{"id":252736,"date":"2023-07-11T06:36:34","date_gmt":"2023-07-10T22:36:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=252736"},"modified":"2023-07-10T19:36:46","modified_gmt":"2023-07-10T11:36:46","slug":"nat-commun-%ef%bc%9a%e5%87%86%e5%9b%ba%e6%80%81%e9%92%a0%e7%94%b5%e6%b1%a0%e4%b8%ad%e9%92%a0%e7%a6%bb%e5%ad%90%e4%bc%a0%e5%af%bc%e9%80%9a%e9%81%93%e7%9a%84%e4%bb%bf%e7%94%9f%e8%ae%be%e8%ae%a1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=252736","title":{"rendered":"Nat. Commun.\uff1a\u51c6\u56fa\u6001\u94a0\u7535\u6c60\u4e2d\u94a0\u79bb\u5b50\u4f20\u5bfc\u901a\u9053\u7684\u4eff\u751f\u8bbe\u8ba1"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u7531\u4e8e\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u9ad8\u53ef\u71c3\u548c\u6613\u6cc4\u6f0f\u7ed9\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u5e26\u6765\u4e86\u5b89\u5168\u6311\u6218\uff0c\u51c6\u56fa\u6001\u7269\u7535\u89e3\u8d28\uff08QSSE\uff09\u5177\u6709\u8f83\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u8f83\u5f3a\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u53ef\u4e3a\u7535\u6c60\u63d0\u4f9b\u7a33\u5b9a\u7684\u5de5\u4f5c\u6761\u4ef6\uff0c\u5728\u56fa\u6001\u94a0\u7535\u6c60\uff08SSB\uff09\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u542b\u6709\u7279\u5b9a\u5b98\u80fd\u56e2\u4fee\u9970\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COF\uff09\u7ed3\u6784\u53ef\u4ee5\u63d0\u4f9b\u5747\u5300\u5206\u6563\u7684\u8df3\u8dc3\u4f4d\u70b9\uff0c\u540c\u65f6\u6d88\u9664\u7535\u89e3\u8d28\u91cd\u7ec4\u4ea7\u751f\u7684\u963b\u6297\uff0c\u8fd9\u8868\u660eCOF\u662fLi+<\/sup>\/Na+<\/sup>\u4f20\u5bfc\u7684\u7406\u60f3\u5e73\u53f0\u3002\u53d7\u751f\u7269\u7cfb\u7edf\u542f\u53d1\uff0c\u4eff\u751f\u6280\u672f\u8d8a\u6765\u8d8a\u53d7\u5230\u5173\u6ce8\uff0c\u5728\u79bb\u5b50\u4f20\u5bfc\u7279\u6027\u65b9\u9762\uff0c\u751f\u7269\u819c\u7684\u79bb\u5b50\u901a\u9053\u5448\u73b0\u5e26\u8d1f\u7535\u8377\uff08-COO–<\/sup>\uff09\u5185\u58c1\u548c\u4e9a\u7eb3\u7c73\u901a\u9053\u7ed3\u6784\uff0c\u53ef\u5b9e\u73b0Na+<\/sup>\/K+<\/sup>\u7684\u9009\u62e9\u6027\u5feb\u901f\u8fd0\u8f93\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u4e9a\u7eb3\u7c73\u7a7a\u95f4\u53ef\u4ee5\u5c06\u6eb6\u5242\u5206\u5b50\u9650\u5236\u5728QSSE\u4e2d\uff0c\u8fd9\u6709\u5229\u4e8e\u63d0\u9ad8\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u76f8\u5bb9\u6027\u5e76\u964d\u4f4e\u9897\u7c92\u4e4b\u95f4\u7684\u754c\u9762\u963b\u6297\u3002\u53d7\u6b64\u542f\u53d1\uff0c\u5728COF\u4e2d\u5f15\u5165\u4e9a\u7eb3\u7c73\u5b54\u5f84\u548c-COO–<\/sup>\u4fee\u9970\u7684\u9aa8\u67b6\u53ef\u4ee5\u88ab\u8ba4\u4e3a\u662f\u6a21\u62df\u751f\u7269\u819c\u79bb\u5b50\u901a\u9053\u7684\u826f\u597d\u65b9\u5f0f\uff0c\u901a\u8fc7\u5728\u539f\u5b50\u6c34\u5e73\u4e0a\u5bf9\u5316\u5b66\u7ed3\u6784\u7684\u7cbe\u786e\u4fee\u9970\uff0c\u57fa\u4e8eCOF\u7684\u751f\u7269\u79bb\u5b50\u901a\u9053\u7684QSSE\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u7814\u7a76\u79bb\u5b50\u4f20\u5bfc\u673a\u5236\u7684\u7406\u60f3\u5e73\u53f0\u3002<\/p>\n

\u00a0<\/strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66\u7684\u8303\u58ee\u519b\u6559\u6388\u3001\u5218\u5f81\u535a\u58eb\u53ca\u71d5\u53cb\u679c\u6559\u6388<\/strong>\u4ee5\u7ec6\u80de\u819c\u7684\u751f\u7269\u79bb\u5b50\u901a\u9053\u4e3a\u7075\u611f\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd-COO–<\/sup>\u4fee\u9970\u7684COF\u4f5c\u4e3aNa+<\/sup>\u51c6\u56fa\u6001\u7535\u89e3\u8d28\uff08QSSE\uff09\u3002\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u79cd\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u5177\u6709\u7531\u76f8\u90bb\u7684-COO–<\/sup>\u57fa\u56e2\u548cCOF\u5185\u58c1\u5f62\u6210\u7684\u4e9a\u7eb3\u7c73Na+<\/sup>\u4f20\u8f93\u533a\uff086.7-11.6 \u00c5\uff09\uff0c\u53ef\u5b9e\u73b0Na+<\/sup>\u6cbf\u7740\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u7535\u8d1f\u6027\u533a\u57df\u4f20\u8f93\uff0c\u4ece\u800c\u4ea7\u751fNa+<\/sup>\u572825 \u00b1 1 \u00b0C\u65f6\uff0c\u7535\u5bfc\u7387\u4e3a1.30\u00d710-4<\/sup> S cm-1<\/sup>\uff0c\u6c27\u5316\u7a33\u5b9a\u6027\u9ad8\u8fbe5.32 V\uff08\u76f8\u5bf9\u4e8eNa+<\/sup>\/Na\uff09\u3002\u5728Na||Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u7ebd\u6263\u7535\u6c60\u914d\u7f6e\u4e2d\u6d4b\u8bd5\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u8bc1\u660e\u4e86\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u3001\u4f4e\u6781\u5316\u7535\u538b\u548c\u572860 mA g-1<\/sup>\u548c25 \u00b1 1 \u00b0C\u4e0b\u8d85\u8fc71000\u4e2a\u5faa\u73af\u7684\u7a33\u5b9a\u5faa\u73af\u6027\u80fd\uff0c\u6bcf\u4e2a\u5faa\u73af\u5bb9\u91cf\u8870\u51cf0.0048%\uff0c\u6700\u7ec8\u653e\u7535\u5bb9\u91cf\u4e3a83.5 mAh g-1<\/sup>\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cBioinspired design of Na-ion conduction channels in covalent organic frameworks for quasi-solid-state sodium batteries<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u7531\u76f8\u90bb\u7684-COO–<\/sup>\u57fa\u56e2\u548cCOF\u5185\u58c1\u5f62\u6210\u4e9a\u7eb3\u7c73Na+<\/sup>\u4f20\u8f93\u533a\uff086.7-11.6 \u00c5\uff09\uff0c\u968f\u540e\u5229\u7528DFT\u8ba1\u7b97\u548cMD\u6a21\u62df\u7814\u7a76\u4e86\u4eff\u751fCOF\u7684Na+<\/sup>\u8f93\u8fd0\u673a\u5236\uff0c\u63ed\u793a\u4e86\u94a0\u79bb\u5b50\u4eff\u751f\u901a\u9053\u8bbe\u8ba1\u53ef\u5b9e\u73b0Na+<\/sup>\u6cbf\u7740\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u7535\u8d1f\u6027\u533a\u57df\u4f20\u8f93\uff0c\u4ece\u800c\u4f7fNa+<\/sup>\u7535\u5bfc\u7387\u9ad8\u8fbe1.30\u00d710-4<\/sup> S cm-1<\/sup>\uff0c\u5e76\u4e14\u572825 \u00b1 1 \u00b0C\u65f6\u6c27\u5316\u7a33\u5b9a\u6027\u9ad8\u8fbe5.32 V\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0 <\/strong>\u7ed3\u6784\u8bbe\u8ba1<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\u7531\u76f8\u90bb\u7684-COO–<\/sup>\u57fa\u56e2\u548cCOF\u5185\u58c1\u6784\u5efa\u7684\u4e9a\u7eb3\u7c73\u7ea7Na+<\/sup>\u8f93\u8fd0\u533a\u7684\u4eff\u751f\u6982\u5ff5\u56fe\u793a\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2\u00a0 COF<\/strong>\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09TPBD\u3001TPDBD\u3001BD\u3001DBD\u548cTP\u7684FTIR\u5149\u8c31\u3002<\/p>\n

\uff08b\uff09TPBD\u548cTPDBD\u7684\u90e8\u5206\u5355\u5143\u7ed3\u6784\u3002<\/p>\n

\uff08c\uff09TPBD\u3001TPDBD\u548c TP\u7684 13C CP-MAS \u56fa\u6001 NMR\u5149\u8c31\u3002<\/p>\n

\uff08d\uff09TPBD\u3001TPDBD\u548c TPDBD-CNa\u7684XPS C 1s\u5149\u8c31\u3002<\/p>\n

\uff08e\uff09TPBD\u3001TPDBD\u548c TPDBD-CNa\u7684XPS O 1s\u5149\u8c31\u3002<\/p>\n

\uff08f\uff09TPDBD\u7684SEM\u56fe\u50cf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3\u00a0 <\/strong>\u4eff\u751f<\/strong>Na+<\/sup><\/strong>\u901a\u9053<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09\u5404\u79cdCOF\u7684Zeta\u7535\u4f4d\u503c\u3002<\/p>\n

\uff08b\uff09TPBD\u3001TPDBD\u548cTPDBD-COO–<\/sup>\u7684\u9759\u7535\u52bf\u56fe\u3002<\/p>\n

\uff08c\uff09NaTFSI\u4e0eTPDBD\u548cTPDBD-COO–<\/sup>\u4e4b\u95f4\u7684\u4f18\u5316\u914d\u4f4d\u7ed3\u6784\u3002<\/p>\n

\uff08d\uff09NaTFSI\u548cTPBD\u3001TPDBD\u548cTPDBD-COO–<\/sup>\u4e4b\u95f4\u7684\u952e\u957f\u3002<\/p>\n

\uff08e\uff09TPDBD-CNa\u4e2d\u7684\u4eff\u751f\u901a\u9053\u793a\u610f\u56fe\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4\u00a0 COF-NaTFSI<\/strong>\u7684<\/strong>Na+<\/sup><\/strong>\u4f20\u8f93\u673a\u5236<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09TPBD\u3001TPDBD\u548cTPDBD-CNa\u4e2dNa+\u548cTFSI-\u7684\u5206\u5e03\u6a21\u5f0f\u3002<\/p>\n

\uff08b\uff09TPDBD-CNa-NaTFSI\u7684MD\u6a21\u62df\u793a\u610f\u56fe\u3002<\/p>\n

\uff08c-e\uff09TPBD-NaTFSI\u3001TPDBD-NaTFSI\u548cTPDBD-CNa-NaTFSI\u7684Na+<\/sup>\u5bc6\u5ea6\u6620\u5c04\u3002<\/p>\n

\uff08f\uff09TPDBD\u901a\u9053\u8fb9\u7f18\u548c\u4e2d\u5fc3\u7684Na+<\/sup>\u4f20\u8f93\u901f\u5ea6\u3002<\/p>\n

\uff08g\uff09\u4e09\u79cdCOF\u4e2dNa+<\/sup>\u968f\u65f6\u95f4\u53d8\u5316\u7684MSD\u7ed3\u679c\u3002<\/p>\n

\uff08h\uff09TPDBD\u4e2d-COOH\/-COO–<\/sup>\u57fa\u56e2\u4e0eNa+<\/sup>\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u80fd\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5\u00a0 COF-QSSE<\/strong>\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u548c<\/strong>Na+<\/sup><\/strong>\u4f20\u5bfc<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09\u5236\u5907\u7684TPDBD-CNa-QSSE\u3001TPBD-QSSE\u548cPC\u6eb6\u5242\u7684FTIR\u5149\u8c31\u3002<\/p>\n

\uff08b\uff09PC-Na\u548cPC-NaTFSI\u4e2d\u7684Na-O\u952e\u957f\u3002<\/p>\n

\uff08c\uff09PC\u3001Na+<\/sup>\u548cTFSI\u2212<\/sup>\u5728TPDBD-CNa\u4e2d\u7684\u5206\u5e03\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff09TPDBD-CNa-QSSE\u548cTPBD-QSSE\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u7684Arrhenius\u56fe\u3002<\/p>\n

\uff08e\uff09Na|TPDBD-CNa-QSSE|Na\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u6d41\u2014\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

\uff08f\uff09\u5df2\u62a5\u9053\u7684Li+<\/sup>\/Na+<\/sup> SSE\u7684\u5178\u578b\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6\u00a0 COF-QSSE<\/strong>\u7684\u7535\u5316\u5b66\u7a97\u53e3\u548c<\/strong>Na<\/strong>\u6c89\u79ef<\/strong>\/<\/strong>\u6eb6\u51fa<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09SS|TPBD-QSSE|Na\u548cSS|TPDBD-CNa-QSSE|Na\u4e0d\u5bf9\u79f0\u7535\u6c60\u7684LSV\u56fe\u3002<\/p>\n

\uff08b\uff09\u57fa\u4e8eDFT\u8ba1\u7b97\u7684TPBD\u548cTPDBD\u7684HOMO\u548cLUMO\u503c\u3002<\/p>\n

\uff08c\uff09\u572825 \u00b1 1 \u00b0C\u548c0.01\u30010.03\u30010.04\u30010.1\u30010.2\u30010.5\u30010.6\u548c 0.8 mA cm-2<\/sup>\u4e0b\uff0cNa|QSSE|Na\u7684Na\u6c89\u79ef\/\u6eb6\u51fa\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\uff08d\uff09Na|QSSE|Na\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.01 mA cm-2<\/sup>\u548c25 \u00b1 1 \u00b0C\u4e0b\u6c89\u79ef\/\u6eb6\u51fa\u66f2\u7ebf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7\u00a0 <\/strong>\u975e\u539f\u4f4d<\/strong>XPS<\/strong>\u548c<\/strong>SEM<\/strong>\u8868\u5f81<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09TPDBD-CNa-QSSE\/TPBD-QSSE\u5728Na||Na\u7535\u6c60\u4e2d0.02 mA cm-2<\/sup>\u548c25 \u00b1 1 \u00b0C\u4e0b\u8d85\u8fc720\u4e2a\u5faa\u73af\u4ee5\u53caTPDBD-CNa-NaTFSI\/TPBD-NaTFSI\u7684C 1s\u3001O 1s\u3001F 1s\u548cNa 1s\u7684XPS\u56fe\u50cf\u3002<\/p>\n

\uff08b\uff09Na|TPDBD-CNa-QSSE|Na\u8d85\u8fc720\u4e2a\u5faa\u73af\u7684\u91d1\u5c5e\u94a0\u6df1\u5ea6\u5256\u9762\u7684C 1s\u3001O 1s\u3001F 1s\u548cNa 1s\u7684XPS\u3002<\/p>\n

\uff08c-d\uff09TPBD-QSSE\u548cTPDBD-CNa-QSSE\u5faa\u73af\u819c\u57280.02 mA cm-2<\/sup>\u548c25 \u00b1 1 \u00b0C\u4e0b\u8d85\u8fc720\u4e2a\u5faa\u73af\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08e-f\uff09TPBD-QSSE\u548cTPDBD-CNa-QSSE\u7684\u5faa\u73af\u94a0\u91d1\u5c5e\u57280.02 mA cm-2<\/sup>\u548c25 \u00b1 1 \u00b0C\u4e0b\u8d85\u8fc720\u4e2a\u5faa\u73af\u7684SEM\u56fe\u50cf\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>8\u00a0 Na|QSSE|NVP\/C<\/strong>\u7535\u6c60\u548c\u5b89\u5168\u7279\u6027<\/strong> \u00a9 2023 The Authors<\/strong><\/p>\n

\uff08a\uff09NVP\/C\u7684XRD\u56fe\u6848\u3002<\/p>\n

\uff08b\uff09NVP\/C\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540c\u6bd4\u7535\u6d41\u4e0b\u7684\u7535\u538b\u6ede\u540e\u67f1\u72b6\u56fe\u3002<\/p>\n

\uff08d\uff09Na|TPDBD-CNa-QSSE|NVP\/C\u548cNa|TPBD-QSSE|NVP\/C\u7535\u6c60\u572812 mA g-1<\/sup>\u4e0b\u7684\u5145\u7535\/\u653e\u7535\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\uff08e\uff09Na|TPDBD-CNa-QSSE|NVP\/C\u548cNa|TPBD-QSSE|NVP\/C\u7535\u6c60\u5728 0.1 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\u3002<\/p>\n

\uff08f\uff09TPDBD-CNa-QSSE\u7684\u71c3\u70e7\u884c\u4e3a\u3002<\/p>\n

\uff08g\uff09\u6eb6\u5242\u6e17\u900f\u73bb\u7483\u7ea4\u7ef4\u9694\u819c\u7684\u71c3\u70e7\u884c\u4e3a\u3002<\/p>\n

\uff08h\uff09Na|TPDBD-CNa-QSSE|NVP\/C\u7535\u6c60\u572860 mA g-1<\/sup>\u4e0b\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\uff08i\uff09Na|TPDBD-CNa-QSSE|NVP\/C\u94fa\u5c55\u7684\u8f6f\u5305\u7535\u6c60\u572812 mA g-1<\/sup>\u4e0b\u5faa\u73af160\u6b21\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u00a0<\/strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u901a\u8fc7\u5c06-COO–<\/sup>\u57fa\u56e2\u5f15\u5165COF\u5185\u58c1\uff0c\u6784\u5efa\u516d\u4e2a\u4e9a\u7eb3\u7c73\u533a\u57df\uff0c\u5236\u5907\u5177\u6709\u4eff\u751fNa+<\/sup>\u901a\u9053\u8bbe\u8ba1\u7684COF-QSSE\u3002\u53d7\u76ca\u4e8e\u7a7a\u8154\u548c\u7fb0\u57fa\u7ed3\u5408\u4f4d\u70b9\u7684\u51c6\u786e\u5c3a\u5bf8\uff0c\u6eb6\u5242\u88ab\u9650\u5236\u5728\u4eff\u751f\u4e9a\u7eb3\u7c73\u901a\u9053\u4e2d\uff0c\u57fa\u4e8eCOF\u7684QSSE\u8868\u73b0\u51fa1.30 \u00d7 10-4<\/sup> S cm-1<\/sup>\u7684\u9ad8\u2009Na+<\/sup>\u7535\u5bfc\u7387\u548c\u572825 \u00b1 1 \u00b0C \u65f6\u9ad8\u8fbe5.32 V\u7684\u6c27\u5316\u7a33\u5b9a\u6027\uff08\u76f8\u5bf9\u4e8eNa+\/Na\uff09\u3002DFT\u8ba1\u7b97\u548cMD\u6a21\u62df\u8868\u660e\uff0cNa+<\/sup>\u5728\u4e9a\u7eb3\u7c73\u901a\u9053\u4e2d\u53d1\u751f\u5b54\u58c1\u5438\u9644\u73b0\u8c61\uff08\u9ad8\u5ea6\u96c6\u4e2d\u4e8e\u7fb0\u57fa\uff09\uff0c\u800c-COO–<\/sup>\u56fa\u5b9a\u5728COF\u5185\u58c1\u4e0a\u7684\u57fa\u56e2\u6709\u5229\u4e8eNaTFSI\u7684\u5feb\u901f\u89e3\u79bb\u3002\u6b64\u5916\uff0cNa\u6c89\u79ef\/\u6eb6\u51fa\u5b9e\u9a8c\u4e2d\u7684\u7535\u89e3\u8d28\/\u7535\u6781\u754c\u9762\u5728900\u5c0f\u65f6\u7684\u5faa\u73af\u4e2d\u662f\u7a33\u5b9a\u7684\u3002\u5f53\u4e0eNVP\/C\u6b63\u6781\u3001Na\u91d1\u5c5e\u8d1f\u6781\u548cTPDBD-CNa-QSSE\u819c\u7ec4\u88c5\u65f6\uff0cSSB\u57281000\u6b21\u5faa\u73af\u540e\u6bcf\u6b21\u5faa\u73af\u663e\u793a0.0048%\u7684\u5bb9\u91cf\u8870\u51cf\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aBioinspired design of Na-ion conduction channels in covalent organic frameworks for quasi-solid-state sodium batteries<\/a> (Nat Commun <\/em>2023<\/strong>, 14<\/em>, 3066)<\/p>\n

\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u7531\u4e8e\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u9ad8\u53ef\u71c3\u548c\u6613\u6cc4\u6f0f\u7ed9\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u5e26\u6765\u4e86\u5b89\u5168\u6311\u6218\uff0c\u51c6\u56fa\u6001\u7269\u7535\u89e3\u8d28\uff08QSSE\uff09\u5177\u6709\u8f83\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u8f83\u5f3a\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u53ef\u4e3a…<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-252736","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252736"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=252736"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252736\/revisions"}],"predecessor-version":[{"id":252746,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/252736\/revisions\/252746"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=252736"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=252736"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=252736"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}