{"id":252524,"date":"2023-07-02T09:13:39","date_gmt":"2023-07-02T01:13:39","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=252524"},"modified":"2023-07-02T09:13:39","modified_gmt":"2023-07-02T01:13:39","slug":"%e8%a5%bf%e5%8d%97%e7%9f%b3%e6%b2%b9%e5%a4%a7%e5%ad%a6inorg-chem-front%ef%bc%9a%e8%b6%85%e9%95%bf%e5%af%bf%e5%91%bd%e5%92%8c%e9%ab%98%e5%80%8d%e7%8e%87%e6%80%a7%e8%83%bd%e9%92%a0%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=252524","title":{"rendered":"\u897f\u5357\u77f3\u6cb9\u5927\u5b66INORG CHEM FRONT\uff1a\u8d85\u957f\u5bff\u547d\u548c\u9ad8\u500d\u7387\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u7814\u53d1"},"content":{"rendered":"

\u897f\u5357\u77f3\u6cb9\u5927\u5b66<\/strong>INORG CHEM FRONT<\/strong>\uff1a\u8d85\u957f\u5bff\u547d\u548c\u9ad8\u500d\u7387\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u7814\u53d1<\/strong><\/p>\n

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u5f00\u53d1\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5faa\u73af\u6027\u80fd\u7684\u65b0\u578b\u8d1f\u6781\u6750\u6599\u53ef\u663e\u8457\u63d0\u5347\u94a0\u79bb\u5b50\u7535\u6c60(SIBs)\u80fd\u91cf\u5bc6\u5ea6\u3002\u5728\u8be5\u9886\u57df\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u662f\u5178\u578b\u7684\u4e00\u7c7b\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u5176\u4e2d\uff0c\u9492\u57fa\u91d1\u5c5e\u786b\u5316\u7269\uff0c\u5982<\/strong>VS2<\/sub><\/strong>\u3001<\/strong>V2<\/sub>S3<\/sub><\/strong>\u3001<\/strong>V3<\/sub>S4<\/sub><\/strong>\u3001<\/strong>V5<\/sub>S8<\/sub><\/strong>\u548c<\/strong>VS4<\/sub><\/strong>\u7b49\uff0c\u56e0\u5176\u5177\u6709\u591a\u79cd\u9492\u4ef7\u6001\uff0c\u53ef\u63d0\u4f9b\u591a\u7535\u5b50\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u5728\u94a0\u57fa\u5b58\u50a8\u5668\u4ef6\u9886\u57df\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002<\/strong><\/p>\n

\u4f5c\u4e3a\u786b\u5316\u9492\u5bb6\u65cf\u7684\u4e00\u5458\uff0cVS4<\/sub>\u7531\u4e00\u4e2aV4+<\/sup>\u8fde\u63a5\u4e24\u4e2aS2<\/sub>2\u2212<\/sup>\u4e8c\u805a\u4f53\u7ec4\u6210\uff0c\u6cbfC\u8f74\u5ef6\u4f38\u5f62\u6210\u94fe\u72b6\u7ed3\u6784\uff0c\u94fe\u95f4\u8ddd\u4e3a5.83 \u00c5\u3002\u8fd9\u79cd\u5927\u7684\u94fe\u95f4\u8ddd\u4e3a\u94a0\u79bb\u5b50\u7684\u5d4c\u5165\/\u8131\u51fa\u63d0\u4f9b\u4e86\u66f4\u65b9\u4fbf\u7684\u901a\u9053\u3002\u6b64\u5916\uff0cV4+<\/sup>\u548cS2<\/sub>2\u2212<\/sup>\u5728VS4<\/sub>\u4e2d\u90fd\u53c2\u4e0e\u4e86\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u56e0\u6b64\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff081196mAh g-1<\/sup>\uff09\u3002\u7136\u800c\uff0c\u7531\u4e8eNa+<\/sup>\u5d4c\u5165\u5230VS4<\/sub>\u4e2d\u662f\u8fde\u7eed\u4e14\u591a\u6b65\u7684\u76f8\u53d8\u53cd\u5e94\uff0c\u5176\u4e2d\u6eb6\u89e3\u7684\u591a\u786b\u5316\u94a0(NaPSs<\/sub>)\u4e2d\u95f4\u4f53\u7684\u751f\u6210\u7c7b\u4f3c\u4e8e\u9502\u786b\u7535\u6c60\u4e2d\u591a\u786b\u5316\u9502\u7684\u7a7f\u68ad\u6548\u5e94\u3002\u901a\u5e38\uff0c\u901a\u8fc7\u5728VS4<\/sub>\u7ed3\u6784\u4e2d\u5f15\u5165\u78b3\u57fa\u6750\u6599\u53ef\u4ee5\u6291\u5236NaPSs<\/sub>\u7684\u6eb6\u89e3\u7a7f\u68ad\u95ee\u9898\u3002\u7136\u800c\uff0c\u78b3\u7eb3\u7c73\u6750\u6599\u7684\u975e\u6781\u6027\u548c\u5f31\u7535\u50ac\u5316\u7279\u6027\u4e0d\u5229\u4e8e\u6709\u6548\u4fdd\u6301\u5176\u957f\u671f\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u9ad8<\/strong>NaPSs<\/sub><\/strong>\u5438\u9644\u6027\u80fd\u7684\u6781\u6027\u57fa\u8d28\uff0c\u6784\u5efa\u5c42\u6b21\u5316\u7684<\/strong>VS4<\/sub><\/strong>\u7eb3\u7c73\u7ed3\u6784\uff0c\u5bf9\u4e8e\u6291\u5236<\/strong>VS4<\/sub><\/strong>\u8fde\u7eed\u76f8\u53d8\u5f15\u8d77\u7684\u7c89\u5316\u95ee\u9898\u548c\u89e3\u51b3<\/strong>NaPSs<\/sub><\/strong>\u4e2d\u95f4\u4f53\u7684\u7a7f\u68ad\u6548\u5e94\u81f3\u5173\u91cd\u8981\u3002<\/strong><\/p>\n

MXene\u662f2011\u5e74\u53d1\u73b0\u7684\u4e00\u79cd\u65b0\u7684\u4e8c\u7ef4(2D)\u8fc7\u6e21\u91d1\u5c5e\u78b3\/\u78b3\u5316\u7269\u3002\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u91d1\u5c5e\u5bfc\u7535\u6027\u3001\u4eb2\u6c34\u6027\u548c\u4f4eNa+<\/sup>\u6269\u6563\u52bf\u5792\uff0c\u5b83\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684SIB\u9633\u6781\u6750\u6599\u3002\u9492\u57faMXenes (V2<\/sub>CTx<\/sub>)\u662fMXenes\u5bb6\u65cf\u7684\u53e6\u4e00\u6210\u5458\uff0c\u5b83\u5177\u6709\u96f6\u5e26\u9699\u548c\u975e\u5e38\u9ad8\u7684\u7535\u5bfc\u7387\u3002\u6b64\u5916\uff0c\u542b\u6709<\/strong>O-<\/strong>\u672b\u7aef\u7684<\/strong>MXenes<\/strong>\u53ef\u4ee5\u4e0e\u591a\u786b\u5316\u7269\u7ed3\u5408\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u7a33\u5b9a\u53ef\u6eb6\u6027\u591a\u786b\u5316\u7269\uff0c\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/strong><\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u5728\u6b64\uff0c\u897f\u5357\u77f3\u6cb9\u5927\u5b66\u65b0\u80fd\u6e90\u4e0e\u6750\u6599\u5b66\u9662\u738b\u660e\u73ca\u526f\u6559\u6388\u548c\u674e\u661f\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u5728\u6eb6\u6db2\u4e2d\u9759\u7535\u81ea\u7ec4\u88c5\u542bVO3<\/sub>\u2212<\/sup>\u7684V2<\/sub>CTx<\/sub>\u548c\u9492\u524d\u9a71\u4f53\uff0c\u7136\u540e\u901a\u8fc7\u6eb6\u5242\u70ed\u5408\u6210\u6cd5\u539f\u4f4d\u6784\u5efa\u951a\u5b9a\u5728V2<\/sub>CTx<\/sub>\u4e0a\u7684VS4<\/sub>\u7eb3\u7c73\u7247\u3002VS4<\/sub>\u548cV2<\/sub>CTx<\/sub>\u4e4b\u95f4\u4ee5S-V-C\u952e\u76f8\u4e92\u4f5c\u7528\u6865\u63a5\u5f62\u6210\u4e86\u5f3a\u94c6\u9489\u7ed3\u6784\uff0c\u6253\u5f00\u4e86\u7535\u5b50\u4f20\u9012\u7684\u4e09\u7ef4\u901a\u9053\uff0c\u534f\u540c\u4fc3\u8fdb\u4e86\u79bb\u5b50\u6269\u6563\u548c\u7535\u8377\u4f20\u9012\u3002\u901a\u8fc7DFT\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86V2<\/sub>CTx<\/sub>\u4e0eVS4<\/sub>\u4e4b\u95f4\u5f62\u6210\u4e86\u8096\u7279\u57fa\u63a5\u89e6\u5f02\u8d28\u7ed3\uff0c\u4fc3\u8fdb\u4e86\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7535\u5b50\u4eceVS4<\/sub>\u6d41\u5411V2<\/sub>CTx<\/sub>\uff0c\u52a0\u5feb\u4e86VS4<\/sub>\u7684\u7535\u8377\u4f20\u8f93\u80fd\u529b\u3002\u6b64\u5916\uff0c\u901a\u8fc7XPS\u8bc1\u660e\u4e86\u5f15\u5165V2<\/sub>CTx<\/sub>\u53ef\u4ee5\u8c03\u8282VS4<\/sub>\u548cV2<\/sub>CTx<\/sub>\u4e2d\u9492\u7684\u4ef7\u6001\uff0c\u901a\u8fc7GITT\u8bc1\u5b9e\u4e86VS4<\/sub>-V2<\/sub>CTx<\/sub>\u590d\u5408\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u548c\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u5f53\u7528\u4f5cSIB\u8d1f\u6781\u65f6\uff0cVS4<\/sub>-V2<\/sub>CTx<\/sub>\u590d\u5408\u6750\u6599\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u8d85\u957f\u5faa\u73af\u6027\u80fd\uff0c\u572810 A g\u22121<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ecf\u8fc74000\u6b21\u5faa\u73af\u540e\u7684\u6bd4\u653e\u7535\u5bb9\u91cf\u4e3a322 mA h g\u22121<\/sup>\u3002\u5236\u5907\u7684\u5168\u9492\u94a0\u79bb\u5b50\u7535\u6c60 (Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>@C\/\/VS4<\/sub>-V2<\/sub>CTx<\/sub>)\u57283 A g\u22121<\/sup>\u4e0b\u5177\u6709234 mA h g\u22121<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff0c\u5177\u6709\u4f18\u5f02\u7684\u50a8\u94a0\u6027\u80fd\uff0c\u8868\u660e\u9492\u57fa\u50a8\u94a0\u5668\u4ef6\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cConstructing a VS4<\/sub>\u2013V2<\/sub>CTx<\/sub> heterojunction inter-<\/em><\/strong>face to realize an ultra-long lifetime and high rate capability in sodium-ion batteries\u2020<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aINORGANIC CHEMISTRY<\/em><\/strong><\/p>\n

FRONTIERS<\/em><\/strong>\u4e0a\u3002<\/p>\n

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\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u8bbe\u8ba1\u4e86\u4e00\u79cd\u53cc\u9492\u57fa\u5316\u5408\u7269\uff08VS4<\/sub>-V2<\/sub>CTx<\/sub>\uff09\u8096\u7279\u57fa\u63a5\u89e6\u5f02\u8d28\u7ed3\u6784\u590d\u5408\u6750\u6599\u3002<\/p>\n

2\u3001\u901a\u8fc7\u8c03\u6574VS4<\/sub>-V2<\/sub>CTx<\/sub>\u4e2d\u7684\u9492\u4ef7\uff0c\u5b9e\u73b0\u4e86\u66f4\u9ad8\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u548c\u66f4\u5f3a\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

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\u56fe<\/strong>1 (a) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5236\u5907<\/strong>\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong>; (b)<\/strong>\u548c<\/strong>(c) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5236\u5907\u7684<\/strong>SEM<\/strong>\u56fe\u50cf<\/strong>(<\/strong>\u63d2\u56fe\u4e3a<\/strong>VS4<\/sub><\/strong>\u7684\u5c3a\u5bf8\u7edf\u8ba1<\/strong>); (d – f) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5236\u5907\u7684<\/strong>TEM<\/strong>\u548c<\/strong>HRTEM<\/strong>\u56fe\u50cf<\/strong>(d<\/strong>\u4e3a<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684\u9009\u53d6\u7535\u5b50\u884d\u5c04<\/strong>)<\/strong>\uff0c<\/strong>(g) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5236\u5907\u7684<\/strong>HAADF-STEM<\/strong>\u56fe\u50cf\u548c<\/strong>(h-j) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5236\u5907\u7684<\/strong>TEM<\/strong>\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/strong>; <\/strong>\u00a9 the Partner organizations 2023.<\/strong><\/p>\n

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\u56fe<\/strong>2<\/strong> (a) V2<\/sub>CTx<\/sub><\/strong>\u3001<\/strong>VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684<\/strong>XRD<\/strong>\u8c31\u56fe<\/strong>; (b) V2<\/sub>CTx<\/sub><\/strong>\u3001<\/strong>VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684\u62c9\u66fc\u5149\u8c31<\/strong>; (c) V2<\/sub>CTx<\/sub><\/strong>\u3001<\/strong>VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684<\/strong>TGA<\/strong>\u66f2\u7ebf<\/strong>(d) VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684<\/strong>FT-IR<\/strong>\u5149\u8c31<\/strong>; (e) XPS<\/strong>\u5168\u8c31\u56fe\uff0c<\/strong>(f) C1s VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>V2<\/sub>CTx<\/sub><\/strong>\u7684<\/strong>XPS<\/strong>\u8868\u5f81<\/strong>; (g) VS4<\/sub><\/strong>\u3001<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>V2<\/sub>CTx<\/sub><\/strong>\u4e2d\u7684<\/strong>V2p; (i) VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u4e2d\u7684<\/strong>S2p; (h) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u3001<\/strong>VS4<\/sub><\/strong>\u548c<\/strong>V2<\/sub>CTx<\/sub><\/strong>\u4e2d<\/strong>V2+<\/sup><\/strong>\u3001<\/strong>V3+<\/sup><\/strong>\u3001<\/strong>V4+<\/sup><\/strong>\u7684\u4ef7\u6001\u542b\u91cf<\/strong>; <\/strong>\u00a9 the Partner organizations 2023.<\/strong><\/p>\n

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\u56fe<\/strong>3<\/strong> (a) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u5728<\/strong>0.1 mV s\u22121<\/sup><\/strong>\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/strong>; (b) 0.1 A g\u22121<\/sup><\/strong>\u7535\u6d41\u5bc6\u5ea6\u4e0b<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/strong>; (c) 1 A g\u22121<\/sup><\/strong>\u65f6<\/strong>VS4<\/sub><\/strong>\u548c<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u7684\u957f\u5faa\u73af\u6027\u80fd<\/strong>; (d) VS4<\/sub><\/strong>\u548c<\/strong>(e) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u5728\u4e0d\u540c\u5faa\u73af\u4e0b\u7684<\/strong>dQ\/ dV-V<\/strong>\u66f2\u7ebf\u6bd4\u8f83<\/strong>; (f) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u6027\u80fd\u548c<\/strong>10 A g\u22121<\/sup><\/strong>\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd<\/strong>; (g) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c\u5176\u4ed6\u91d1\u5c5e\u786b\u5316\u7269\u8d1f\u6781\u5728<\/strong>SIBs<\/strong>\u4e2d\u7684\u7535\u5316\u5b66\u6bd4\u8f83<\/strong>; (h) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/strong>; <\/strong>\u00a9 the Partner organizations 2023.<\/strong><\/p>\n

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\u56fe<\/strong>4<\/strong> (a) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5728<\/strong>0.1~1.0 mV s\u22121<\/sup><\/strong>\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684<\/strong>CV<\/strong>\u66f2\u7ebf<\/strong>; (b) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u9634\u6781\u548c\u9633\u6781\u5cf0\u5904<\/strong>log i(<\/strong>\u5cf0\u503c\u7535\u6d41<\/strong>)<\/strong>\u4e0e<\/strong>log \u03bd(<\/strong>\u626b\u63cf\u901f\u7387<\/strong>)<\/strong>\u5173\u7cfb\u62df\u5408\u66f2\u7ebf<\/strong>; (c) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u5728<\/strong>1.0 mV s\u22121<\/sup><\/strong>\u65f6\u5bf9<\/strong>CV<\/strong>\u66f2\u7ebf\u7684\u7535\u5bb9\u8d21\u732e<\/strong>; (d)<\/strong>\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b<\/strong>VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7535\u6781\u7684\u7535\u5bb9\u8d21\u732e<\/strong>; (e) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>VS4<\/sub><\/strong>\u7535\u6781\u7684\u5145\u653e\u7535\u8fc7\u7a0b\u7684<\/strong>GITT<\/strong>\u66f2\u7ebf<\/strong>; (f) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>VS4<\/sub><\/strong>\u7535\u6781\u7684\u653e\u7535<\/strong>\/<\/strong>\u5145\u7535\u8fc7\u7a0b\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570<\/strong>; <\/strong>\u00a9 the Partner organizations 2023.<\/strong><\/p>\n

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\u56fe<\/strong>5<\/strong> DFT<\/strong>\u8ba1\u7b97<\/strong>; (a) V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>VS4<\/sub><\/strong>\u8ba1\u7b97\u5f0f\u8868\u9762<\/strong>; (b) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7684\u5e73\u9762\u9759\u7535\u52bf\u53ca\u7535\u8377\u5bc6\u5ea6\u5dee\u66f2\u7ebf\uff0c\u6b63\u503c\u8868\u793a\u7535\u8377\u79ef\u7d2f\uff0c\u8d1f\u503c\u8868\u793a\u7535\u8377\u8017\u6563<\/strong>; (c) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u548c<\/strong>VS4<\/sub><\/strong>\u5f02\u8d28\u7ed3\u6784\u7684<\/strong>TDOS; (d)<\/strong>\u5185\u5efa\u7535\u6c60\u5f62\u6210\u793a\u610f\u56fe<\/strong>; (e) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u7ed3\u6784\u754c\u9762\u5904\u7684\u7535\u8377\u5dee\u5bc6\u5ea6<\/strong>; (f) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5f02\u8d28\u7ed3\u6784\u7535\u5316\u5b66\u6027\u80fd\u589e\u5f3a\u673a\u7406\u7efc\u8ff0<\/strong>;<\/strong> \u00a9 the Partner organizations 2023.<\/strong><\/p>\n

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\u56fe<\/strong>6<\/strong> (a) VS4<\/sub>-V2<\/sub>CTx<\/sub><\/strong>\u5728<\/strong>0.01~2.5 V<\/strong>\u7535\u538b\u8303\u56f4\u5185\u7684\u653e\u7535\u548c\u5145\u7535\u66f2\u7ebf\u4ee5\u53ca\u7b2c\u4e00\u6b21\u5145\u653e\u7535\u65f6\u4e0d\u540c\u5145\u653e\u7535\u7535\u538b\u4e0b\u7684<\/strong>XRD<\/strong>\u56fe\u8c31<\/strong>; (b)<\/strong>\u5168\u7535\u6c60\u793a\u610f\u56fe<\/strong>; (c)<\/strong>\u7535\u6d41\u5bc6\u5ea6\u4e3a<\/strong>0.1 A g\u22121<\/sup><\/strong>\u65f6\uff0c<\/strong>0.5 ~ 3.8 V<\/strong>\u7535\u538b\u8303\u56f4\u5185\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/strong>; (d) VS4<\/sub>-V2<\/sub>CTx<\/sub>\/\/Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>@C<\/strong>\u5168\u7535\u6c60\u5728<\/strong>0.2 A g\u22121<\/sup><\/strong>\u7535\u6d41\u5bc6\u5ea6\u4e0b<\/strong>(<\/strong>\u524d<\/strong>3<\/strong>\u6b21\u4e3a<\/strong>0.1 A g\u22121<\/sup>)<\/strong>\u7684\u957f\u5468\u671f\u6027\u80fd<\/strong>; (e) VS4<\/sub>-V2<\/sub>CTx<\/sub>\/\/Na3<\/sub>V2<\/sub>(PO4)3<\/sub>@C<\/strong>\u5168\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd<\/strong>; <\/strong>\u00a9 the Partner organizations 2023.<\/strong><\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u8be5\u7814\u7a76\u63d0\u51fa\u5728\u6eb6\u6db2\u4e2d\u52a0\u5165\u5c11\u5c42V2<\/sub>CTx<\/sub>\u7c89\u672b\u548c\u542b\u6709VO3<\/sub>\u2212<\/sup>\u7684\u524d\u9a71\u4f53\uff0c\u901a\u8fc7\u9759\u7535\u81ea\u7ec4\u88c5\u548c\u8fdb\u4e00\u6b65\u7684\u6eb6\u5242\u70ed\u53cd\u5e94\uff0c\u5728V2<\/sub>CTx<\/sub>\u8868\u9762\u539f\u4f4d\u751f\u957fVS4<\/sub>\u53f6\u72b6\u7eb3\u7c73\u7247\u7684\u590d\u5408\u7ed3\u6784\u3002\u8fd9\u79cd\u53f6\u72b6\u76843D\u7ed3\u6784\u5177\u6709\u8f83\u5927\u7684\u5b54\u9699\u7ed3\u6784\uff0c\u5141\u8bb8\u7535\u6781\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u6709\u5145\u5206\u7684\u63a5\u89e6\u3002\u6b64\u5916\uff0c\u5728VS4<\/sub>\u548cV2<\/sub>CTx<\/sub>\u4e4b\u95f4\u5f62\u6210\u5177\u6709\u8096\u7279\u57fa\u63a5\u89e6\u7684\u5f02\u8d28\u7ed3\uff0c\u5e76\u901a\u8fc7S-V-C\u952e\u8026\u5408\u3002\u6b64\u5916\uff0cV2<\/sub>CTx<\/sub>\u7684\u5f15\u5165\u8c03\u8282\u4e86\u590d\u5408\u6750\u6599\u4e2d\u9492\u7684\u5316\u5b66\u4ef7\u6001\uff0cXPS\u548cGITT\u7684\u7ed3\u5408\u8bc1\u5b9e\u4e86VS4<\/sub>-V2<\/sub>CTx<\/sub>\u590d\u5408\u6750\u6599\u4e2d\u9492\u5316\u5b66\u4ef7\u6001\u63d0\u5347\u5177\u6709\u66f4\u9ad8\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u548c\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u8fd9\u4f7f\u5f97\u8be5\u6750\u6599\u5177\u6709\u51fa\u8272\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u5faa\u73af\u6027\u80fd\uff0c\u8be5\u7814\u7a76\u6709\u671b\u4e3a\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6784\u5efa\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>Constructing a VS4<\/sub>\u2013V2<\/sub>CTx<\/sub> heterojunction inter-face to realize an ultra-long lifetime and high rate capability in sodium-ion batteries\u2020<\/em><\/strong>\uff0c<\/strong>2023<\/strong>\uff0c<\/strong>https:\/\/doi.org\/10.1039\/d3qi00712j<\/strong>\uff09<\/strong><\/p>\n

 <\/p>\n

\u672c\u6587\u7531LWB\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u897f\u5357\u77f3\u6cb9\u5927\u5b66INORG CHEM FRONT\uff1a\u8d85\u957f\u5bff\u547d\u548c\u9ad8\u500d\u7387\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u7814\u53d1 \u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u5f00\u53d1\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5faa\u73af\u6027\u80fd\u7684\u65b0\u578b\u8d1f\u6781\u6750\u6599\u53ef\u663e\u8457\u63d0\u5347\u94a0\u79bb\u5b50\u7535\u6c60(…<\/p>\n","protected":false},"author":38813,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-252524","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252524"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/38813"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=252524"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252524\/revisions"}],"predecessor-version":[{"id":252562,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252524\/revisions\/252562"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=252524"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=252524"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=252524"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}