{"id":256862,"date":"2024-01-11T06:52:47","date_gmt":"2024-01-10T22:52:47","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=256862"},"modified":"2024-01-10T20:53:33","modified_gmt":"2024-01-10T12:53:33","slug":"nature-materials%ef%bc%9a%e7%b1%bb%e6%b2%b8%e7%9f%b3%e5%92%aa%e5%94%91%e9%85%af%e9%aa%a8%e6%9e%b6%e6%9d%90%e6%96%99%ef%bc%88zifs%ef%bc%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=256862","title":{"rendered":"Nature Materials\uff1a\u7c7b\u6cb8\u77f3\u54aa\u5511\u916f\u9aa8\u67b6\u6750\u6599\uff08ZIFs\uff09"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u73bb\u7483\u4e00\u822c\u5b9a\u4e49\u4e3a\u957f\u7a0b\u65e0\u5e8f\u3001\u77ed\u7a0b\u6709\u5e8f\u7684\u5177\u6709\u73bb\u7483\u8f6c\u53d8\u7684\u56fa\u4f53\u3002\u6839\u636e\u5316\u5b66\u7ec4\u6210\uff0c\u73bb\u7483\u5206\u4e3a\u65e0\u673a\u3001\u6709\u673a\u548c\u91d1\u5c5e\u4e09\u5927\u5bb6\u65cf\u3002\u57282015\u5e74\uff0c\u79d1\u5b66\u5bb6\u53d1\u73b0\u4e86\u4e00\u4e2a\u65b0\u7684\u73bb\u7483\u5bb6\u65cf-\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u73bb\u7483\u3002\u4e0e\u4e09\u5927\u4f20\u7edf\u73bb\u7483\u4e0d\u540c\u7684\u662f\uff0cMOF\u73bb\u7483\u4ee5\u6709\u673a\u65e0\u673a\u5316\u5b66\u7ec4\u6210\u548c\u914d\u4f4d\u952e\u4e3a\u7279\u5f81\u3002\u76ee\u524d\uff0c\u53ef\u4ee5\u5f62\u6210\u73bb\u7483\u7684MOF\u4e3b\u8981\u6765\u81ea\u5b83\u7684\u4e00\u4e2a\u5206\u652f\uff1a\u6cb8\u77f3\u54aa\u5511\u916f\u9aa8\u67b6\uff08ZIF\uff09\u6676\u4f53\u3002\u8fc4\u4eca\uff0cZIF\u73bb\u7483\u7684\u5947\u5999\u7279\u6027\u88ab\u9010\u6e10\u53d1\u6398\uff0c\u4f8b\u5982\u8d85\u9ad8\u7684\u73bb\u7483\u5f62\u6210\u80fd\u529b\u4ee5\u53ca\u5316\u5b66\u7ec4\u6210\u53ef\u63a7\u6027\u5f3a\u7b49\uff1b\u6b64\u5916\uff0cZIF\u73bb\u7483\u5728\u6c14\u4f53\u5438\u9644\u5b58\u50a8\u3001\u6c14\u4f53\u5206\u79bb\u3001\u8d28\u5b50\u4f20\u5bfc\u3001\u8d85\u5bbd\u4e2d\u7ea2\u5916\u53d1\u5149\u3001\u7535\u6c60\u6750\u6599\u7b49\u9886\u57df\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u548c\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u4eba\u4eec\u76ee\u524d\u53d1\u73b0\u591a\u5b54MOF\u6750\u6599\u80fd\u591f\u7528\u4e8e\u89e3\u51b3\u73b0\u4ee3\u793e\u4f1a\u9762\u4e34\u7684\u8bb8\u591a\u56f0\u96be\uff0c\u6bd4\u5982CO<sub>2<\/sub>\u5c01\u5b58\u5904\u7406\u3002\u4eba\u4eec\u53d1\u73b0\u7c7b\u6cb8\u77f3\u54aa\u5511\u916f\u9aa8\u67b6\u6750\u6599\uff08ZIF, Zeolitic imidazolate framework\uff09\u80fd\u591f\u751f\u6210ZIF\u73bb\u7483\u6750\u6599\uff0c\u7c7b\u6cb8\u77f3\u54aa\u5511\u916fZIF\u73bb\u7483\uff0c\u8fd9\u79cdZIF\u73bb\u7483\u5177\u6709\u7ecf\u5178\u73bb\u7483\u6750\u6599\u7684\u6db2\u4f53\u5904\u7406\uff0c\u4ee5\u53ca\u80fd\u591f\u7528\u4e8e\u6c14\u4f53\u5206\u79bb\u8fc7\u7a0b\u3002\u8fd1\u65e5\uff0c\u8036\u62ff\u5927\u5b66Alexander Knebel\u7b49\u901a\u8fc7\u6784\u7b51\u6beb\u7c73\u5c3a\u5bf8\u7684ZIF-62\u5355\u6676\u548c\u5398\u7c73\u5c3a\u5bf8ZIF-62\u73bb\u7483\uff0c\u8bf4\u660e\u8fd9\u79cdZIF-62\u6750\u6599\u7684\u5927\u89c4\u6a21\u5904\u7406\u548c\u5e94\u7528\u7684\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cPrecise control over gas-transporting channels in zeolitic imidazolate framework glasses\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature Materials\u4e0a\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256863\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/0.png\" alt=\"\" width=\"1025\" height=\"507\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/0.png 1025w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/0-300x148.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/0-768x380.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/0-1024x507.png 1024w\" sizes=\"(max-width: 1025px) 100vw, 1025px\" \/><\/p>\n<p style=\"text-align: center;\">\u4e8c\u3001\u3010\u79d1\u5b66\u8d21\u732e\u3011<\/p>\n<p>\u00a0 \u00a0 \u00a0 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K\u4e0bTm=450\u00b0C\u548cTg=322\u00b0C\u3002\u9002\u5f53\u6d17\u6da4\u5e76\u771f\u7a7a\u5e72\u71e5ZIF-62\uff0c\u7136\u540e\u5728\u7194\u878d\u65f6\u5f62\u6210\u900f\u660e\u548c\u7eb3\u7c73\u591a\u5b54\u73bb\u7483\u3002\u901a\u8fc7\u5728400\u00b0C\u4e0b\u56de\u706b\u5904\u7406agZIF-62nP\u548cagZIF-62P\uff0c\u5206\u522b\u8bb0\u4e3aagZIF-62P\u2192T\u548cagZIF-62P\u2192T\u3002<\/p>\n<p>\u901a\u8fc7\u7ea2\u5916\u6210\u50cf\u8868\u5f81\u6280\u672f\u7814\u7a76\u6c14\u4f53\u5728ZIF\u6676\u4f53\u548cZIF\u73bb\u7483\u5185\u7684\u7a7f\u900f\u60c5\u51b5\uff0c\u7ed9\u51fa\u4e86\u00e5ngstr\u00f6m\u5c3a\u5ea6\u7684\u6269\u6563\u7cfb\u6570\u4ee5\u53ca\u968f\u7740\u5b54\u7ed3\u6784\u7684\u6539\u53d8\u3002\u91c7\u7528\u8d28\u8c31\u8868\u5f81\u65b9\u6cd5\u7814\u7a76\u6676\u4f53\u8f6c\u5316\u4e3a\u73bb\u7483\u6001\u4ee5\u53ca\u70ed\u5904\u7406\u529f\u80fd\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256864\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/1.png\" alt=\"\" width=\"971\" height=\"797\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/1.png 971w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/1-300x246.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/1-768x630.png 768w\" sizes=\"(max-width: 971px) 100vw, 971px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1. \u6c14\u4f53\u6269\u6563\u52a8\u529b\u5b66\u7684\u539f\u4f4d\u6269\u6563\u7814\u7a76\u3002\u00a9 2023 Nature<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256865\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/2.png\" alt=\"\" width=\"820\" height=\"816\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/2.png 820w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/2-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/2-300x300.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/2-768x764.png 768w\" sizes=\"(max-width: 820px) 100vw, 820px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2. \u6c14\u4f53\u6269\u6563\u52a8\u529b\u5b66\u7684\u539f\u4f4d\u6269\u6563\u7814\u7a76\u3002\u00a9 2023 Nature<\/p>\n<p>\u4f7f\u7528\u5177\u6709\u663e\u5fae\u529f\u80fd\u7684\u52a0\u70ed\u53f0\u8868\u5f81\u4e0d\u540c\u5c3a\u5ea6\u4e0a\u6750\u6599\u5728\u7194\u878d\u8fc7\u7a0b\u548c\u52a0\u5de5\u5904\u7406\u8fc7\u7a0b\u4e2d\u7684\u53d8\u5316\u60c5\u51b5\uff0c\u5e76\u4e14\u901a\u8fc7TEM\u8868\u5f81\u6280\u672f\u5206\u6790\u5fae\u7ed3\u6784\u3002\u8868\u5f81\u73bb\u7483\u7684\u4f53\u79ef\u53d8\u5316\u548c\u5bc6\u5ea6\u53d8\u5316\uff0c\u8ffd\u8e2a\u5728\u52a0\u5de5\u5904\u7406\u73bb\u7483\u8fc7\u7a0b\u4e2d\u7684\u5b54\u9053\u574d\u584c\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256866\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/3.png\" alt=\"\" width=\"737\" height=\"774\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/3.png 737w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/3-286x300.png 286w\" sizes=\"(max-width: 737px) 100vw, 737px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3. \u5b54\u9699\u901a\u9053\u7684TEM\u663e\u5fae\u7ed3\u6784\u7814\u7a76\u3002\u00a9 2023 Nature<\/p>\n<p>\u4ee5\u4e0a\u7684\u8868\u5f81\u548c\u5206\u6790\u6709\u52a9\u4e8e\u66f4\u597d\u7684\u7406\u89e3ZIF\u73bb\u7483\u4e2d\u6c14\u4f53\u4f20\u8f93\u901a\u9053\u7684\u6539\u53d8\u4ee5\u53ca\u901a\u8fc7\u8bbe\u8ba1\u5bf9\u5176\u8fdb\u884c\u8c03\u63a7\uff0c\u6839\u636e\u5b9e\u9a8c\u7ed3\u679c\u80fd\u591f\u8bf4\u660eZIF\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u6c14\u4f53\u4f20\u8f93\u6027\u8d28\u80fd\u591f\u975e\u5e38\u597d\u7684\u8fdb\u884c\u63a7\u5236\uff0c\u800c\u4e14\u5b9e\u73b0\u4e86\u5bf9\u5927\u91cf\u4e0d\u540c\u79cd\u7c7b\u6c14\u4f53\u7684\u5c3a\u5bf8\u6392\u65a5\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256867\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/4.png\" alt=\"\" width=\"897\" height=\"779\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/4.png 897w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/4-300x261.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/4-768x667.png 768w\" sizes=\"(max-width: 897px) 100vw, 897px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4. \u56de\u706b\u5bf9ZIF-62\u5408\u91d1\u5b54\u9699\u7387\u7684\u5f71\u54cd\u3002\u00a9 2023 Nature<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-256868\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/5.png\" alt=\"\" width=\"924\" height=\"675\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/5.png 924w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/5-300x219.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/01\/5-768x561.png 768w\" sizes=\"(max-width: 924px) 100vw, 924px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5. 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