{"id":255051,"date":"2023-10-12T08:46:54","date_gmt":"2023-10-12T00:46:54","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=255051"},"modified":"2023-10-12T08:46:54","modified_gmt":"2023-10-12T00:46:54","slug":"%e6%9c%89%e6%9c%ba%e7%a1%85%ef%bc%8cnature%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=255051","title":{"rendered":"\u6709\u673a\u7845\uff0cNature\uff01"},"content":{"rendered":"<p><strong>1.<\/strong><strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u6709\u673a\u7845\u6750\u6599\u5728\u81ea\u7136\u754c\u4e2d\u5e76\u4e0d\u5b58\u5728\uff0c\u4f46\u5728\u73b0\u4ee3\u5316\u5b66\u4e2d\u7845\u78b3\u7ec4\u5408\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002\u5229\u7528\u201c\u76f4\u63a5\u6cd5\u201d\u5de5\u827a\u5236\u5907\u542b\u7845\u7684\u5927\u5b97\u5316\u5b66\u54c1\u770b\u8d77\u6765\u7b80\u5355\uff0c\u4f46\u9009\u62e9\u6027\u5236\u5907\u82b3\u57fa\u53d6\u4ee3\u548c\u70f7\u57fa\u53d6\u4ee3\u7684\u7845\u5316\u5408\u7269\uff08\u7845\u70f7\uff09\u5374\u5e76\u975e\u6613\u4e8b\u3002\u5982\u6c2f\u7845\u70f7Me<sub>4\u2212n<\/sub>SiCl<sub>n<\/sub>\uff08n = 1-3\uff09\u548cSiCl<sub>4<\/sub>\uff08n = 4\uff09\u5c31\u662f\u5408\u6210\u542b\u7845\u5206\u5b50\u7684\u5e38\u89c1\u8d77\u59cb\u7269\uff0c<strong>\u7845\u70f7\u7684\u5236\u5907\u5e38\u9047\u5230\u5206\u79bb\u95ee\u9898\u7684\u6311\u6218<\/strong>\u3002\u76f8\u53cd\uff0c<strong>\u542b\u6709\u56db\u4e2a\u70f7\u57fa\u7684\u7845\u70f7\u88ab\u8ba4\u4e3a\u662f\u5408\u6210\u6b7b\u89d2<\/strong>\u3002<\/p>\n<p><strong>2.<\/strong><strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u7814\u7a76\u80cc\u666f\uff0c\u67cf\u6797\u5de5\u4e1a\u5927\u5b66<strong>Martin Oestreich<\/strong><strong>\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u4ecb\u7ecd\u4e86\u4e00\u79cd\u82b3\u79bb\u5b50\u50ac\u5316\u5168\u70f7\u57fa\u5316\u7845\u70f7\u7684\u5364\u4ee3\u8131\u70f7\u57fa\u53cd\u5e94\uff0c\u5b83\u53ef\u4ee5\u6709\u6548\u5730\u5c06Me<sub>4<\/sub>Si\u548c\u76f8\u5173\u7684\u56db\u5143\u7845\u70f7\u8f6c\u5316\u4e3a\u591a\u79cd\u529f\u80fd\u5316\u884d\u751f\u7269\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cArenium-ion-catalysed halodealkylation of fully alkylated silanes\u201d\u4e3a\u9898\u53d1\u8868\u5728\u6700\u65b0\u4e00\u671f<strong><em>Nature<\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255052\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u5c01\u9762.png\" alt=\"\" width=\"769\" height=\"383\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u5c01\u9762.png 769w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u5c01\u9762-300x149.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u5c01\u9762-768x383.png 768w\" sizes=\"(max-width: 769px) 100vw, 769px\" \/><\/p>\n<p><strong>3.<\/strong><strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<ol>\n<li>\u63d0\u51fa\u4e86\u82b3\u79bb\u5b50\u50ac\u5316\u5168\u70f7\u57fa\u5316\u7845\u70f7\u7684\u5364\u4ee3\u8131\u70f7\u57fa\u4e24\u6b65\u6cd5\u53cd\u5e94\u3002<\/li>\n<li>\u6210\u529f\u5b9e\u73b0\u4e86\u56db\u5143\u6709\u673a\u7845\u591a\u529f\u80fd\u884d\u751f\u7269\u7684\u8f6c\u5316\uff0c\u8fd9\u79cd\u81ea\u4e0a\u800c\u4e0b\u6cd5\u4e5f\u88ab\u8bc1\u660e\u5177\u6709\u66f4\u5927\u4f18\u52bf\u3002<\/li>\n<\/ol>\n<p><strong>4.<\/strong><strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255053\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72471-7.png\" alt=\"\" width=\"2104\" height=\"1023\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72471-7.png 2104w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72471-7-300x146.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72471-7-768x373.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72471-7-1024x498.png 1024w\" sizes=\"(max-width: 2104px) 100vw, 2104px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u7845\u539f\u5b50\u4e0a\u7684\u53d6\u4ee3\u53cd\u5e94<\/strong><strong>\u3002<\/strong>\u00a9 2023 Springer Nature<\/p>\n<p>\uff08a\uff09\u81ea\u4e0b\u800c\u4e0a\u548c\u81ea\u4e0a\u800c\u4e0b\u9010\u6b65\u63a7\u5236\u56db\u4ef7\u7845\u539f\u5b50\u53d6\u4ee3\u7684\u53cd\u5e94\u6d41\u7a0b\u56fe\u3002<\/p>\n<p>\uff08b\uff09\u5168\u70f7\u57fa\u53d6\u4ee3\u7845\u70f7\u7684\u5316\u5b66\u8ba1\u91cf\u8131\u70f7\u57fa\u53cd\u5e94\u3002<\/p>\n<p>\uff08c\uff09\u8bbe\u8ba1\u7684\u5364\u5316\u5076\u8054\u7684\u50ac\u5316\u53d8\u4f53\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255054\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72472-8.png\" alt=\"\" width=\"1033\" height=\"1780\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72472-8.png 1033w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72472-8-174x300.png 174w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72472-8-768x1323.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72472-8-594x1024.png 594w\" sizes=\"(max-width: 1033px) 100vw, 1033px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u56db\u70f7\u57fa\u7845\u70f7\u7684\u5316\u5b66\u9009\u62e9\u6027\u5364\u4ee3\u8131\u70f7\u57fa\u53cd\u5e94<\/strong><strong>\u3002<\/strong>\u00a9 2023 Springer Nature<\/p>\n<p>\uff08a\uff09\u4e0d\u540c\u5364\u4ee3\u5143\u7d20\uff08X = Cl, Br and I\uff09\u3002<\/p>\n<p>\uff08b\uff09 \u4e0d\u540c\u7684\u56db\u70f7\u57fa\u7845\u70f7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255055\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72473-9.png\" alt=\"\" width=\"2151\" height=\"2499\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72473-9.png 2151w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72473-9-258x300.png 258w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72473-9-768x892.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72473-9-881x1024.png 881w\" sizes=\"(max-width: 2151px) 100vw, 2151px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u5316\u5b66\u9009\u62e9\u6027\u6c2f\u8131\u70f7\u57fa\uff0c\u540e\u78b3\u548c\u6742\u539f\u5b50\u4eb2\u6838\u8bd5\u5242\u884d\u751f\u5316\u3002<\/strong>\u00a9 2023 Springer Nature<\/p>\n<p>\uff08a\uff09\u56db\u7532\u57fa\u7845\u70f7\u51fa\u53d1\u9010\u6b65\u4eb2\u6838\u53d6\u4ee3\u3002<\/p>\n<p>\uff08b\uff09\u56db\u4e59\u57fa\u7845\u70f7\u51fa\u53d1\u9010\u6b65\u4eb2\u6838\u53d6\u4ee3\u3002<\/p>\n<p>\uff08c\uff09\u5168\u70f7\u57fa\u5316\u7845\u70f7\u7684\u6c2f\u53bb\u7532\u57fa\u5316\u5236\u5907\u6742\u539f\u5b50\u53d6\u4ee3\u7845\u70f7\u3002<\/p>\n<p>\uff08d\uff09\u542b\u82b3\u9999\u57fa\u56e2\u7684\u5168\u70f7\u57fa\u7845\u70f7\u6c2f\u8131\u70f7\u57fa\u53cd\u5e94\u548c\u540e\u7eed\u4ee3\u8868\u6027\u7845\u70f7\u7684\u6c27\u5316\u964d\u89e3\u3002<\/p>\n<p>\uff08e\uff09\u5364\u4ee3\u8131\u70f7\u57fa\u5728\u542b\u7845\u836f\u7269\u524d\u4f53\u5408\u6210\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<p>\uff08f\uff09\u4e8c\u7845\u70f7\u81ea\u4e0a\u800c\u4e0b\u7684\u53cd\u5e94\u64cd\u4f5c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255056\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72474-7.png\" alt=\"\" width=\"1012\" height=\"1255\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72474-7.png 1012w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72474-7-242x300.png 242w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72474-7-768x952.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/10\/\u56fe\u72474-7-826x1024.png 826w\" sizes=\"(max-width: 1012px) 100vw, 1012px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u63d0\u51fa\u7684\u82b3\u6b63\u79bb\u5b50\u4fc3\u8fdb\u7684\u5168\u70f7\u57fa\u5316\u7845\u70f7\u5364\u4ee3\u8131\u70f7\u57fa\u53cd\u5e94\u5f15\u53d1\u4e0e\u50ac\u5316\u5faa\u73af\u3002<\/strong>\u00a9 2023 Springer Nature<\/p>\n<p><strong>5.<\/strong><strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u4e2d\uff0c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u6709\u6548\u7684\u5364\u4ee3\u8131\u70f7\u57fa\u5316\u53cd\u5e94\uff0c\u7528\u4e8e\u5168\u70f7\u57fa\u5316\u7684\u7845\u70f7\u548c\u53cc\u7845\u70f7\u7684\u529f\u80fd\u5316\uff0c\u6574\u4e2a\u53cd\u5e94\u5305\u62ec\u8131\u70f7\u57fa\u5316\u548c\u5364\u5316\u4e24\u4e2a\u6b65\u9aa4\u3002<strong>\u8fd9\u4e00\u53cd\u5e94\u7b56\u7565\u518d\u6b21\u5c55\u793a\u4e86\u201c\u8d28\u5b50<\/strong><strong>&#8211;<\/strong><strong>\u7845\u9393\u79bb\u5b50\u201d\u8f6c\u5316\u7684\u5f3a\u5927\u529b\u91cf<\/strong>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u65f6\uff0c\u5f53\u5364\u4ee3\u8131\u70f7\u57fa\u5316\u4e4b\u540e\u662f\u5364\u4ee3\u7845\u70f7\u4e2d\u95f4\u4f53\u7684\u4eb2\u6838\u53d6\u4ee3\u65f6\uff0c\u8be5\u65b9\u6cd5\u8fd8\u53ef\u4ee5\u91cd\u590d\u5e94\u7528\u4e8e\u7845\u70f7\u5e95\u7269\u3002\u901a\u8fc7\u8fd9\u79cd\u65b9\u5f0f\uff0c\u60f0\u6027\u7684\u7845\u70f7\u548c\u4ef7\u503c\u8f83\u4f4e\u7684\u7845\u70f7\u53ef\u4ee5\u6309\u7167\u6240\u9700\u53d6\u4ee3\u6a21\u5f0f\u8f6c\u5316\u4e3a\u6742\u914d\u7684\u7845\u70f7\u5316\u5408\u7269\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a He, T., Klare, H.F.T. &amp; Oestreich, M. Arenium-ion-catalysed halodealkylation of fully alkylated silanes. Nature (2023). <a href=\"https:\/\/doi.org\/10.1038\/s41586-023-06646-9\">https:\/\/doi.org\/10.1038\/s41586-023-06646-9<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>1.\u3010\u5bfc\u8bfb\u3011 \u6709\u673a\u7845\u6750\u6599\u5728\u81ea\u7136\u754c\u4e2d\u5e76\u4e0d\u5b58\u5728\uff0c\u4f46\u5728\u73b0\u4ee3\u5316\u5b66\u4e2d\u7845\u78b3\u7ec4\u5408\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002\u5229\u7528\u201c\u76f4\u63a5\u6cd5\u201d\u5de5\u827a\u5236\u5907\u542b\u7845\u7684\u5927\u5b97\u5316\u5b66\u54c1\u770b\u8d77\u6765\u7b80\u5355\uff0c\u4f46\u9009\u62e9\u6027\u5236\u5907\u82b3\u57fa\u53d6\u4ee3\u548c\u70f7\u57fa\u53d6\u4ee3&#8230;<\/p>\n","protected":false},"author":35692,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-255051","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/255051"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35692"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=255051"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/255051\/revisions"}],"predecessor-version":[{"id":255057,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/255051\/revisions\/255057"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=255051"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=255051"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=255051"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}