50\u7535\u6c60\u56de\u6536\u9886\u57df\u4e2d\u5bf9\u6b63\u6781\u6750\u6599\u7684\u8d85\u5feb\u56de\u6536\u7684\u6700\u65b0\u5de5\u4f5c\u6210\u679c\u3002\u8be5\u56e2\u961f\u5f00\u53d1\u7684\u8d85\u5feb\u4fee\u590d\u6cd5\u53ef\u4ee5\u57288s\u5185\u9ad8\u6548\u5730\u76f4\u63a5\u4fee\u590d\u5e9f\u65e7\u7535\u6c60\u6b63\u6781\u6750\u6599\uff08LCO\uff09\uff0c\u4fee\u590d\u540e\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u4e0e\u65b0\u5236\u5907\u7684\u6b63\u6781\u6750\u6599\u6027\u80fd\u76f8\u5f53\u3002\u6b64\u9879\u5173\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u4fee\u590d\u7814\u7a76\uff0c\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53ef\u518d\u751f\u53d1\u5c55\u548c\u8d44\u6e90\u518d\u5229\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u6548\u3001\u8282\u80fd\u7684\u65b9\u6cd5\u3002\u7814\u7a76\u6210\u679c\u4ee5\u201c<span class=\"hlFld-Title\">Rapid, Direct Regeneration of Spent LiCoO<sub>2<\/sub>\u00a0Cathodes for Li-Ion Batteries\u201d\u4e3a\u9898\u53d1\u8868\u4e8eACS Energy Lett\u3002\u7b2c\u4e00\u4f5c\u8005\u5c39\u4e91\u8d85\u3001\u674e\u8d85\uff0c\u901a\u8baf\u4f5c\u8005\u4e07\u4f73\u96e8\u526f\u6559\u6388\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-252096\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-1-9.png\" alt=\"\" width=\"700\" height=\"222\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-1-9.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-1-9-300x95.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09\u5177\u6709\u9ad8\u7535\u538b\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u957f\u7b49\u7279\u70b9\uff0c\u5728\u5404\u79cd\u7535\u5b50\u4ea7\u54c1\u3001\u7535\u52a8\u6c7d\u8f66\u548c\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u968f\u7740\u65b0\u80fd\u6e90\u6280\u672f\u548c\u7535\u5b50\u5de5\u4e1a\u7684\u5feb\u901f\u53d1\u5c55\uff0cLIBs\u7684\u6d88\u8017\u91cf\u5448\u7206\u53d1\u5f0f\u589e\u957f\u3002\u7531\u4e8eLIB\u7684\u5bff\u547d\u6709\u9650\uff0c\u5728\u4e0d\u4e45\u7684\u5c06\u6765\u5c06\u4ea7\u751f\u5927\u91cf\u62a5\u5e9fLIB\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u5bf9\u5e9f\u65e7LIB\u8fdb\u884c\u56de\u6536\u5229\u7528\uff0c\u4ee5\u4fbf\u5b9e\u73b0\u8d44\u6e90\u548c\u73af\u5883\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n<p><strong>\u3010\u672c\u6587\u4eae\u70b9\u3011<\/strong><\/p>\n<p>\u53d7\u80e1\u826f\u5175\u8bfe\u9898\u7ec4\u7126\u8033\u70ed\u8d85\u5feb\u5408\u6210\u65b9\u6cd5\uff08Ultrafast High Temperature Synthesis\uff09\u7684\u542f\u53d1\uff0c\u7814\u7a76\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u8d85\u5feb\u4fee\u590d\u65b9\u6cd5\uff0c\u9996\u6b21\u8bc1\u660e\u53ef\u4ee5\u5728\u51e0\u79d2\u949f\u5185\u518d\u751f\u5e9f\u65e7\u7535\u6c60\u6b63\u6781\u6750\u6599S-LCO\u3002\u4e0e\u4f20\u7edf\u7684\u51b6\u91d1\u5de5\u827a\u548c\u57fa\u4e8e\u9ad8\u6e29\u7089\u7684\u76f4\u63a5\u4fee\u590d\u5de5\u827a\u76f8\u6bd4\uff0c\u8be5\u8d85\u5feb\u4fee\u590d\u65b9\u6cd5\u5229\u7528\u76f4\u6d41\u7535\u4ea7\u751f\u7126\u8033\u70ed\uff0c\u5177\u6709\u9ad8\u52a0\u70ed\u901f\u7387\u3001\u53ef\u8c03\u6e29\u5ea6\u548c\u9ad8\u51b7\u5374\u901f\u7387\u7684\u4f18\u70b9\uff0c\u53ef\u4ee5\u5927\u5927\u51cf\u5c11\u4e0d\u53ef\u907f\u514d\u7684\u70ed\u8017\u6563\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cURM\u7684\u53cd\u5e94\u6e29\u5ea6\u76f8\u5bf9\u9ad8\u4e8e\u5176\u4ed6\u4f20\u7edf\u56de\u6536\u65b9\u6cd5\uff0c\u4f7fS-LCO\u53ef\u4ee5\u57288\u79d2\u5185\u5f97\u5230\u5feb\u901f\u4fee\u590d\u3002\u8fc7\u7a0b\u7684\u5feb\u901f\u4e0d\u4ec5\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u4e86\u9502\u6e90\u5728\u9ad8\u6e29\u4e0b\u7684\u6325\u53d1\u635f\u5931\uff0c\u800c\u4e14\u907f\u514d\u4e86\u9502\u6e90\u7684\u7194\u5316\u8fc7\u7a0b\u548c\u4e0e\u5bb9\u5668\u4e4b\u95f4\u53ef\u80fd\u53d1\u751f\u7684\u8150\u8680\u53cd\u5e94\u3002\u5c3d\u7ba1\u53cd\u5e94\u8fc7\u7a0b\u5feb\u901f\uff0c\u4f46\u5e9f\u65e7\u6b63\u6781\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u53ef\u4ee5\u5b8c\u5168\u6062\u590d\uff0c\u5176\u4e2d\u5728\u957f\u671f\u5faa\u73af\u5f62\u6210\u7684\u5c16\u6676\u77f3Co<sub>3<\/sub>O<sub>4<\/sub>\u5df2\u5168\u90e8\u8f6c\u5316\u4e3a\u5c42\u72b6\u7ed3\u6784\u7684LCO\u3002\u518d\u751f\u94b4\u9178\u9502\u7684\u7535\u5316\u5b66\u6027\u80fd\u53ef\u4e0e\u5546\u4e1a\u6b63\u6781\u6750\u6599\u76f8\u5ab2\u7f8e\u3002\u6240\u5f00\u53d1\u7684\u65b9\u6cd5\u662f\u4e00\u79cd\u9ad8\u6548\u4e14\u53ef\u80fd\u901a\u7528\u7684\u7535\u6c60\u6b63\u6781\u518d\u751f\u65b9\u6cd5\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u6790\u3011<\/strong><\/p>\n<p>\uff081\uff09\u00a0\u8d85\u5feb\u4fee\u590d\u6cd5\u7684\u4f18\u52bf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-252098\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-3-8.png\" alt=\"\" width=\"700\" height=\"777\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-3-8.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/\u56fe\u7247-3-8-270x300.png 270w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe1\u00a0\u4e2d\u7814\u7a76\u8005\u5f00\u53d1\u4e86\u65b0\u578b\u7684\u8d85\u5feb\u4fee\u590d\u6cd5\u7528\u4ee5\u5feb\u901f\u4fee\u590d\u6b63\u6781\u6750\u6599\u3002\u76f8\u6bd4\u4f20\u7edf\u7684\u4fee\u590d\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u53ef\u4ee5\u57288s\u5185\u5b9e\u73b0\u6b63\u6781\u6750\u6599\u7684\u4fee\u590d\uff0c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u4e0d\u5fc5\u8981\u7684\u80fd\u8017\u548c\u64cd\u4f5c\u65f6\u95f4\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u53cd\u5e94\u65f6\u95f4\u77ed\uff0c\u6240\u4ee5\u5f88\u597d\u5730\u907f\u514d\u957f\u65f6\u95f4\u9ad8\u6e29\u4e0b\u9502\u6e90\u6325\u53d1\u7684\u95ee\u9898\u3002<\/p>\n<p>\u56fe1.\u00a0(a) \u8d85\u5feb\u4fee\u590d\u8fc7\u7a0b\u548c (b) \u7194\u7089\u4fee\u590d\u65b9\u6cd5\u7684\u793a\u610f\u56fe\uff1b (c) \u518d\u751f\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b (d) S-LCO\u4fee\u590d\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b (e) S-LCO\u7684SEM\u56fe\uff1b (f) S-LCO \u548c URM-LCO \u7684 XRD \u56fe\uff1b (g) \u4e0d\u540c\u518d\u751f\u8fc7\u7a0b\u7684\u80fd\u8017\u548c\u8fd0\u884c\u65f6\u95f4\u3002<\/p>\n<p>\uff082\uff09\u6b63\u6781\u6750\u6599\u7ed3\u6784\u7684\u4fee\u590d<\/p>\n<p>\u56fe2\u4e2d\u7814\u7a76\u8005\u5bf9\u4fee\u590d\u524d\u540e\u6b63\u6781\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81\u53d1\u73b0\u7531\u4e8e\u957f\u65f6\u95f4\u7684\u7535\u5316\u5b66\u5faa\u73af\u6b63\u6781\u6750\u6599\u7684\u7ed3\u6784\u53d1\u751f\u6539\u53d8\uff0c\u90e8\u5206\u5f62\u6210\u4e86\u5c16\u6676\u77f3\u76f8\u7684Co<sub>3<\/sub>O<sub>4<\/sub>\u3002\u800c\u901a\u8fc7\u8d85\u5feb\u4fee\u590d\u6cd5\u4e4b\u540e\u5f97\u5230\u7684\u6b63\u6781\u6750\u6599\u5219\u5b8c\u5168\u6062\u590d\u4e3a\u5b8c\u7f8e\u7684\u5c42\u72b6\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-252100\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/000.png\" alt=\"\" width=\"700\" height=\"706\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/000.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/000-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/000-297x300.png 297w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe2. \u4fee\u590d\u524d\u540e\u6b63\u6781\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81<\/p>\n<p>\uff083\uff09\u7f3a\u9677\u7c7b\u578b\u5206\u6790<\/p>\n<p>\u56fe3\u4e2d\u7814\u7a76\u8005\u4f18\u5316\u4fee\u590d\u8fc7\u7a0b\u4e2d\u7684\u6e29\u5ea6\u3002\u968f\u7740\u53cd\u5e94\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u6dfb\u52a0\u9502\u6e90\u7684\u6837\u54c1\u5168\u90e8\u90fd\u8868\u73b0\u51fa\u5c42\u72b6\u7ed3\u6784\uff0c\u6ca1\u6709\u5176\u4ed6\u6742\u8d28\u5cf0\u7684\u51fa\u73b0\u3002\u800c\u5f53\u6e29\u5ea6\u4e3a1440K\u65f6\uff0c\u7535\u5316\u5b66\u6027\u8d28\u8868\u73b0\u51fa\u6700\u4f18\u6027\u80fd\u3002\u6ce8\u610f\u5230\uff0c\u8d85\u5feb\u4fee\u590d\u6cd5\u4e2d\u4f7f\u7528\u7684\u6e29\u5ea6\u660e\u663e\u9ad8\u4e8e\u4f20\u7edf\u65b9\u6cd5\u4f7f\u7528\u7684\u6e29\u5ea6\uff0c\u8fd9\u6709\u5229\u4e8e\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\u3002\u53e6\u5916\uff0c\u76ee\u524d\u7814\u7a76\u5df2\u7ecf\u8868\u660e\u5728\u6240\u6709\u6e29\u5ea6\u4e0b\u5c42\u72b6\u7ed3\u6784\u7684LCO\u5177\u6709\u8f83\u4f4e\u7684\u81ea\u7531\u80fd\u3002\u8fd9\u4e9b\u7ed3\u8bba\u8bf4\u660e\u94b4\u9178\u9502\u53ef\u4ee5\u5728\u77ed\u65f6\u95f4\u5185\u627f\u53d7\u9ad8\u6e29\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-252101\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/001.png\" alt=\"\" width=\"700\" height=\"589\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/001.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/06\/001-300x252.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe3.\u00a0(a) \u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u7684\u6e29\u5ea6\u53d8\u5316\uff1b (b) \u4e0d\u540c\u6e29\u5ea6\u4e0b\u4ee5Li<sub>2<\/sub>CO<sub>3<\/sub>\u4e3a\u9502\u6e90\u7684R-LCO\u7684XRD\u56fe\u8c31\uff1b (c) \u4e0d\u540c\u6e29\u5ea6\u4e0b\u65e0\u9502\u6e90\u518d\u751fLiCO<sub>2<\/sub>\u7684XRD\u56fe\u8c31\uff1b (d) \u4ee5Li<sub>2<\/sub>CO<sub>3<\/sub>\u4e3a\u9502\u6e90\u7684R-LCO\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd\uff1b (e) R-LCO-Li-1440\uff08\u5b9e\u7ebf\uff09\u548cR-LCO-1440\uff08\u865a\u7ebf\uff09\u5728\u4e0d\u540c\u7535\u6d41\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b (f) R-LCO-Li-T\u7684EIS\u66f2\u7ebf\uff1b (g) S-LCO\u3001R-LCO-Li-1440 \u548c R-LCO-Li-1440 \u5728 0.2 C \u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b (h) 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