{"id":258910,"date":"2024-03-28T06:03:24","date_gmt":"2024-03-27T22:03:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=258910"},"modified":"2024-03-27T19:08:41","modified_gmt":"2024-03-27T11:08:41","slug":"%e5%8d%97%e5%b7%a5%e9%99%88%e8%8b%8f%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fam%ef%bc%9a%e5%9f%ba%e4%ba%8e%e9%ab%98%e5%9b%ba%e5%90%ab%e9%87%8f%e8%83%b6%e4%bd%93%e5%85%89%e5%ad%90%e6%99%b6%e4%bd%93%e5%be%ae","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=258910","title":{"rendered":"\u5357\u5de5\u9648\u82cf\u6559\u6388\u56e2\u961fAM\uff1a\u57fa\u4e8e\u9ad8\u56fa\u542b\u91cf\u80f6\u4f53\u5149\u5b50\u6676\u4f53\u5fae\u7403\u7684\u8d85\u6750\u6599"},"content":{"rendered":"<p>\u8d85\u6750\u6599(Metamaterial)\u662f\u4e00\u7c7b\u5177\u6709\u7279\u6b8a\u6027\u8d28\u7684\u4eba\u9020\u6750\u6599\uff0c\u8fd9\u4e9b\u6750\u6599\u662f\u81ea\u7136\u754c\u6ca1\u6709\u7684\u3002\u5b83\u4eec\u62e5\u6709\u4e00\u4e9b\u7279\u522b\u7684\u6027\u8d28\uff0c\u6bd4\u5982\u8ba9\u5149\u6539\u53d8\u5b83\u4eec\u7684\u901a\u5e38\u6027\u8d28\uff0c\u800c\u8fd9\u6837\u7684\u6548\u679c\u662f\u4f20\u7edf\u6750\u6599\u65e0\u6cd5\u5b9e\u73b0\u7684\u3002\u76ee\u524d\uff0c\u8d85\u6750\u6599\u901a\u5e38\u662f\u901a\u8fc7\u5bf9\u8ba1\u7b97\u673a\u6a21\u62df\u7ed3\u6784\u8fdb\u884c\u7269\u7406\u5149\u523b\u6765\u5b8c\u6210\uff0c\u5f88\u96be\u91c7\u7528\u5316\u5b66\u5408\u6210\u7684\u65b9\u6cd5\u5b9e\u73b0\u3002\u80f6\u4f53\u5149\u5b50\u6676\u4f53(Colloidal photonic crystals, CPC)\u662f\u4e00\u7c7b\u7531\u5355\u5206\u6563\u5fae\u7403\u81ea\u7ec4\u88c5\u800c\u6210\u7684\u65b0\u578b\u5149\u5b66\u5fae\u7ed3\u6784\u6750\u6599\uff0c\u5176\u5177\u6709\u72ec\u7279\u7684\u5149\u5b66\u7279\u6027\uff08\u5149\u6269\u6563\u3001\u5149\u5b66\u589e\u5f3a\u548c\u5e03\u62c9\u683c\u884d\u5c04\u6548\u5e94\uff09\uff0c\u5c24\u5176\u662f\u5176\u7279\u5b9a\u6ce2\u957f\u7684\u5149\u5b50\u5e26\u9699\u53ef\u9009\u62e9\u6027\u7684\u64cd\u7eb5\u5149\u5b50\u7684\u4f20\u64ad\uff0c\u4fc3\u8fdb\u5149\u5b50\u53d1\u5c04\u589e\u5f3a\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u5316\u5b66\u5408\u6210\u7684\u80f6\u4f53\u5149\u5b50\u6676\u4f53\u5fae\u7403\u7684\u8d85\u6750\u6599\u5236\u5907\u88ab\u5bc4\u4e88\u671f\u671b\u3002<\/p>\n<p>\u5c3d\u7ba1\u80f6\u4f53\u5149\u5b50\u6676\u4f53\u81ea1957\u5e74\u53d1\u660e\u4ee5\u6765\uff0c\u5176\u56fa\u542b\u91cf\uff08\u901a\u5e38\u57285-10%\uff09\u4e0e\u7ec4\u88c5\u6548\u7387\u4f4e\u5236\u7ea6\u5176\u5927\u89c4\u6a21\u5de5\u4e1a\u5316\u5e94\u7528\u3002\u5e38\u89c4\u4e73\u6db2\u805a\u5408\u901a\u5e38\u4f7f\u7528\u5355\u4e00\u8868\u9762\u6d3b\u6027\u5242\uff0c\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u9ad8\u56fa\u542b\u91cf\u4e0e\u5355\u5206\u6563\u6027\u4e8c\u8005\u96be\u4ee5\u540c\u65f6\u6ee1\u8db3\u3002\u4e00\u65b9\u9762\uff0c\u5728\u5408\u6210\u9ad8\u56fa\u542b\u91cf\u4e73\u6db2\u65f6\uff0c\u5355\u4e00\u79bb\u5b50\u8868\u9762\u6d3b\u6027\u5242\u63d0\u4f9b\u7684\u5fae\u7403\u4e4b\u95f4\u7684\u6392\u65a5\u529b\u4e0d\u8db3\uff0c\u5e38\u51fa\u73b0\u56e2\u805a\u73b0\u8c61\uff0c\u65e0\u6cd5\u83b7\u5f97\u5355\u5206\u6563\u7684\u7c92\u5f84\u5206\u5e03\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7531\u4e8e\u4e73\u6db2\u7684\u7c98\u5ea6\u968f\u7740\u56fa\u4f53\u542b\u91cf\u7684\u589e\u52a0\u800c\u589e\u52a0\uff0c\u8f83\u9ad8\u7684\u7c98\u5ea6\u4f1a\u5f71\u54cd\u4e73\u80f6\u7684\u5355\u5206\u6563\u6027\u3002<\/p>\n<p>\u9488\u5bf9\u4e0a\u8ff0\u96be\u9898\u95ee\u9898\uff0c<strong>\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5316\u5de5\u5b66\u9662\u3001\u6750\u6599\u5316\u5b66\u5de5\u7a0b\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4<\/strong><strong>\u9648\u82cf\u6559\u6388\u56e2\u961f\u8bbe\u8ba1\u51fa<\/strong><strong>\u9759\u7535\u548c\u7a7a\u95f4\u53cc\u7a33\u5b9a\u5e73\u8861\u4f53\u7cfb\uff0c\u5236\u5907\u51fa\u56fa\u542b\u91cf\u4e3a<\/strong><strong>55 wt.%<\/strong><strong>\u7684\u5355\u5206\u6563\u805a\uff08\u82ef\u4e59\u70ef<\/strong><strong>&#8211;<\/strong><strong>\u4e19\u70ef\u9178\u4e01\u916f<\/strong><strong>&#8211;<\/strong><strong>\u7532\u57fa\u4e19\u70ef\u9178\uff09\uff08<\/strong><strong>P(St-BA-MAA)<\/strong><strong>\uff09\u80f6\u4f53\u4e73\u6db2\u3002\u4e0e\u4f20\u7edf\u4f4e\u56fa\u542b\u91cf\u80f6\u4f53\u5149\u5b50\u6676\u4f53\uff08<\/strong><strong>10%<\/strong><strong>\uff09\u76f8\u6bd4\u5176\u7ec4\u88c5\u6548\u7387\u63d0\u4f9b\u4e86<\/strong><strong>280%<\/strong><strong>\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u901a\u8fc7\u78c1\u63a7\u6e85\u5c04\u6cd5\u5b9e\u73b0\u4e86\u6298\u5c04\u7387\u63a5\u8fd1\u96f6\u7684\u94f6\u6d82\u5c42\u80f6\u4f53\u5149\u5b50\u6676\u4f53\uff08<\/strong><strong>Ag@CPC<\/strong><strong>\uff09\u5236\u5907\uff0c\u5448\u73b0\u51fa\u72ec\u7279\u8d85\u6750\u6599\u7684\u7279\u6027\u3002<\/strong>\u7531\u4e8e\u5176\u7ec4\u88c5\u6548\u7387\u9ad8\uff0cAg@CPC\u8d85\u6750\u6599\u6d82\u5c42\u5b9e\u73b0\u4e86CdSe@ZnS\u91cf\u5b50\u70b9(Quantum dots, QDs)\u7ea611\u500d\u5149\u81f4\u53d1\u5149\uff08PL\uff09\u589e\u5f3a\uff0c\u4e3a\u9ad8\u8d28\u91cf\u3001\u8282\u80fd\u7684\u6db2\u6676\u663e\u793a\uff08LCD\uff09\u5668\u4ef6\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\u3002\u6b64\u5916\uff0cAg@CPC\u8d85\u6750\u6599\u6d82\u5c42\u5177\u6709\u5f3a\u5927\u7684\u8282\u80fd\u529f\u80fd\u3002<\/p>\n<p>\u8be5\u7814\u7a76\u6210\u679c\u4e8e\u8fd1\u65e5\u53d1\u8868\u5728\u56fd\u9645\u91cd\u8981\u520a\u7269\u300a<em><strong>Advanced Materials<\/strong><\/em>\u300b\u4e0a\u3002(Facile Access to High Solid Content Monodispersed Microspheres via Dual-Component Surfactants Regulation towards High-Performance Colloidal Photonic Crystals, DOI: 10.1002\/adma.202312879)\u3002\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u535a\u58eb\u540e<strong>\u4e8e\u6653\u6674<\/strong>\u548c\u7855\u58eb\u7814\u7a76\u751f<strong>\u5434\u5a55<\/strong>\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002\u5357\u4eac\u5de5\u4e1a\u5927\u5b66<strong>\u9648\u82cf\u6559\u6388\u3001\u674e\u6674\u526f\u6559\u6388\u3001\u674e\u56fd\u661f\u535a\u58eb\u540e<\/strong>\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p>\u8be5\u8bfe\u9898\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u3001\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u56fd\u5bb6\u9752\u5e74\u81ea\u7136\u57fa\u91d1\u3001\u6c5f\u82cf\u7701\u9ad8\u6821\u4f18\u52bf\u5b66\u79d1\u5efa\u8bbe\u5de5\u7a0b\u3001\u6750\u6599\u5316\u5b66\u5de5\u7a0b\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7b49\u57fa\u91d1\u7684\u8d44\u52a9\u548c\u652f\u6301\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-258912\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/1-32.png\" alt=\"\" width=\"797\" height=\"850\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/1-32.png 797w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/1-32-281x300.png 281w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/1-32-768x819.png 768w\" sizes=\"(max-width: 797px) 100vw, 797px\" \/><\/p>\n<p>\u56fe1. \u56fa\u542b\u91cf55 wt.%\u80f6\u4f53\u4e73\u6db2\u7684\u5927\u89c4\u6a21\u5236\u5907\u4e0e\u5e94\u7528\u3002(a) \u9ad8\u56fa\u542b\u91cf\u5355\u5206\u6563P(St-BA-MAA)\u4e73\u6db2\u7684\u805a\u5408\u3002\u4e73\u6db2\u5177\u6709\u7406\u60f3\u7684\u56fa\u542b\u91cf (55 wt.%)\u3001\u9ad8\u5355\u5206\u6563\u6027(PDI &lt; 0.05)\u548c\u5f3a\u7a33\u5b9a\u6027(Zeta\u7535\u4f4d~ -25 mV)\uff0c\u5448\u73b0\u5f69\u8679\u8272\u3002(b) \u78c1\u63a7\u6e85\u5c04\u5236\u5907\u8fd1\u96f6\u6298\u5c04\u7387\u7684Ag@CPC\u8d85\u6750\u6599\u6d82\u5c42\u793a\u610f\u56fe\u3002(c) \u8282\u80fdLCD\u5668\u4ef6\u7684\u8bbe\u8ba1\uff0cAg@CPC\u8d85\u6750\u6599\u6d82\u5c42\u786e\u4fdd\u4e86CdSe@ZnS\u91cf\u5b50\u70b9\u768411\u500d\u8367\u5149\u589e\u5f3a\u3002(d) \u5efa\u7b51\u5899\u9762\u6eda\u6d82\u5f69\u8272\u6d82\u5c42\u7684\u7167\u7247\u3002(e) \u9ad8\u56fa\u542b\u91cf\u5355\u5206\u6563\u5fae\u7403\u5728\u8282\u80fd\u9886\u57df\u5e94\u7528\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-258913\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/2-33.png\" alt=\"\" width=\"827\" height=\"651\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/2-33.png 827w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/2-33-300x236.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/2-33-768x605.png 768w\" sizes=\"(max-width: 827px) 100vw, 827px\" \/><\/p>\n<p>\u56fe2. \u9ad8\u56fa\u542b\u91cf\u5355\u5206\u6563\u80f6\u4f53\u4e73\u6db2\u7684\u805a\u5408\u673a\u7406\u53ca\u81ea\u7ec4\u88c5\u3002(a) \u9ad8\u56fa\u542b\u91cf\u5355\u5206\u6563\u4e73\u6db2\u7684\u9759\u7535\u548c\u7a7a\u95f4\u53cc\u7a33\u5b9a\u793a\u610f\u56fe\u3002(b) \u9ad8\u56fa\u542b\u91cf\u4e73\u6db2(55 wt.%)\u548c\u4f4e\u56fa\u542b\u91cf\u4e73\u6db2(10 wt.%)\u84b8\u53d1\u8fc7\u7a0b\u4e2d\u7684\u81ea\u7ec4\u88c5\u6a21\u5f0f\u3002\u9ad8\u56fa\u542b\u91cf\u4e73\u6db2(55 wt.%)\u503e\u5411\u4e8e\u6392\u5217\u6210\u9762\u5fc3\u7acb\u65b9\u7ed3\u6784\uff0c\u4f4e\u56fa\u542b\u91cf\u4e73\u6db2(10 wt.%)\u4ee5\u7b80\u5355\u7684\u7acb\u65b9\u7ed3\u6784\u7ec4\u88c5\u3002(c, d) \u9ad8\u56fa\u542b\u91cf\u4e73\u6db2(55% wt.%)\u7ec4\u88c5CPC\u6a2a\u622a\u9762\u7684SEM\u56fe\u50cf\u3002\u63d2\u56fe\u663e\u793a\u9ad8\u56fa\u542b\u91cf\u4e73\u6db2\u7684\u7c92\u5f84\u5206\u5e03\u3002(e) \u4f4e\u56fa\u542b\u91cf\u4e73\u6db2\u4e73\u80f6(10 wt.%)\u7ec4\u88c5CPC\u6a2a\u622a\u9762\u7684SEM\u56fe\u50cf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-258914\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/3-31.png\" alt=\"\" width=\"700\" height=\"827\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/3-31.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/3-31-254x300.png 254w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe3. CPC\u6d82\u5c42\u7684\u5149\u5b66\u6027\u80fd\u3002(a) 10 wt.%(\u4e0a\u6392)\u548c55 wt.%(\u4e0b\u6392)\u4e0d\u540c\u56fa\u542b\u91cf\u80f6\u4f53\u6db2\u6ef4\u84b8\u53d1\u5e72\u71e5\u8fc7\u7a0b\u7167\u7247\u3002\u6bd4\u4f8b\u5c3a\uff1a1\u5398\u7c73\u3002(b) \u201c\u81ea\u5265\u76ae\u201d\u8c03\u8282\u7684\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\u6bd4\u4f8b\u5c3a\uff1a2\u5398\u7c73\u3002(c) \u753155% \u56fa\u542b\u91cf\u80f6\u4f53\u4e73\u6db2\u7ec4\u88c5\u800c\u6210CPC\u7684\u4e8c\u7ef4\u548c\u4e09\u7ef4AFM\u56fe\u50cf\u3002(d) CPC\u7684\u89d2\u5ea6\u76f8\u5173\u7ed3\u6784\u8272\u548c\u5bf9\u5e94\u7684\u53cd\u5c04\u5149\u8c31\u3002(e) \u8986\u76d6\u6574\u4e2a\u53ef\u89c1\u5149\u8c31\u7684\u4e0d\u540c\u7ed3\u6784\u8272CPC\u8584\u819c\u3002\u6bd4\u4f8b\u5c3a\uff1a2\u5398\u7c73\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-258915\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/4-29.png\" alt=\"\" width=\"700\" height=\"756\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/4-29.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/03\/4-29-278x300.png 278w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe4. \u9ad8\u56fa\u542b\u91cf\u4e73\u6db2\u5728\u5149\u5b66\u9886\u57df\u7684\u5e94\u7528\u3002(a) Ag@CPC\u8d85\u6750\u6599\u7684\u793a\u610f\u56fe\u3002(b) CPC\u548cAg@CPC\u8d85\u6750\u6599\u7684\u663e\u5fae\u5149\u5b66\u7167\u7247\u53caAg@CPC\u8d85\u6750\u6599\u7684SEM\u56fe\u50cf\u3002(c) Ag@CPC\u8d85\u6750\u6599\u4e8c\u7ef4AFM\u56fe\u53ca\u7eb5\u5411\u9ad8\u5ea6\u5206\u5e03\u3002(d) \u7eafCPC(\u9ed1\u8272)\u3001Ag\u5c42(\u84dd\u8272) \u548cAg@CPC\u8d85\u6750\u6599(\u7ea2\u8272)\u6709\u6548\u6298\u5c04\u7387\u7684\u5b9e\u90e8(\u5b9e\u7ebf)\u548c\u865a\u90e8(\u865a\u7ebf)\u3002\u84dd\u8272\u9634\u5f71\u8868\u793a\u53ef\u89c1\u5149\u533a\u57df\u3002(f) CdSe@ZnS 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