{"id":255195,"date":"2023-10-20T06:56:38","date_gmt":"2023-10-19T22:56:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=255195"},"modified":"2023-10-19T21:56:58","modified_gmt":"2023-10-19T13:56:58","slug":"%e9%98%bf%e5%be%b7%e8%8e%b1%e5%be%b7%e5%a4%a7%e5%ad%a6%e9%83%ad%e5%86%8d%e8%90%8d%e3%80%81%e5%bc%a0%e4%bb%95%e6%9e%97nat-commun%ef%bc%9a%e7%94%9f%e7%89%a9%e7%9b%b8%e5%ae%b9%e6%80%a7%e7%94%b5%e8%a7%a3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=255195","title":{"rendered":"\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u90ed\u518d\u840d\u3001\u5f20\u4ed5\u6797Nat. Commun\uff1a\u751f\u7269\u76f8\u5bb9\u6027\u7535\u89e3\u8d28\u4f7f\u950c\u79bb\u5b50\u7535\u6c60\u5177\u6709\u9ad8\u5ea6\u53ef\u9006\u7684\u950c\u9633\u6781"},"content":{"rendered":"

01<\/strong>\u3001\u5bfc\u8bfb<\/strong><\/p>\n

\u67d4\u6027\u53ef\u7a7f\u6234\u548c\u690d\u5165\u5f0f\u7535\u5b50\u8bbe\u5907\u5728\u6301\u7eed\u51c6\u786e\u76d1\u6d4b\u4eba\u4f53\u5065\u5eb7\u72b6\u51b5\u5177\u6709\u5de8\u5927\u6f5c\u529b\uff0c\u73b0\u5df2\u5e94\u7528\u4e8e\u4e0e\u533b\u7597\u4fdd\u5065\u76f8\u5173\u7684\u5404\u4e2a\u9886\u57df\u3002\u7136\u800c\u76ee\u524d\u7f3a\u4e4f\u901a\u7528\u6784\u5efa\u7535\u6e90\u7684\u65b9\u6848\u4e3a\u67d4\u6027\u4f20\u611f\u5668\u63d0\u4f9b\u80fd\u91cf\u3002\u53ef\u5145\u7535\u6c34\u6027\u7535\u6c60\u7531\u4e8e\u5176\u672c\u8eab\u5b89\u5168\u4e14\u5ec9\u4ef7\u7684\u6c34\u6027\u7535\u89e3\u8d28\u5f15\u8d77\u4e86\u79d1\u7814\u4eba\u5458\u5173\u6ce8\u3002\u5728\u8fd9\u4e9b\u7cfb\u7edf\u4e2d\uff0c\u6c34\u950c\u91d1\u5c5e\u7535\u6c60(AZMBs)\u5c24\u5176\u5177\u6709\u5438\u5f15\u529b\uff0c\u7136\u800c\uff0cAZMBs\u4e2d\u7684Zn\u9633\u6781\u53d7\u5230\u4e0d\u53ef\u9006\u8f6c\u95ee\u9898\u7684\u56f0\u6270\uff0c\u8fd9\u5bfc\u81f4Zn\u7535\u6781\u548c\u7535\u89e3\u8d28\u7684\u6301\u7eed\u6d88\u8017\u3002<\/p>\n

\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u63a2\u7d22\u4e86\u591a\u79cd\u7b56\u7565\u53bb\u6539\u5584\u76f8\u5173\u95ee\u9898\uff0c\u7136\u800c\uff0c\u8bb8\u591a\u89e3\u51b3\u65b9\u6848\u5927\u591a\u4f9d\u8d56\u6709\u6bd2\u5316\u5b66\u54c1\uff0c\u5bf9\u73af\u5883\u4e0d\u53cb\u597d\u3002\u6b64\u5916\uff0c\u5728\u67d4\u6027AZMBs\u4e2d\uff0c\u6db2\u4f53\u7535\u89e3\u8d28\u5728\u5916\u529b\u4e0b\u6613\u6cc4\u6f0f\uff0c\u5e76\u4e14\u9020\u6210\u5206\u79bb\u5668\u53ef\u80fd\u8131\u843d\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u6c34\u51dd\u80f6\u7cfb\u7edf\u5177\u6709\u4f18\u8d8a\u62c9\u4f38\u6027\u4e0e\u67d4\u97e7\u6027\uff0c\u53ef\u4f5c\u4e3a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u66ff\u4ee3\u54c1\u3002\u7531\u751f\u7269\u76f8\u5bb9\u6027\u548c\u751f\u7269\u5927\u5206\u5b50\u7ec4\u4ef6\u7ec4\u6210\u7684\u7cfb\u7edf\u5728\u751f\u7269\u754c\u9762\u5e94\u7528\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u6f5c\u529b\u3002\u7531\u4e8e\u6c34\u51dd\u80f6\u4e2dH2<\/sub>O\u548c\u5b98\u80fd\u56e2\u4e4b\u95f4\u7684\u6c22\u952e\uff0c\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u5728\u6291\u5236\u4e0e\u6c34\u76f8\u5173\u7684\u5bc4\u751f\u526f\u53cd\u5e94\u65b9\u9762\u5177\u6709\u660e\u663e\u7684\u4f18\u52bf\u3002\u5c3d\u7ba1\u6709\u8fd9\u4e9b\u4f18\u70b9\uff0c\u4f46\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u5b58\u5728\u4e0e\u950c\u6c89\u79ef\u7684\u8c03\u8282\u548c\u4e0d\u7406\u60f3\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u76f8\u5173\u7684\u7f3a\u70b9\uff0c\u8fd9\u9650\u5236\u4e86\u5b83\u4eec\u540c\u65f6\u63d0\u4f9b\u957f\u5bff\u547d\u548c\u9ad8\u4f53\u79ef\u5bb9\u91cf\u548c\u6df1\u653e\u7535\u7684\u80fd\u529b\u3002<\/p>\n

02<\/strong>\u3001\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u5728\u6b64\uff0c\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u79d1\u5b66\u5f20\u4ed5\u6797\u7814\u7a76\u5458\u3001\u90ed\u518d\u840d\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5185\u5728\u751f\u7269\u76f8\u5bb9\u6027\u7684\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u5b83\u7531\u900f\u660e\u8d28\u9178(HA)\u3001\u6c34\u548cZnSO4<\/sub>\u76d0\u7ec4\u6210\uff0c\u5728AZMBs\u4e2d\u4f7f\u7528\u65f6\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u4f7f\u7528\u8be5\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u5bf9\u79f0\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1 mA cm-2<\/sup>\uff0c\u5bb9\u91cf\u4e3a1 mA h cm-2<\/sup>\u7684\u60c5\u51b5\u4e0b\u7a33\u5b9a\u3001\u957f\u671f\u5faa\u73af\u8d85\u8fc75500\u5c0f\u65f6\uff0c\u5728\u8d85\u8fc7250\u5c0f\u65f6\u7684\u60c5\u51b5\u4e0b\uff0c\u950c\u7684\u5229\u7528\u7387\u9ad8\u8fbe80%\uff0c\u5e73\u5747\u9540\u950c\/\u5265\u950c\u5e93\u4ed1\u6548\u7387(CE)\u4e3a99.71%\u3002\u7814\u7a76\u4eba\u5458\u4f7f\u7528WST-1\u7ec6\u80de\u589e\u6b96\u548c\u7ec6\u80de\u6bd2\u6027\u6d4b\u5b9a\u8bd5\u5242\u76d2\u786e\u8ba4\u4e86\u8fd9\u79cd\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u751f\u7269\u76f8\u5bb9\u6027\u3002\u66f4\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u662f\uff0c\u5f53\u4e0e\u5404\u79cd\u9634\u6781\uff0c\u5982LiMn2<\/sub>O4 <\/sub>(LMO)\u548c\u7898(I2<\/sub>)\u914d\u5bf9\u65f6\uff0c\u5177\u6709\u8fd9\u79cd\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u7684AZMBs\u8868\u73b0\u51fa\u8d85\u957f\u5bff\u547d\uff0cZn\/\/LMO\u7535\u6c60\u57283\u2103\u7684\u7535\u6d41\u4e0b\u8d85\u8fc71000\u6b21\u5faa\u73af\uff0cZn\/\/I2<\/sub>\u7535\u6c60\u572810\u2103\u7684\u7535\u6d41\u4e0b\u8d85\u8fc720000\u6b21\u5faa\u73af\uff0c\u8fd9\u7a81\u51fa\u4e86\u8fd9\u4e9b\u7075\u6d3b\u7535\u6c60\u5728\u53ef\u7a7f\u6234\u8bbe\u5907\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u3002\u901a\u8fc7\u76f8\u5173\u6750\u6599\u8868\u5f81\u3001\u7535\u5316\u5b66\u6d4b\u8bd5\u3001\u539f\u4f4d\u5149\u8c31\u6280\u672f\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u4e00\u6b65\u9610\u660e\u4e86\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u589e\u5f3a\u6027\u80fd\u6e90\u4e8eHA\u5206\u5b50\u51cf\u8f7b\u6c34\u53cd\u5e94\u6027\u548c\u8c03\u8282Zn2+<\/sup>\/SO4<\/sub>2-<\/sup>\u79bb\u5b50\u901a\u91cf\u7684\u80fd\u529b\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u5bf9\u4e8e\u5f00\u53d1\u9ad8\u6027\u80fd\u6c34\u51dd\u80f6\u57faAZMBs\u7528\u4e8e\u5148\u8fdb\u7684\u8f6f\u53ef\u7a7f\u6234\u548c\u690d\u5165\u5f0f\u8bbe\u5907\u5177\u6709\u91cd\u8981\u7684\u5b9e\u9645\u610f\u4e49\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA biocompatible electrolyte enables highly reversible Zn anode for zinc ion battery<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Communications<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

03<\/strong>\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

1\u3001\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u751f\u7269\u76f8\u5bb9\u6027\u7684\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u5229\u7528\u900f\u660e\u8d28\u9178\uff0c\u5176\u4e2d\u542b\u6709\u4e30\u5bcc\u7684\u4eb2\u6c34\u6027\u5b98\u80fd\u56e2\u3002\u51dd\u80f6\u57fa\u7535\u89e3\u8d28\u5bf9\u950c\u9633\u6781\u5177\u6709\u826f\u597d\u7684\u6297\u8150\u8680\u80fd\u529b\uff0c\u5e76\u80fd\u8c03\u8282\u950c\u7684\u6210\u6838\/\u751f\u957f\u3002<\/p>\n

2\u3001\u51dd\u80f6\u7535\u89e3\u8d28\u63d0\u4f9b\u4e86\u9ad8\u7535\u6c60\u6027\u80fd\uff0c\u5305\u62ec99.71%\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u8d85\u8fc75500\u5c0f\u65f6\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u5728\u9ad8\u8fbe80%\u7684\u950c\u5229\u7528\u7387\u4e0b\u63d0\u9ad8\u4e86250\u5c0f\u65f6\u7684\u5faa\u73af\u5bff\u547d\uff0c\u4ee5\u53ca\u9ad8\u751f\u7269\u76f8\u5bb9\u6027\u3002\u91cd\u8981\u7684\u662f\uff0cZn\/\/LiMn2<\/sub>O4<\/sub>\u7535\u6c60\u57283\u2103\u4e0b\u5faa\u73af1000\u6b21\u540e\u663e\u793a\u51fa82%\u7684\u5bb9\u91cf\u4fdd\u7559\u3002<\/p>\n

04<\/strong>\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>\u900f\u660e\u8d28\u9178\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u7269\u7406\u6027\u8d28\u53ca\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u8868\u5f81<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 <\/strong>\u950c\u9633\u6781\u8150\u8680\u884c\u4e3a\u7684\u8868\u5f81<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>\u950c\u9633\u6781\u7684\u6210\u6838\u548c\u751f\u957f\u884c\u4e3a<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u950c\u7535\u6c89\u79ef\u8c03\u63a7\u673a\u7406\u7684\u8ba4\u8bc6<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>\u950c\u9633\u6781\u7684\u7535\u5316\u5b66\u8868\u5f81<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6 <\/strong>\u751f\u7269\u76f8\u5bb9\u6027\u548c\u67d4\u6027\u7535\u6c60\u7684\u5e94\u7528<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

05<\/strong>\u3001\u6210\u679c\u542f\u793a<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u751f\u7269\u76f8\u5bb9\u6027\u7684\u900f\u660e\u8d28\u9178\u51dd\u80f6\u7535\u89e3\u8d28\u4f5c\u4e3a\u89e3\u51b3\u950c\u8150\u8680\u95ee\u9898\u548c\u8c03\u8282\u950c\u6210\u6838\u548c\u751f\u957f\u884c\u4e3a\u7684\u975e\u5e38\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002HA\u7cd6\u80fa\u805a\u7cd6\u9aa8\u67b6\u542b\u6709\u4e30\u5bcc\u7684\u4eb2\u6c34\u6027\u5b98\u80fd\u56e2\uff0c\u901a\u8fc7\u4e0e\u6c34\u5f62\u6210\u5f3a\u6c22\u952e\uff0c\u964d\u4f4e\u4e86\u6c34\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u51cf\u8f7b\u4e86\u6790\u6c22\u526f\u53cd\u5e94\u4ee5\u53ca\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u5e26\u8d1f\u7535\u8377\u7684HA\u5206\u5b50\u901a\u8fc7\u524a\u5f31Zn2+<\/sup>\u4e0eH2<\/sub>O\/SO4<\/sub>2-<\/sup>\u4e4b\u95f4\u7684\u9759\u7535\u529b\uff0c\u4fc3\u8fdbZn2+<\/sup>\u7684\u8131\u6eb6\uff0c\u4ece\u800c\u4ea7\u751f\u6301\u4e45\u7684\u5c4f\u853d\u4f5c\u7528\uff0c\u4f7fZn\u8868\u9762\u7535\u8377\u5206\u5e03\u5747\u5300\uff0c\u4ece\u800c\u963b\u6b62Zn\u679d\u6676\u7684\u5f62\u6210\u3002\u4f18\u5316\u7684HA\u51dd\u80f6\u7535\u89e3\u8d28\u4e2d\u7684Zn\u6c89\u79ef\u884c\u4e3a\u5bfc\u81f4\u7ec4\u88c5\u7684AZMBs\u5177\u6709\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u6700\u597d\u7684\u51dd\u80f6\u7535\u89e3\u8d28\u57faAZMBs\u4e4b\u4e00\u3002\u8be5\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u524d\u9014\u7684\u51dd\u80f6\u5316\u5b66\uff0c\u4e3a\u751f\u7269\u76f8\u5bb9\u6027\u80fd\u6e90\u76f8\u5173\u5e94\u7528\u53ca\u5176\u4ed6\u9886\u57df\u63d0\u4f9b\u4e86\u5de8\u5927\u7684\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A biocompatible electrolyte enables highly reversible Zn anode for zinc ion battery<\/strong>\uff0c<\/strong>2023<\/strong>\uff0c<\/strong>https:\/\/doi.org\/10.1038\/s41467-023-42333-z<\/strong>\uff09<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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