{"id":255967,"date":"2023-11-20T06:23:25","date_gmt":"2023-11-19T22:23:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=255967"},"modified":"2023-11-19T20:20:32","modified_gmt":"2023-11-19T12:20:32","slug":"%e6%b8%a4%e6%b5%b7%e5%a4%a7%e5%ad%a6%e8%94%a1%e5%85%8b%e8%bf%aa-%e9%83%8e%e7%ac%91%e7%9f%b3%e5%9b%a2%e9%98%9f-j-energy-storage%ef%bc%9a-%e8%ae%be%e8%ae%a1%e4%b8%80%e7%a7%8d%e6%96%b0%e5%9e%8b%e6%a1%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=255967","title":{"rendered":"\u6e24\u6d77\u5927\u5b66\u8521\u514b\u8fea-\u90ce\u7b11\u77f3\u56e2\u961f J Energy Storage\uff1a \u8bbe\u8ba1\u4e00\u79cd\u65b0\u578b\u6851\u6939\u72b6 Ag\/AgCl@TiO2\/V2O5-x \u590d\u5408\u6750\u6599\uff0c\u53ef\u4f5c\u4e3a\u957f\u5bff\u547d\u94be\u6c27\u7535\u6c60\u7684\u7a33\u5b9a\u50ac\u5316\u5242"},"content":{"rendered":"
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\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/span><\/span><\/p>\n

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\u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/strong><\/span><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u6e24\u6d77\u5927\u5b66\u8521\u514b\u8fea\u6559\u6388\u3001\u90ce\u7b11\u77f3\u526f\u6559\u6388\u3001\u5f20\u6653\u6c11\u7814\u7a76\u751f\u901a\u8fc7\u7b80\u5355\u7684\u6c34\u70ed\u6cd5\u53ca\u6c34\u6d74\u6cd5\u5408\u7406\u7684\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u6851\u845a\u72b6Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5<\/sub>-x\u00a0<\/sub>\u590d\u5408\u9634\u6781\u50ac\u5316\u5242\uff0c \u5e76\u5c06\u5176\u7528\u4e8e\u94be\u6c27\u7535\u6c60\u4e0a\u3002\u590d\u5408\u50ac\u5316\u5242\u4ee5\u5176\u591a\u7ec4\u5206\u7269\u8d28\u5f62\u6210\u7684\u6d3b\u6027\u754c\u9762\u5bf9\u94be\u6c27\u7535\u6c60\u00a0 \u8fdb\u884c\u591a\u65b9\u4f4d\u8c03\u63a7\uff0cTiO2<\/sub>\u00a0\u589e\u52a0\u4e86 K+\u63d2\u5165\u7684\u901f\u7387\u548c\u80fd\u529b\uff0c\u5177\u6709\u7f3a\u6c27\u7ed3\u6784\u7684 V2<\/sub>O5-x<\/sub>\u00a0\u5438\u00a0 \u5f15\u66f4\u591a\u7684 O2<\/sub>\u00a0\u8f6c\u53d8\u6210 O2<\/sub>–<\/sup>\u00a0\uff0c\u4fc3\u8fdb\u5176\u4e0e K+<\/sup>\u00a0\u7684\u7ed3\u5408\uff0c\u8fdb\u800c\u4fc3\u8fdb\u653e\u7535\u4ea7\u7269 KO2<\/sub>\u00a0\u7684\u5f62\u6210\u3002\u00a0 AgCl \u5177\u6709\u8f83\u9ad8\u7684 OER \u50ac\u5316\u6d3b\u6027\u3002Ag \u7684\u52a0\u5165\u5141\u8bb8\u66f4\u591a\u7684\u7535\u5b50\u4ece\u96c6\u7535\u6781\u8f6c\u79fb\u5230\u7535\u00a0 \u6781\u8868\u9762\uff0c\u589e\u5f3a\u4e86\u6750\u6599\u7684\u7535\u5bfc\u7387\u3002\u901a\u8fc7\u626b\u63cf\u7535\u955c\u548c\u900f\u5c04\u7535\u955c\u7684\u6d4b\u8bd5\uff0c\u8bc1\u660e\u4e86\u6851\u845a\u72b6\u00a0 \u7684\u6837\u8c8c\u548c\u6d3b\u6027\u754c\u9762\u7684\u5f62\u6210\u3002N2<\/sub>\u00a0\u5438\u8131\u9644\u66f2\u7ebf\u6d4b\u8bd5\u5219\u662f\u8868\u660e\u8be5\u590d\u5408\u9634\u6781\u50ac\u5316\u5242\u5177\u6709\u00a0 \u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u53ef\u4ee5\u63d0\u4f9b\u66f4\u591a\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3002\u5728 0.02mA\/cm2<\/sup>\u00a0\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c \u7531\u8be5\u590d\u5408\u9634\u6781\u50ac\u5316\u5242\u6240\u88c5\u914d\u7684\u94be\u6c27\u7535\u6c60\u5177\u6709 1391.72mAh \u00b7g-1<\/sup>\u00a0\u7684\u9996\u6b21\u653e\u7535\u5bb9\u91cf\u548c\u63a5 \u8fd1 80\u00a0\u00a0 \u6b21 \u7684 \u957f \u5faa \u73af \u5bff \u547d \u3002 \u76f8 \u5173 \u6210 \u679c \u4ee5 \u300a A \u00a0\u00a0novel\u00a0\u00a0 mulberry-like Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u00a0composite as a stable catalyst for long-life potassium- oxygen batteries\u300b\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u300aJournal of Energy Storage\u300b\u4e0a\u53d1\u8868\u3002<\/span><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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\uff08d\uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684 EDS \u56fe<\/span><\/p>\n

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\uff08f\uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684\u6c27\u5206\u538b\u963b\u6297\u56fe<\/span><\/p>\n

\"\"<\/p>\n

\uff08a \uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x\u00a0<\/sub>\u7684 Ti \u3001V \u3001O \u3001Ag \u3001Cl \u3001C \u7684 XPS \u56fe\u8c31<\/span><\/p>\n

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\uff08c \uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684 V 2p \u7684 XPS \u56fe\u8c31<\/span><\/p>\n

\uff08d\uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684 Ag 3d \u7684 XPS \u56fe\u8c31<\/span><\/p>\n

\uff08e \uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684 O1s \u7684 XPS \u56fe\u8c31<\/span><\/p>\n

\uff08f\uff0915% Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7684\u00a0N2<\/sub>\u00a0\u5438\u9644\/\u89e3\u5438\u7b49\u6e29\u7ebf\u548c\u5b54\u9699\u5206\u5e03\uff08\u63d2\u56fe\uff09<\/span><\/p>\n

\"\"<\/p>\n

\uff08a \uff09Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u7cfb\u5217\u6750\u6599\u7684\u653e\u7535\u66f2\u7ebf<\/span><\/p>\n

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\u3010\u6210\u679c\u4ecb\u7ecd\u3011<\/strong><\/span><\/span><\/p>\n

\u6210\u529f\u6784\u5efa\u4e86\u4e00\u79cd\u5177\u6709\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u65b0\u578b\u6851\u6939\u72b6 Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u590d\u5408\u6750\u6599\u3002\u5176\u7c97\u7cd9 \u548c\u591a\u9897\u7c92\u5f62\u6001\u5177\u6709\u8f83\u5927\u7684\u50ac\u5316\u6bd4\u8868\u9762\u79ef\uff0c\u4f5c\u4e3a\u4e00\u4e2a\u6709\u5438\u5f15\u529b\u7684\u50ac\u5316\u9ad8\u6027\u80fd K-O2<\/sub>\u00a0 \u7535\u6c60\u6750\u6599\uff0c \u5b83\u8bc1\u5b9e\u4e86 V2O5-x\u00a0\u7f3a\u6c27\u7ed3\u6784\u5438\u5f15\u66f4\u591a\u7684 O2<\/sub>\u00a0\u8f6c\u53d8\u6210 O2<\/sub>\u2212<\/sup>\u00a0\u3002TiO2<\/sub>\u00a0\u7684\u52a0\u5165\u63d0\u9ad8\u4e86 K+\u00a0\u7684\u63d2\u5165\u7387\uff0c\u4fc3\u8fdb KO2<\/sub>\u00a0\u7684\u5f62\u6210\uff0c\u4ece\u800c\u52a0\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u3002 \u7531 TiO2<\/sub>\u00a0\u548c V2<\/sub>O5-x<\/sub>\u00a0\u7ec4\u6210\u7684\u6d3b\u6027\u754c\u9762\u4e5f\u80fd\u6709\u6548\u4fc3\u8fdb\u754c\u9762\u7535\u00a0 \u8377\u8f6c\u79fb\uff0cAg \u5143\u7d20\u90e8\u5206\u4ee5 AgCl \u7684\u5f62\u5f0f\u589e\u5f3a\u4e86\u6750\u6599\u7684 OER \u548c ORR \u6d3b\u6027\uff0c\u5e76\u8c03\u8282\u4e86\u5176\u7535\u5b50\u7ed3\u00a0 \u6784\u3002\u53e6\u4e00\u90e8\u5206\u4ee5 Ag \u7eb3\u7c73\u9897\u7c92\u7684\u5f62\u5f0f\u63d0\u9ad8\u4e86\u7535\u5bfc\u7387\uff0c\u8d35\u91d1\u5c5e\u7684\u52a0\u5165\u4e0d\u4ec5\u4f1a\u63d0\u9ad8\u6750\u6599\u7684\u7535\u5bfc\u7387\uff0c \u800c\u4e14\u4f1a\u63d0\u9ad8\u6c27\u7684\u7ed3\u5408\u80fd\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u4fc3\u8fdb\u8d85 KO2<\/sub>\u00a0\u7684\u5f62\u6210\uff0c\u540c\u65f6\u964d\u4f4e KO2<\/sub>\u00a0\u7684\u5206\u89e3\u00a0 \u80fd\u5792\uff0c\u5b9e\u73b0 O2\u00a0<\/sub>\u7684\u5feb\u901f\u6269\u6563\u3002\u5b83\u4eec\u660e\u663e\u5206\u88c2\uff0c\u4f46\u540c\u65f6\u53d1\u6325\u7740\u534f\u540c\u4f5c\u7528\u3002\u4e0e\u5355\u4e00\u91d1\u5c5e\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u591a\u79cd\u91d1\u5c5e\u50ac\u5316\u5242\u53ef\u4ee5\u53d1\u6325\u534f\u540c\u50ac\u5316\u4f5c\u7528\uff0c \u4ee5\u63d0\u9ad8\u94be\u6c27\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u6851\u845a\u72b6Ag\/AgCl@TiO2<\/sub>\/V2<\/sub>O5-x<\/sub>\u00a0\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u00a0K-O2<\/sub>\u00a0\u7535\u6c60\u7684\u9634\u6781\u50ac\u5316\u5242\u4e0d\u4ec5\u5177\u6709\u9ad8\u50ac\u5316\u6d3b\u6027\uff0c\u8fd8\u80fd\u89e3\u51b3\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u5dee\u7684\u95ee\u9898\uff0c\u540c\u65f6\u4e5f\u4e3a\u5546\u4e1a\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u5f00\u53d1\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/span><\/p>\n

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\"\"<\/p>\n

\u8521\u514b\u8fea\uff0c\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u8fbd\u5b81\u7279\u8058\u6559\u6388\uff0c\u5174\u8fbd\u82f1\u624d\u8ba1\u5212\u201c \u9752 \u5e74\u62d4\u5c16\u4eba\u624d\u201d \uff0c\u8fbd\u5b81\u7701\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u201c \u767e\u4eba\u5c42\u6b21\u201d \u3002\u83b7\u4e2d\u56fd\u4ea7\u5b66\u7814\u5408 \u4f5c\u521b\u65b0\u5956\uff082018 \u5e74\uff09\uff0c\u8fbd\u5b81\u9752\u5e74\u79d1\u6280\u5956\uff082019 \u5e74\uff09\uff0c\u8fbd\u5b81\u7701\u4f18\u79c0\u79d1 \u6280\u5de5\u4f5c\u8005\uff082022 \u5e74\uff09\u3002\u73b0\u4efb\u6e24\u6d77\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u5de5\u7a0b\u5b66\u9662\u526f\u9662\u957f\uff0c \u7535\u5316\u5b66\u50a8\u80fd\u6750\u6599\u4e0e\u6280\u672f\u7814\u7a76\u6240\u6240\u957f\u3002\u4e2d\u56fd\u8d85\u7ea7\u7535\u5bb9\u5668\u4ea7\u4e1a\u8054\u76df\u9752\u5e74\u7406\u4e8b\uff0c\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u9752\u5e74\u5de5\u4f5c\u59d4\u5458\u4f1a\u7406\u4e8b\uff0c\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ad8\u7ea7\u4f1a\u5458\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u51fd\u8bc4\u4e13\u5bb6\uff0c\u6559\u80b2\u90e8\u5b66\u4f4d\u4e2d\u5fc3\u8bc4\u5ba1\u4e13\u5bb6\uff0c\u591a\u7701\u5e02\u79d1\u6280\u5956\u8bc4\u5ba1\u4e13\u5bb6\u3002<\/span><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u4e3b\u8981\u4ece\u4e8b\u80fd\u6e90\u5316\u5b66\u4e0e\u80fd\u6e90\u6750\u6599\u9886\u57df\u7684\u57fa\u7840\u5e94\u7528\u7814\u7a76\uff0c\u5148 \u540e\u4e3b\u6301\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u57fa\u91d1\u3001\u8fbd\u5b81\u7701\u79d1\u6280\u5385\u91cd\u70b9\u7814 \u53d1\u8ba1\u5212\u7b49 20 \u4f59\u9879\u56fd\u5bb6\u53ca\u7701\u90e8\u7ea7\u8bfe\u9898 \uff0c\u5148\u540e\u5728 Composites Part B \u3001 Journal of Energy Chemistry\u3001ACSAMI \u7b49\u56fd\u5185\u5916\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587 100 \u4f59\u7bc7\uff0c\u5176\u4e2d 5 \u7bc7\u6587\u7ae0\u5165\u9009 ESI \u9ad8\u88ab\u5f15\u8bba\u6587\u30014 \u7bc7\u6587\u7ae0\u5165\u9009 ESI \u70ed \u70b9\u8bba\u6587\u3002\u7533\u62a5 82 \u9879\u56fd\u5bb6\u4e13\u5229\u30012 \u9879\u56fd\u9645\u4e13\u5229\uff0c\u5176\u4e2d\u6388\u6743 76 \u9879\uff08\u7b2c\u4e00 \u53d1\u660e\u4eba 34 \u9879\uff09\uff0c\u79d1\u6280\u6210\u679c\u8f6c\u5316 4 \u9879\uff0c\u76f4\u63a5\u6216\u95f4\u63a5\u7ecf\u6d4e\u5229\u6da6\u8fd1\u5343\u4e07\u5143\uff0c\u53c2\u4e0e\u5236\u5b9a\u56e2\u4f53\u6807\u51c6 2 \u9879\uff0c\u4e3b\u7f16\u300a\u5316\u5b66\u7535\u6e90\u6280\u672f\u300b\u7b49\u5b66\u672f\u8457\u4f5c 3 \u90e8\u3002<\/span><\/p>\n

\u6587\u7ae0\u4fe1\u606f\uff1aA novel mulberry-like Ag\/AgCl@TiO2\/V2O5-x composite as a stable\u00a0 catalyst\u00a0 for\u00a0 long-life\u00a0 potassium- oxygen\u00a0 batteries,\u00a0 Journal\u00a0 of Energy Storage 75 (2024) 109590<\/span><\/p>\n

DOI:10.1016\/j.est.2023.109590<\/span><\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1a<\/span><\/p>\n

https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S2352152X23029882<\/span><\/p>\n

\u4f9b\u7a3f\u4eba\uff1a\u5f20\u6653\u6c11<\/span><\/p>\n

<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"

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