{"id":254479,"date":"2023-09-20T06:54:47","date_gmt":"2023-09-19T22:54:47","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=254479"},"modified":"2023-09-19T21:55:06","modified_gmt":"2023-09-19T13:55:06","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6-%e4%b8%8a%e6%b5%b7%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6angew-%e4%ba%8c%e5%97%aacofs%e5%85%89%e5%82%ac%e5%8c%96%e5%90%88%e6%88%90h2o2%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=254479","title":{"rendered":"\u5357\u4eac\u5927\u5b66\/\u4e0a\u6d77\u7406\u5de5\u5927\u5b66Angew: \u4e8c\u55eaCOFs\u5149\u50ac\u5316\u5408\u6210H2O2\uff01"},"content":{"rendered":"

1.<\/strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u8fc7\u6c27\u5316\u6c22\uff08H2<\/sub>O2<\/sub>\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u6548\u7eff\u8272\u6c27\u5316\u5242\uff0c\u88ab\u8ba4\u4e3a\u662f21\u4e16\u7eaa\u6700\u91cd\u8981\u7684\u5316\u5b66\u54c1\u4e4b\u4e00\uff0c H2<\/sub>O2<\/sub>\u7684\u5236\u5907\u4e3b\u8981\u4f9d\u8d56\u4f20\u7edf\u84bd\u918c\u6cd5\uff0c\u4f46\u8be5\u65b9\u6cd5\u6210\u672c\u9ad8\uff0c\u4e14\u5371\u9669\u6709\u6bd2\u3002\u5149\u50ac\u5316\u662f\u4e00\u79cd\u751f\u4ea7H2<\/sub>O2<\/sub>\u975e\u5e38\u6709\u524d\u666f\u7684\u65b9\u6cd5\uff0c\u5177\u6709\u7a81\u51fa\u7684\u50ac\u5316\u6548\u7387\u548c\u9009\u62e9\u6027\u3002\u9664\u4e86\u5e38\u89c1\u7684\u65e0\u673a\u50ac\u5316\u5242\uff0c\u65e0\u91d1\u5c5e\u6709\u673a\u805a\u5408\u7269\u56e0\u5176\u4f4e\u6210\u672c\u3001\u957f\u5bff\u547d\u548c\u9ad8\u6548\u7387\u8fd1\u5e74\u6765\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5176\u4e2d\uff0c\u4ee3\u8868\u6027\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u6750\u6599\u6210\u4e3a\u7814\u7a76\u7684\u524d\u6cbf\u70ed\u70b9\u3002COFs\u7684\u9ad8\u5171\u8f6d\u7ed3\u6784\u4f7f\u5176\u5177\u6709\u5e7f\u8c31\u5149\u5438\u6536\u548c\u9002\u5f53\u7684\u5e26\u9699\uff0c\u5176\u591a\u5b54\u6027\u548c\u4e30\u5bcc\u7684\u901a\u9053\u6709\u5229\u4e8e\u53cd\u5e94\u7269\u548c\u751f\u6210\u7269\u7684\u4f20\u8d28\uff0c\u6b64\u5916\uff0c\u53ef\u4ee5\u5bf9COFs\u53cd\u5e94\u4f4d\u70b9\u548c\u80fd\u5e26\u7ed3\u6784\u8fdb\u884c\u7cbe\u7ec6\u8c03\u63a7\uff0c\u4ece\u800c\u589e\u5f3a\u5149\u50ac\u5316\u6027\u80fd\u3002\u6c2e\u6742\u73af\u7531\u4e8e\u5176\u5171\u8f6d\u4f53\u7cfb\u548c\u4f18\u5f02\u7684\u7535\u5b50\u4eb2\u548c\u6027\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u5b66\u548c\u7535\u5b66\u6027\u8d28\uff0c\u6709\u5229\u4e8e\u5149\u50ac\u5316ORR\u53cd\u5e94\u3002\u76ee\u524d\uff0c\u7814\u7a76\u8005\u5df2\u5c06\u5421\u5576\u3001\u4e09\u55ea\u3001\u8054\u5421\u5576\u3001\u548c\u5e9a\u55ea\u7b49\u6c2e\u6742\u73af\u5316\u5408\u7269\u6574\u5408\u5230<\/strong>COF<\/strong>\u57fa\u5149\u50ac\u5316\u5242\u7ed3\u6784\u4e2d\uff0c\u4f46\u6c2e\u539f\u5b50\u7684\u76f8\u5bf9\u4f4d\u7f6e\u5bf9\u6c2e\u6742\u73af\u7684\u5f71\u54cd\u5728\u5149\u50ac\u5316\u9886\u57df\u5c1a\u672a\u5f97\u5230\u7cfb\u7edf\u7814\u7a76\u4e0e\u9610\u8ff0\u3002<\/strong><\/p>\n

2.<\/strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u4ee5\u4e0a\u7814\u7a76\u80cc\u666f\uff0c\u5357\u4eac\u5927\u5b66\u88ad\u9534\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4e0e\u4e0a\u6d77\u7406\u5de5\u5927\u5b66\u738b\u4e01\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u3001\u674e\u6167\u73fa\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c<\/strong>\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e09\u79cd\u7531\u54d2\u55ea\u3001\u5627\u5576\u548c\u5421\u55ea\u7b49\u4e8c\u6c2e\u6742\u73af\u5316\u5408\u7269\uff08\u4e8c\u55ea\uff09\u529f\u80fd\u5316\u7684COFs\u6750\u6599\uff08\u547d\u540d\u4e3aTpDz, TpMd\u548cTpPz\uff09\uff0c\u7528\u4e8e\u5149\u50ac\u5316\u9ad8\u6548\u5236\u5907H2<\/sub>O2<\/sub>\u3002\u8fd9\u4e9b\u4e8c\u55ea\u529f\u80fd\u5316COFs\uff08DAzCOFs\uff09\u5728\u65e0\u727a\u7272\u5242\u6761\u4ef6\u5236\u5907H2<\/sub>O2<\/sub>\u4e2d\u8868\u73b0\u51fa\u51fa\u8272\u7684\u5149\u50ac\u5316\u6d3b\u6027\uff0c\u4f5c\u8005\u540c\u65f6\u7ed3\u5408\u5b9e\u9a8c\u548c\u8ba1\u7b97\uff0c\u5bf9DAzCOFs\u7684\u4f5c\u7528\u673a\u7406\u548c\u6d3b\u6027\u4f4d\u70b9\u8fdb\u884c\u4e86\u7cfb\u7edf\u6df1\u5165\u7684\u7814\u7a76\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cRegulating Relative Nitrogen Locations of Diazine Functionalized Covalent Organic Frameworks for Overall H2<\/sub>O2<\/sub> Photosynthesis\u201d\u4e3a\u9898\u53d1\u8868\u5728Angewandte Chemie International Edition<\/em><\/strong>\u671f\u520a\u4e0a\u3002\u5357\u4eac\u5927\u5b66\u535a\u58eb\u6bd5\u4e1a\u751f\u3001\u4e0a\u6d77\u7406\u5de5\u5927\u5b66\u9752\u5e74\u6559\u5e08\u5ed6\u5ced\u6ce2\u535a\u58eb\uff0c\u4e0a\u6d77\u7406\u5de5\u5927\u5b66\u7855\u58eb\u7814\u7a76\u751f\u5b59\u5029\u6960\u548c\u5357\u4eac\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u5f90\u660a\u6210\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\"\"<\/p>\n

3.<\/strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

    \n
  1. \u8bbe\u8ba1\u5236\u5907\u4e86\u4e09\u79cd\u4e8c\u55eaCOFs\u6750\u6599\uff08TpDz, TpMd\u548cTpPz\uff09\uff0c\u7528\u4e8e\u5149\u50ac\u5316\u9ad8\u6548\u5236\u5907H2<\/sub>O2<\/sub>\u3002<\/li>\n
  2. \u7eaf\u6c34\u6761\u4ef6\u4e0b\u54d2\u55ea\u529f\u80fd\u5316COFs\uff08TpDz\uff09H2<\/sub>O2<\/sub>\u4ea7\u7387\u8fbe\u52307327 \u03bcmol g\u22121<\/sup> h\u22121<\/sup>\uff0c\u8868\u73b0\u51fa\u6700\u4f18\u7684\u5149\u50ac\u5316\u6027\u80fd\u3002<\/li>\n
  3. \u5b9e\u9a8c\u7ed3\u5408\u8ba1\u7b97\uff0c\u7cfb\u7edf\u6df1\u5165\u7684\u7814\u7a76\u4e86\u4e8c\u55eaCOFs\u4f53\u7cfb\u4e2d\u6c2e\u539f\u5b50\u4f4d\u7f6e\u5bf9\u5149\u50ac\u5316\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/li>\n<\/ol>\n

     <\/p>\n

    4.<\/strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>1.<\/strong>\u4e0d\u540c\u76f8\u5bf9\u6c2e\u4f4d\u7f6e\u7684<\/strong>DAzCOFs<\/strong>\u5316\u5b66\u7ed3\u6784\u793a\u610f\u56fe<\/strong>\u3002<\/strong>\u00a9 1999-2023 John Wiley & Sons, Inc.<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>2. <\/strong>\u00a9 1999-2023 John Wiley & Sons, Inc.<\/p>\n

    \uff08a-c\uff09TpDz\u3001TpMd\u548cTpPz AA\u5806\u53e0\u6a21\u5f0f\u548cAB\u5806\u53e0\u6a21\u5f0f\u4e0b\u7684\u6a21\u62dfPXRD\u56fe\u3002<\/p>\n

    \uff08d-f\uff09AA\u5806\u53e0\u6a21\u5f0f\u4e0b\u6240\u642d\u5efa\u6676\u80de\u7684\u6b63\u89c6\u56fe\u4e0e\u4fa7\u89c6\u56fe\u3002<\/p>\n

    \uff08g\uff0977 K\u4e0b\u7684N2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

    \uff08h\uff09\u7528NLDFT\u8ba1\u7b97\u7684DAzCOFs\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

    \uff08j\uff09TpDz\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>3. <\/strong>\u00a9 1999-2023 John Wiley & Sons, Inc.<\/p>\n

    \uff08a\uff09TpDz, TpMd\u4e0eTpPz\u7684\u7d2b\u5916\/\u53ef\u89c1DRS\u5149\u8c31\u3002<\/p>\n

    \uff08b\uff09TpDz, TpMd\u4e0eTpPz\u7684Tauc\u56fe\u3002<\/p>\n

    \uff08c\uff09VBXPS\u6d4b\u5b9a\u7684TpDz, TpMd\u4e0eTpPz\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

    \uff08d\uff09TpDz, TpMd\u4e0eTpPz\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>4. <\/strong>\u00a9 1999-2023 John Wiley & Sons, Inc.<\/p>\n

    \uff08a\uff09TpDz, TpMd, TpPz\u4e0e g-C3<\/sub>N4<\/sub>\u7684\u5149\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

    \uff08b\uff09DAzCOFs\u4e0e\u5176\u4ed6\u5df2\u62a5\u9053COFs\u57fa\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

    \uff08c\uff09TpDz\u5728\u7279\u5b9a\u6ce2\u957f\uff08420, 450, 500\u548c600 nm\uff09\u4e0b\u7684\u8868\u89c2\u91cf\u5b50\u4ea7\u7387\u3002<\/p>\n

    \uff08d\uff09\u4e0d\u540c\u6e05\u9664\u5242\u5bf9TpMd\u76f8\u5bf9\u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u4ea7\u7387\u7684\u5f71\u54cd\u3002<\/p>\n

    \uff08e\uff09\u57fa\u4e8eTpDz\u7684\u5149\u50ac\u5316\u4f53\u7cfb\u9ed1\u6697\u5904\u548c\u53ef\u89c1\u5149\u7167\u5c045 min\u540e\u7684EPR\u5149\u8c31\u3002<\/p>\n

    \uff08f\uff09-1.0 V\uff08vs. Ag\/AgCl\uff09\u4e0bRDE\u7535\u5316\u5b66\u6d4b\u8bd5\u5f97\u5230\u7684Koutecky-Levich\u56fe\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>5. <\/strong>\u00a9 1999-2023 John Wiley & Sons, Inc.<\/p>\n

    \uff08a\uff09TpDz\uff0cTpMd\u548cTpPz\u5149\u50ac\u5316ORR\u8def\u5f84\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

    \uff08b\uff09\u7406\u8bba\u8ba1\u7b97\u63a8\u6d4b\u7684\u6d3b\u5316O2<\/sub>\u5206\u5b50\u7684\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

    \uff08c\uff092700-3000 cm-1<\/sup>\u548c\uff08d\uff09850-1150 cm-1<\/sup>\u5904TpDz\u5bf9\u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u5408\u6210\u4f5c\u7528\u7684DRIFTS\u5149\u8c31\u3002<\/p>\n

    \uff08e\uff09\u63a8\u6d4b\u7684\u57fa\u4e8eTpDz\u7684\u5149\u50ac\u5316\u5408\u6210H2<\/sub>O2<\/sub>\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

    5.<\/strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u8005\u8bbe\u8ba1\u5408\u6210\u4e86\u4e09\u79cd\u4e8c\u55ea\u529f\u80fd\u5316COFs\uff0c\u7528\u4e8eH2<\/sub>O2<\/sub>\u7684\u9ad8\u6548\u5149\u50ac\u5316\u5236\u5907\u3002\u5176\u4e2d\uff0cTpDz\u5728\u4e09\u79cdCOFs\u4e2d\u8868\u73b0\u51fa\u6700\u4f73\u7684\u5149\u50ac\u5316\u6027\u80fd\uff0c\u662f\u76ee\u524d\u5df2\u62a5\u9053\u7684\u7528\u4e8e\u5408\u6210H2<\/sub>O2<\/sub>\u7684\u6700\u4f73COF\u57fa\u5149\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u9664\u4e86\u7a81\u51fa\u7684\u50ac\u5316\u6027\u80fd\uff0c\u672c\u7814\u7a76\u540c\u65f6\u7cfb\u7edf\u7814\u7a76\u4e86\u6c2e\u76f8\u5bf9\u4f4d\u7f6e\u5bf9\u6742\u6c2e\u529f\u80fd\u5316COFs\u5149\u50ac\u5316\u5242\u7684\u5f71\u54cd\uff0c\u5bf9\u5408\u7406\u8bbe\u8ba1\u7528\u4e8e\u5149\u50ac\u5316\u5408\u6210\u7684\u591a\u5b54\u805a\u5408\u7269\u57fa\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u7684\u63a8\u52a8\u4e0e\u501f\u9274\u610f\u4e49\u3002<\/p>\n

     <\/p>\n

    \u539f\u6587\u8be6\u60c5<\/strong>\uff1aLiao, Qiaobo, et al. Regulating relative nitrogen locations of diazine functionalized covalent organic frameworks for overall H2<\/sub>O2<\/sub> photosynthesis. Angew. Chem. Int. Ed.<\/em> (2023). https:\/\/doi.org\/10.1002\/anie.202310556<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

    1.\u3010\u5bfc\u8bfb\u3011 \u8fc7\u6c27\u5316\u6c22\uff08H2O2\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u6548\u7eff\u8272\u6c27\u5316\u5242\uff0c\u88ab\u8ba4\u4e3a\u662f21\u4e16\u7eaa\u6700\u91cd\u8981\u7684\u5316\u5b66\u54c1\u4e4b\u4e00\uff0c H2O2\u7684\u5236\u5907\u4e3b\u8981\u4f9d\u8d56\u4f20\u7edf\u84bd\u918c\u6cd5\uff0c\u4f46\u8be5\u65b9\u6cd5\u6210\u672c\u9ad8\uff0c\u4e14\u5371\u9669\u6709\u6bd2\u3002\u5149…<\/p>\n","protected":false},"author":35692,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-254479","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254479"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35692"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=254479"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254479\/revisions"}],"predecessor-version":[{"id":254488,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254479\/revisions\/254488"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=254479"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=254479"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=254479"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}