{"id":254557,"date":"2023-09-21T08:36:10","date_gmt":"2023-09-21T00:36:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=254557"},"modified":"2023-09-21T08:36:10","modified_gmt":"2023-09-21T00:36:10","slug":"%e5%8f%8c%e5%8e%9f%e5%ad%90%e5%82%ac%e5%8c%96%ef%bc%81%ef%bc%81%e6%96%b0%e5%8a%a0%e5%9d%a1%e5%9b%bd%e7%ab%8b-%e6%b8%85%e5%8d%8e-epfl-astar%e5%9b%9b%e6%a0%a1%e8%81%94%e5%8f%91nature%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=254557","title":{"rendered":"\u53cc\u539f\u5b50\u50ac\u5316\uff01\uff01\u65b0\u52a0\u5761\u56fd\u7acb\/\u6e05\u534e\/EPFL\/A*STAR\u56db\u6821\u8054\u53d1Nature\uff01"},"content":{"rendered":"<p><strong><b>\u4e00\u3001<\/b><\/strong><strong><b>\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5bf9\u4e8e\u53d1\u5c55\u6709\u673a\u5408\u6210\u4e2d\u7684\u5206\u5b50\u590d\u6742\u6027\u81f3\u5173\u91cd\u8981\uff0c\u901a\u5e38\u5229\u7528\u5747\u76f8\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u3002\u5c3d\u7ba1\u5177\u6709\u65e0\u4e0e\u4f26\u6bd4\u7684\u5408\u6210\u80fd\u529b\uff0c\u4f46\u4f7f\u7528\u5747\u76f8\u50ac\u5316\u5242\u5f15\u8d77\u7684\u95ee\u9898\u5305\u62ec\u5176\u6f5c\u5728\u7684\u9ad8\u751f\u4ea7\u6210\u672c\u3001\u4e0e\u4ea7\u54c1\u5206\u79bb\u548c\u7eaf\u5316\u4ee5\u53ca\u50ac\u5316\u5242\u56de\u6536\u6311\u6218\u76f8\u5173\u7684\u73af\u5883\u5f71\u54cd\u3002\u5f00\u53d1\u591a\u76f8\u50ac\u5316\u5de5\u827a\u5bf9\u4e8e\u5927\u89c4\u6a21\u751f\u4ea7\u5177\u6709\u5f88\u9ad8\u7684\u5438\u5f15\u529b\uff0c\u4ee5\u4fc3\u8fdb\u50ac\u5316\u5242\u7684\u5206\u79bb\u3001\u56de\u6536\u548c\u518d\u5229\u7528\uff0c\u5e76\u63d0\u9ad8\u8fde\u7eed\u6d41\u5408\u6210\u7684\u9002\u5e94\u6027\u3002\u8fd9\u4e9b\u6f5c\u5728\u7684\u4f18\u52bf\u5f15\u53d1\u4e86\u5bf9\u56fa\u5b9a\u5316\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u548c\u7eb3\u7c73\u7ed3\u6784\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5e7f\u6cdb\u7814\u7a76\u3002\u5c3d\u7ba1\u6709\u4e9b\u5df2\u7ecf\u5728\u5de5\u4e1a\u5316\u751f\u4ea7\u4e2d\u6210\u529f\u5e94\u7528\uff0c\u4f46\u7531\u4e8e\u5bf9\u6d3b\u6027\u4f4d\u70b9\u7ed3\u6784\u7684\u63a7\u5236\u4e0d\u4f73\u6216\u4e0e\u8f7d\u4f53\u7684\u76f8\u4e92\u4f5c\u7528\u8f83\u5f31\uff0c\u4f7f\u5176\u5728\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u9002\u7528\u6027\u4ecd\u7136\u6709\u9650\u3002\u7814\u7a76\u8868\u660e\uff0c\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SACs\uff09\u5177\u6709\u660e\u786e\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f7f\u5176\u5bf9\u6709\u673a\u5408\u6210\u5177\u6709\u6f5c\u5728\u529f\u80fd\uff0c\u4f46\u7531\u4e8e\u7a7a\u95f4\u73af\u5883\u548c\u7535\u5b50\u91cf\u5b50\u6001\u7684\u9650\u5236\uff0c\u8fd9\u4e9b\u7a33\u5b9a\u5728\u56fa\u4f53\u8f7d\u4f53\u4e0a\u7684\u5355\u6838\u91d1\u5c5e\u7ed3\u6784\u53ef\u80fd\u4e0d\u662f\u50ac\u5316\u590d\u6742\u5206\u5b50\u8f6c\u5316\u7684\u6700\u4f73\u9009\u62e9\uff0c\u8fd9\u4e5f\u5f15\u53d1\u4e86\u5173\u4e8e\u5355\u6838\u91d1\u5c5e\u4f4d\u70b9\u662f\u5426\u4e3a\u590d\u6742\u5206\u5b50\u8f6c\u5316\u63d0\u4f9b\u6700\u4f73\u7ed3\u6784\u7684\u4e89\u8bba\u3002<\/p>\n<p><strong><b>\u4e8c\u3001<\/b><\/strong><strong><b>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n<p>\u5728\u6b64\uff0c<strong>\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u5415\u70af\u6559\u6388\uff0cMing 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catalysis for cross-coupling\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><em><i>N<\/i><\/em><\/strong><strong><em><i>ature<\/i><\/em><\/strong>\u4e0a\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254558\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u5c01\u9762-1.jpg\" alt=\"\" width=\"600\" height=\"310\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u5c01\u9762-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u5c01\u9762-1-300x155.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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class=\"aligncenter size-full wp-image-254559\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-2.jpg\" alt=\"\" width=\"600\" height=\"329\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-2.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-2-300x165.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 Cu<\/b><\/strong><strong><sub><b>g<\/b><\/sub><\/strong><strong><b>\/PCN\u7684\u5408\u6210\u4e0e\u8868\u5f81\u00a9 2023 Springer Nature<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254560\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2.jpg\" alt=\"\" width=\"600\" height=\"671\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2-268x300.jpg 268w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2 Cu<\/b><\/strong><strong><sub><b>g<\/b><\/sub><\/strong><strong><b>\/PCN\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u7684\u886c\u5e95\u8303\u56f4\u00a9 2023 Springer Nature<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254561\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-3.jpg\" alt=\"\" width=\"600\" height=\"693\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-3.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-3-260x300.jpg 260w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3 \u63d0\u51fa\u4e86\u5728Cu<\/b><\/strong><strong><sub><b>g<\/b><\/sub><\/strong><strong><b>\/PCN\u7684\u57fa\u7840\u4e0a\u8fdb\u884cC-O\u5076\u8054\u7684\u50ac\u5316\u673a\u7406\u00a9 2023 Springer Nature<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254562\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-3.jpg\" alt=\"\" width=\"600\" height=\"607\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-3.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-3-297x300.jpg 297w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4 \u53cc\u539f\u5b50\u50ac\u5316\u6709\u673a\u5408\u6210\u7684\u4f18\u52bf\u00a9 2023 Springer Nature<\/b><\/strong><\/p>\n<p><strong><b>\u4e94\u3001<\/b><\/strong><strong><b>\u3010\u6210\u679c\u542f\u793a\u3011<\/b><\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u7c7b\u65b0\u7684\u7531\u4e00\u5bf9\u4f4e\u4ef7\u91d1\u5c5e\u4e2d\u5fc3\u7ec4\u6210\u7684\u5f02\u8d28GAC\uff0c\u5176\u5177\u6709\u89c4\u5219\u7684\u57fa\u6001\u5206\u79bb\u548c\u9002\u5f53\u7684\u914d\u4f4d\u52a8\u529b\u5b66\u3002\u8fd0\u7528\u8be5\u6982\u5ff5\u951a\u5b9a\u4e86\u5728\u7eb3\u7c73\u6676PCN\u8f7d\u4f53\u4e0a\u7684\u94dc\u539f\u5b50\uff0c\u5b9a\u4e49\u4e86\u7ea64 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href=\"https:\/\/doi.org\/10.1038\/s41586-023-06529-z\"><strong><u>Geminal-atom catalysis for cross-coupling<\/u><\/strong><\/a><strong>\u201d<\/strong><strong>\uff08<\/strong><strong><em><i>N<\/i><\/em><\/strong><strong><em><i>ature<\/i><\/em><\/strong><strong><b>\uff0c<\/b><\/strong><strong>202<\/strong><strong>3<\/strong><strong>\uff0c<\/strong><strong>10.1038\/s41586-023-06529-z<\/strong><strong>\uff09<\/strong><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4ebaCYM\u7f16\u8bd1\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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