{"id":253073,"date":"2023-07-23T06:55:11","date_gmt":"2023-07-22T22:55:11","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=253073"},"modified":"2023-07-22T19:55:24","modified_gmt":"2023-07-22T11:55:24","slug":"%e9%83%91%e5%b7%9e%e5%a4%a7%e5%ad%a6nature%e5%ad%90%e5%88%8a%ef%bc%9a-%e6%a1%a5%e6%8e%a5%e5%a4%9a%e5%b0%ba%e5%ba%a6%e7%95%8c%e9%9d%a2%e4%bb%a5%e5%bc%80%e5%8f%91%e7%a6%bb%e5%ad%90%e5%af%bc%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=253073","title":{"rendered":"\u90d1\u5dde\u5927\u5b66Nature\u5b50\u520a\uff1a \u6865\u63a5\u591a\u5c3a\u5ea6\u754c\u9762\u4ee5\u5f00\u53d1\u79bb\u5b50\u5bfc\u7535\u9ad8\u538b\u542b\u786b\u9178\u94c1\u94a0\u57fa\u7535\u6c60\u6b63\u6781"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u73af\u5883\u6c61\u67d3\u548c\u5316\u77f3\u80fd\u6e90\u5bf9\u4e8e\u63a8\u52a8\u53ef\u518d\u751f\u6e05\u6d01\u80fd\u6e90\u7684\u53d1\u5c55\u662f\u6709\u9650\u7684\uff0c\u5176\u95f4\u6b47\u6027\u548c\u533a\u57df\u6027\u7279\u70b9\uff0c\u9700\u8981\u5927\u89c4\u6a21\u7684\u50a8\u80fd\u7cfb\u7edf\u5171\u540c\u53d1\u6325\u4f5c\u7528\u3002\u94a0\u79bb\u5b50\u7535\u6c60\uff08SiBs\uff09\u4f5c\u4e3a\u6700\u6709\u524d\u9014\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u4e4b\u4e00\uff0c\u7531\u4e8e\u4e30\u5bcc\u7684\u94a0\u50a8\u91cf\u53ca\u5176\u5168\u7403\u5206\u5e03\u800c\u5e26\u6765\u4e86\u65b0\u7684\u673a\u9047\u3002\u9ad8\u7535\u538b\uff08>3.6V vs. Na+<\/sup>\/Na\uff09\u548c\u8d44\u6e90\u4e30\u5bcc\u4e14\u4f7f\u7528\u957f\u5bff\u547d\u9634\u6781\u7684\u5f00\u53d1\u8fc5\u901f\u53d1\u5c55\uff0c\u4ee5\u89c4\u907f\u539f\u6750\u6599\u548c\u6210\u672c\u7684\u9650\u5236\u3002\u5728\u6b64\u65b9\u9762\uff0c\u4e9a\u94dd\u94c1\u77ff\u578b\u94c1\u57fa\u786b\u9178\u76d0\u7531\u4e8e\u5176\u4e30\u5bcc\u7684\u8d44\u6e90\u3001\u9ad8\u7535\u538b\uff083.8V vs. Na+<\/sup>\/Na\uff09\u548c\u575a\u56fa\u7684\u805a\u9634\u79bb\u5b50\u6846\u67b6\u800c\u88ab\u8ba4\u4e3a\u662f\u6709\u524d\u9014\u7684\u6b63\u6781\u6d3b\u6027\u6750\u6599\u5019\u9009\u8005\u3002\u7136\u800c\uff0c\u5927\u5e26\u9699\u963b\u788d\u8f7d\u6d41\u5b50\uff08Na+<\/sup>\u3001\u7535\u5b50\uff09\u7684\u5feb\u901f\u8f6c\u79fb\u548c\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5bfc\u81f4\u7535\u6c60\u7684\u5faa\u73af\u53ef\u9006\u6027\u548c\u500d\u7387\u6027\u80fd\u8f83\u5dee\u3002\u6b64\u5916\uff0c\u7535\u89e3\u8d28\u5728\u9ad8\u7535\u538b\u4e0b\u906d\u53d7\u4e25\u91cd\u7684\u6c27\u5316\u5206\u89e3\uff0c\u5f62\u6210\u56fa\u4f53\u754c\u9762\uff0c\u5373\u9634\u6781\u7535\u89e3\u8d28\u754c\u9762\uff08CEI\uff09\u3002CEI\u5f71\u54cdNa+\u4ece\u6eb6\u5242\u5316\u76f8\u63d2\u5165\u56fa\u76f8\uff0c\u56e0\u6b64\u6784\u6210\u5927\u591a\u6570\u9634\u6781\u94a0\u5316\u7684\u989d\u5916\u9650\u901f\u6b65\u9aa4\u3002<\/p>\n

\u9634\u6781\u5185\u9ad8\u5ea6\u8fde\u63a5\u7684\u79bb\u5b50\u4f20\u5bfc\u8def\u5f84\u4e3a\u907f\u514d\u4e0a\u8ff0\u95ee\u9898\u63d0\u4f9b\u4e86\u6709\u6548\u7b56\u7565\uff0c\u5176\u6784\u9020\u9700\u8981\u8003\u8651\u6b63\u6781\u4e2d\u7684\u6240\u6709\u57fa\u672c\u6210\u5206\uff0c\u5305\u62ec\u6d3b\u6027\u6750\u6599\u9897\u7c92\u53ca\u7535\u6c60\u6c34\u5e73\u7535\u89e3\u8d28\u76f8\u5bb9\u6027\u3002\u5bf9\u4e8e\u9897\u7c92\u7684\u8bbe\u8ba1\uff0c\u901a\u5e38\u4f7f\u7528\u9634\u6781\u6750\u6599\u7eb3\u7c73\u5de5\u7a0b\u6765\u51cf\u5c11\u79bb\u5b50\u8f6c\u79fb\u8ddd\u79bb\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u6548\u679c\u53d7\u5230\u7535\u6781\u6750\u6599\u4e0a\u9650\u7684\u9650\u5236\u3002\u901a\u8fc7\u5f15\u5165\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u9644\u52a0\u6750\u6599\u6765\u4fc3\u8fdb\u590d\u5408\u9634\u6781\u7684\u79bb\u5b50\u52a8\u529b\u5b66\u3002\u7136\u800c\uff0c\u5177\u6709\u590d\u6742\u805a\u9634\u79bb\u5b50\u9aa8\u67b6\u7684\u6b63\u6781\u5f02\u8d28\u5316\u5b66\u7ed3\u6784\u5c1a\u672a\u89c1\u62a5\u9053\uff0c\u5e76\u4e14\u53d7\u5230\u82db\u523b\u5408\u6210\u6761\u4ef6\u7684\u5f71\u54cd\u3002\u5757\u4f53\u6750\u6599\u7684\u5f02\u8d28\u7ed3\u6784\u8bbe\u8ba1\u4ecd\u7136\u9700\u8981\u63a2\u7d22\uff0c\u624d\u80fd\u5728\u9ad8\u538b\u9634\u6781\u4e0a\u83b7\u5f97\u4ee4\u4eba\u6ee1\u610f\u7684\u6027\u80fd\u3002<\/p>\n

CEI\u7684\u4e3b\u8981\u6784\u9020\u672c\u8d28\u4e0a\u53d6\u51b3\u4e8e\u9634\u6781\u8868\u9762\u4e0a\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u53cd\u5e94\u3002\u901a\u5e38\uff0c\u53d7\u9634\u6781\u8868\u9762\u5f3a\u4eb2\u6838\u6027\u7684\u9650\u5236\u3002\u9634\u6781\u6750\u6599\u7684\u66b4\u9732\u6676\u9762\u4e0e\u5176\u7535\u5b50\u7ed3\u6784\u548c\u539f\u5b50\u6027\u8d28\u5bc6\u5207\u76f8\u5173\uff0c\u662f\u64cd\u7eb5CEI\u5f62\u6210\u7684\u5173\u952e\u53c2\u6570\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u76ee\u524d\u5bf9\u9634\u6781CEI\u5f62\u6210\u7684\u5f71\u54cd\uff0c\u7279\u522b\u662f\u5176\u66b4\u9732\u7684\u6676\u9762\u548c\u7ed3\u6784\uff0c\u5c1a\u672a\u5f97\u5230\u5145\u5206\u7814\u7a76\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u4e3a\u6b64\uff0c\u90d1\u5dde\u5927\u5b66\u9648\u536b\u534e\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u63d0\u51faNa2.26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u591a\u5c3a\u5ea6\u754c\u9762\u5de5\u7a0b\uff0c\u5f02\u8d28\u7ed3\u6784\u548c\u6676\u9762\u88ab\u8c03\u6574\u4ee5\u63d0\u9ad8Na\u79bb\u5b50\u5b58\u50a8\u6027\u80fd\u3002\u7269\u7406\u5316\u5b66\u8868\u5f81\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660eNa6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u5f02\u8d28\u7ed3\u6784\u76f8\u901a\u8fc7\u81f4\u5bc6\u94a0\u79bb\u5b50\u8fc1\u79fb\u901a\u9053\u548c\u964d\u4f4e\u80fd\u5792\u6765\u4fc3\u8fdb\u79bb\u5b50\u52a8\u529b\u5b66\u3002Na2.26Fe1.87(SO4)3\u7684(11)\u9762\u4fc3\u8fdb\u4e86\u7535\u89e3\u6db2ClO4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u548c\u6c1f\u4ee3\u78b3\u9178\u4e9a\u4e59\u916f\u5206\u5b50\u7684\u5438\u9644\uff0c\u5728\u6b63\u6781\u5f62\u6210\u5bcc\u542b\u65e0\u673a\u7269\u7684Na\u79bb\u5b50\u5bfc\u7535\u754c\u9762\u3002\u5f53\u5728\u5b9e\u9a8c\u5ba4\u89c4\u6a21\u7684\u5355\u5c42\u8f6f\u5305\u7535\u6c60\u914d\u7f6e\u4e2d\u4e0e\u9884\u5148\u5904\u7406\u7684FeS\/\u78b3\u57fa\u8d1f\u6781\u7ed3\u5408\u8fdb\u884c\u6d4b\u8bd5\u65f6\uff0c\u53d1\u73b0\u57fa\u4e8eNa2.26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u7684\u6b63\u6781\u53ef\u5b9e\u73b0\u7ea683.9 mAh g-1<\/sup>\u7684\u521d\u59cb\u653e\u7535\u5bb9\u91cf\uff0c\u572824 mA g-1<\/sup>\u548c 25\u2103\u4e0b\u8fdb\u884c40\u4e2a\u5faa\u73af\u540e\uff0c\u5e73\u5747\u7535\u6c60\u653e\u7535\u7535\u538b\u4e3a2.35 V\uff0c\u6bd4\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a97%\u5de6\u53f3\u3002<\/p>\n

\"\"<\/p>\n

\u90d1\u5dde\u5927\u5b66\u9648\u536b\u534e\u6559\u6388\u7b49\u4eba\u5c06\u6b64\u5de5\u4f5c\u4ee5\u201c<\/strong>Bridging multiscale interfaces for developing ionically conductive high-voltage iron sulfate-containing sodium-based battery positive electrodes<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u9876\u7ea7\u7efc\u5408\u6027\u671f\u520a\u300a<\/strong>Nature Communications<\/em><\/strong>\u300b\u4e0a\u3002<\/strong><\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u63d0\u51faNa26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u591a\u5c3a\u5ea6\u754c\u9762\u5de5\u7a0b\u3002<\/p>\n

2\u3001\u5f02\u8d28\u7ed3\u6784\u76f8\u901a\u8fc7\u81f4\u5bc6\u94a0\u79bb\u5b50\u8fc1\u79fb\u901a\u9053\u548c\u964d\u4f4e\u80fd\u5792\u6765\u4fc3\u8fdb\u79bb\u5b50\u52a8\u529b\u5b66\u3002<\/p>\n

3\u3001Na26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u5177\u6709\u4f18\u5f02\u7684\u521d\u59cb\u653e\u7535\u5bb9\u91cf\u3001\u5e73\u5747\u653e\u7535\u7535\u538b\u548c\u6bd4\u5bb9\u91cf\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>\u5f02\u8d28\u7ed3\u6784\u793a\u610f\u56fe\u3002\u84dd\u8272\u548c\u7ea2\u8272\u533a\u57df\u5206\u522b\u4ee3\u8868\u6b63\u6781\u6750\u6599\u4e2d\u7684Na2.26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u548cNa6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u3002\u767d\u8272\u548c\u9ed1\u8272\u7bad\u5934\u5206\u522b\u4ee3\u8868Na2.26<\/sub>Fe1.87<\/sub>(SO4<\/sub>)3<\/sub>\u548cNa6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u4e2d\u7684\u94a0\u79bb\u5b50\u4f20\u8f93\u3002\u00a92023 Springer Nature.<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 <\/strong>a\u548cb\u4e3a\u539f\u59cb\u72b6\u6001HAADF-STEM\u56fe\u50cf, c\u4e3a\u653e\u5927\u56fe\u50cf\u3002b\u548cd\u5728\u521d\u59cb\u5faa\u73af\u65f6\u5145\u75354.5V\uff0ce\u4e3a\u653e\u75352.0V\u3002\u84dd\u8272\u9634\u5f71\u4ee3\u8868Na6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u76f8\u6750\u6599\u3002\u786e\u5b9a\u4e86\u4e24\u79cdFe\u6392\u5217\uff0c\u5176\u7279\u5f81\u662f\u6765\u81ea\u9ad8\u539f\u5b50\u5e8f\u6570\u660e\u4eaeFe\u539f\u5b50\u3002\u00a9 Springer Nature.<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>NFS-H\u6b63\u6781\u975e\u539f\u4f4d\u7269\u7406\u5316\u5b66\u7279\u6027\u3002\u00a9 Springer Nature.<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u975e\u6c34\u94a0\u91d1\u5c5e\u7ebd\u6263\u7535\u6c60\u914d\u7f6e\u4e2d\u57fa\u4e8eNFS-H\u548cNFS-L\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u00a9 Springer Nature.<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>\u5b9e\u9a8c\u5ba4\u89c4\u6a21\u94c1\u786b\u57fa\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u00a9 Springer Nature.<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u4f5c\u8005\u901a\u8fc7\u5171\u6c89\u6dc0\u548c\u7145\u70e7\u5236\u5907\u4e86\u5177\u6709\u6709\u6548\u7535\u5b50\u4f20\u5bfc\u6027\u7684\u78b3\u7f51\u7edc\u79bb\u5b50\u8f6c\u79fb\u589e\u5f3a\u94c1\u57fa\u786b\u9178\u76d0\uff0c\u4f5c\u4e3a\u975e\u6c34\u94a0\u57fa\u7535\u6c60\u7684\u9ad8\u538b\u6b63\u6781\u6d3b\u6027\u6750\u6599\u3002HAADF\u56fe\u50cf\u8bc1\u5b9e\u9897\u7c92\u5185\u90e8\u5b58\u5728Na6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u76f8(10.5 wt%)\u5f02\u8d28\u7ed3\u6784\u3002BVSE\u8ba1\u7b97\u8868\u660e\uff0c\u4e30\u5bcc\u7684Na+<\/sup>\u6269\u6563\u901a\u9053\u548cNa6<\/sub>Fe(SO4<\/sub>)4<\/sub>\u7684\u4f4e\u52bf\u5792\uff0c\u589e\u5f3a\u4e86\u9634\u6781\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4e3b\u76f8\uff08Na2.26<\/sub>Fe\uff09\u7684\u4f4e\u7535\u5b50\u5bc6\u5ea6\u8bf1\u5bfcFEC\u548cClO4<\/sub>–<\/sup>\u7684\u5f3a\u70c8\u5438\u9644\uff0c\u7528\u4e8e\u6784\u5efa\u949d\u5316EDL\uff0c\u4ece\u800c\u884d\u751f\u51fa\u96c6\u6210\u4e14\u5bcc\u542b\u65e0\u673a\u7269\u7684CEI\u3002\u8fd9\u4e9b\u63a8\u6d4b\u5f97\u5230\u4e86\u975e\u539f\u4f4d\u51b7\u51bbTEM\u548cXPS\u6d4b\u91cf\u548c\u5206\u6790\u4ee5\u53caDFT\u8ba1\u7b97\u7684\u652f\u6301\u3002CEI\u7684\u65e0\u673a\u6210\u5206\u63d0\u4f9b\u4e86\u6709\u6548\u7684Na+<\/sup>\u6269\u6563\u901a\u9053\uff0c\u5e76\u6709\u52a9\u4e8e\u63d0\u9ad8Na+<\/sup>\u6269\u6563\u7cfb\u6570\u3002\u5747\u5300\u7684CEI\u6709\u6548\u9632\u6b62\u7535\u89e3\u6db2\u5728\u9ad8\u7535\u538b\uff084.5 V\uff09\u4e0b\u7684\u5206\u89e3\u3002\u91c7\u7528\u590d\u5408\u786b\u9178\u94c1\u57fa\u6b63\u6781\u7684Na\u91d1\u5c5e\u7535\u6c60\u57286 mA g-1<\/sup>\u4e0b\u9996\u6b21\u653e\u7535\u5bb9\u91cf\u4e3a101.3 mAh g-1<\/sup>\uff08\u5e73\u5747\u653e\u7535\u7535\u6c60\u7535\u538b\u7ea6\u4e3a3.75 V\uff09\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u6587\uff1a\u65e9\u65e9\uff09<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1038\/s41467-023-39384-7<\/u><\/p>\n","protected":false},"excerpt":{"rendered":"

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