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\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n

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\u4e8c\u3001\u3010\u79d1\u5b66\u8d21\u732e\u3011<\/strong><\/p>\n

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\u56fe<\/strong>1 cyanoRbMnFeCo<\/strong>\u7684\u6676\u4f53\u7ed3\u6784\u548c\u7535\u8377\u8f6c\u79fb\u76f8\u53d8<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

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\u56fe<\/strong>2 cyanoRbMnFeCo<\/strong>\u7684\u53ef\u9006\u538b\u70ed\u6548\u5e94<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

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\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>\u76f4\u63a5\u6d4b\u91cf\u6e29\u5ea6\u53d8\u5316<\/strong>(\u0394Tobs<\/sub>)<\/strong>\u5728\u65bd\u52a0\u548c\u91ca\u653e\u538b\u529b\u7684<\/strong>cyanoRbMnFeCo<\/strong>\u4e2d\u7684\u6c14\u538b\u6548\u5e94<\/strong> \u00a9 2023 The Author(s)<\/strong><\/p>\n

\u4e3a\u4e86\u5b9e\u9645\u6d4b\u91cf\u65bd\u52a0\u548c\u91ca\u653e\u538b\u529b\u65f6\u7684\u6e29\u5ea6\u53d8\u5316(\u0394Tobs<\/sub>)\uff0c\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u70ed\u7535\u5076\u6784\u5efa\u4e86\u4e00\u4e2a\u81ea\u5236\u7684\u4eea\u5668\u3002\u70ed\u7535\u5076\u5b89\u88c5\u5728\u6837\u54c1\u5185\u90e8\u4ee5\u6d4b\u91cf\u6837\u54c1\u6e29\u5ea6\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u70ed\u7535\u5076\u76f4\u63a5\u6d4b\u91cfcyanoRbMnFeCo\u6e29\u5ea6\u53d8\u5316\u663e\u793a\u51fa+44 K\u65bd\u52a0\u538b\u529b\u3002\u5728\u65bd\u52a0\u538b\u529b\u548c\u91ca\u653e\u538b\u529b\u65f6\uff0c\u6e29\u5ea6\u7684\u5347\u9ad8\u548c\u964d\u4f4e\u53ef\u4ee5\u91cd\u590d\u8d85\u8fc7100\u4e2a\u5faa\u73af\uff0c\u800c\u4e0d\u4f1a\u964d\u4f4e\u6027\u80fd\uff0c\u5728cyano-RbMnFeCo\u4e2d\uff0c\u7531\u4e8e\u901a\u8fc7\u5f15\u5165Co\u79bb\u5b50\u6765\u8c03\u6574\u9ad8\u6e29\u76f8\u548c\u4f4e\u6e29\u76f8\u4e4b\u95f4\u7684\u76f8\u53d8\u6e29\u5ea6\uff0c\u56e0\u6b64\u5728\u5ba4\u6e29\u4ee5\u4e0a\u548c\u5ba4\u6e29\u4ee5\u4e0b\u7684\u5bbd\u6e29\u5ea6\u8303\u56f4\u5185\u5b9e\u73b0\u4e86\u8fd9\u79cd\u538b\u70ed\u6548\u5e94\u3002\u8be5\u6750\u6599\u7cfb\u5217\u8fd8\u5177\u670920.4 W m\u22121<\/sup> K\u22121<\/sup>\u7684\u9ad8\u5bfc\u70ed\u7cfb\u6570\u503c\u3002\u8be5\u6750\u6599\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u4f18\u5f02\u7684\u56fa\u6001\u5236\u51b7\u5242\u6750\u6599\uff0c\u5177\u6709\u4f18\u5f02\u7684\u538b\u70ed\u6548\u5e94\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cGiant adiabatic temperature change and its direct measurement of a barocaloric effect in a charge-transfer solid<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Communications<\/em><\/strong>\u4e0a\u3002\u5176\u4ee5\u6709\u522b\u4e8e\u4f20\u7edf\u56fa\u6001\u51dd\u805a\u6001\u6750\u6599\u7684\u5de8\u5927\u538b\u70ed\u6548\u5e94\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u7684\u70ed\u8bae\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u4e00\u79cd\u65b0\u578b\u65e0\u673a\u6676\u4f53\u6846\u67b6\u6750\u6599cyano-RbMnFeCo\u88ab\u6210\u529f\u5236\u5907\uff0c\u8be5\u6750\u6599\u88ab\u5e94\u7528\u4e8e\u56fa\u6001\u5236\u51b7\u5242\u4f7f\u7528\uff0c\u4ea7\u751f\u4e86\u6709\u522b\u4e8e\u4f20\u7edf\u56fa\u6001\u51dd\u805a\u6001\u6750\u6599\u7684\u5de8\u5927\u538b\u70ed\u6548\u5e94\u3002<\/p>\n

2\u3001\u8be5\u6750\u6599\u5728\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u56fa\u4f53-\u56fa\u4f53\u76f8\u53d8\u6750\u6599\u70ed\u6548\u5e94\u4e2d\u5177\u6709\u6700\u5927\u7684\u53ef\u9006\u7edd\u70ed\u6e29\u5ea6\u53d8\u5316\u3002<\/p>\n

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\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u5de5\u4f5c\u7814\u7a76\u7684\u7684Cyano-RbMnFeCo\u8868\u73b0\u51fa\u5de8\u5927\u7684\u53ef\u9006\u538b\u70ed\u6548\u5e94\u3002\u5de8\u5927\u53ef\u9006\u538b\u70ed\u6548\u5e94\u6e90\u4e8e\u56db\u4e2a\u56e0\u7d20\u3002(1)\u538b\u529b\u4f5c\u7528\u4e0b\u76f8\u53d8\u7684\u6e29\u79fb\u5177\u6709\u8f83\u5927\u7684dT\/dp\u503c\u3002(2) \u0394Srev<\/sub>\u6765\u6e90\u4e8e\u81ea\u65cb\u8f68\u9053\u71b5\u548c\u4f34\u968f\u7535\u8377\u8f6c\u79fb\u7684\u632f\u52a8\u71b5Svib<\/sub>\u7684\u8d21\u732e\u3002(3)\u9ad8\u6e29\u76f8\u548c\u4f4e\u6e29\u76f8\u7684\u71b5\u66f2\u7ebf\u5728\u5ba4\u6e29\u9644\u8fd1\u6709\u5e73\u7f13\u7684\u659c\u7387\u3002\u8fd9\u5728\u6052\u5b9a\u71b5\u7684\u7edd\u70ed\u51b7\u5374\u6216\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u5f88\u5927\u7684\u6e29\u5ea6\u53d8\u5316\u3002(4) cyanoRbMnFeCo\u5177\u6709\u9ad8\u8fbe533 K(260\u00b0C)\u7684\u9ad8\u8010\u70ed\u6027\u4ee5\u53ca\u5bf9\u4f20\u70ed\u4ecb\u8d28\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n

\u4ece\u7814\u7a76\u524d\u666f\u6765\u770b\uff0c(i)\u9ad8\u5bfc\u70ed\u7cfb\u6570\uff0c(ii)\u4f4e\u5fc5\u8981\u538b\u529b\uff0c\u4ee5\u53ca(iii)\u8de8\u8d8a\u5ba4\u6e29\u7684\u5bbd\u6e29\u5ea6\u7a97\u5bf9\u4e8e\u5f00\u53d1\u70ed\u5668\u4ef6\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u4ece\u5668\u4ef6\u5e94\u7528\u7684\u5b9e\u9645\u89d2\u5ea6\u6765\u770b\uff0c\u5c06\u8be5\u7814\u7a76\u6750\u6599\u9644\u7740\u5728\u538b\u7535\u57fa\u677f\u4e0a\u53ef\u4ee5\u5b9e\u73b0\u7d27\u51d1\u7684\u56fa\u4f53\u5236\u51b7\u5242\u4f7f\u7528\uff0c\u4ece\u800c\u6709\u6548\u9632\u6b62\u5668\u4ef6\u8fc7\u70ed\u3002<\/p>\n

\u8be5\u7814\u7a76\u5de5\u4f5c\u5c06\u4e3a\u538b\u70ed\u6548\u5e94\u6750\u6599\u9886\u57df\u5f00\u8f9f\u65b0\u7684\u53ef\u80fd\u6027\uff0c\u5e76\u6709\u52a9\u4e8e\u5f00\u53d1\u9002\u7528\u4e8e\u7a7a\u8c03\u548c\u98df\u54c1\u50a8\u5b58\u7684\u65b0\u578b\u5236\u51b7\u5242\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Giant adiabatic temperature change and its direct measurement of a barocaloric effect in a charge-transfer solid<\/strong>\uff0c<\/strong>2023<\/strong>\uff0c<\/strong>https:\/\/doi.org\/10.1038\/s41467-023-44350-4<\/strong>\uff09<\/strong><\/p>\n

 <\/p>\n

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