{"id":255706,"date":"2023-11-09T06:31:26","date_gmt":"2023-11-08T22:31:26","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=255706"},"modified":"2023-11-08T15:40:50","modified_gmt":"2023-11-08T07:40:50","slug":"small%ef%bc%9a-inzn%e5%8f%8c%e9%87%91%e5%b1%9e-mofs-%e8%a1%8d%e7%94%9f%e4%b8%ad%e7%a9%ba%e7%a2%b3%e7%ae%a1%e5%be%ae%e7%bb%93%e6%9e%84%e7%b2%be%e5%87%86%e8%b0%83%e6%8e%a7%e6%9e%84%e5%bb%ba%e9%ab%98","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=255706","title":{"rendered":"Small\uff1a InZn\u53cc\u91d1\u5c5e MOFs \u884d\u751f\u4e2d\u7a7a\u78b3\u7ba1\u5fae\u7ed3\u6784\u7cbe\u51c6\u8c03\u63a7\u6784\u5efa\u9ad8\u6027\u80fd\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u53cc\u7528\u9014\u65b0\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u4e3a\u52a0\u901f\u7535\u52a8\u6c7d\u8f66\u5546\u4e1a\u5316\u53ca\u63a8\u52a8\u4ea4\u901a\u9886\u57df\u78b3\u4e2d\u548c\uff0c\u53d1\u5c55\u7ecf\u6d4e\u9ad8\u6548\u3001\u9ad8\u80fd\u91cf\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u7535\u5316\u5b66\u7535\u6e90\u81f3\u5173\u91cd\u8981\u3002\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u5177\u6709\u6bd4\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u66f4\u4e30\u5bcc\u7684\u8d44\u6e90\u4e30\u5ea6\u548c\u9ad8\u5b89\u5168\u6027\uff0c\u6709\u671b\u6210\u4e3a\u5927\u89c4\u6a21\u50a8\u80fd\u7535\u6c60\u3002\u8d85\u7ea7\u7535\u5bb9\u5668\uff08SCs\uff09\u867d\u7136\u6bd4\u80fd\u91cf\u8f83\u4f4e\uff0c\u5b83\u7684\u5feb\u901f\u5145\u653e\u7535\u80fd\u91cf\u3001\u9ad8\u529f\u7387\u5bc6\u5ea6\u548c\u957f\u5bff\u547d\u7b49\u4f18\u52bf\uff0c\u6210\u4e3a\u52a8\u529b\u7535\u6c60\u6709\u6548\u7684\u529f\u7387\u8f85\u52a9\u7535\u6e90\u3002\u672c\u7814\u7a76\u4ece\u94df\u950c\u53cc\u91d1\u5c5eMOF\u51fa\u53d1\uff0c\u901a\u8fc7\u7cbe\u51c6\u8c03\u63a7\u8be5MOF\u884d\u751f\u4e2d\u7a7a\u591a\u5b54\u78b3\u7ba1\u7684\u5fae\u7eb3\u7ed3\u6784\uff0c\u5b9e\u73b0\u5176\u5728\u8d85\u7535\u548c\u94a0\u79bb\u5b50\u7684\u53cc\u5e94\u7528\uff0c\u4e3a\u8fdb\u4e00\u6b65\u5f00\u53d1\u8d85\u9ad8\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u78b3\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7b56\u7565\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u671f\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6f58\u519b\u9752\u6559\u6388\u8bfe\u9898\u7ec4\u63d0\u51fa\u4e86\u901a\u8fc7\u8c03\u8282\u94df\u950c\u53cc\u91d1\u5c5eMOF\uff08Inx<\/sub>Zny<\/sub>-MIL-68\uff09\u7684\u91d1\u5c5e\u6bd4\u4f8b\uff0c\u5236\u5907\u4e86\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u7684\u65b0\u578b\u53ef\u8c03\u63a7\u7684\u591a\u5b54\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ba1\uff08PHCNT-x\uff09\u3002\u5236\u5907\u7684Inx<\/sub>Zny<\/sub>-MIL-68\u4e2d\u7684In\u4f1a\u9996\u5148\u5f62\u6210\u6c27\u5316\u94df\uff0c\u968f\u540e\u8fd8\u539f\u4e3a\u6db2\u6001\u91d1\u5c5eIn\uff08\u7194\u70b9\uff1a156.61\u00a0o<\/sup>C\uff09\uff0c\u5e76\u9010\u6b65\u805a\u96c6\u3001\u878d\u5408\u548c\u6d41\u51fa\u540e\u5f62\u6210\u4e2d\u7a7a\u78b3\u7ed3\u6784\u3002\u6dfb\u52a0\u7684\u950c\u79bb\u5b50\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u6d88\u8017\u5468\u56f4\u78b3\u539f\u5b50\uff0c\u5e76\u4f34\u968f\u950c\u7684\u84b8\u53d1\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff08\u56fe1\uff09\u3002\u4f18\u5316\u540e\u7684PHCNT-4\u7535\u6781\u5177\u6709\u72ec\u7279\u7684\u4e2d\u7a7a\u7ed3\u6784\u548c\u5408\u9002\u7684\u5fae\u5b54\/\u4ecb\u5b54\u542b\u91cf\uff0c\u5728SCs\u548cSIBs\u7684\u5e94\u7528\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6bd4\u7535\u5bb9\uff08358.6 F g-1<\/sup>\u00a0@1 A g-1<\/sup>\uff1b318.2 mAh g-1<\/sup>\u00a0@0.1 A g-1<\/sup>\uff09\u548c\u500d\u7387\u6027\u80fd\uff08235.0 F g-1<\/sup>\u00a0@300 A g-1<\/sup>\uff1b193.4 mAh g-1<\/sup>\u00a0@5 A g-1<\/sup>\uff09\uff0c\u663e\u793a\u51fa\u5176\u5353\u8d8a\u7684\u7535\u5bb9\u50a8\u80fd\u80fd\u529b\u3002\u8fd9\u9879\u5de5\u4f5c\u901a\u8fc7\u7cbe\u786e\u8c03\u8282\u53cc\u91d1\u5c5eMOF\u884d\u751f\u78b3\u6750\u6599\u7684\u6210\u5206\uff0c\u5b9e\u73b0\u4e86\u4e9a\u7eb3\u7c73\u7ea7\u4e2d\u7a7a\u7ba1\u9053\u7684\u76f4\u5f84\u548c\u5b54\u5f84\u7684\u7cbe\u51c6\u8c03\u63a7\uff0c\u4e3a\u8fdb\u4e00\u6b65\u5f00\u53d1\u8d85\u9ad8\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u78b3\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u4e2a\u524d\u666f\u5149\u660e\u7684\u7b56\u7565\u3002\u76f8\u5173\u6210\u679c\u4ee5\u6807\u9898\u4e3a\u201cPrecise tuning of hollow and pore size of bimetallic MOFs derivate to construct high performance nanoscale materials for supercapacitors and sodium-ion batteries\u201d\u53d1\u8868\u5728Small\uff08DOI\uff1a10.1002\/smll.2306272\uff09\u3002\u8bfe\u9898\u7ec4\u5b8b\u91d1\u7984\u7855\u58eb\u751f\u548c\u67f4\u8def\u8def\u535a\u58eb\u751f\u4e3a\u8bba\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe2.<\/b><\/strong>\uff08a\uff09PHCNT-1\u3001\uff08b\uff09PHCNT-2\u3001\uff08c\uff09PHCNT-3\u3001\uff08d\uff09PHCNT-4\u7684TEM\u56fe\u50cf\u3002\uff08e\uff09In1<\/sub>Zn2<\/sub>-MIL-68\u3001\uff08f\uff09HCNT-4\uff08\u9178\u8680\u523b\u524d\uff09\u548c\uff08g\uff09PHCNT-4\uff08\u9178\u8680\u523b\u540e\uff09\u4e2dC\u3001O\u3001In\u548cZn\u7684SEM\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

\u901a\u8fc7In\u548cZn\u7684\u6eb6\u89e3\u8fc7\u7a0b\uff0cPHCNT-x\u7684\u4e2d\u7a7a\u901a\u9053\u76f4\u5f84\u9010\u6e10\u4ece170 nm\u589e\u52a0\u5230280 nm\uff08\u56fe2a-d\uff09\uff0c\u78b3\u5b54\u7ed3\u6784\u66f4\u52a0\u4e30\u5bcc\uff0c\u4e3a\u9ad8\u7535\u5bb9\u548cNa+<\/sup>\u5b58\u50a8\u6027\u80fd\u63d0\u4f9b\u4e86\u7ed3\u6784\u57fa\u7840\u3002\u8fd9\u4e9b\u7ed3\u6784\u901a\u8fc7\u70ed\u89e3\uff08\u56fe2e\uff0cf\uff09\u548c\u9178\u8680\uff08\u56fe2g\uff09\u5f97\u5230\u5f3a\u5316\uff0c\u5f62\u6210\u5177\u6709\u5927\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u5b54\u7ed3\u6784\u7684\u591a\u5b54PHCNT-4\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3.\uff08a\uff09In1<\/sub>Zn2<\/sub>-MIL-68\u7684TGA\u66f2\u7ebf\u3002\uff08b\uff09In1<\/sub>Zn2<\/sub>-MIL-68\u3001HCNT-4\u548cPHCNT-4\u7684XRD\u56fe\u8c31\u3002PHCNT-1\u3001PHCNT-2\u3001PHCNT-3\u548cPHCNT-4\u7684\uff08c\uff09\u62c9\u66fc\u5149\u8c31\u3001\uff08d\uff09N2<\/sub>\u5438\u9644-\u8131\u9644\u7b49\u6e29\u7ebf\u3001\uff08e\uff09\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u548c\uff08f\uff09\u5e73\u5747\u5b54\u5f84\u3002HCNT-4\u548cPHCNT-4\u7684\uff08g\uff09C1s\u3001\uff08h\uff09O1s\u548c\uff08i\uff09In 3d\u7684XPS\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u3002<\/p>\n

\u901a\u8fc7\u8c03\u8282In\u548cZn\u7684\u6bd4\u4f8b\uff0c\u7814\u7a76\u4e86In1<\/sub>Zn2<\/sub>-MIL-68\u7684\u70ed\u91cd\u5206\u6790\uff08TGA\uff09\u66f2\u7ebf\uff0c\u663e\u793a\u4e86\u4e24\u4e2a\u5931\u91cd\u9636\u6bb5\uff0c\u5206\u522b\u5bf9\u5e94\u8131\u7fa7\u8fc7\u7a0b\u4e2dIn2<\/sub>O3<\/sub>\u7684\u8f6c\u5316\u548c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8fd8\u539f\u7684\u6db2\u6001\u91d1\u5c5eIn\uff08\u56fe3a\uff09\u3002\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\uff08PXRD\uff09\u56fe\u663e\u793a\uff0cMOF\u6210\u529f\u5730\u8f6c\u53d8\u4e3a\u65e0\u5b9a\u5f62\u78b3\u7ed3\u6784\uff0c\u8fd9\u4e0eSEM\u548cTEM\u7684\u7ed3\u679c\u4e00\u81f4\uff08\u56fe3b\uff09\u3002\u62c9\u66fc\u5149\u8c31\u4e2d\u7684ID<\/sub>\/IG<\/sub>\u503c\u8868\u660ePHCNT-4\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\u66f4\u9ad8\uff0c\u5c24\u5176\u662f\u5728\u542b\u6709\u66f4\u591aZn\u7684\u60c5\u51b5\u4e0b\u3002\u5728\u78b3\u5316\u8fc7\u7a0b\u4e2d\uff0cIn1<\/sub>Zn2<\/sub>-MIL-68\u9996\u5148\u53d1\u751f\u8131\u7fa7\u548c\u70ed\u5206\u89e3\uff0c\u91ca\u653eCO\u6c14\u4f53\u5e76\u5f62\u6210In\/ZnO\/C\u590d\u5408\u6750\u6599\u3002\u4e0eIn3+<\/sup>\u7269\u79cd\u76f8\u6bd4\uff0cZn2+<\/sup>\u7269\u79cd\u7684\u4ef7\u6001\u8f83\u4f4e\uff0c\u56e0\u6b64\u5728\u9ad8\u6e29\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6d88\u8017\u7684\u78b3\u7eb3\u7c73\u7c92\u5b50\u66f4\u5c11\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u77f3\u58a8\u5316\u7a0b\u5ea6\uff08\u56fe3c\uff09\u3002\u8fd9\u79cd\u77f3\u58a8\u5316\u8fc7\u7a0b\u5c06\u65e0\u5b9a\u5f62\u78b3\u7ed3\u6784\u8f6c\u53d8\u4e3a\u9ad8\u5bfc\u7535\u6027\u7684\u77f3\u58a8\u7ed3\u6784\uff0c\u589e\u52a0\u7535\u5b50\u4f20\u5bfc\u901a\u9053\uff0c\u63d0\u9ad8\u8868\u9762\u79ef\uff0c\u6539\u5584\u5b54\u9699\u7ed3\u6784\uff0c\u4fc3\u8fdb\u79bb\u5b50\u4f20\u8f93\uff0c\u4ece\u800c\u589e\u5f3a\u78b3\u6750\u6599\u7684\u5bfc\u7535\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0cN2<\/sub>\u7b49\u6e29\u7ebf\u548c\u76f8\u5e94\u7684\u5b54\u5f84\u5206\u5e03\uff08PSD\uff09\u66f2\u7ebf\u7814\u7a76\u8868\u660e\uff08\u56fe3d-f\uff09\uff0cIn1<\/sub>Zn2<\/sub>-MIL-68\u5177\u6709\u7279\u5f81I\u578b\u7b49\u6e29\u7ebf\uff0c\u5fae\u5b54\u4e3a1.1-1.3 nm\u3002\u800cHCNT-4\u548cPHCNT-4\u8868\u73b0\u51faIV\u578b\u7b49\u6e29\u7ebf\uff0c\u63ed\u793a\u4e86\u7531\u4e8eMOF\u7ed3\u6784\u4e2d\u7684\u9aa8\u67b6\u584c\u9677\u4ee5\u53ca\u76f8\u5173\u7269\u8d28\u7684\u5206\u89e3\/\u84b8\u53d1\u800c\u4ea7\u751f\u7684\u5fae\u5b54\u548c\u4ecb\u5b54\u7ed3\u6784\u3002PHCNT-4\u5177\u6709\u66f4\u5927\u7684\u5b54\u5bb9\u548cBET\u6bd4\u8868\u9762\u79ef\uff0c\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u91d1\u5c5e\u9897\u7c92\u7684\u6709\u6548\u53bb\u9664\u5728\u78b3\u9aa8\u67b6\u4e2d\u4ea7\u751f\u4e86\u989d\u5916\u7684\u7a7a\u9699\u5e76\u6fc0\u6d3b\u4e86\u78b3\u8868\u9762\u3002X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u6d4b\u8bd5\u63ed\u793a\u4e86\u6837\u54c1\u7684\u8868\u9762\u5143\u7d20\u6001\uff08\u56fe3g-i\uff09\u3002C 1s\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u663e\u793a\u4e86\u516d\u4e2a\u5cf0\uff0c\u5305\u62ecC-C sp2\u3001C-C sp3\u3001C-O\u3001C=C\u3001-COO\u548c\u536b\u661f\u5cf0\u3002O 1s\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u8bc1\u5b9e\u4e86\u9178\u523b\u540ePHCNT-4\u6750\u6599\u4e2d\u7684In-O\u952e\u7684\u6d88\u5931\uff0c\u8fd9\u4e0eTEM\u548cPXRD\u7ed3\u679c\u4e00\u81f4\uff0c\u8868\u660e\u9178\u5316\u6210\u529f\u53bb\u9664\u4e86\u6b8b\u7559\u7684\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4.<\/b><\/strong>\uff08a\uff09PHCNT-4\u7528\u4e8eSC\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09HCNT-4\u548cPHCNT-4\u7684GCD\u66f2\u7ebf\u3002PHCNT-1\u3001PHCNT-2\u3001PHCNT-3\u548cPHCNT-4\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a\uff08c\uff09100 mV s-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff0c\uff08d\uff09100 A g-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\uff0c\uff08e\uff09\u5948\u594e\u65af\u7279\u56fe\uff0c\uff08f\uff09100 mV s-1<\/sup>\u4e0b\u4e0d\u540c\u6750\u6599\u5728CV\u66f2\u7ebf\u4e2d\u7684\u7535\u5bb9\u8d21\u732e\uff0c\u4ee5\u53ca\uff08g\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9\u6bd4\u8f83\u3002\uff08h\uff09\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u4e0e\u6587\u732e\u7684\u6bd4\u8f83\u3002\uff08i\uff091 A g-1<\/sup>\u65f6\u7684\u4e2d\u5b54\u5927\u5b54\u767e\u5206\u6bd4\u4e0e\u500d\u7387\u4fdd\u7559\u7387\u7684\u5173\u7cfb\uff0c\u4ee5\u53ca\uff08j\uff09\u6bd4\u8868\u9762\u79ef\u548c\u6bd4\u5bb9\u91cf\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe4a\u5c55\u793a\u4e86PHCNT-4\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u7684\u793a\u610f\u56fe\u3002\u4e2d\u7a7a\u591a\u5b54\u7ed3\u6784\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u66f4\u5927\u7684\u5185\u90e8\u5bb9\u79ef\uff0c\u6709\u52a9\u4e8e\u7535\u89e3\u8d28\u7684\u6709\u6548\u6e17\u900f\u548c\u79bb\u5b50\u6269\u6563\uff0c\u589e\u52a0\u4e86\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\uff0c\u4fc3\u8fdb\u4e86\u79bb\u5b50\u5728\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7684\u5feb\u901f\u4f20\u8f93\uff0c\u7f29\u77ed\u4e86\u79bb\u5b50\u6269\u6563\u8ddd\u79bb\u3002\u56fe4b\u663e\u793a\u4e86HCNT-4\u548cPHCNT-4\u7535\u6781\u7684\u7535\u5bb9\u6027\u80fd\u3002\u7ed3\u679c\u8868\u660e\uff0cPHCNT-4\u7684\u6bd4\u7535\u5bb9\uff08358.6 F g-1<\/sup>\uff09\u8fdc\u9ad8\u4e8eHCNT-4\uff08221.2 F g-1<\/sup>\uff09\u3002\u6240\u6709\u6750\u6599\u7684CV\u66f2\u7ebf\u90fd\u5448\u73b0\u8fd1\u4f3c\u77e9\u5f62\u7684\u5f62\u72b6\uff08\u56fe4c\uff09\uff0c\u8bc1\u5b9e\u78b3\u6750\u6599\u5177\u6709\u8f83\u7406\u60f3\u7684\u7535\u53cc\u5c42\u7535\u5bb9\u5668\uff08EDLC\uff09\u884c\u4e3a\u3002\u56fe4d\u663e\u793a\u4e86\u4e0a\u8ff0\u6837\u54c1\u5728100 A g-1<\/sup>\u65f6\u7684GCD\u66f2\u7ebf\u3002PHCNT-4\u8868\u73b0\u51fa\u6700\u957f\u7684\u653e\u7535\u65f6\u95f4\uff084.6\u79d2\uff09\u548c\u5185\u963b\uff08IR\uff09\u4e0b\u964d\u6700\u5c0f\uff0860 mV\uff09\uff0c\u8868\u660e\u5176\u5177\u6709\u6700\u9ad8\u7684\u6bd4\u7535\u5bb9\u548c\u500d\u7387\u6027\u80fd\u3002PHCNT-4\u7684\u4e5f\u5c55\u793a\u4e86\u6700\u4f4e\u7684\u963b\u6297\u503c\uff0c\u5176\u7b49\u6548\u4e32\u8054\u7535\u963bRs<\/sub>\u00a0\u4e3a0.18 \u03a9\uff0c\u4ece\u53e6\u4e00\u4e2a\u65b9\u9762\u5c55\u73b0\u4e86\u4f18\u79c0\u7684\u6da6\u6e7f\u6027\u548c\u53d1\u8fbe\u7684\u5b54\u9699\u7ed3\u6784\u3002\u56fe4f\u8868\u660e\uff0cPHCNT-4\u5728100 mV s-1<\/sup>\u65f6\u4ecd\u8d21\u732e\u4e86\u6700\u4f73\u7684\u6bd4\u7535\u5bb9\u3002PHCNT-4\u5728300 A g-1<\/sup>\u65f6\u7684\u7535\u5bb9\u4fdd\u6301\u7387\u6bd4\u5176\u4ed6\u7535\u6781\u9ad8\u51fa65.5%\uff0c\u663e\u793a\u4e86\u51fa\u8272\u7684\u5feb\u901f\u5145\u653e\u7535\u6027\u80fd\uff08\u56fe4g\uff09\u3002\u56fe4h\u603b\u7ed3\u4e86PHCNT-4\u7684\u901f\u7387\u6027\u80fd\uff0c\u663e\u8457\u4f18\u4e8e\u5176\u5b83MOF\u884d\u751f\u78b3\u6750\u6599\u3002\u56fe4i-j\u8868\u660e\u4f4e\u901f\u7535\u5bb9\u6027\u80fd\u4e3b\u8981\u53d7\u5fae\u5b54\u548c\u6bd4\u8868\u9762\u79ef\u7684\u5f71\u54cd\uff0c\u800c\u4ecb\u5b54\u548c\u5927\u5b54\u7ed3\u6784\u6709\u5229\u4e8e\u63d0\u9ad8\u79bb\u5b50\u6269\u6563\u52a8\u529b\u5b66\u548c\u9ad8\u901f\u7387\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>.<\/b><\/strong>\uff08a\uff09\u78b3\u6750\u6599\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7684PHCNT-4\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09PHCNT-4\u548cCNT\u7684CV\u66f2\u7ebf\uff0c\uff08c\uff09PHCNT-4\u548cCNT\u57281 A g-1<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff0c\uff08d\uff09PHCNT-4\u548cCNT\u7684EIS\u66f2\u7ebf\u53ca\u7b49\u6548\u7535\u8def\uff0c\uff08e\uff09PHCNT-4\u548cCNT\u88c5\u914d\u7684SIB\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3001\uff08f\uff09PHCNT-4\u548cCNT\u7684\u500d\u7387\u6027\u80fd\u66f2\u7ebf\uff1b\uff08g\uff09PHCNT-4\u7ec4\u88c5\u7684SIB\u4e0e\u5176\u4ed6\u5df2\u62a5\u9053\u6750\u6599\u7684\u6bd4\u8f83\uff1b\uff08h\uff09PHCNT-4\u7ec4\u88c5\u7684SIB\u7684\u5faa\u73af\u66f2\u7ebf\uff1b\u4ee5\u53caPHCNT-4\uff08i\uff09\u5faa\u73af\u524d\u548c\uff08j\uff09\u5faa\u73af\u540e\u7684SEM\u548c\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u6211\u4eec\u901a\u8fc7\u6263\u5f0f\u7535\u6c60\u6d4b\u8bd5\u7814\u7a76\u4e86PHCNT-4\u6750\u6599\u7684\u94a0\u79bb\u5b50\u5b58\u50a8\u6027\u80fd\u3002\u56fe5a\u63cf\u8ff0\u4e86PHCNT-4\u7684\u50a8\u94a0\u673a\u5236\u793a\u610f\u56fe\u3002PHCNT-4\u7684\u4e2d\u7a7a\u7ed3\u6784\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u94a0\u79bb\u5b50\u7684\u5145\u8db3\u50a8\u5b58\u7a7a\u95f4\u3002\u5185\u90e8\u4e2d\u7a7a\u548c\u591a\u5b54\u58c1\u7ed3\u6784\u4e5f\u6709\u52a9\u4e8e\u94a0\u79bb\u5b50\u7684\u5feb\u901f\u6269\u6563\u3001\u5438\u6536\u548c\u91ca\u653e\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u7535\u5bb9\u91cf\u3001\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u5bff\u547d\u3002\u56fe5b\u663e\u793a\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u7684\u5f62\u6210\u8fc7\u7a0b\uff0c\u7ecf\u8fc7\u524d3\u4e2a\u5faa\u73af\u540e\uff0cCV\u66f2\u7ebf\u9010\u6e10\u91cd\u53e0\uff0c\u8868\u660e\u94a0\u79bb\u5b50\u5b58\u50a8\u8fc7\u7a0b\u5177\u6709\u826f\u597d\u7684\u53ef\u9006\u6027\u3002PHCNT-4\u7535\u6781\u7684\u4e0d\u53ef\u9006\u9762\u79ef\u5c0f\u4e8eCNT\u7535\u6781\uff0c\u8fd9\u662fPHCNT-4\u7535\u6781\u521d\u59cb\u5e93\u4f26\u6548\u7387\u8f83\u9ad8\u7684\u539f\u56e0\u3002\u56fe5c\u663e\u793a\u4e86PHCNT-4\u548cCNT\u57280.1 A g-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\uff0cPHCNT-4\u7684\u521d\u59cb\u5e93\u4f26\u6548\u7387\u8f83\u9ad8\u3002EIS\u6d4b\u8bd5\u8868\u660ePHCNT-4\u5f97\u76ca\u4e8e\u5176\u4e2d\u7a7a\u548c\u591a\u5b54\u7ed3\u6784\uff0c\u963b\u6297\u503c\u8fdc\u8fdc\u4f4e\u4e8eCNT\uff0c\u8fd9\u6709\u5229\u4e8e\u79bb\u5b50\u4ea4\u6362\u80fd\u529b\uff08\u56fe5d\uff09\u3002\u56fe5e\u3001f\u5c55\u793a\u4e86PHCNT-4\u548cCNT\u4e4b\u95f4\u7684\u500d\u7387\u6027\u80fd\u6bd4\u8f83\u3002PHCNT-4\u7535\u6781\u57280.1\u30010.5\u548c1A g-1\u65f6\u5206\u522b\u8868\u73b0\u51fa318.6\u3001275.1\u548c256.9 mAh g-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u5360CNT\u7684\u5206\u522b\u4e3a122.4\u300162.7\u548c53.1 mAh g-1<\/sup>\u7684260-484%\u3002\u5f53\u7535\u6d41\u5bc6\u5ea6\u964d\u81f30.05 A g-1<\/sup>\u540e\uff0cPHCNT-4\u7535\u6781\u7684\u53ef\u9006\u5bb9\u91cf\u57fa\u672c\u4e0a\u5f97\u4ee5\u6062\u590d\uff0c\u8868\u660e\u500d\u7387\u6027\u80fd\u548c\u8010\u4e45\u6027\u826f\u597d\u3002\u56fe5g\u5bf9\u6bd4\u6bd4\u8f83\u4e86\u51e0\u79cd\u78b3\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u548c\u901f\u7387\u6027\u80fd\uff0c\u5176\u4e2dPHCNT-4\u56e0\u5177\u6709\u4e30\u5bcc\u7684\u5fae\u5b54\/\u4ecb\u5b54\u3001\u5927\u5b54\u4f53\u79ef\u3001\u589e\u5f3a\u7684\u8868\u9762\u79ef\u548c\u4f18\u5f02\u7684\u7535\u5bfc\u7387\uff0c\u8868\u73b0\u4e86\u6bd4\u78b3\u7eb3\u7c73\u7ba1\u7b49\u6750\u6599\u66f4\u9ad8\u7684\u6bd4\u7535\u5bb9\u548c\u5faa\u73af\u5bb9\u91cf\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u68c0\u6d4b\u5f62\u8c8c\/\u7ed3\u6784\u7279\u5f81\u7684\u53d8\u5316\uff0c\u8fdb\u884c\u4e86SEM\u548c\u5143\u7d20\u6620\u5c04\u6d4b\u8bd5\uff0c\u4ee5\u68c0\u67e5PHCNT-4\u5728\u5faa\u73af\u6d4b\u8bd5\u540e\u7684\u5f62\u6001\u3002\u4ece\u56fe5i\u3001j\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u5b83\u4ecd\u7136\u4fdd\u6301\u7740\u539f\u59cb\u7684\u68d2\u72b6\u5f62\u6001\uff0c\u4ec5\u6c27\u542b\u91cf\u7565\u5fae\u589e\u52a0\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5438\u6536\u4e86\u6b8b\u7559\u7684NaClO4<\/sub>\u7535\u89e3\u8d28\uff0c\u8868\u660e\u5176\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u5177\u6709\u51fa\u8272\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>.<\/b><\/strong>\uff08a\uff09PHCNT-4\u548cCNT\u4e2dNa+<\/sup>\u5b58\u50a8\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09Na+<\/sup>\u6cbfPHCNT-4\u548cCNT\u8fc1\u79fb\u7684\u80fd\u91cf\u5206\u5e03\uff0c\u5176\u4e2d\u4e24\u4e2a\u63d2\u56fe\u663e\u793a\u4e86Na+<\/sup>\u7684\u8fc1\u79fb\u8def\u5f84\u3002\uff08c\uff09PHCNT-4\u548cCNT\u7684\u6001\u5bc6\u5ea6\uff08DOS\uff09\u3002\uff08d\uff09\u548c\uff08e\uff09PHCNT-4\u8868\u9762\u7f3a\u9677\u7684\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002\uff08f\uff09\u548c\uff08g\uff09\u5145\u653e\u7535\u524d\u540ePHCNT-4\u548cCNT\u4e4b\u95f4Na+<\/sup>\u542b\u91cf\u7684\u6bd4\u8f83\u3002<\/p>\n

PHCNT-4\u7684\u5353\u8d8a\u6027\u80fd\u6e90\u4e8e\u5176\u4e2d\u7a7a\u591a\u5b54\u7ed3\u6784\uff0c\u5b83\u4fc3\u8fdb\u4e86Na+<\/sup>\u7684\u5feb\u901f\u6269\u6563\u548c\u6709\u6548\u50a8\u5b58\uff0c\u4e3a\u50a8\u5b58\u78b1\u91d1\u5c5e\u79bb\u5b50\u63d0\u4f9b\u4e86\u66f4\u591a\u6d3b\u6027\u4f4d\u70b9\uff0c\u5e76\u63d0\u4f9b\u4e86\u7262\u56fa\u7684\u6846\u67b6\u6765\u5bb9\u7eb3\u94a0\u79bb\u5b50\u3002\u8fdb\u800c\u63d0\u9ad8\u4e86\u7535\u5316\u5b66\u6027\u80fd\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u7ed3\u679c\u663e\u793a\uff0cPHCNT-4\u4e2d\u7684Na+<\/sup>\u8fc1\u79fb\u53d7\u5230\u7f3a\u9677\u7684\u663e\u8457\u5f71\u54cd\uff0c\u5176\u8fc1\u79fb\u52bf\u5792\u8fdc\u4f4e\u4e8eCNT\uff0c\u8fd9\u6709\u5229\u4e8eNa+<\/sup>\u7684\u5438\u9644\u548c\u8fc1\u79fb\u3002\u6b64\u5916\uff0c\u7535\u5b50\u6001\u5bc6\u5ea6\uff08DOS\uff09\u51fd\u6570\u5206\u6790\u63ed\u793a\u4e86PHCNT-4\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5bfc\u7387\uff0c\u8fd9\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u4e00\u81f4\uff0c\u8868\u660e\u5176\u66f4\u9002\u5408\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u3002\u8fdb\u4e00\u6b65\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u7814\u7a76\u663e\u793a\uff0cNa+<\/sup>\u4e0ePHCNT-4\u7684\u7f3a\u9677\u7ed3\u6784\u4e4b\u95f4\u5b58\u5728\u66f4\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd9\u6709\u52a9\u4e8e\u66f4\u6709\u6548\u5730\u50a8\u5b58\u548c\u91ca\u653eNa+<\/sup>\u3002\u5728\u5faa\u73af\u6d4b\u8bd5\u4e2d\uff0cPHCNT-4\u548cCNT\u8868\u9762\u7684Na+<\/sup>\u542b\u91cf\u53d1\u751f\u663e\u8457\u53d8\u5316\uff0c\u4f46PHCNT-4\u7684Na+<\/sup>\u542b\u91cf\u53d8\u5316\u8303\u56f4\u66f4\u5927\uff0c\u7279\u522b\u662f\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5176Na+<\/sup>\u542b\u91cf\u660e\u663e\u9ad8\u4e8eCNT\u3002\u8fd9\u8868\u660ePHCNT-4\u80fd\u591f\u66f4\u591a\u5730\u5bb9\u7eb3Na+<\/sup>\uff0c\u8fd9\u8981\u5f52\u529f\u4e8e\u5176\u4e2d\u7a7a\u591a\u5b54\u7ed3\u6784\uff0c\u4f7f\u5176\u6210\u4e3a\u51fa\u8272\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/p>\n

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