{"id":254601,"date":"2023-09-25T06:30:48","date_gmt":"2023-09-24T22:30:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=254601"},"modified":"2023-09-24T18:45:37","modified_gmt":"2023-09-24T10:45:37","slug":"%e5%8c%97%e5%a4%a7%e9%83%ad%e5%b0%91%e5%86%9bjacs%ef%bc%9a%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e7%9a%84%e6%b0%9f%e5%8c%96%e5%bc%ba%e5%8c%96%e4%ba%86%e9%92%af%e7%ba%b3%e7%b1%b3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=254601","title":{"rendered":"\u5317\u5927\u90ed\u5c11\u519bJACS\uff1a\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u6c1f\u5316\u5f3a\u5316\u94af\u7eb3\u7c73\u56e2\u7c07\u7ea6\u675f \u589e\u5f3a\u8fc7\u6c27\u5316\u6c22\u5149\u5408\u4f5c\u7528"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u5bfc\u8bfb<\/strong><\/p>\n<p>\u5728\u9633\u5149\u7684\u9a71\u52a8\u4e0b\u901a\u8fc7\u53cc\u7535\u5b50\u6c27\u8fd8\u539f\u5408\u6210\u8fc7\u6c27\u5316\u6c22(H<sub>2<\/sub>O<sub>2<\/sub>)\u662f\u76ee\u524d\u5149\u50ac\u5316\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5404\u79cd\u6709\u673a\u5149\u50ac\u5316\u5242\u3001\u65e0\u673a\u5149\u50ac\u5316\u5242\u548c\u590d\u5408\u5149\u50ac\u5316\u5242\u90fd\u88ab\u5f00\u53d1\u7528\u4e8e\u589e\u5f3aH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u5149\u5408\u6210\u4f5c\u7528\u3002\u5176\u4e2d\uff0cPd\u91d1\u5c5e\u5206\u79bb\u7c07\uff08ICs\uff09\uff0c\u4f5c\u4e3a\u7eb3\u7c73\u6750\u6599\u548c\u5355\u539f\u5b50\u4e4b\u95f4\u7684\u4e2d\u95f4\u7269\u8d28\uff0c\u7531\u4e8e\u5176\u53bb\u7535\u5b50\u8f68\u9053\u7684\u9ad8\u5ea6\u91cd\u53e0\uff0c\u5728H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u5149\u5408\u4f5c\u7528\u4e2d\u8868\u73b0\u51fa\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u5c3d\u7ba1\u5982\u6b64\uff0cPd ICs\u901a\u5e38\u56e0\u9ad8\u8868\u9762\u81ea\u7531\u80fd\u800c\u7a33\u5b9a\u6027\u8f83\u5dee\u3002<\/p>\n<p>\u7a33\u5b9a\u91d1\u5c5e\u5206\u79bb\u56e2\u7c07\u7684\u4e00\u4e2a\u5173\u952e\u7b56\u7565\u662f\u5c06\u5b83\u4eec\u7269\u7406\u9650\u5236\u5728\u591a\u5b54\u8f7d\u4f53\u4e2d\uff0c\u5982\u6cb8\u77f3\u3001\u4e2d\u5b54\u4e8c\u6c27\u5316\u7845\u3001\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u3001\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u3002\u7136\u800c\uff0c\u7b80\u5355\u7684\u7269\u7406\u9650\u5236\u4f1a\u53d7\u5230\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u8870\u51cf\u7684\u5f71\u54cd\u3002\u5f3a\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\uff08MSI\uff09\u5df2\u88ab\u8bc1\u660e\u53ef\u4ee5\u7a33\u5b9a\u91d1\u5c5e\u56e2\u7c07\u7684\u5206\u79bb\u5e76\u540c\u65f6\u4fc3\u8fdb\u7535\u5b50\u4f20\u8f93\uff0c\u8fd9\u4f1a\u5f71\u54cd\u50ac\u5316\u7684\u8010\u4e45\u6027\u548c\u6d3b\u6027\u3002\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u5408\u7406\u8bbe\u8ba1\u8f7d\u4f53\u4ee5\u63d0\u9ad8MSI\u5bf9\u4e8e\u7a33\u5b9a\u5206\u79bb\u91d1\u5c5e\u56e2\u7c07\u548c\u8c03\u6574\u5176\u50ac\u5316\u6d3b\u6027\u662f\u975e\u5e38\u6709\u8da3\u7684\uff0c\u8fd9\u5f15\u8d77\u4e86\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5f3a\u70c8\u5174\u8da3\u3002\u4f46\u8be5\u9886\u57df\u5c3d\u7ba1\u505a\u51fa\u4e86\u91cd\u8981\u7684\u52aa\u529b\uff0c\u5728\u62a5\u9053\u7684\u5149\u50ac\u5316\u7cfb\u7edf\u4e2d\uff0cMIC\u7684\u5f31\u9650\u5236\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u4ecd\u7136\u8f83\u4f4e\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u5728\u6b64\uff0c\u5317\u4eac\u5927\u5b66\u90ed\u5c11\u519b\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684\u6c1f\u5316\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u7b56\u7565\uff0c\u901a\u8fc7\u63d0\u9ad8MSI\u6765\u5f3a\u70c8\u9650\u5236Pd ICs\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u5149\u5408\u6210\u4f5c\u7528\u7684\u5149\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e24\u79cd\u5177\u6709~ 3nm\u7eb3\u7c73\u7a7a\u8154\u542b\u6c1f\u7684COFs (TAPT-TFPA COFs)\u548c\u4e0d\u542b\u6c1f\u7684COFs (TABT-BPA COFs)\u3002\u4e0d\u540c\u7684\u8868\u5f81\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5236\u5907\u7684COFs\u4e2d\uff0c\u5f3a\u7535\u8d1f\u6027\u6c1f\u4e0d\u4ec5\u589e\u5f3a\u4e86MSI\uff0c\u4fc3\u8fdb\u4e86\u5149\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u8fd8\u8c03\u8282\u4e86\u7eb3\u7c73\u7ea7\u9650\u5236\u533a\u57df\u7684\u5c40\u90e8\u5316\u5b66\u73af\u5883\uff0c\u4ece\u800c\u4f18\u5316\u4e86Pd ICs\u7684d\u6ce2\u6bb5\u4e2d\u5fc3\u3002\u6240\u5236\u5f97\u7684TAPT-TFPA COFs@Pd ICs\u5177\u6709\u8f83\u9ad8\u7684\u5149\u50ac\u5316H<sub>2<\/sub>O<sub>2<\/sub>\u901f\u7387(2143 \u03bcmol h<sup>\u22121<\/sup> g<sup>\u22121<\/sup>)\u548c\u826f\u597d\u7684100 h\u5149\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u662f\u6240\u62a5\u9053\u7684\u5149\u50ac\u5316\u5242\u4e2d\u6700\u597d\u7684\u3002<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong><em>Fluorination of Covalent Organic Framework Reinforcing the Confinement of Pd Nanoclusters Enhances Hydrogen Peroxide Photosynthesis<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u520a<strong><em>Journal of the American Chemical Society<\/em><\/strong>\u4e0a\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254602\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-11.png\" alt=\"\" width=\"692\" height=\"290\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-11.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-11-300x126.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>1\u3001\u8be5\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u6c1f\u5316\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u7684\u65b0\u7b56\u7565\uff0c\u4ee5\u5f3a\u70c8\u9650\u5236Pd ICs\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u5149\u5408\u6210\u4f5c\u7528\u7684\u5149\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<p>2\u3001\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\u5747\u8868\u660e\uff0c\u5f3a\u7535\u8d1f\u6027\u6c1f\u53ef\u4ee5\u589e\u52a0\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u5149\u50ac\u5316H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u3002\u3002<\/p>\n<p>3\u3001\u6700\u4f73\u5149\u50ac\u5316\u5242H<sub>2<\/sub>O<sub>2<\/sub>\u4ea7\u7387\u7a33\u5b9a\u57282143 \u03bcmol h<sup>\u22121<\/sup> g<sup>\u22121<\/sup>\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u81ea\u5236\u7684TPT-TFPA COFs@Pd ICs\u5728100 h\u4ee5\u4e0a\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u662f\u6240\u62a5\u9053\u7684\u6750\u6599\u4e2d\u6700\u597d\u7684\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254603\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-9.png\" alt=\"\" width=\"692\" height=\"324\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-9.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-9-300x140.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>TAPT-PBA COFs@Pd ICs<\/strong><strong> (<\/strong><strong>Pd ICs<\/strong><strong>\u7684\u7269\u7406\u7ea6\u675f<\/strong><strong>)<\/strong><strong>\u548c<\/strong><strong>TPT-TFPA COFs@Pd ICs<\/strong><strong> (COFs<\/strong><strong>\u7684\u6c1f\u5316\u4ee5\u52a0\u5f3a<\/strong><strong>Pd ICs<\/strong><strong>\u7684\u7ea6\u675f<\/strong><strong>)<\/strong><strong>\u7684\u793a\u610f\u56fe\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254604\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-8.png\" alt=\"\" width=\"692\" height=\"358\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-8.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-8-300x155.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>TAPT<\/strong><strong>\u3001<\/strong><strong>TFPA<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>FT-IR<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>TAPT<\/strong><strong>\u3001<\/strong><strong>TFPA<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA COFs@PdICs<\/strong><strong>\u7684\u62c9\u66fc\u5149\u8c31\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs<\/strong><strong>\u7684\u56fa\u6001<\/strong><strong><sup>13<\/sup><\/strong><strong>C NMR<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09\u5177\u6709<\/strong><strong>A\u2212A<\/strong><strong>\u5806\u53e0\u7684<\/strong><strong>TAPT-TFPA COFs<\/strong><strong>\u7684\u5206\u5b50\u7ed3\u6784\u3002\uff08<\/strong><strong>e<\/strong><strong>\uff09\u5177\u6709<\/strong><strong>A\u2212B<\/strong><strong>\u5806\u53e0\u7684<\/strong><strong>TAPT-TFPA COFs<\/strong><strong>\u7684\u5206\u5b50\u7ed3\u6784\u3002\uff08<\/strong><strong>f<\/strong><strong>\uff09\u5b9e\u9a8c\u548c\u6a21\u62df<\/strong><strong>TAPT-TFPA COFs<\/strong><strong>\u7684<\/strong><strong>XRD<\/strong><strong>\u56fe\u8c31\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254605\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-7.png\" alt=\"\" width=\"692\" height=\"330\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-7.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-7-300x143.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA@Pd Ics<\/strong><strong>\u5728<\/strong><strong>77 K<\/strong><strong>\u4e0b\u7684<\/strong><strong>N<sub>2<\/sub><\/strong><strong>\u5438\u9644\u7b49\u6e29\u7ebf\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@PdICs<\/strong><strong>\u7684<\/strong><strong>TEM<\/strong><strong>\u56fe\u50cf\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>HRTEM<\/strong><strong>\u56fe\u50cf\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@PdICs<\/strong><strong>\u7684<\/strong><strong>TEM<\/strong><strong>\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u56fe\u8c31\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254606\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72475-5.png\" alt=\"\" width=\"692\" height=\"502\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72475-5.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72475-5-300x218.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u5149\u50ac\u5316<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u5408\u6210\u5728\u5177\u6709\u4e0d\u540c<\/strong><strong>Pd<\/strong><strong>\u542b\u91cf\u7684\u5149\u50ac\u5316\u5242\u4e0a\u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>TAPT-TPA COFs@Pd ICs<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA COFs@PdICs<\/strong><strong>\u7684\u5149\u50ac\u5316<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u6d3b\u6027\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd Ics<\/strong><strong>\u5728\u4e0d\u540c\u5149\u8f90\u5c04\u6ce2\u957f\u4e0b<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u5149\u5408\u4f5c\u7528\u7684<\/strong><strong>AQE<\/strong><strong>\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA-COFs<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>PL<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>e<\/strong><strong>\uff09<\/strong><strong>TAPTPBA-COFs<\/strong><strong>\u548c<\/strong><strong>TAPT-PBA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>PL<\/strong><strong>\u5149\u8c31\u3002\uff08<\/strong><strong>f<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA-COFs<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684\u65f6\u95f4\u5206\u8fa8<\/strong><strong>PL<\/strong><strong>\u8870\u51cf\u3002\uff08<\/strong><strong>g<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u548c<\/strong><strong>TAPT-PBA COFs@Pd ICs<\/strong><strong>\u7684\u5149\u7535\u6d41\u3002\uff08<\/strong><strong>h<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>EPR<\/strong><strong>\u8c31\u3002\uff08<\/strong><strong>i<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u548c<\/strong><strong>TAPT-PBA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>EPR<\/strong><strong>\u5f3a\u5ea6\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254607\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72476-5.png\" alt=\"\" width=\"692\" height=\"661\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72476-5.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72476-5-300x287.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA@Pd ICs<\/strong><strong>\u7684\u4fef\u89c6\u56fe\u548c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4fa7\u89c6\u56fe\u7535\u8377\u5bc6\u5ea6\u5dee<\/strong><strong>(<\/strong><strong>\u9ec4\u8272\u548c\u84dd\u8272\u533a\u57df\u5206\u522b\u4ee3\u8868\u7535\u5b50\u79ef\u7d2f\u548c\u8017\u5c3d<\/strong><strong>)<\/strong><strong>\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09\u8ba1\u7b97<\/strong><strong>TAPT-TFPA@Pd ICs<\/strong><strong>\u4e2d<\/strong><strong>Pd<\/strong><strong>\u7684<\/strong><strong>DOS<\/strong><strong>\u3002<\/strong><strong>(d) TAPT-PBA@Pd ICs<\/strong><strong>\u7684<\/strong><strong>Pd DOS<\/strong><strong>\u8ba1\u7b97\u3002\uff08<\/strong><strong>e<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA@Pd ICs<\/strong><strong>\u5149\u50ac\u5316<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u673a\u7406\u793a\u610f\u56fe\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254608\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72477-3.png\" alt=\"\" width=\"692\" height=\"361\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72477-3.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72477-3-300x157.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u5149\u50ac\u5316\u5408\u6210<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u7684\u7a33\u5b9a\u6027\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u5149\u50ac\u5316\u5408\u6210<\/strong><strong>H<sub>2<\/sub>O<sub>2<\/sub><\/strong><strong>\u7684\u6d3b\u6027\u548c\u6700\u5148\u8fdb\u7684\u5149\u50ac\u5316\u5242\u6bd4\u8f83\u3002\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong> <strong>\u5149\u50ac\u5316\u540e\u7684<\/strong><strong>TAPT-TFPA COFs@Pd ICs<\/strong><strong>\u7684<\/strong><strong>TEM<\/strong><strong>\u56fe\u50cf\u3002\uff08<\/strong><strong>d<\/strong><strong>\uff09\u5149\u50ac\u5316\u540e\u7684<\/strong><strong>TAPT-PBA COFs@Pb ICs<\/strong><strong>\u7684<\/strong><strong>TEM<\/strong><strong>\u56fe\u50cf\u3002\uff08<\/strong><strong>e<\/strong><strong>\uff09\u7528\u4e8e\u52a0\u5f3a<\/strong><strong>Pd-ICs<\/strong><strong>\u9650\u5236\u7684<\/strong><strong>COFs<\/strong><strong>\u7684\u6c1f\u5316\u793a\u610f\u56fe\u3002\uff08<\/strong><strong>f<\/strong><strong>\uff09\u9650\u5236\u5728<\/strong><strong>TAPT-PBA<\/strong><strong>\u548c<\/strong><strong>TAPT-TFPA<\/strong><strong> COFs<\/strong><strong>\u4e2d\u7684<\/strong><strong>Pd-ICs<\/strong><strong>\u7684\u81ea\u7531\u80fd\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684\u6c1f\u5316COFs\u7b56\u7565\u6765\u52a0\u5f3aPd ICs\u7684\u9650\u5236\uff0c\u4ee5\u589e\u5f3aH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u5149\u5408\u6210\u4f5c\u7528\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728\u7531TPT-TFPA COFs\u6784\u5efa\u7684\u7eb3\u7c73\u7ea6\u675f\u533a\u4e2d\u5f15\u5165\u5f3a\u7535\u8d1f\u6027\u6c1f\u53ef\u4ee5\u589e\u5f3aPd-ICs\u4e0e\u8f7d\u4f53\u4e4b\u95f4\u7684\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u4f18\u5316Pd-ICs\u7684d\u6ce2\u6bb5\u4e2d\u5fc3\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u5149\u50ac\u5316\u5408\u6210H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u3002\u5236\u5907\u7684TAPT-TFPA COFs@Pd ICs\u96c6\u6210\u4f53\u7cfb\u5177\u6709\u8f83\u9ad8\u7684\u5149\u50ac\u5316H<sub>2<\/sub>O<sub>2<\/sub>\u4ea7\u7387\uff0c\u8fbe\u52302143 \u03bcmol h<sup>\u22121<\/sup> g<sup>\u22121<\/sup>\u3002\u6700\u91cd\u8981\u7684\u662f\uff0cTAPT-TFPA COFs@Pd ICs\u5bf9H<sub>2<\/sub>O<sub>2<\/sub>\u5408\u6210\u5177\u6709\u4f18\u5f02\u7684\u5149\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u8d85\u8fc7100 h\uff0c\u662f\u6240\u6709\u62a5\u9053\u7684\u5149\u50ac\u5316\u6750\u6599\u4e2d\u6700\u597d\u7684\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u5f00\u8f9f\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u7cbe\u786e\u5730\u5c06\u5f3a\u7535\u8d1f\u6027F\u539f\u5b50\u5f15\u5165\u6784\u5efa\u7684\u7eb3\u7c73\u7ea7\u9650\u5236\u533a\u57df\u6765\u63d0\u9ad8\u5149\u50ac\u5316\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><strong>Fluorination of Covalent Organic Framework Reinforcing the Confinement of Pd Nanoclusters Enhances Hydrogen Peroxide Photosynthesis<\/strong><strong>\uff0c<\/strong><strong>2023 <\/strong><strong>\uff0c<\/strong><strong>https:\/\/doi.org\/10.1021\/jacs.3c05914<\/strong><strong>\uff09<\/strong><\/p>\n<p>\u672c\u6587\u7531LWB\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb 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