{"id":257464,"date":"2024-01-26T06:45:23","date_gmt":"2024-01-25T22:45:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=257464"},"modified":"2024-01-25T14:50:22","modified_gmt":"2024-01-25T06:50:22","slug":"%e6%b2%88%e9%98%b3%e5%8c%96%e5%b7%a5%e5%a4%a7%e5%ad%a6%e5%92%8c%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e9%9d%92%e6%b5%b7%e7%9b%90%e6%b9%96%e7%a0%94%e7%a9%b6%e6%89%80chem-eng-j-%e2%88%a3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=257464","title":{"rendered":"\u6c88\u9633\u5316\u5de5\u5927\u5b66\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u6d77\u76d0\u6e56\u7814\u7a76\u6240Chem. Eng. J.\u2223\u78c1\u6027MOF\u5b54\u5f84\u9650\u57df\u79bb\u5b50\u6db2\u4f53\u4e9a\u7eb3\u7c73\u7ed3\u6784\u50ac\u5316\u5242\u6784\u7b51\u53ca\u50ac\u5316\u6027\u80fd\u7814\u7a76"},"content":{"rendered":"

\u00a0\u3010<\/b><\/strong>\u7814\u7a76\u80cc\u666f\u3011<\/b><\/strong><\/p>\n

\u82b3\u57fa\u6076\u5511\u70f7\u916e\u662f\u4e00\u7c7b\u5177\u6709\u751f\u7269\u6d3b\u6027\u7684\u6c2e\u6742\u73af\u5316\u5408\u7269\uff0c\u5728\u533b\u836f\u3001\u519c\u836f\u4ee5\u53ca\u6297\u83cc\u548c\u9664\u8349\u7b49\u9886\u57df\u90fd\u5177\u6709\u975e\u5e38\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5408\u6210\u5177\u6709\u82b3\u57fa\u6076\u5511\u70f7\u916e\u7c7b\u836f\u7269\u548c\u4e2d\u95f4\u4f53\uff0c\u4e00\u76f4\u662f\u5316\u5b66\u754c\u548c\u836f\u7269\u5408\u6210\u754c\u7814\u7a76\u7684\u70ed\u70b9\u3002\u5177\u6709\u591a\u6d3b\u6027\u4f4d\u70b9\u5747\u76f8\u79bb\u5b50\u6db2\u4f53\u50ac\u5316\u5242\u5c55\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u4f46\u6d3b\u6027\u7ec4\u5206\u6613\u6d41\u5931\uff0c\u65e0\u6cd5\u957f\u6548\u5faa\u73af\u5229\u7528\uff0c\u4e14\u50ac\u5316\u5242\u4e0d\u6613\u5206\u79bb\u3002\u5982\u4f55\u5145\u5206\u53d1\u6325\u5747\u76f8\u79bb\u5b50\u6db2\u4f53\u50ac\u5316\u5242\u591a\u529f\u80fd\u6027\u548c\u9ad8\u6d3b\u6027\uff0c\u540c\u65f6\u5b9e\u73b0\u9ad8\u6548\u5206\u79bb\u548c\u53ef\u5faa\u73af\u5229\u7528\u662f\u50ac\u5316\u5242\u4ea7\u4e1a\u5316\u5e94\u7528\u4e9f\u5f85\u89e3\u51b3\u7684\u74f6\u9888\u95ee\u9898\u3002<\/p>\n

\u3010\u6587\u7ae0\u6982\u8ff0\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6c88\u9633\u5316\u5de5\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u7eff\u8272\u50ac\u5316\u6750\u6599\u4e0e\u8fc7\u7a0b\u6280\u672f\u7814\u7a76\u56e2\u961f\u8054\u5408\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u6d77\u76d0\u6e56\u7814\u7a76\u6240\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u79cd\u78c1\u6027MOF\u9650\u57df\u50ac\u5316\u5242MAG-UiO-66-IL(OAc)\u4e9a\u7eb3\u7c73\u7ed3\u6784\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u5728\u82b3\u80fa\u548c\u73af\u72b6\u78b3\u9178\u916f\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e\u7684\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u8d8a\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u6536\u7387\u9ad8\u8fbe95%\uff0c\u4e14\u663e\u8457\u63d0\u5347\u4e86\u7a33\u5b9a\u6027\uff0c\u91cd\u590d\u4f7f\u752810\u6b21\uff0c\u4ea7\u7387\u7a33\u5b9a\u572890%\u4ee5\u4e0a\u3002\u8be5\u9879\u6210\u679c\u4ee5\u9898\u4e3a\u201cA magnetic pore-confined catalyst with ionic liquids supported on MOFs for the synthesis of aryl-oxazolidinones: design, performance, and recyclability\u201d\u53d1\u8868\u5728\u5316\u5de5\u9886\u57df\u77e5\u540d\u671f\u520aChemical Engineering Journal (\u4e2d\u79d1\u9662\u4e00\u533a\uff0cIF=15.1)\u3002\u6c88\u9633\u5316\u5de5\u5927\u5b66\u79cd\u601d\u9896\u3001\u674e\u4f7c\u598d\u4e3a\u672c\u7814\u7a76\u7b2c\u4e00\u4f5c\u8005\uff0c\u738b\u5eb7\u519b\u6559\u6388\u3001\u5f20\u96c5\u9759\u6559\u6388\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u6d77\u76d0\u6e56\u7814\u7a76\u6240\u67f3\u745e\u745e\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c\u8d75\u723d\u3001\u9ec4\u521a\u4f1f\u53c2\u4e0e\u7814\u7a76\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

(1) \u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u7684<\/b><\/strong>\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\u50ac\u5316\u5242\u901a\u8fc7\u805a\u82ef\u4e59\u70ef\u78fa\u9178\u94a0\u00a0(PSS) \u4fee\u9970\u5177\u6709SiO2<\/sub>\u5305\u8986\u5c42\u7684Fe3<\/sub>O4<\/sub>\uff0c\u5e76\u5728\u5916\u5c42\u539f\u4f4d\u6784\u5efa\u53ef\u5b9e\u73b0\u78c1\u6027\u5206\u79bb\u7684Fe3<\/sub>O4<\/sub>@MOF\u6750\u6599 (MAG-UiO-66)\uff0c\u540e\u5229\u7528MOF\u4e9a\u7eb3\u7c73\u7a7a\u95f4\u5b54\u5f84\u9650\u57df\u81ea\u7ec4\u88c5\u79bb\u5b50\u6db2\u4f53\u6d3b\u6027\u7ec4\u5206 [C4<\/sub>mim] [OAc]\uff0c\u6784\u5efa\u4e00\u79cd\u78c1\u6027MOF\u9650\u57df\u50ac\u5316\u5242MAG-UiO-66-IL(OAc)\uff0c\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u601d\u8def\u5982\u56fe1\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. \u78c1\u6027MOF\u9650\u57df\u50ac\u5316\u5242MAG-UiO-66-IL(OAc)\u8bbe\u8ba1\u56fe<\/p>\n

(2) \u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u7684<\/b><\/strong>\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\u5b9e\u9a8c\u6570\u636e\u8868\u660e\uff0c\u5408\u6210\u7684\u78c1\u6027\u9650\u57df\u50ac\u5316\u5242MAG-UiO-66-IL(OAc)\u4f9d\u7136\u4fdd\u6301UIO-66\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u5176\u6d3b\u6027\u7ec4\u5206[C4<\/sub>mim] [OAc]\u88ab\u6210\u529f\u9650\u57df\u81ea\u7ec4\u88c5\u81f3\u78c1\u6027\u8f7d\u4f53MAG-UIO-66\u4e2d\u5e76\u5b58\u5728\u4e8e\u7eb3\u7c73\u7b3c\u5185\uff0c\u50ac\u5316\u5242\u7684\u90e8\u5206\u8868\u5f81\u6570\u636e\u5982\u56fe2\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. \u78c1\u6027MOF\u9650\u57df\u50ac\u5316\u5242\u90e8\u5206\u8868\u5f81\u6570\u636e\u793a\u610f\u56fe<\/p>\n

(3) \u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u50ac\u5316<\/b><\/strong>\u73af\u72b6\u78b3\u9178\u916f<\/b><\/strong>\u548c\u82b3\u80fa\u4e00\u9505\u6cd5\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e<\/b><\/strong>\u6027\u80fd\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\u8be5\u50ac\u5316\u5242\u5e94\u7528\u4e8e\u50ac\u5316\u78b3\u9178\u4e19\u70ef\u916f\u548c\u82ef\u80fa\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e\uff0c\u4ee595%\u7684\u9ad8\u4ea7\u7387\u5f97\u5230\u82b3\u57fa\u6076\u5511\u70f7\u916e\uff0c\u4e14\u8be5\u50ac\u5316\u5242\u5177\u6709\u975e\u5e38\u9ad8\u7684\u53ef\u91cd\u590d\u5229\u7528\u6027\uff0c\u7528\u78c1\u94c1\u5c31\u53ef\u4ee5\u8f7b\u6613\u56de\u6536\uff0c\u91cd\u590d\u4f7f\u752810\u6b21\uff0c\u4ea7\u7387\u4f9d\u7136\u80fd\u591f\u8fbe\u523090%\u4ee5\u4e0a\uff0c\u5982\u56fe3\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

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(4) \u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u7684<\/b><\/strong>\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97<\/b><\/strong><\/p>\n

\u672c\u7814\u7a76\u4e2d\u9650\u57df\u50ac\u5316\u5242\u7684\u6784\u5efa\u662f\u5229\u7528MOF\u5185\u90e8\u7a7a\u8154\u548c\u7a97\u53e3\u7684\u5c3a\u5bf8\u5dee\u5f02\uff0c\u5373MOF\u7684\u5b54\u9699\u8db3\u591f\u5927\uff0c\u4ee5\u5bb9\u7eb3\u6d3b\u6027\u6210\u5206\uff0c\u540c\u65f6\u7a97\u53e3\u8db3\u591f\u5c0f\uff0c\u4ee5\u9650\u5236\u548c\u9632\u6b62\u6d3b\u6027\u7ec4\u5206\u7684\u9038\u51fa\uff0c\u4ece\u800c\u4f9d\u9760\u5206\u5b50\u5c3a\u5ea6\u8fdb\u884c\u7cbe\u51c6\u9650\u57df\u3002\u5728\u914d\u4f53\u9884\u5206\u6563\u8fc7\u7a0b\u4e2d\uff0c\u5c0f\u5c3a\u5bf8\u6d3b\u6027\u79bb\u5b50\u6db2\u4f53\u524d\u9a71\u4f53\u53ef\u4ee5\u81ea\u7531\u6269\u6563\u81f3MOF\u7a7a\u8154\u5185\uff0c\u5728\u7eb3\u7c73\u5b54\u9053\u4e2d\u81ea\u7ec4\u88c5\u4e3a\u79bb\u5b50\u6db2\u4f53\u6d3b\u6027\u7ec4\u5206\uff0cMOF\u7a7a\u8154\u5c3a\u5bf8\u53ef\u4ee5\u5bb9\u7eb3\u79bb\u5b50\u6db2\u4f53\u6d3b\u6027\u7ec4\u5206\u3002\u540c\u65f6\uff0c\u5229\u7528MOF\u8f83\u5c0f\u7684\u7a97\u53e3\u5c3a\u5bf8\uff0c\u6709\u6548\u9632\u6b62\u6d3b\u6027\u7ec4\u5206\u6ea2\u51fa\uff0c\u5de7\u5999\u7684\u5c06\u79bb\u5b50\u6db2\u4f53\u6d3b\u6027\u7ec4\u5206\u9650\u57df\u5728MOF\u7eb3\u7c73\u7b3c\u5185\u3002MOF\u5185\u90e8\u7a7a\u8154\u53ca\u5176\u7a97\u53e3\u7684\u7eb3\u7c73\u5c3a\u5bf8\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\uff0c\u5177\u4f53\u8ba1\u7b97\u7ed3\u679c\u5982\u56fe4\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u00a04.\u00a0\u00a0\u78c1\u6027MOF\u8f7d\u4f53\u7a97\u53e3\u548c\u5b54\u5f84\u5c3a\u5bf8\u7cbe\u51c6\u9650\u57df\u5206\u5b50\u6a21\u62df<\/p>\n

(5) \u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u50ac\u5316<\/b><\/strong>\u73af\u72b6\u78b3\u9178\u916f<\/b><\/strong>\u548c\u82b3\u80fa\u4e00\u9505\u6cd5\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e\u673a\u7406\u7814\u7a76<\/b><\/strong><\/p>\n

\u672c\u9879\u76ee\u91c7\u7528\u7ecf\u5178\u5206\u5b50\u52a8\u529b\u5b66 (CMD) \u6a21\u62df\u65b9\u6cd5\u83b7\u53d6\u79bb\u5b50\u6db2\u4f53\u5728MOF\u5b54\u9053\u4e2d\u7684\u805a\u96c6\u5f62\u6001\u548c\u6269\u6563\u8fc7\u7a0b\uff0c\u5206\u6790\u79bb\u5b50\u6db2\u4f53\u4e0eMOF\u95f4\u7684\u4e3b\u8981\u754c\u9762\u76f8\u4e92\u4f5c\u7528\u529b\uff0c\u5e76\u5b9e\u73b0\u754c\u9762\u76f8\u4e92\u4f5c\u7528\u7684\u53ef\u89c6\u5316\uff1b\u5229\u7528\u7b2c\u4e00\u6027\u539f\u7406\u5206\u5b50\u52a8\u529b\u5b66 (AIMD) \u6a21\u62df\u7684\u65b9\u6cd5\u83b7\u53d6\u79bb\u5b50\u6db2\u4f53\u5728MOF\u5b54\u9053\u4e2d\u7684\u7ed3\u6784\u7ec6\u8282\u3001\u6c22\u952e\u7f51\u7edc\u62d3\u6251\u3001\u6269\u6563\u673a\u7406\u4ee5\u53ca\u50ac\u5316\u5242\u4e0eMOF\u7684\u7ed3\u6784\u5355\u5143\u4e4b\u95f4\u7684\u754c\u9762\u4f5c\u7528\u673a\u5236\uff1b\u6700\u540e\u91c7\u7528\u91cf\u5b50\u5316\u5b66 (QM) \u7684\u65b9\u6cd5\u63a2\u7a76\u50ac\u5316\u53cd\u5e94\u4e2d\u6bcf\u4e00\u6b65\u57fa\u5143\u53cd\u5e94\u7684\u53cd\u5e94\u8def\u5f84\uff0c\u63d0\u51fa\u50ac\u5316\u5242\u5bf9\u73af\u72b6\u78b3\u9178\u916f\u548c\u82b3\u80fa\u4e00\u9505\u6cd5\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e\u53cd\u5e94\u7684\u50ac\u5316\u673a\u7406\uff0c\u5982\u56fe5\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5.\u00a0\u78c1\u6027\u9650\u57df\u50ac\u5316\u5242\u53cd\u5e94\u673a\u7406\u8ba1\u7b97\u8fc7\u7a0b<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/b><\/strong><\/p>\n

\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u4e9a\u7eb3\u7c73\u5c3a\u5ea6MOF\u5b54\u5f84\u9650\u57df\u79bb\u5b50\u6db2\u4f53\u50ac\u5316\u5242\u7684\u6784\u5efa\u7b56\u7565\u3002\u8be5\u50ac\u5316\u5242\u5728\u73af\u72b6\u78b3\u9178\u916f\u548c\u82b3\u80fa\u5408\u6210\u82b3\u57fa\u6076\u5511\u70f7\u916e\u7684\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3001\u5e7f\u6cdb\u7684\u5e95\u7269\u9002\u7528\u6027\u3001\u78c1\u6027\u6613\u56de\u6536\u548c\u826f\u597d\u7684\u91cd\u590d\u4f7f\u7528\u6027\u3002\u901a\u8fc7\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u4e0e\u5b9e\u9a8c\u9a8c\u8bc1\uff0c\u63a2\u7a76\u4e86MOFs\u9650\u57df\u5b54\u9053\u5185\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u4f20\u8f93\u673a\u5236\uff0c\u8f7d\u4f53\u548c\u79bb\u5b50\u6db2\u4f53\u534f\u540c\u50ac\u5316\u53cd\u5e94\u89c4\u5f8b\u4ee5\u53ca\u5e95\u7269\u4e0e\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u5206\u5b50\u95f4\u4f5c\u7528\u673a\u5236\uff0c\u4e3a\u9610\u8ff0\u9650\u57df\u578b\u50ac\u5316\u5242\u4e3b\u5ba2\u4f53\u4ea4\u4e92\u4f5c\u7528\u63d0\u4f9b\u7406\u8bba\u4f9d\u636e\uff0c\u4e3a\u78c1\u6027MOF\u9650\u57df\u7a7a\u95f4\u5185\u50ac\u5316\u6027\u80fd\u8c03\u63a7\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

Chong S, Li J, Zhao S, et al. A magnetic pore-confined catalyst with ionic liquids supported on MOFs for the synthesis of aryl-oxazolidinones: design, performance, and recyclability[J]. Chemical Engineering Journal, 2024,\u00a0481, 148678.<\/p>\n

DOI: 10.1016\/j.cej.2024.148678<\/p>\n

https:\/\/doi.org\/10.1016\/j.cej.2024.148678<\/p>\n

https:\/\/authors.elsevier.com\/a\/1iSBT4x7R2k5zX<\/p>\n","protected":false},"excerpt":{"rendered":"

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