{"id":256246,"date":"2023-11-30T08:36:27","date_gmt":"2023-11-30T00:36:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=256246"},"modified":"2023-11-30T08:47:26","modified_gmt":"2023-11-30T00:47:26","slug":"%e5%90%8c%e6%b5%8e%e5%a4%a7%e5%ad%a6%e8%ae%b8%e7%bb%b4%e6%95%99%e6%8e%88%e6%9c%80%e6%96%b0nature%ef%bc%9a%e8%8a%b3%e9%a6%99%e6%97%8f%e7%8e%af10%e7%a2%b3%e5%92%8c%e7%8e%af14%e7%a2%b3%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=256246","title":{"rendered":"\u540c\u6d4e\u5927\u5b66\u8bb8\u7ef4\u6559\u6388\u6700\u65b0Nature\uff1a\u82b3\u9999\u65cf\u73af[10]\u78b3\u548c\u73af[14]\u78b3\u7684\u8868\u9762\u5408\u6210"},"content":{"rendered":"<p style=\"text-align: center;\">\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u57fa\u4e8esp<sup>2<\/sup>\u6742\u5316\u539f\u5b50\u7684\u5168\u78b3\u6750\u6599\uff0c\u5982\u5bcc\u52d2\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\uff0c\u7531\u4e8e\u5176\u663e\u8457\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u548c\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u800c\u5907\u53d7\u5173\u6ce8\u3002\u53e6\u4e00\u4e2a\u4e0d\u5bfb\u5e38\u7684\u5168\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\u5bb6\u65cf\u662f\u7531\u4e24\u4e2a\u914d\u4f4d\u7684<em><i>sp<\/i><\/em>\u6742\u5316\u539f\u5b50\u7ec4\u6210\u7684\u73af[n]\u78b3(C<sub>n<\/sub>)\u3002\u5b83\u4eec\u81ea\u4e8c\u5341\u4e16\u7eaa\u4ee5\u6765\u4e00\u76f4\u5728\u6c14\u76f8\u4e2d\u88ab\u7814\u7a76\uff0c\u4f46\u5b83\u4eec\u7684\u9ad8\u53cd\u5e94\u6d3b\u6027\u610f\u5473\u7740\u51dd\u805a\u76f8\u5408\u6210\u548c\u5b9e\u7a7a\u95f4\u8868\u5f81\u4e00\u76f4\u5177\u6709\u6311\u6218\u6027\uff0c\u4f7f\u5f97\u5b83\u4eec\u7684\u786e\u5207\u5206\u5b50\u7ed3\u6784\u6709\u5f85\u5546\u69b7\u3002\u4ec5\u57282019\u5e74\uff0c\u901a\u8fc7\u952e\u5206\u8fa8\u539f\u5b50\u529b\u663e\u5fae\u955c\u63ed\u793a\u4e86\u5728\u8868\u9762\u751f\u6210\u7684\u5b64\u7acbC<sub>18<\/sub>\u53ca\u5176\u591a\u7094\u7ed3\u6784\uff0c\u968f\u540e\u53c8\u6709\u5173\u4e8eC<sub>16<\/sub>\u7684\u6700\u65b0\u62a5\u9053\u3002\u5c3d\u7ba1\u8f83\u5c0f\u7684C<sub>n<\/sub>\u540c\u7d20\u5f02\u5f62\u4f53\u7684\u5408\u6210\u548c\u8868\u5f81\u4ecd\u7136\u5341\u5206\u56f0\u96be\uff0c\u4f46C<sub>18<\/sub>\u5de5\u4f5c\u6fc0\u53d1\u4e86\u7406\u8bba\u7814\u7a76\uff0c\u9610\u660e\u4e86\u76f4\u5230C<sub>100<\/sub>\u7684\u73af[n]\u78b3\u7ed3\u6784\u3002<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p><strong><b>\u4eca\u65e5\uff0c\u540c\u6d4e\u5927\u5b66\u8bb8\u7ef4\u6559\u6388\u8bfe\u9898\u7ec4\u6539\u8fdb\u4e86\u65e9\u671f\u7684\u8868\u9762\u5408\u6210\u65b9\u6cd5\uff0c\u901a\u8fc7\u9488\u5c16\u8bf1\u5bfc\u5168\u6c2f\u4ee3\u8418(C<\/b><\/strong><strong><sub><b>10<\/b><\/sub><\/strong><strong><b>C<\/b><\/strong><strong><sub><b>l8<\/b><\/sub><\/strong><strong><b>)\u548c\u84bd(C<\/b><\/strong><strong><sub><b>14<\/b><\/sub><\/strong><strong><b>Cl<\/b><\/strong><strong><sub><b>10<\/b><\/sub><\/strong><strong><b>)\u5206\u5b50\u7684\u8131\u5364\u548c\u53cd\u4f2f\u683c\u66fc\u5f00\u73af\u5206\u522b\u5236\u5907\u4e86\u73af[10]\u78b3(C<\/b><\/strong><strong><sub><b>10<\/b><\/sub><\/strong><strong><b>)\u548c\u73af[14]\u78b3(C<\/b><\/strong><strong><sub><b>14<\/b><\/sub><\/strong><strong><b>)<\/b><\/strong>\u3002\u672c\u5de5\u4f5c\u4f7f\u7528\u539f\u5b50\u529b\u663e\u5fae\u955c\u6210\u50cf\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u4e0eC<sub>18<\/sub>\u548cC<sub>16<\/sub>\u76f8\u6bd4\uff0cC<sub>10<\/sub>\u548cC<sub>14<\/sub>\u5206\u522b\u5177\u6709\u7c7b\u4f3c\u4e8e\u805a\u661f\u866b\u548c\u7d2f\u79ef\u53cc\u952e\u5316\u5408\u7269\u7684\u7ed3\u6784\u3002<strong><b>\u672c\u5de5\u4f5c\u7684\u7ed3\u679c\u8bc1\u660e\u4e86\u4e00\u79cd\u5728\u8868\u9762\u751f\u6210\u73af\u78b3\u7684\u66ff\u4ee3\u7b56\u7565\uff0c\u4e3a\u8868\u5f81\u73af\u72b6\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\u7684\u7ed3\u6784\u548c\u7a33\u5b9a\u6027\u63d0\u4f9b\u4e86\u4e00\u79cd\u9014\u5f84<\/b><\/strong>\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\u201c<strong><b>On-surface synthesis of aromatic cyclo[10]carbon and cyclo[14]carbon<\/b><\/strong>\u201d\u7684\u8bba\u6587\u53d1\u8868\u5728<strong><em><b><i>Nature<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-256247\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72471-18.png\" alt=\"\" width=\"698\" height=\"234\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72471-18.png 698w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72471-18-300x101.png 300w\" sizes=\"(max-width: 698px) 100vw, 698px\" \/><b><\/b><\/p>\n<p style=\"text-align: center;\">\u3010\u6570\u636e\u6982\u51b5\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-256248\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-18.png\" alt=\"\" width=\"514\" height=\"557\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-18.png 514w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-18-277x300.png 277w\" sizes=\"(max-width: 514px) 100vw, 514px\" \/><\/p>\n<p><strong><b>\u56fe1. \u5f62\u6210\u73af[10]\u78b3\u548c\u73af[14]\u78b3\u7684\u53cd\u5e94\u65b9\u6848\u00a9 2023 Springer Nature Limited<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-256249\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-19.png\" alt=\"\" width=\"514\" height=\"557\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-19.png 514w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72472-19-277x300.png 277w\" sizes=\"(max-width: 514px) 100vw, 514px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>. \u73af[10]\u78b3\u7684\u56db\u79cd\u53ef\u80fd\u7ed3\u6784\u00a9 2023 Springer Nature Limited<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-256250\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72474-18.png\" alt=\"\" width=\"600\" height=\"565\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72474-18.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72474-18-300x283.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>. \u8868\u9762\u751f\u6210\u7684\u524d\u9a71\u4f53\u3001\u4e2d\u95f4\u4f53\u548c\u4ea7\u7269(C<\/b><\/strong><strong><sub><b>10<\/b><\/sub><\/strong><strong><b>)\u00a9 2023 Springer Nature Limited<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-256251\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72475-16.png\" alt=\"\" width=\"619\" height=\"568\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72475-16.png 619w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2023\/11\/\u56fe\u72475-16-300x275.png 300w\" sizes=\"(max-width: 619px) 100vw, 619px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>. \u8868\u9762\u751f\u6210\u7684\u4e2d\u95f4\u4f53\uff0c\u4ea7\u7269(C<\/b><\/strong><strong><sub><b>14<\/b><\/sub><\/strong><strong><b>)\u548c\u4e0d\u540cBLAs\u7684C<\/b><\/strong><strong><sub><b>14<\/b><\/sub><\/strong><strong><b>\u7684AFM\u6a21\u62df\u00a9 2023 Springer Nature Limited<\/b><\/strong><\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p><strong><b>\u603b\u4e4b\uff0c<\/b><\/strong><strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u57284.7\u2009K\u7684NaCl\/Au(111)\u53cc\u5c42\u8868\u9762\u4e0a\u901a\u8fc7\u539f\u5b50\u64cd\u7eb5\u6210\u529f\u5730\u751f\u6210\u4e86\u82b3\u9999\u73af[10]\u78b3\u548c\u73af[14]\u78b3\uff0c\u8fd9\u4f7f\u5f97\u672c\u5de5\u4f5c\u901a\u8fc7\u952e\u5206\u8fa8AFM\u6210\u50cf\u8bc1\u5b9e\u4e86C<\/b><\/strong><strong><sub><b>10<\/b><\/sub><\/strong><strong><b>\u7684\u5806\u79ef\u7ed3\u6784<\/b><\/strong>\uff0c\u6b63\u5982\u7406\u8bba\u9884\u6d4b\u7684\u90a3\u6837\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0c\u76ae\u5c14\u65af\u76f8\u53d8\u4e2d\u95f4\u4f53(Peierls-transition intermediate)C<sub>14<\/sub>\u7684\u5b9e\u9a8cAFM\u56fe\u50cf\u4e5f\u663e\u793a\u51fa\u7d2f\u79ef\u7279\u6027\u3002\u867d\u7136AFM\u6210\u50cf\u5206\u8fa8\u7387\u4e0d\u8db3\u4ee5\u68c0\u6d4b\u8be5\u5206\u5b50\u8ba1\u7b97\u5f97\u5230\u76840.05\u2009\u00c5\u7684\u5c0f\u952e\u957f\u53d8\u5316\uff0c\u4f46\u5b83\u7684\u786e\u5c06C<sub>14<\/sub>\u8bc6\u522b\u4e3a\u4ecb\u4e8e\u805a\u7094C<sub>10<\/sub>\u548c\u805a\u7094C<sub>18<\/sub>\u4e4b\u95f4\u7684\u4e2d\u95f4\u7ed3\u6784\u3002\u672c\u5de5\u4f5c\u9884\u8ba1\uff0c\u672c\u5de5\u4f5c\u548c\u4ee5\u524d\u7684\u8868\u9762\u5408\u6210\u7b56\u7565\u7684\u8865\u5145\u5c06\u4f7f\u5176\u4ed6\u53ef\u80fd\u8868\u73b0\u51fa\u6709\u8da3\u6027\u8d28\u7684\u73af[n]\u78b3\u7684\u751f\u6210\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-023-06741-x\"><u>https:\/\/www.nature.com\/articles\/s41586-023-06741-x<\/u><\/a><\/p>\n<p>\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5bfc\u8bfb\u3011 \u57fa\u4e8esp2\u6742\u5316\u539f\u5b50\u7684\u5168\u78b3\u6750\u6599\uff0c\u5982\u5bcc\u52d2\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\uff0c\u7531\u4e8e\u5176\u663e\u8457\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u548c\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u800c\u5907\u53d7\u5173\u6ce8\u3002\u53e6\u4e00\u4e2a\u4e0d\u5bfb\u5e38\u7684\u5168\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\u5bb6\u65cf\u662f\u7531\u4e24\u4e2a&#8230;<\/p>\n","protected":false},"author":34419,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[5098,4273],"class_list":["post-256246","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-5098","tag-4273"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/256246"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/34419"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=256246"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/256246\/revisions"}],"predecessor-version":[{"id":256254,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/256246\/revisions\/256254"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=256246"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=256246"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=256246"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}