{"id":257622,"date":"2024-02-02T06:41:55","date_gmt":"2024-02-01T22:41:55","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=257622"},"modified":"2024-02-01T19:47:17","modified_gmt":"2024-02-01T11:47:17","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e9%99%88%e7%bb%b4%e5%9b%a2%e9%98%9f-%e9%a6%96%e6%ac%a1%e5%ae%9e%e7%8e%b0%e8%b6%85%e9%ab%98%e6%95%88%e7%8e%87%e7%9a%84%e9%94%b0%e9%87%91%e5%b1%9e%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=257622","title":{"rendered":"\u4e2d\u79d1\u5927\u9648\u7ef4\u56e2\u961f | \u9996\u6b21\u5b9e\u73b0\u8d85\u9ad8\u6548\u7387\u7684\u9530\u91d1\u5c5e\u7535\u6c60"},"content":{"rendered":"

\u4e00\u3001\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n

\u8003\u8651\u5230\u9502\u79bb\u5b50\u7535\u6c60\u539f\u6750\u6599\u77ed\u7f3a\u548c\u4ef7\u683c\u4e0d\u65ad\u4e0a\u6da8\u7684\u95ee\u9898\uff0c\u5177\u6709\u4f4e\u6210\u672c\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u6f5c\u5728\u5019\u9009\u6750\u6599\u8d8a\u6765\u8d8a\u53d7\u5230\u4e16\u754c\u5404\u5730\u7814\u7a76\u4eba\u5458\u7684\u5173\u6ce8\u3002\u591a\u4ef7\u91d1\u5c5e\u7535\u6c60\uff08multivalent metal battery, MMB\uff09\u7531\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u4f5c\u4e3a\u7535\u8377\u8f7d\u4f53\uff0c\u6bcf\u4e2a\u539f\u5b50\u53ef\u5b58\u50a8\u4e24\u4e2a\u751a\u81f3\u4e09\u4e2a\u7535\u5b50\uff0c\u4e0e\u5355\u8377\u7535\u7684\u78b1\u91d1\u5c5e\u79bb\u5b50\u76f8\u6bd4\uff0c\u53ef\u63d0\u4f9b\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u6b64\u5916\uff0c\u591a\u4ef7\u91d1\u5c5e\u5143\u7d20\u79cd\u7c7b\u4e30\u5bcc\u3001\u50a8\u91cf\u5145\u8db3\uff0c\u6709\u5229\u4e8e\u5927\u5927\u964d\u4f4eMMBs\u4ea7\u54c1\u7684\u751f\u4ea7\u6210\u672c\u3002\u4e3a\u4e86\u6700\u5927\u9650\u5ea6\u5730\u63d0\u9ad8MMBs\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4ee5\u591a\u4ef7\u91d1\u5c5e\u7684\u6c89\u79ef\u548c\u6eb6\u89e3\u53cd\u5e94\u4f5c\u4e3a\u8d1f\u6781\uff0c\u53ef\u63d0\u4f9b\u6240\u5728\u4f53\u7cfb\u4e2d\u6700\u4f4e\u7684\u8d1f\u6781\u5de5\u4f5c\u7535\u4f4d\u548c\u6700\u9ad8\u7684\u8d1f\u6781\u6bd4\u5bb9\u91cf\u3002\u7136\u800c\uff0c\u7531\u4e8e\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u7684\u7535\u8377\u5bc6\u5ea6\u8fdc\u5927\u4e8e\u78b1\u91d1\u5c5e\u79bb\u5b50\uff0c\u591a\u4ef7\u79bb\u5b50\u4e0e\u6eb6\u5242\u5206\u5b50\u4e4b\u95f4\u5f3a\u5927\u7684\u9759\u7535\u5438\u5f15\u529b\u6781\u5927\u5730\u963b\u788d\u4e86\u591a\u4ef7\u79bb\u5b50\u7684\u6c89\u79ef\u8fc7\u7a0b\uff0c\u4f7f\u5176\u96be\u4ee5\u5b9e\u73b0\u4f4e\u8fc7\u7535\u4f4d\u548c\u9ad8\u5e93\u4ed1\u6548\u7387\u7b49\u6027\u80fd\u3002<\/p>\n

\u4e8c\u3001\u6587\u7ae0\u7b80\u4ecb<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u9648\u7ef4\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u56fd\u9645\u671f\u520aJoule<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cA rechargeable, non-aqueous manganese metal battery enabled by electrolyte regulation\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8bba\u6587\u9996\u6b21\u63ed\u793a\u4e86\u5364\u7d20\u4ecb\u5bfc\u578b\u6eb6\u5242\u5316\u7ed3\u6784\u5bf9\u591a\u4ef7\u79bb\u5b50\u8131\u6eb6\u5242\u5316\u8fc7\u7a0b\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u5e76\u4ee5\u9530\u91d1\u5c5e\u7535\u6c60\u4f5c\u4e3a\u7814\u7a76\u5e73\u53f0\u5145\u5206\u5c55\u793a\u4e86\u5364\u7d20\uff08\u4ee5Cl\u5143\u7d20\u4f5c\u4e3a\u4e3b\u8981\u7814\u7a76\u5bf9\u8c61\uff09\u4ecb\u5bfc\u673a\u7406\u964d\u4f4e\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u6c89\u79ef\u8fc7\u7535\u4f4d\u3001\u63d0\u5347\u6c89\u79ef\u8fc7\u7a0b\u5e93\u4f26\u6548\u7387\u548c\u80fd\u91cf\u6548\u7387\u7684\u91cd\u8981\u4f5c\u7528\uff08\u56fe1\uff09\u3002\u901a\u8baf\u4f5c\u8005\u4e3a\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u5e94\u7528\u5316\u5b66\u7cfb\u6559\u6388\u3001\u5408\u80a5\u56fd\u5bb6\u5fae\u5c3a\u5ea6\u7269\u8d28\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3\u6559\u6388\u9648\u7ef4\uff0c<\/strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u5e94\u7528\u5316\u5b66\u7cfb\u7279\u4efb\u526f\u7814\u7a76\u5458\u4faf\u4e4b\u56fd<\/strong>\u3002\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u5e94\u7528\u5316\u5b66\u7cfb\u535a\u58eb\u751f\u6c88\u51ac\u9633<\/strong>\u4e3a\u672c\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1. <\/strong>\u6240\u53d1\u8868\u6587\u7ae0\u5c01\u9762\u56fe\u53ca\u9530\u91d1\u5c5e\u7535\u6c60\u7535\u89e3\u6db2\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/strong><\/p>\n

\u4e09\u3001\u7814\u7a76\u5185\u5bb9<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u9530\u91d1\u5c5e\u7535\u6c60\u7684\u4f18\u52bf\u4ee5\u53ca\u5364\u7d20\u4ecb\u5bfc\u673a\u7406\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/strong>\uff08A\uff09\u9530\u91d1\u5c5e\u8d1f\u6781\u548c\u5176\u5b83\u91d1\u5c5e\u8d1f\u6781\u7684\u5bf9\u6bd4\uff1b\uff08B-D\uff09\u9530\u79bb\u5b50\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff1b\uff08E\uff09\u9530\u79bb\u5b50\u5728\u4e0d\u540c\u4f53\u7cfb\u4e0b\u7684\u6c89\u79ef\u6eb6\u89e3\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u5bf9\u6bd4\u3002<\/p>\n

\u4f5c\u8005\u901a\u8fc7\u5c06\u7406\u8bba\u8ba1\u7b97\u4e0e\u5b9e\u9a8c\u76f8\u7ed3\u5408\u7684\u65b9\u5f0f\uff0c\u5145\u5206\u8bc1\u5b9e\u4e86\u5728\u6240\u8bbe\u8ba1\u7684\u7535\u89e3\u6db2\u4e2d\uff0cCl\u539f\u5b50\u5145\u5206\u53c2\u4e0e\u4e86Mn2+<\/sup>\u7684\u6eb6\u5242\u5316\u4f5c\u7528\uff0c\u5c06\u4f20\u7edf\u7684[Mn(Osol<\/sub>)6<\/sub>]2+<\/sup>\u6eb6\u5242\u5316\u7ed3\u6784\u8f6c\u53d8\u6210\u4e3a[Mn(Osol<\/sub>)3<\/sub>Cl3<\/sub>]2+<\/sup>\u3002\u7531\u4e8eCl\u539f\u5b50\u7684\u534a\u5f84\u66f4\u5927\u3001\u7535\u8377\u5bc6\u5ea6\u66f4\u5c0f\uff0c\u6eb6\u5242\u5316\u540e\u7684Mn-Cl\u952e\u6709\u7740\u6bd4Mn-O\u952e\u66f4\u5f31\u7684\u952e\u5408\u4f5c\u7528\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u5728\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u7684\u53bb\u6eb6\u5242\u5316\u80fd\uff08\u56fe2\uff09\uff0c\u51cf\u5c0f\u4e86\u9530\u91d1\u5c5e\u7684\u6c89\u79ef\u8fc7\u7535\u4f4d\u5e76\u663e\u8457\u63d0\u9ad8\u4e86\u6c89\u79ef\u6eb6\u89e3\u8fc7\u7a0b\u7684\u5e93\u4f26\u6548\u7387\uff0c\u4e3a\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u7684\u7535\u89e3\u6db2\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u53ef\u9760\u53c2\u8003\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3. <\/strong>\u9530\u91d1\u5c5e\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u6c89\u79ef\u884c\u4e3a\u5bf9\u6bd4\u3002<\/strong>\uff08A\uff09\u9530\u7247\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\uff08AE\uff09\u4e2d\u7684\u7167\u7247\uff1b\uff08B\uff09\u5728AE\u4e2d\u6d78\u6ce1\u524d\u540e\u9530\u7247\u7684XRD\u5bf9\u6bd4\uff0c\u63d2\u56fe\u4e3a\u6d78\u6ce1\u540e\u9530\u7247\u8868\u9762\u7684SEM\u7167\u7247\uff1b\uff08C\uff09\u9530\u7247\u5728\u65e0\u4ecb\u5bfc\u6709\u673a\u7cfb\u7535\u89e3\u6db2\uff08NM-NAE\uff09\u4e2d\u7684\u7167\u7247\uff1b\uff08D\uff09\u5728NM-NAE\u4e2d\u6d78\u6ce1\u524d\u540e\u9530\u7247\u7684XRD\u5bf9\u6bd4\uff0c\u63d2\u56fe\u4e3a\u6d78\u6ce1\u540e\u9530\u7247\u8868\u9762\u7684SEM\u7167\u7247\uff1b\uff08E\uff09\u9530\u7247\u5728\u5364\u7d20\u4ecb\u5bfc\u6709\u673a\u7cfb\u7535\u89e3\u6db2\uff08HM-NAE\uff09\u4e2d\u7684\u7167\u7247\uff1b\uff08F\uff09\u5728HM-NAE\u4e2d\u6d78\u6ce1\u524d\u540e\u9530\u7247\u7684XRD\u5bf9\u6bd4\uff0c\u63d2\u56fe\u4e3a\u6d78\u6ce1\u540e\u9530\u7247\u8868\u9762\u7684SEM\u7167\u7247\uff1b\uff08G\uff09\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\u5bf9\u79f0\u7535\u6c60\u5bf9\u6bd4\uff1b\uff08H-J\uff09\u4e0d\u540c\u4f53\u7cfb\u4e2d\u5728\u94dc\u7b94\u57fa\u5e95\u4e0a\u6c89\u79ef\u9530\u91d1\u5c5e\u540e\u7684SEM\u8868\u9762\u56fe\u548c\u622a\u9762\u56fe\u53ca\u5176mapping\u7ed3\u679c\u3002<\/p>\n

\u901a\u8fc7\u5bf9\u6bd4\u9530\u7247\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u53d1\u73b0\uff0c\u5728AE\u4e2d\uff0c\u9530\u7247\u5267\u70c8\u53cd\u5e94\uff0c\u8bc1\u660e\u9530\u91d1\u5c5e\u4e0eAE\u7684\u5316\u5b66\u4e0d\u517c\u5bb9\u6027\u3002\u800c\u5728NM-NAE\u548cHM-NAE\u4e2d\uff0c\u9530\u7247\u5e76\u4e0d\u4f1a\u53d1\u751f\u53cd\u5e94\u751f\u6210\u6742\u8d28\u3002\u5bf9\u6bd4\u5bf9\u79f0\u7535\u6c60\u6570\u636e\u53ef\u4ee5\u53d1\u73b0\uff0c\u5728AE\u4e2d\u7535\u6c60\u53ea\u80fd\u5faa\u73af\u51e0\u5708\uff0c\u968f\u540e\u505c\u6b62\u5de5\u4f5c\u3002\u800c\u5728NM-NAE\u4e2d\uff0c\u5bf9\u79f0\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af\uff0c\u4f46\u662f\u5145\u653e\u7535\u66f2\u7ebf\u8868\u660e\uff0c\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0c\u9530\u79bb\u5b50\u7684\u6c89\u79ef\u6eb6\u89e3\u6781\u5316\u5f88\u5927\uff0c\u4e0d\u80fd\u652f\u6491\u9530\u91d1\u5c5e\u7535\u6c60\u7684\u5de5\u4f5c\u3002\u5728HM-NAE\u4e2d\uff0c\u6781\u5316\u5927\u5927\u964d\u4f4e\u3002\u901a\u8fc7\u5bf9\u6c89\u79ef\u9530\u91d1\u5c5e\u540e\u7684\u94dc\u96c6\u6d41\u4f53\u7684SEM\u8868\u5f81\u53d1\u73b0\uff0c\u5728AE\u4e2d\u9530\u91d1\u5c5e\u51e0\u4e4e\u4e0d\u80fd\u6c89\u79ef\u3002\u5728NM-NAE\u4e2d\uff0c\u867d\u7136\u9530\u91d1\u5c5e\u80fd\u591f\u6c89\u79ef\uff0c\u4f46\u662f\u7531\u4e8e\u6c89\u79ef\u8fc7\u7535\u4f4d\u975e\u5e38\u5927\uff0c\u5bfc\u81f4\u6c89\u79ef\u51fa\u7684\u9530\u91d1\u5c5e\u5c55\u73b0\u51fa\u591a\u5b54\u7684\u72b6\u6001\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5728HM-NAE\u4e2d\u6c89\u79ef\u51fa\u7684\u9530\u91d1\u5c5e\u81f4\u5bc6\u4e14\u6ca1\u6709\u679d\u6676\u3002\u5145\u5206\u8868\u660e\u4e86\u5364\u7d20\u4ecb\u5bfc\u5728\u964d\u4f4e\u91d1\u5c5e\u9530\u6c89\u79ef\u6eb6\u89e3\u8fc7\u7535\u4f4d\u548c\u6539\u5584\u6c89\u79ef\u5f62\u8c8c\u65b9\u9762\u7684\u4f5c\u7528\uff08\u56fe3\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4. HM-NAE<\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/strong>\uff08A\uff09\u4e0d\u540c\u4f53\u7cfb\u95f4\u5bf9\u79f0\u7535\u6c60\u7684\u6027\u80fd\u5bf9\u6bd4\uff1b\uff08B\uff09HM-NAE\u5728\u5bf9\u79f0\u7535\u6c60\u4e2d\u7684\u500d\u7387\u5faa\u73af\u6027\u80fd\uff1b\uff08C\uff09\u5bf9\u79f0\u7535\u6c60\u500d\u7387\u6027\u80fd\u76f8\u5173\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b\uff08D\uff09HM-NAE\u5728\u4e0d\u540c\u96c6\u6d41\u4f53\u4e0a\u6c89\u79ef\u6eb6\u89e3\u5faa\u73af\u7684\u975e\u5bf9\u79f0\u7535\u6c60\u7684\u6027\u80fd\uff1b\uff08E\uff09\u4e0d\u540c\u96c6\u6d41\u4f53\u7684\u975e\u5bf9\u79f0\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b\uff08F\uff09\u4e0d\u540c\u6c89\u79ef\u9762\u5bb9\u91cf\u7684\u975e\u5bf9\u79f0\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

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\"\"<\/p>\n

\u56fe<\/strong>5. <\/strong>\u5364\u7d20\u4ecb\u5bfc\u673a\u7406\u7684\u63a2\u7a76\u3002<\/strong>\uff08A-B\uff09HM-NAE\u548cNM-NAE\u7684\u5206\u5b50\u52a8\u529b\u5b66\u5feb\u7167\uff1b\uff08C-D\uff09Mn2+<\/sup>\u79bb\u5b50\u5728HM-NAE\u548cNM-NAE\u4e2d\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u53ca\u914d\u4f4d\u73af\u5883\uff1b\uff08E-F\uff09Mn2+<\/sup>\u79bb\u5b50\u5728HM-NAE\u548cNM-NAE\u4e2d\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff1b\uff08G\uff09Mn2+<\/sup>\u79bb\u5b50\u5728HM-NAE\u548cNM-NAE\u4e2d\u7684\u53bb\u6eb6\u5242\u5316\u80fd\uff1b\uff08H\uff09\u9634\u79bb\u5b50\u6a21\u5f0f\u4e0bHM-NAE\u7684\u9ad8\u5206\u8fa8\u8d28\u8c31\u56fe\uff1b\uff08I\uff09\u5355\u6676\u884d\u5c04\u6d4b\u8bd5\u7ed3\u679c\uff1b\uff08J\uff09\u9884\u6d4b\u51fa\u7684HM-NAE\u7684\u53cd\u5e94\u8def\u5f84\u3002<\/p>\n

\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u3001\u9ad8\u6e05\u8d28\u8c31\u548c\u5355\u6676X-\u5c04\u7ebf\u884d\u5c04\u7684\u7406\u8bba\u7ed3\u5408\u5b9e\u9a8c\u7684\u7814\u7a76\u65b9\u6cd5\u53d1\u73b0\uff0cMn2+<\/sup>\u79bb\u5b50\u5728NM-NAE\u548cHM-NAE\u4e2d\u5b8c\u5168\u4e0d\u540c\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u51b3\u5b9a\u4e86\u5176\u5b8c\u5168\u4e0d\u540c\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5728NM-NAE\u4e2d\u9530\u79bb\u5b50\u4e0e\u6eb6\u5242\u4e2d\u76846\u4e2a\u6c27\u539f\u5b50\u914d\u4f4d\uff0c\u975e\u5e38\u5f3a\u7684Mn-O\u952e\u5408\u4f5c\u7528\u963b\u788d\u4e86\u5728\u8131\u6eb6\u5242\u5316\u8fc7\u7a0b\u4e2dMn-O\u952e\u7684\u65ad\u88c2\uff0c\u5bfc\u81f4\u6c89\u79ef\u8fc7\u7535\u4f4d\u975e\u5e38\u5927\u3002\u800c\u5728HM-NAE\u4e2d\uff0c\u9530\u79bb\u5b50\u4e0e\u8d77\u6865\u63a5\u4f5c\u7528\u7684\u4e09\u4e2a\u6c2f\u539f\u5b50\u952e\u5408\u3002\u7531\u4e8e\u6c2f\u539f\u5b50\u7684\u534a\u5f84\u5927\uff0c\u7535\u8377\u5bc6\u5ea6\u5c0f\uff0c\u4e0eMn2+<\/sup>\u79bb\u5b50\u7684\u952e\u5408\u4f5c\u7528\u5f31\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u7684\u8131\u6eb6\u5242\u5316\u80fd\uff0c\u4ece\u800c\u964d\u4f4e\u4e86\u6c89\u79ef\u8fc7\u7535\u4f4d\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u63d0\u51fa\u4e86\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u7535\u89e3\u6db2\u53ef\u80fd\u7684\u8fc7\u7a0b\u673a\u7406\uff08\u56fe5\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6. <\/strong>\u9530\u91d1\u5c5e\u5168\u7535\u6c60\u7684\u8bbe\u8ba1\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002<\/strong>\uff08A\uff09\u9530\u91d1\u5c5e\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u56fe\uff1b\uff08B\uff09Mo6<\/sub>S8<\/sub>\u6b63\u6781\u6750\u6599\u7684XRD\u56fe\u8c31\uff0c\u63d2\u56fe\u4e3aMo6<\/sub>S8<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\u548cSEM\u7167\u7247\uff1b\uff08C\uff09Mo6<\/sub>S8<\/sub>\uff08+\uff09||HM-NAE||Mn\uff08\uff0d\uff09\u5168\u7535\u6c60\u7684\u957f\u5faa\u73af\u66f2\u7ebf\u53ca\u5176\u4e0e\u6709\u673a\u7cfb\u950c\u91d1\u5c5e\u7535\u6c60\u7684\u5bf9\u6bd4\uff1b\uff08D\uff09\u4e0d\u540c\u5145\u653e\u7535\u5708\u6570\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b\uff08E\uff09Mo6<\/sub>S8<\/sub>\uff08+\uff09||HM-NAE||Mn\uff08\uff0d\uff09\u5168\u7535\u6c60\u7684\u500d\u7387\u5faa\u73af\u6027\u80fd\uff1b\uff08F\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5168\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

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\"\"<\/p>\n

\u56fe<\/strong>7. Mo6<\/sub>S8<\/sub><\/strong>\u7684\u50a8\u9530\u673a\u7406\u3002<\/strong>\uff08A\uff09\u975e\u539f\u4f4d\u6d4b\u8bd5\u6837\u54c1\u7684\u53d6\u70b9\u793a\u610f\u56fe\uff1b\uff08B\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u6781\u7247\u7684XRD\u56fe\u8c31\uff1b\uff08C-D\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bMn\u548cMo\u7684XPS\u56fe\u8c31\uff1b\uff08E\uff09Mo6<\/sub>S8<\/sub>\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

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\u56db\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/strong><\/p>\n

\u5728\u6b64\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u9996\u6b21\u63d0\u51fa\u4e86\u5364\u7d20\u4ecb\u5bfc\u6eb6\u5242\u5316\u7ed3\u6784\u7684\u6982\u5ff5\uff0c\u5e76\u4ee5\u9530\u91d1\u5c5e\u7535\u6c60\u4f5c\u4e3a\u5e73\u53f0\uff0c\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u4e0e\u5b9e\u9a8c\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\uff0c\u5145\u5206\u8bc1\u660e\u4e86\u5364\u7d20\u4ecb\u5bfc\u5728\u964d\u4f4e\u591a\u4ef7\u79bb\u5b50\u91d1\u5c5e\u6c89\u79ef\u8fc7\u7535\u4f4d\u3001\u63d0\u5347\u6c89\u79ef\u6eb6\u89e3\u6548\u7387\u65b9\u9762\u7684\u4f5c\u7528\u3002\u6240\u5f00\u53d1\u51fa\u7684HM-NAE\u5177\u6709\u4e0e\u9530\u91d1\u5c5e\u5b8c\u5168\u517c\u5bb9\u3001\u7a33\u5b9a\u6027\u9ad8\u3001\u7535\u5316\u5b66\u7a97\u53e3\u5bbd\u7b49\u4f18\u52bf\uff0c\u80fd\u591f\u652f\u6301\u5bf9\u79f0\u7535\u6c60\u3001\u975e\u5bf9\u79f0\u7535\u6c60\u4ee5\u53ca\u9530\u91d1\u5c5e\u5168\u7535\u6c60\u7684\u7a33\u5b9a\u5de5\u4f5c\u3002<\/p>\n

Authors:<\/strong> Dongyang Shen, Xinhua Zheng, Ruihao Luo, Taoli Jiang, Mingming Wang, Mingying Zhang, Qia Peng, Li Song, Shiming Zhou, Zhiguo Hou*, Yitai Qian, and Wei Chen*<\/p>\n

Title: <\/strong>A rechargeable, non-aqueous manganese metal battery enabled by electrolyte regulation<\/p>\n

Published on: <\/strong>Joule<\/em>, https:\/\/doi.org\/10.1016\/j.joule.2024.01.012<\/u><\/p>\n

\u4f5c\u8005\u7b80\u4ecb<\/strong>:<\/strong><\/p>\n

\u901a\u8baf\u4f5c\u8005<\/strong><\/p>\n

\u9648\u7ef4\uff0c<\/strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5e94\u7528\u5316\u5b66\u7cfb\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5408\u80a5\u5fae\u5c3a\u5ea6\u7269\u8d28\u79d1\u5b66\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u6559\u6388\u30022008\u5e74\u4e8e\u5317\u4eac\u79d1\u6280\u5927\u5b66\u83b7\u6750\u6599\u7269\u7406\u5b66\u58eb\u5b66\u4f4d\uff1b2013\u5e74\u4e8e\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u83b7\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u535a\u58eb\u5b66\u4f4d\uff1b2014-2018\u5e74\u4e8e\u65af\u5766\u798f\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff1b2018-2019\u5e74\u5728EEnotech\u516c\u53f8\u62c5\u4efb\u79d1\u5b66\u5bb6\uff1b2019\u5e747\u6708\u5165\u804c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\uff0c\u4e13\u6ce8\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u7535\u6c60\u3001\u7535\u50ac\u5316\u7b49\u7814\u7a76\u3002\u72ec\u7acb\u5efa\u7ec4\u4ee5\u6765\uff0c\u4f5c\u4e3a(\u5171\u540c)\u901a\u8baf\u4f5c\u8005\u5728Chemical Reviews, Nature Communications (2), Joule (2), Journal of the American Chemical Society (3), Angewandte Chemie International Edition (4), Advanced Materials (4), Energy & Environmental Science,\u00a0Advanced Energy Materials (4), Advanced Functional Materials, Nano Letters (10), ACS Nano (2), ACS Catalysis, eScience (2), Energy Storage Materials (6)<\/em> \u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u658760\u4f59\u7bc7\uff0c\u8bba\u6587\u603b\u88ab\u5f1512 000\u4f59\u6b21\uff0cH\u56e0\u5b5053\u3002\u7814\u7a76\u6210\u679c\u83b7\u5f97\u7f8e\u56fd\u4e13\u52295\u9879\uff0c\u4e2d\u56fd\u53d1\u660e\u4e13\u522920\u4f59\u9879\u3002\u62c5\u4efbeScience, Nano Research Energy, Energy Materials Advances<\/em>\u7b49\u591a\u4e2a\u6742\u5fd7\u9752\u5e74\u7f16\u59d4\u3002<\/p>\n

\u9648\u7ef4\u8bfe\u9898\u7ec4\u7f51\u9875\uff1ahttp:\/\/staff.ustc.edu.cn\/~weichen1<\/a><\/p>\n

\u7b2c\u4e00\u4f5c\u8005<\/strong><\/p>\n

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