{"id":254867,"date":"2023-10-05T08:46:51","date_gmt":"2023-10-05T00:46:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=254867"},"modified":"2023-10-06T20:38:00","modified_gmt":"2023-10-06T12:38:00","slug":"%e6%9c%80%e6%96%b0nature%ef%bc%81%ef%bc%81%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=254867","title":{"rendered":"\u6700\u65b0Nature\uff01\uff01\uff01"},"content":{"rendered":"<p style=\"text-align: center;\">\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u5728\u6709\u673a\u5408\u6210\u7684\u5386\u53f2\u4e0a\uff0c\u6784\u5efa\u542b\u67091,2-\u30011,3-\u5f02\u539f\u5b50\u53d6\u4ee3\u7247\u6bb5\u7684\u591a\u5b98\u80fd\u78b3\u6846\u4e00\u76f4\u662f\u6709\u673a\u5408\u6210\u7684\u6838\u5fc3\u4e3b\u9898\u3002\u4eba\u4eec\u5df2\u7ecf\u5f00\u53d1\u51fa\u8bb8\u591a\u65b9\u6cd5\u6765\u83b7\u53d6\u8fd9\u7c7b\u57fa\u56e2\uff0c\u800c\u8fd9\u7c7b\u53cd\u5e94\u7684\u7b56\u7565\u6027\u4f7f\u7528\u5386\u6765\u90fd\u662f\u4ee5\u6781\u6027\u9006\u5408\u6210\u5206\u6790\uff082e<sup>&#8211;<\/sup>\u65ad\u5f00\uff09\u4e3a\u6307\u5bfc\u3002\u636e\u62a5\u9053\uff0c\u8fd9\u4e9b\u53cc\u7535\u5b50\u6781\u6027\u53cd\u5e94\u7c7b\u578b\u7684\u53d8\u4f53\u6570\u4ee5\u5343\u8ba1\uff0c\u4ece\u800c\u6784\u6210\u4e86\u9006\u5408\u6210\u5206\u6790\u903b\u8f91\u7684\u57fa\u77f3\u3002\u7136\u800c\uff0c\u4f7f\u7528\u8fd9\u4e9b\u65b9\u6cd5\u8bbe\u590d\u6742\u5206\u5b50\u7ed3\u6784\uff0c\u5f80\u5f80\u9700\u8981\u8003\u8651\u7acb\u4f53\u9009\u62e9\u6027\u3001\u533a\u57df\u9009\u62e9\u6027\u548c\u5316\u5b66\u9009\u62e9\u6027\uff0c\u540c\u65f6\u8fd8\u8981\u5e73\u8861\u9002\u5f53\u7684\u6c27\u5316\u8fd8\u539f\u72b6\u6001\u3002\u56e0\u6b64\uff0c\u4eba\u4eec\u5f00\u53d1\u4e86\u5927\u91cf\u7684\u4fdd\u62a4\u57fa\u56e2\u3001\u8bd5\u5242\u548c\u7acb\u4f53\u5316\u5b66\u6807\u51c6\uff0c\u8fd8\u8981\u9002\u5f53\u5730\u90e8\u7f72\u5404\u79cd\u53cd\u5e94\uff0c\u9700\u8981\u591a\u5e74\u7684\u7ecf\u9a8c\u79ef\u7d2f\u3002\u8fd1\u5e74\u6765\uff0c\u4e00\u79cd\u4e0d\u540c\u7684\u9006\u5408\u6210\u65b9\u6cd5\uff1a\u4f7f\u7528\u57fa\u4e8e\u81ea\u7531\u57fa\u7684\u903b\u8f91\uff081e<sup>&#8211;<\/sup>\u65ad\u5f00\uff09\u6765\u521b\u5efa\u65b0\u7684C-C\u952e\uff0c\u5e76\u5728\u6b64\u8fc7\u7a0b\u4e2d\u907f\u514d\u4e0b\u6e38\u5b98\u80fd\u56e2\/\u4fdd\u62a4\u57fa\u7684\u64cd\u4f5c\u548c\u65e0\u5173\u7684\u6c27\u5316\u8fd8\u539f\u6ce2\u52a8\u3002\u4e3a\u6b64\uff0c\u53cc\u8131\u7fa7\u4ea4\u53c9\u5076\u8054\uff08dDCC\uff09\u662f\u5b9e\u73b0\u8fd9\u4e00\u613f\u666f\u7684\u6709\u529b\u5de5\u5177\u3002<\/p>\n<p style=\"text-align: center;\">\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c\u7f8e\u56fd\u65af\u514b\u91cc\u666e\u65af\u7814\u7a76Phil S. Baran\u6559\u6388\u548cYu Kawamata\u6559\u6388\u63d0\u51fa\u4e86\u4e00\u79cd\u7535\u50ac\u5316\u8131\u7fa7\u4ea4\u53c9\u5076\u8054\u65b9\u6cd5\u6765\u5408\u6210\u590d\u6742\u7684\u6709\u673a\u5206\u5b50\uff1a\u57fa\u4e8e\u81ea\u7531\u57fa\u7684Ni\/Ag\u7535\u50ac\u5316\u03b1-\u53d6\u4ee3\u5206\u5b50\u7fa7\u9178\u7684\u4ea4\u53c9\u5076\u8054\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u4e00\u79cd\u76f4\u89c2\u548c\u6a21\u5757\u5316\u7684\u65b9\u6cd5\u6765\u5408\u6210\u590d\u6742\u7684\u7ed3\u6784\u3002\u8fd9\u79cd\u65b9\u6cd5\u7684\u5f00\u53d1\u4e3a\u6709\u673a\u5316\u5b66\u9886\u57df\u7684\u5206\u5b50\u5408\u6210\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201c<em>Complex molecule synthesis by electrocatalytic decarboxylative cross-coupling<\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728<em>Nature<\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254868\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/0.png\" alt=\"\" width=\"1525\" height=\"751\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/0.png 1525w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/0-300x148.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/0-768x378.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/0-1024x504.png 1024w\" sizes=\"(max-width: 1525px) 100vw, 1525px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>\u4f5c\u8005\u5229\u7528Ag\u6dfb\u52a0\u5242\u5f62\u6210\u6d3b\u6027Ag\u7eb3\u7c73\u9897\u7c92\u6d82\u5c42\u7535\u6781\u8868\u9762\uff0c\u5b9e\u73b0\u4e86\u57fa\u4e8e\u81ea\u7531\u57fa\u7684Ni\/Ag\u7535\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u3002\u8fd9\u79cd\u65b9\u6cd5\u907f\u514d\u4e86\u4f7f\u7528\u4fdd\u62a4\u57fa\u548c\u7cbe\u786e\u53cd\u5e94\u7f16\u6392\u7b49\u95ee\u9898\uff0c\u5e76\u4e14\u5177\u6709\u9ad8\u5ea6\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254869\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/1.png\" alt=\"\" width=\"774\" height=\"541\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/1.png 774w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/1-300x210.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/1-768x537.png 768w\" sizes=\"(max-width: 774px) 100vw, 774px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1 \u00a0\u901a\u8fc7\u6781\u6027\uff082e<sup>&#8211;<\/sup>\uff09\u548c\u81ea\u7531\u57fa\uff081e<sup>&#8211;<\/sup>\uff09\u65ad\u5f00\u8fde\u63a5\u8fdb\u5165\u591a\u5b98\u80fd\u56e2\u78b3\u6846\u67b6\u3002 \u00a0\u00a92023 <strong>Springer Nature<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254870\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/2.png\" alt=\"\" width=\"785\" height=\"868\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/2.png 785w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/2-271x300.png 271w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/2-768x849.png 768w\" sizes=\"(max-width: 785px) 100vw, 785px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2\u00a0 \u7b2c\u4e8c\u4ee3 dDCC \u7684\u5f00\u53d1\u548c\u8303\u56f4\u3002\u00a0 \u00a92023 <strong>Springer Nature<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254871\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/3.png\" alt=\"\" width=\"793\" height=\"1034\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/3.png 793w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/3-230x300.png 230w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/3-768x1001.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/3-785x1024.png 785w\" sizes=\"(max-width: 793px) 100vw, 793px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3\u00a0 \u901a\u8fc7\u7b2c\u4e8c\u4ee3 dDCC \u4ece\u6839\u672c\u4e0a\u7b80\u5316\u5929\u7136\u4ea7\u7269\u5408\u6210\u7684\u793a\u8303\u3002\u00a0 \u00a92023 <strong>Springer Nature<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254872\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/4.png\" alt=\"\" width=\"784\" height=\"693\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/4.png 784w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/4-300x265.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/4-768x679.png 768w\" sizes=\"(max-width: 784px) 100vw, 784px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4 \u901a\u8fc7\u7b2c\u4e8c\u4ee3 dDCC \u5b9e\u73b0\u57fa\u4e8e\u5404\u79cd\u624b\u6027\u7fa7\u9178\u7684\u5929\u7136\u4ea7\u7269\u5408\u6210\u3002\u00a0 \u00a92023 <strong>Springer Nature<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u5728\u5229\u7528Ag\u7eb3\u7c73\u7c92\u5b50\u4f5c\u4e3a\u6dfb\u52a0\u5242\u7684\u6761\u4ef6\u4e0b\u6269\u5927dDCC\u7684\u8303\u56f4\uff0c\u5305\u62ec\u03b1-\u6742\u539f\u5b50\u53d6\u4ee3\u7684\u7fa7\u9178\uff0c\u53ef\u4ee5\u5927\u5927\u7b80\u5316\u901a\u8fc7\u4f20\u7edf\u6781\u6027\u9006\u5408\u6210\u5206\u6790\u6cd5\u5236\u5907\u5206\u5b50\u7684\u5408\u6210\u8fc7\u7a0b\u3002\u5e73\u5747\u800c\u8a00\uff0c\u57fa\u4e8edDCC\u7684\u5408\u6210\u4ec5\u9700\u89816\u4e2a\u6b65\u9aa4\u5c31\u80fd\u5b8c\u6210\uff0c\u5e76\u4e14\u5220\u9664\u4e86\u4e00\u7cfb\u5217\u4fdd\u62a4\u57fa\u56e2\u3001\u6c27\u5316\u8fd8\u539f\u64cd\u4f5c\u3001\u5b98\u80fd\u56e2\u76f8\u4e92\u8f6c\u6362\u3001Wittig\/Grignard\u8bd5\u5242\u3001\u53d1\u706b\u8bd5\u5242\u3001\u6709\u6bd2\/\u4e0d\u53ef\u6301\u7eed\u91d1\u5c5e\u3001\u6602\u8d35\u7684\u624b\u6027\u914d\u4f53\u548c\u91cd\u6c2e\u5316\u5408\u7269\u7b49\u9644\u52a0\u56e0\u7d20\u3002\u8fd9\u79cd\u65b9\u6cd5\u53ef\u80fd\u4f1a\u63a8\u52a8\u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u5b9a\u5236\u5c5e\u6027\u7684\u590d\u6742\u6709\u673a\u5206\u5b50\uff0c\u63a8\u6709\u673a\u5408\u6210\u9886\u57df\u7684\u53d1\u5c55\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p><a href=\"https:\/\/www.nature.com\/articles\/s41586-023-06677-2\">https:\/\/www.nature.com\/articles\/s41586-023-06677-2<\/a><\/p>\n<p>\u672c\u6587\u7531WYH\u4f9b\u7a3f<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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