{"id":254526,"date":"2023-09-21T06:54:47","date_gmt":"2023-09-20T22:54:47","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=254526"},"modified":"2023-09-20T16:07:44","modified_gmt":"2023-09-20T08:07:44","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%ae%81%e6%95%99%e6%8e%88-%e5%88%98%e6%95%8f%e6%95%99%e6%8e%88nano-energy-%e5%8c%ae%e7%94%b5%e5%ad%90%e9%92%b4%e7%ba%b3%e7%b1%b3%e6%99%b6%e4%bf%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=254526","title":{"rendered":"\u4e2d\u5357\u5927\u5b66\u5f20\u5b81\u6559\u6388\/\u5218\u654f\u6559\u6388Nano Energy: \u532e\u7535\u5b50\u94b4\u7eb3\u7c73\u6676\u4fc3\u8fdb\u785d\u9178\u6839\u7535\u50ac\u5316\u8fd8\u539f\u5408\u6210\u6c28"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u6768\u5b9d\u9e4f<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u5f20\u5b81*\uff0c\u5218\u654f*<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u4e2d\u5357\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\uff0c\u4e2d\u5357\u5927\u5b66\u7269\u7406\u4e0e\u7535\u5b50\u5b66\u9662<\/p>\n<p><strong><b>\u7814\u7a76\u80cc\u666f<\/b><\/strong><\/p>\n<p>\u6c28(NH<sub>3<\/sub>)\u662f\u4e00\u79cd\u91cd\u8981\u7684\u5de5\u4e1a\u5316\u5b66\u54c1\uff0c\u662f\u5236\u4f5c\u5316\u5de5\u54c1\u4e0e\u5316\u80a5\u7684\u91cd\u8981\u539f\u6599\uff0c\u540c\u65f6\u4e5f\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u7eff\u8272\u80fd\u6e90\u50a8\u5b58\/\u8f6c\u5316\u7684\u8f7d\u4f53\u3002\u5728\u4f20\u7edf\u5de5\u4e1a\u4e0a\uff0cNH<sub>3<\/sub>\u662f\u5728\u9ad8\u6e29\u9ad8\u538b\u4e0b\u901a\u8fc7Haber-Bosch\u5de5\u827a\u751f\u4ea7\u7684\uff0c\u8be5\u5de5\u827a\u4e0d\u4ec5\u80fd\u8017\u9ad8\uff0c\u800c\u4e14\u8fd8\u4f1a\u6392\u653e\u5927\u91cf\u5730\u6e29\u5ba4\u6c14\u4f53\u3002\u785d\u9178\u76d0(NO<sub>3<\/sub><sup>\u2212<\/sup>)\u4f5c\u4e3a\u4eba\u7c7b\u6d3b\u52a8\u7684\u4e00\u79cd\u5e38\u89c1\u4ea7\u7269\uff0c\u5176\u5927\u91cf\u5b58\u5728\u4e8e\u5e9f\u6c34\u4e2d\uff0c\u4e0d\u4ec5\u6c61\u67d3\u6c34\u8d28\u7834\u574f\u751f\u6001\u5e73\u8861\uff0c\u8fd8\u4f1a\u5f15\u8d77\u4e25\u91cd\u75be\u75c5\u5a01\u80c1\u4eba\u7c7b\u5065\u5eb7\u3002\u4ece\u73af\u4fdd\u548c\u80fd\u6e90\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u901a\u8fc7\u7eff\u8272\u7535\u80fd\u7684\u9a71\u52a8\uff0c\u5c06\u5e9f\u6c34\u4e2d\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u7684NH<sub>3<\/sub>\u662f\u4e00\u79cd\u65e2\u8282\u80fd\u53c8\u73af\u4fdd\u7684\u9014\u5f84\u3002\u56e0\u6b64\uff0c\u7535\u50ac\u5316NO<sub>3<\/sub><sup>\u2212<\/sup>\u8fd8\u539f\u5408\u6210\u6c28\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u53ef\u66ff\u4ee3Haber-Bosch\u5de5\u827a\u7684\u7eff\u8272\u5236\u6c28\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u76ee\u524d\u7535\u50ac\u5316NO<sub>3<\/sub><sup>\u2212<\/sup>\u8fd8\u539f\u5236NH<sub>3<\/sub>\u7684\u6548\u7387\u8f83\u4f4e\uff0c\u4ecd\u4e0d\u80fd\u6ee1\u8db3\u5b9e\u9645\u5de5\u4e1a\u5e94\u7528\u9700\u6c42\u3002\u63a2\u7d22\u548c\u5f00\u53d1\u9ad8\u6548\u50ac\u5316\u5242\u662f\u5b9e\u73b0NO<sub>3<\/sub><sup>\u2212<\/sup>\u8fd8\u539f\u5236NH<sub>3<\/sub>\u5de5\u4e1a\u5316\u5e94\u7528\u7684\u5173\u952e\u3002<\/p>\n<p><strong><b>\u6587\u7ae0\u7b80\u4ecb<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea<strong><b>\u4e2d\u5357\u5927\u5b66<\/b><\/strong>\u7684<strong><b>\u5f20\u5b81\u6559\u6388<\/b><\/strong>\u56e2\u961f\u4e0e<strong><b>\u5218\u654f\u6559\u6388<\/b><\/strong>\u56e2\u961f\u5408\u4f5c\uff0c\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aNano\u00a0Energy\u4e0a\u53d1\u8868\u9898\u4e3a\u201cElectron-deficient cobalt nanocrystals for promoted nitrate electrocatalytic\u00a0reduction to synthesize ammonia\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u8bba\u6587\u8bbe\u8ba1\u4e86\u4e00\u79cd\u532e\u7535\u5b50\u7684Co\u91d1\u5c5e\u7eb3\u7c73\u6676\u6765\u4fc3\u8fdb\u785d\u9178\u6839\u8fd8\u539f\u5236\u6c28\u3002\u5c06\u5421\u5576\u6c2e\u63ba\u6742\u7684\u78b3\u4e0e\u91d1\u5c5eCo\u7ed3\u5408(Co\/PN-C)\uff0c\u901a\u8fc7PN-C\u7684\u5438\u7535\u5b50\u6548\u5e94\u4f7f\u91d1\u5c5eCo\u5931\u53bb\u7535\u5b50\u3002\u532e\u7535\u5b50\u6001\u7684Co\u6709\u5229\u4e8eNO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u540c\u65f6\u4fc3\u8fdb*NH\u7684\u6c22\u5316\u5f62\u6210NH<sub>3<\/sub>\uff0c\u4ece\u800c\u5b9e\u73b0\u4e00\u4e2a\u9ad8\u6548\u5730\u785d\u9178\u6839\u8fd8\u539f\u5236\u6c28\u8fc7\u7a0b\u3002\u8be5\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u8c03\u8282\u91d1\u5c5e\u50ac\u5316\u5242\u7535\u5b50\u6001\u7684\u7b56\u7565\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u785d\u9178\u6839\u8fd8\u539f\u5236\u6c28\u7535\u50ac\u5316\u5242\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254528\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-1-5.png\" alt=\"\" width=\"700\" height=\"347\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-1-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-1-5-300x149.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u672c\u6587\u8981\u70b9<\/b><\/strong><\/p>\n<p><strong><b>\u8981\u70b9\u4e00\uff1a<\/b><\/strong>\u901a\u8fc7DFT\u8ba1\u7b97\u7814\u7a76\u4e86\u77f3\u58a8\u78b3(C)\uff0c\u77f3\u58a8\u6c2e\u63ba\u6742\u7684\u78b3(GN-C)\uff0c\u5421\u5576\u6c2e\u63ba\u6742\u7684\u78b3(PN-C)\u4e0e\u91d1\u5c5eCo\u590d\u5408\u7684\u754c\u9762\u7535\u5b50\u7ed3\u6784\uff0c\u53d1\u73b0PN-C\u5177\u6709\u8f83\u5f3a\u7684\u5438\u7535\u5b50\u80fd\u529b\uff0c\u590d\u5408\u540e\u9020\u6210\u91d1\u5c5eCo\u5931\u53bb\u7535\u5b50\u53d8\u6210\u532e\u7535\u5b50\u6001\u7684Co\u3002\u532e\u7535\u5b50\u7684Co\u80fd\u591f\u589e\u5f3aNO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u540c\u65f6\u4f18\u5316*NH\u7684\u5438\u9644\u5e76\u4fc3\u8fdb\u52a0\u6c22\u8fc7\u7a0b\uff0c\u4f7f\u5f97\u51b3\u901f\u6b65\u7684\u53cd\u5e94\u80fd\u5792\u964d\u4f4e\uff0c\u4ece\u800c\u6709\u5229\u4e8eNH<sub>3<\/sub>\u7684\u751f\u6210\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e8c\uff1a<\/b><\/strong>\u901a\u8fc7\u9ad8\u6e29\u70ed\u89e3\u8fd8\u539fCo-MOF\u6210\u529f\u5730\u5236\u5907\u51faCo\/PN-C\u50ac\u5316\u5242\u3002\u4e00\u7cfb\u5217\u7ed3\u6784\u8868\u5f81\u8868\u660e\uff0c\u7eb3\u7c73\u7ea7\u7684\u91d1\u5c5eCo\u9897\u7c92\u88ab\u5747\u5300\u5730\u5206\u6563\u5728PN-C\u5305\u8986\u5c42\u5185\u3002XPS\u8bc1\u5b9e\u5305\u8986\u5c42\u4e3b\u8981\u662f\u5421\u5576\u6c2e\u63ba\u6742\u7684\u78b3\uff0cPN-C\u7684\u5305\u8986\u4f7f\u5f97Co\u5931\u53bb\u7535\u5b50\uff0c\u7ed3\u5408\u80fd\u53d8\u9ad8\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e09\uff1a<\/b><\/strong>\u5728\u6db2\u6d41\u7535\u89e3\u6c60\u4e2d\uff0c\u4e0e\u91d1\u5c5eCo\u76f8\u6bd4\uff0cCo\/PN-C\u5c55\u73b0\u51fa\u4e86\u4e00\u4e2a\u660e\u663e\u589e\u5f3a\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u8fd8\u539f\u6027\u80fd\u3002\u5176\u751f\u6210NH<sub>3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe97.8 \u00b1 2.0%\uff0c\u5728\u4f4e\u6d53\u5ea6\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u7535\u89e3\u6db2\u4e2d\uff0cNO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u53bb\u9664\u7387\u63a5\u8fd1100%\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u56db\uff1a<\/b><\/strong>\u5728\u819c\u7535\u6781\u7ec4\u4ef6\u7cfb\u7edf\u4e2d\uff0cCo\/PN-C\u4ecd\u7136\u4fdd\u6301\u8f83\u9ad8\u7684\u9009\u62e9\u6027\uff0c\u5176\u4ea7NH<sub>3<\/sub>\u7684\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe1.3\u00a0A cm<sup>\u22122<\/sup>\uff0cNH<sub>3<\/sub>\u7684\u4ea7\u7387\u8fbe\u5230109 mg h<sup>\u22121<\/sup>\u00a0cm<sup>\u22122<\/sup>\u3002\u540c\u65f6\uff0c\u4e0e\u91d1\u5c5eCo\u76f8\u6bd4\uff0cCo\/PN-C\u5448\u73b0\u51fa\u4e00\u4e2a\u660e\u663e\u589e\u5f3a\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5176\u5404\u65b9\u9762\u6027\u80fd\u4f18\u4e8e\u5927\u591a\u6570\u62a5\u9053\u7684\u50ac\u5316\u5242\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u4e94\uff1a<\/b><\/strong>\u901a\u8fc7\u539f\u4f4d\u7535\u5316\u5b66\u62c9\u66fc\u548c\u7ea2\u5916\u5149\u8c31\u7814\u7a76\uff0c\u8bc1\u5b9e\u4e86\u6027\u80fd\u6539\u5584\u7684\u4e3b\u8981\u539f\u56e0\u662f\u7f3a\u7535\u5b50\u7684Co\u6539\u5584\u4e86NO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u540c\u65f6\u7a33\u5b9a*NH\u4e2d\u95f4\u4f53\u3002\u6b64\u5916\uff0cCo\/PN-C\u80fd\u591f\u4fc3\u8fdb\u6c34\u89e3\u63d0\u4f9b\u5927\u91cf\u7684\u8d28\u5b50\u53c2\u4e0e*NH\u7684\u6c22\u5316\u8fc7\u7a0b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254529\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-3-5.png\" alt=\"\" width=\"700\" height=\"639\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-3-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-3-5-300x274.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0DFT<\/b><\/strong><strong><b>\u8ba1\u7b97\u6a21\u62df<\/b><\/strong>\uff1a(a) Co\/C, Co\/GN-C\u548cCo\/PN-C\u7684\u539f\u5b50\u7ed3\u6784\u6a21\u578b\u548c\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u56fe\uff1b(b)\u00a0\u53cd\u5e94\u4e2d\u95f4\u4f53\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53f0\u9636\u56fe\uff1b(c) *NO<sub>3<\/sub>\u4e2d\u95f4\u4f53\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5438\u9644\u80fd\uff0c\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u53ca\u7535\u5b50\u8f6c\u79fb\u60c5\u51b5\uff1b(d) *NH\u4e2d\u95f4\u4f53\u5438\u9644\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u6295\u5f71\u6676\u4f53\u8f68\u9053\u6c49\u5bc6\u5c14\u987f\u5e03\u5c45(pCOHP)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254530\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-4-5.png\" alt=\"\" width=\"700\" height=\"685\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-4-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-4-5-300x294.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Co\u548cCo\/PN-C\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong>\uff1a(a) XRD\u56fe\u8c31\uff1b(b) Co\/PN-C\u7684SEM\u56fe\uff1b(c) Co\/PN-C\u7684TEM\u56fe\uff1b(d, e) Co\/PN-C\u7684HR-TEM\u56fe\uff1b(f) N 1s\u7684XPS\u56fe\u8c31\uff1b(g) Co\u00a02p\u7684XPS\u56fe\u8c31\uff1b(h) X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\u8c31\uff1b(i) \u5085\u91cc\u53f6\u53d8\u6362X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u8c31\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254531\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-2-5.png\" alt=\"\" width=\"700\" height=\"429\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-2-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-2-5-300x184.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Flow<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Cell\u7535\u89e3\u6c60\u4e2d\u7684<\/b><\/strong><strong><b>NO<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><sup><b>\u2212<\/b><\/sup><\/strong><strong><b>\u8fd8\u539f\u6027\u80fd<\/b><\/strong>\uff1a(a) \u53cd\u5e94\u88c5\u7f6e\u5185\u90e8\u793a\u610f\u56fe\uff1b(b) \u4e0d\u540c\u7535\u4f4d\u4e0b\u751f\u6210NH<sub>3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff1b(c) \u4e0d\u540c\u7535\u4f4d\u4e0bNH<sub>3<\/sub>\u7684\u4ea7\u7387\uff1b(d) \u4e0d\u540c\u7535\u89e3\u6db2\u6d53\u5ea6\u4e2dNH<sub>3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff1b(e) Co\/PN-C\u5728\u4f4e\u6d53\u5ea6\u7535\u89e3\u6db2\u4e2d\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u53bb\u9664\u7387\uff1b(f) Co\u5728\u4f4e\u6d53\u5ea6\u7535\u89e3\u6db2\u4e2d\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u53bb\u9664\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254532\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-5-5.png\" alt=\"\" width=\"700\" height=\"369\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-5-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-5-5-300x158.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u56fe4<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>MEA\u7535\u89e3\u6c60\u4e2d\u7684<\/b><\/strong><strong><b>NO<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><sup><b>\u2212<\/b><\/sup><\/strong><strong><b>\u8fd8\u539f\u6027\u80fd<\/b><\/strong>\uff1a(a, b) \u53cd\u5e94\u88c5\u7f6e\u7ed3\u6784\u793a\u610f\u56fe\uff1b(c) \u4e0d\u540c\u7535\u4f4d\u4e0b\u751f\u6210NH<sub>3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u7535\u6d41\u5bc6\u5ea6\uff1b(d) \u4e0d\u540c\u7535\u4f4d\u4e0bNH<sub>3<\/sub>\u7684\u4ea7\u7387\uff1b(e) \u5faa\u73af\u7a33\u5b9a\u6027\uff1b(f) \u591a\u65b9\u9762\u7684\u6027\u80fd\u5bf9\u6bd4\u7ed3\u679c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254533\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-6-2.png\" alt=\"\" width=\"700\" height=\"794\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-6-2.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u7247-6-2-264x300.png 264w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>\u56fe5<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u539f\u4f4d\u7535\u5316\u5b66\u62c9\u66fc\u548c\u7ea2\u5916\u5149\u8c31\u7814\u7a76<\/b><\/strong>\uff1a(a, b) \u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff1b(c, d) \u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\uff1b(e) \u4e0d\u540c\u7535\u4f4d\u4e0bO-N-O\u632f\u52a8\u5e26\u7684\u5cf0\u9762\u79ef\u53d8\u5316\u60c5\u51b5\uff1b(f) \u4e0d\u540c\u7535\u4f4d\u4e0bN-H\u632f\u52a8\u5e26\u7684\u5cf0\u9762\u79ef\u53d8\u5316\u60c5\u51b5\uff1b(g) \u50ac\u5316\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n<p><strong><b>\u6587\u7ae0\u7ed3\u8bba<\/b><\/strong><\/p>\n<p>\u4e00\u79cd\u532e\u7535\u5b50\u7684\u91d1\u5c5eCo\u7eb3\u7c73\u6676\u6781\u5927\u5730\u63d0\u5347\u4e86\u7535\u50ac\u5316\u785d\u9178\u6839\u8fd8\u539f\u5236\u6c28\u7684\u6548\u7387\u3002\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u9884\u6d4b\u4e86\u5421\u5576\u6c2e\u63ba\u6742\u7684\u78b3\u4e0e\u91d1\u5c5eCo\u590d\u5408\u80fd\u591f\u6709\u6548\u5730\u8bf1\u5bfcCo\u5931\u53bb\u7535\u5b50\uff0c\u5f62\u6210\u532e\u7535\u5b50\u6001\u7684Co\u3002\u8fd9\u79cd\u532e\u7535\u5b50\u6001\u7684Co\u6539\u5584\u4e86NO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u540c\u65f6\u4fc3\u8fdb*NH\u52a0\u6c22\u5f62\u6210NH<sub>3<\/sub>\u3002\u4e0e\u91d1\u5c5eCo\u76f8\u6bd4\uff0cCo\/PN-C\u5c55\u73b0\u51fa\u4e00\u4e2a\u660e\u663e\u589e\u5f3a\u7684NO<sub>3<\/sub><sup>\u2212<\/sup>\u8fd8\u539f\u6027\u80fd\u3002\u5176\u4ea7NH<sub>3<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe97.8 \u00b1 2.0%\uff0cNO<sub>3<\/sub><sup>\u2212<\/sup>\u7684\u53bb\u9664\u7387\u63a5\u8fd1100%\uff0c\u4ea7NH<sub>3<\/sub>\u7684\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe1.3\u00a0A\u00a0cm<sup>\u22122<\/sup>\uff0cNH<sub>3<\/sub>\u7684\u4ea7\u7387\u4e3a109 mg h<sup>\u22121<\/sup>\u00a0cm<sup>\u22122<\/sup>\u3002\u4f18\u5f02\u7684\u6027\u80fd\u8868\u660eCo\/PN-C\u6709\u4e00\u4e2a\u8f83\u597d\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p><strong><b>\u6587\u7ae0\u94fe\u63a5<\/b><\/strong><\/p>\n<p>Electron-deficient cobalt nanocrystals for promoted nitrate electrocatalytic\u00a0reduction to synthesize ammonia<\/p>\n<p>Baopeng Yang, Yulong Zhou, Zhencong Huang, Binbao Mei, Qing Kang, Gen Chen, Xiaohe Liu, Zheng Jiang, Min Liu*, and Ning Zhang*<\/p>\n<p>https:\/\/doi.org\/10.1016\/j.nanoen.2023.108901<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u6768\u5b9d\u9e4f \u901a\u8baf\u4f5c\u8005\uff1a\u5f20\u5b81*\uff0c\u5218\u654f* \u901a\u8baf\u5355\u4f4d\uff1a\u4e2d\u5357\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\uff0c\u4e2d\u5357\u5927\u5b66\u7269\u7406\u4e0e\u7535\u5b50\u5b66\u9662 \u7814\u7a76\u80cc\u666f \u6c28(NH3)\u662f\u4e00\u79cd\u91cd\u8981\u7684\u5de5\u4e1a\u5316\u5b66\u54c1\uff0c\u662f\u5236\u4f5c\u5316&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-254526","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254526"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=254526"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254526\/revisions"}],"predecessor-version":[{"id":254534,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/254526\/revisions\/254534"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=254526"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=254526"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=254526"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}