{"id":258685,"date":"2024-03-21T06:42:00","date_gmt":"2024-03-20T22:42:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=258685"},"modified":"2024-03-21T21:00:33","modified_gmt":"2024-03-21T13:00:33","slug":"%e5%bd%ad%e4%ba%89%e6%98%a5%e3%80%81%e5%bc%a0%e7%bf%8a%e5%9b%a2%e9%98%9f%e3%80%8aafm%e3%80%8b%ef%bc%9a%e5%9f%ba%e4%ba%8emxene-pda%e5%bf%ab%e9%80%9f%e7%94%b5%e6%b2%89%e7%a7%af%e5%b7%a5%e8%89%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=258685","title":{"rendered":"\u5f6d\u4e89\u6625\u3001\u5f20\u7fca\u56e2\u961fAFM\uff1a\u57fa\u4e8eMXene\/PDA\u5feb\u901f\u7535\u6c89\u79ef\u5de5\u827a\u7684\u9ad8\u6027\u80fd\u751f\u7269\u7535\u6781"},"content":{"rendered":"

\u8111\u673a\u63a5\u53e3\u7814\u7a76\u8feb\u5207\u9700\u8981\u5f00\u53d1\u9ad8\u6027\u80fd\u3001\u591a\u529f\u80fd\u7684\u751f\u7269\u7535\u6781\uff0c\u7528\u4e8e\u5065\u5eb7\u76d1\u6d4b\u3001\u4e34\u5e8a\u8bca\u65ad\u548c\u7cbe\u51c6\u6cbb\u7597\u7b49\u3002\u7406\u60f3\u7684\u751f\u7269\u7535\u5b50\u754c\u9762\u901a\u5e38\u8981\u6c42\u751f\u7269\u7535\u6781\u5177\u6709\u4f4e\u754c\u9762\u963b\u6297\u3001\u9ad8<\/strong>\u7535\u8377\u6ce8\u5165\u80fd\u529b<\/strong>\u3001\u957f\u671f\u7a33\u5b9a\u6027\u548c\u751f\u7269\u5b89\u5168\u6027\u3002<\/strong>\u5f15\u5165\u751f\u7269\u53cb\u597d\u578b\u7eb3\u7c73\u6750\u6599\u4ee5\u589e\u52a0\u6709\u6548\u8868\u9762\u79ef\u548c\u76f8\u5e94\u7684\u7535\u5316\u5b66\u6027\u80fd\u662f\u8fd1\u5e74\u6765\u5e38\u7528\u7684\u751f\u7269\u7535\u6781\u8868\u9762\u5904\u7406\u7b56\u7565\u4e4b\u4e00\uff0c\u4f46\u8be5\u9886\u57df\u7684\u7814\u7a76\u6d3b\u52a8\u4e3b\u8981\u805a\u7126\u5728\u8d35\u91d1\u5c5e\u6750\u6599\u548c\u6602\u8d35\u7684\u5236\u9020\u5de5\u827a\uff0c\u4e25\u91cd\u9650\u5236\u4e86\u751f\u7269\u7535\u6781\u7684\u89c4\u6a21\u5316\u751f\u4ea7\u548c\u666e\u53ca\u5e94\u7528\u3002<\/strong><\/p>\n

MXene\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u578b\u4e8c\u7ef4\u6750\u6599\uff0c\u81ea2011\u5e74\u88ab\u53d1\u73b0\u4ee5\u6765\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\uff0c\u5e76\u9010\u6b65\u7528\u4e8e\u751f\u7269\u533b\u5b66\u9886\u57df\u3002\u7136\u800c\uff0cMXene\u4e0e\u57fa\u5e95\u7684\u7c98\u9644\u5f3a\u5ea6\u666e\u904d\u8f83\u4f4e\uff0c\u56e0\u6b64\uff0c\u5728\u5927\u591a\u6570\u6587\u732e\u62a5\u9053\u4e2d\uff0c\u901a\u5e38\u5c06\u5176\u4f5c\u4e3a\u63ba\u6742\u6210\u5206\u4e4b\u4e00\uff0c\u6216\u4f5c\u4e3a\u5bfc\u7535\u6cb9\u58a8\uff0c\u7136\u540e\u901a\u8fc7\u6ef4\u6d82\u3001\u65cb\u6d82\u3001\u5370\u5237\u7b49\u65b9\u5f0f\u52a0\u5de5\u6210\u6240\u9700\u7684\u7535\u6781\u3002\u8fd1\u5e74\u6765\uff0c\u591a\u4e2a\u7814\u7a76\u5c0f\u7ec4\u62a5\u9053\u4e86\u5728\u78b3\u6750\u6599\u57fa\u5e95\u4e0a\u539f\u4f4d\u6c89\u79ef\u5236\u5907MXene\u8584\u819c\u7535\u6781\uff0c\u4f46\u4e3b\u8981\u9488\u5bf9\u7535\u50ac\u5316\u7b49\u5de5\u4e1a\u5e94\u7528\uff0c\u800c\u91c7\u53d6\u5feb\u6377\u3001\u6e29\u548c\u7684\u5de5\u827a\u5236\u5907\u7a33\u5b9a\u6027\u826f\u597d\u7684<\/strong>MXene<\/strong>\u57fa\u751f\u7269\u7535\u6781\u9c9c\u6709\u62a5\u9053\u3002<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6df1\u5733\u5927\u5b66\u5f6d\u4e89\u6625<\/strong>\u6559\u6388\u56e2\u961f\u4e0e\u4e2d\u56fd\u79d1\u5b66\u9662\u6df1\u5733\u5148\u8fdb\u6280\u672f\u7814\u7a76\u9662\u5f20\u7fca<\/strong>\u9ad8\u5de5\u56e2\u961f\u8054\u5408\u62a5\u9053\u4e86\u4e00\u79cd\u5feb\u901f\u7535\u5316\u5b66\u6c89\u79ef<\/strong>MXene<\/strong>\u4e0e\u805a\u591a\u5df4\u80fa<\/strong>(PDA)<\/strong>\u590d\u5408\u6750\u6599\u7684\u65b9\u6cd5\uff0c\u4e3a\u9ad8\u6027\u80fd\u751f\u7269\u7535\u5b50\u754c\u9762\u63d0\u4f9b\u4e86\u65b0\u601d\u8def<\/strong>\uff0c\u8be5\u5de5\u4f5c\u7ed3\u5408\u4e86PDA\u7684\u9ad8\u7c98\u9644\u6027\u3001\u4eb2\u6c34\u6027\u548cMXene\u7684\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u5b98\u80fd\u56e2\u3001\u7c7b\u91d1\u5c5e\u5bfc\u7535\u6027\u7684\u4f18\u70b9\u3002<\/strong>\u56e2\u961f\u91c7\u7528\u5faa\u73af\u4f0f\u5b89\u6cd5\u9996\u5148\u5728\u91d1\u5c5e\u886c\u5e95\u4e0a\u6c89\u79efPDA\u7c98\u9644\u5c42\uff0c\u7136\u540e\u91c7\u7528\u7535\u6cf3\u6c89\u79ef\u5de5\u827a\u5728PDA\u5c42\u4e0a\u5236\u5907MXene\u529f\u80fd\u5c42\u3002\u5176\u4e2dPDA\u7c98\u9644\u5c42\u589e\u5f3a\u4e86MXene\u4e0e\u91d1\u5c5e\u886c\u5e95\u4e4b\u95f4\u7684\u9644\u7740\u529b\uff0c\u5e76\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u7535\u6781\u8868\u9762\u7684\u4eb2\u6c34\u6027\uff0c\u5229\u4e8e\u529f\u80fd\u5316\u4fee\u9970\u3002\u6240\u5f97\u5230\u7684MXene\u57fa\u751f\u7269\u7535\u6781\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u3001\u5149\u70ed\u3001\u5149\u7535\u6027\u80fd\uff0c\u4ee5\u53ca\u8f83\u5f3a\u7684\u7a33\u5b9a\u6027\u548c\u751f\u7269\u76f8\u5bb9\u6027\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cFast Electrodeposition of MXene\/PDA Composites for High-Performance Bioelectronic Interfaces: An In Vitro Evaluation<\/em>\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u4e8eWiley\u6750\u6599\u9886\u57df\u9876\u7ea7\u671f\u520a\u300aAdvanced Functional Materials<\/em><\/a>\u300b\u4e0a<\/strong>\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u591a\u5df4\u80fa\u662f\u4e00\u79cd\u4eff\u751f\u5206\u5b50\uff0c\u5728\u5b9e\u9645\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u5f3a\u6c22\u952e\u548c\u03c0-\u03c0\u5806\u53e0\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u805a\u5408\u5728\u4e0d\u540c\u7684\u8868\u9762\u5f62\u6210\u805a\u591a\u5df4\u80fa\uff08PDA\uff09\u6d82\u5c42\uff0c\u4ece\u800c\u83b7\u5f97\u66f4\u597d\u7684\u5177\u6709\u5f3a\u7c98\u9644\u529b\u7684\u751f\u7269\u7535\u5b50\u754c\u9762\u3002\u56e0\u800c\uff0c\u5728\u886c\u5e95\u4e0a\u5f15\u5165\u4e00\u5c42PDA\u7c98\u9644\u5c42\u662f\u5236\u5907\u51fa\u9ad8\u6027\u80fdMXene\u57fa\u751f\u7269\u7535\u6781\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe1 MXene\/PDA\u590d\u5408\u7535\u6781\u7684\u7535\u6c89\u79ef\u5236\u5907\u8fc7\u7a0b\u548c\u673a\u7406\u3002(a)-(c) MXene\/PDA\u590d\u5408\u7535\u6781\u5feb\u901f\u7535\u6c89\u79ef\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\u5305\u62ec\u57280.5 M H2<\/sub>SO4<\/sub>\u4e2d\u8fdb\u884c\u7535\u5316\u5b66\u5904\u7406\uff0c\u5728PBS\u4e2d\u7535\u5316\u5b66\u805a\u5408PDA\u7c98\u9644\u5c42\uff0c\u4ee5\u53ca\u7535\u6cf3\u6c89\u79efMXene\u529f\u80fd\u5c42\u3002\u76f8\u5e94\u7684MXene\u7535\u6cf3\u8fc1\u79fb\u793a\u610f\u56fe\u5982\u56fec(ii)\u6240\u793a\uff1b(d) PDA\u7535\u5316\u5b66\u805a\u5408\u7684\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u4f18\u70b9\u4e00<\/strong>\uff1aMXene\u529f\u80fd\u5c42\u4e0ePDA\u7c98\u9644\u5c42\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5305\u62ec\u590d\u5408\u6750\u6599\u7684\u591a\u5b54\u6027\u53caMXene\u672c\u8eab\u7684\u9ad8\u7535\u5bfc\u7387\u548c\u8d5d\u7535\u5bb9\u6027\u80fd\uff0c\u53ef\u663e\u8457\u964d\u4f4e\u795e\u7ecf\u7535\u6781\u754c\u9762\u963b\u6297\uff08\u5728\u4f4e\u9891\u533a\u4f18\u52bf\u663e\u8457\uff0c\u53ef\u964d\u4f4e~98%\uff09\uff0c\u5e76\u6709\u6548\u63d0\u5347\u7535\u6781\u7684\u7535\u8377\u5b58\u50a8\u80fd\u529b\uff08\u7ea6\u4e3a\u91d1\u5c5e\u7535\u6781\u7684140\u500d\uff09\u548c\u7535\u8377\u6ce8\u5165\u80fd\u529b\u3002\u56e0\u6b64\uff0c\u8be5\u751f\u7269\u7535\u6781\u4e3a\u5b9e\u73b0\u76f8\u540c\u7684\u523a\u6fc0\/\u8bb0\u5f55\u6548\u679c\u6240\u9700\u8981\u80fd\u8017\u66f4\u4f4e\u3002\u6b64\u5916\uff0c\u8be5\u751f\u7269\u7535\u6781\u5728\u7ecf\u8fc7<\/strong>1<\/strong>\u4ebf\u591a\u6b21\u7535\u8109\u51b2\u523a\u6fc0\u548c<\/strong>1000<\/strong>\u6b21<\/strong>CV<\/strong>\u5468\u671f\u7684\u8fde\u7eed\u7535\u523a\u6fc0\u540e\uff0c\u4ecd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/strong><\/p>\n

\"\"<\/a><\/p>\n

\u56fe2 (a)\u4e0d\u540c\u7535\u6781\uff08\u88f8Pt\u3001PDA\u3001MXene\u3001MXene\/PDA\uff09\u7684\u65b9\u963b\u5bf9\u6bd4\uff1b(b)-(c)\u4e0d\u540c\u4fee\u9970\u7535\u6781\u5728PBS\u6eb6\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u963b\u6297\u6027\u80fd\uff1b(d)-(e)\u4e0d\u540c\u4fee\u9970\u7535\u6781\u5728PBS\u6eb6\u6db2\u4e2d\u7684\u7535\u8377\u5b58\u50a8\u80fd\u529b\u548c\u6ce8\u5165\u80fd\u529b\u5bf9\u6bd4\uff1b(f)-(i) MXene\/PDA\u590d\u5408\u7535\u6781\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u3001\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u53ca\u6837\u54c1\u5b58\u653e\u7a33\u5b9a\u6027\u3002<\/p>\n

\u4f18\u70b9\u4e8c\uff1a<\/strong>\u9274\u4e8eMXenes\u5728\u8fd1\u7ea2\u5916\uff08NIR\uff09\u7167\u5c04\u4e0b\u5177\u6709\u4f18\u5f02\u7684\u5149\u70ed\u6027\u80fd\uff0c\u8be5\u56e2\u961f\u5f00\u53d1\u7684\u751f\u7269\u7535\u6781<\/strong>\u5177\u6709\u9ad8\u6548\u4e14\u5feb\u901f\u7684\u5149\u70ed\u54cd\u5e94<\/strong>\uff0c\u4e14\u5149\u70ed\u53cd\u5e94\u524d\u540e\u7684\u7535\u6781\u8868\u9762\u6ca1\u6709\u660e\u663e\u53d8\u5316\uff0c\u5c55\u73b0\u51faMXene\/PDA\u590d\u5408\u6750\u6599\u4e0e\u57fa\u5e95\u4e4b\u95f4\u7684\u9ad8\u9644\u7740\u529b\u548c\u5149\u70ed\u7a33\u5b9a\u6027\u3002\u8fd9\u4e3a\u5176\u5728\u795e\u7ecf\u5143\u7535\u6d3b\u52a8\u7684\u5149\u70ed\u523a\u6fc0\u53ca\u764c\u75c7\u7684\u5149\u70ed\u6cbb\u7597\u7b49\u9886\u57df\u7684\u5e94\u7528\u6253\u4e0b\u4e86\u575a\u5b9e\u7684\u57fa\u7840\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe3 (a)\u7528\u4e8e\u7814\u7a76\u7535\u6781\u5149\u70ed\u884c\u4e3a\u7684\u5b9e\u9a8c\u88c5\u7f6e\u793a\u610f\u56fe\uff1b(b)\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a2 W cm\u22122<\/sup>\u7684808 nm\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\u4e0b\uff0c\u88f8Pt\u3001PDA\u3001MXene\u3001MXene\/PDA\u590d\u5408\u7535\u6781\u7684\u5149\u70ed\u54cd\u5e94\u66f2\u7ebf\uff1b(c)\u4e3a(b)\u7684\u524d10s\u6e29\u5347\u7ebf\u6027\u66f2\u7ebf\u5bf9\u6bd4\u653e\u5927\u56fe\uff1b(d)\u8fd1\u7ea2\u5916\u6fc0\u5149\u529f\u7387\u5bc6\u5ea60.25~1.5 W cm\u22122<\/sup>\u4e0bMXene\/PDA\u590d\u5408\u7535\u6781\u7684\u6e29\u5ea6\u5206\u5e03\uff0c\u63d2\u56fe\u663e\u793a\u4e86\u76f8\u5e94\u7684\u5149\u70ed\u56fe\u50cf\uff1b(e)\u6fc0\u5149\u7167\u5c04300 s\u65f6MXene\/PDA\u590d\u5408\u7535\u6781\u7684\u5347\u6e29\u548c\u964d\u6e29\u60c5\u51b5\uff1b(f) MXene\/PDA\u590d\u5408\u7535\u67816\u6b21\u6fc0\u5149ON\/OFF\u5468\u671f\u7684\u6e29\u5ea6-\u65f6\u95f4\u66f2\u7ebf\uff1b(g)MXene\/PDA\u590d\u5408\u7535\u6781\u5728\u4e0d\u540c\u65f6\u95f4\u95f4\u9694\u8fd1\u7ea2\u5916\u7167\u5c04\u4e0b\u7684\u7ea2\u5916\u70ed\u50cf\u56fe\u3002<\/p>\n

\u4f18\u70b9\u4e09\uff1a<\/strong>\u5f97\u76ca\u4e8e\u5149\u7535\u5b50\u5728MXene\/PDA\u590d\u5408\u6750\u6599\u4e2d\u7684\u9ad8\u6548\u8f6c\u79fb\uff0c\u8be5\u751f\u7269\u7535\u6781\u8fd8\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u5176\u5149\u7535\u6d41\u54cd\u5e94\u5ea6\u6bd4\u91d1\u5c5e\u7535\u6781\u9ad8\u51fa\u8fd1<\/strong>40<\/strong>\u500d\uff0c\u4e14\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u7535\u5316\u5b66\u68c0\u6d4b\u6027\u80fd<\/strong>\u3002\u8fd9\u5bf9\u672a\u6765\u8bb0\u5f55\u795e\u7ecf\u4fe1\u53f7\u3001\u7ec6\u80de\u6d3b\u52a8\u7b49\u751f\u7269\u7535\u5b50\u5b66\u5e94\u7528\u5177\u6709\u91cd\u8981\u4ef7\u503c\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe4 (a)\u5149\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u91cf\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b(b)\u4e0d\u540cEPD\u65f6\u95f4\u4e0bMXene\/PDA\u590d\u5408\u7535\u6781\u5728PBS\u4e2d\u7684\u5149\u7535\u6d41\u54cd\u5e94\uff1b(c)\u88f8Pt\u3001PDA\u548cMXene\/PDA\u590d\u5408\u7535\u6781\u7684\u5149\u7535\u6d41\u54cd\u5e94\uff1b(d)-(e)6\u6b21\u6fc0\u5149ON\/OFF\u5468\u671f\u4e0b\uff0cMXene\/PDA\u590d\u5408\u7535\u6781\u5728\u4e0d\u540c\u65f6\u95f4\u95f4\u9694(Dt: 10~50 s)\u7684\u5149\u7535\u6d41\u54cd\u5e94\u66f2\u7ebf\u3002<\/p>\n

\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

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