{"id":258919,"date":"2024-03-28T06:28:59","date_gmt":"2024-03-27T22:28:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=258919"},"modified":"2024-03-27T19:32:58","modified_gmt":"2024-03-27T11:32:58","slug":"%e6%b5%b7%e5%8d%97%e5%a4%a7%e5%ad%a6%e7%a7%a6%e6%a2%93%e5%96%bb%e3%80%81%e5%b0%b9%e5%ad%a6%e7%90%bcafm%ef%bc%9a%e6%8a%97%e8%8f%8c%e7%bc%ba%e9%99%b7%e6%80%81mofs%e5%9f%ba%e6%9f%94%e6%80%a7%e4%bc%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=258919","title":{"rendered":"\u6d77\u5357\u5927\u5b66\u79e6\u6893\u55bb\u3001\u5c39\u5b66\u743cAFM\uff1a\u6297\u83cc\u7f3a\u9677\u6001MOFs\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5236\u5907\u4e0e\u591a\u529f\u80fd\u68c0\u6d4b\u5e94\u7528"},"content":{"rendered":"

\u4e00\u3001<\/strong> \u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u67d4\u6027\u7535\u963b\u5f0f\u4f20\u611f\u5668\u56e0\u5176\u4fbf\u6377\u7075\u6d3b\u3001\u7a7f\u6234\u8212\u9002\u548c\u975e\u4fb5\u5165\u5f0f\u68c0\u6d4b\u7b49\u7279\u70b9\uff0c\u5728\u4e2a\u4eba\u5065\u5eb7\u3001\u5ba4\u5185\u5916\u73af\u5883\u7a7a\u6c14\u8d28\u91cf\u548c\u6709\u6bd2\u6c14\u4f53\u76d1\u6d4b\u7b49\u5e94\u7528\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u76ee\u524d\u591a\u6570\u67d4\u6027\u4f20\u611f\u5668\u53ea\u5177\u5907\u6c14\u4f53\u6216\u5e94\u529b\u5e94\u53d8\u5355\u4e00\u4fe1\u53f7\u68c0\u6d4b\u529f\u80fd\uff0c\u82e5\u591a\u5668\u4ef6\u96c6\u6210\u4f7f\u7528\u5219\u7535\u8def\u67b6\u6784\u590d\u6742\uff0c\u5bb9\u6613\u9020\u6210\u5668\u4ef6\u635f\u574f\u4e14\u7ef4\u62a4\u6210\u672c\u9ad8\uff0c\u8fd9\u5e76\u4e0d\u5229\u4e8e\u67d4\u6027\u4f20\u611f\u5668\u9ad8\u6548\u68c0\u6d4b\u548c\u957f\u671f\u7a7f\u6234\u5e94\u7528\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\uff0c\u80fd\u5426\u57fa\u4e8e\u5355\u4e2a\u67d4\u6027\u4f20\u611f\u5668\u5b9e\u73b0\u5bf9\u6c14\u4f53\u548c\u5e94\u529b\u591a\u91cd\u4fe1\u53f7\u611f\u77e5\u8bc6\u522b\uff0c\u5bf9\u4e8e\u63a8\u8fdb\u67d4\u6027\u4f20\u611f\u5668\u591a\u529f\u80fd\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d77\u5357\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u79e6\u6893\u55bb\u3001\u5c39\u5b66\u743c\u6559\u6388\u8054\u5408\u62a5\u9053\u4e86\u4e00\u79cd\u7f3a\u9677\u6001ZIF-8\/\u805a\u5421\u54af\uff08PPY\uff09\/\u7ec6\u83cc\u7ea4\u7ef4\u7d20\uff08BC\uff09\u57fa\u67d4\u6027\u4f20\u611f\u6750\u6599\uff0c\u5b9e\u73b0\u4e86\u5ba4\u6e29\u4e0b\u5bf9\u4e8c\u6c27\u5316\u6c2e\uff08NO2<\/sub>\uff09\u6c14\u4f53\u548c\u5e94\u529b\u5e94\u53d8\u9ad8\u6548\u611f\u77e5\u3002\u8be5\u5de5\u4f5c\u7ed3\u5408\u4e86\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOFs\uff09\u9ad8\u6c14\u4f53\u5438\u9644\u6027\u3001\u6297\u83cc\u6027\u3001PPY\u5bfc\u7535\u6027\u548cBC\u9ad8\u673a\u68b0\u5f3a\u5ea6\u3001\u8d28\u5730\u8f7b\u76c8\u4e14\u591a\u5b54\u900f\u6c14\u7684\u4f18\u70b9\uff0c\u901a\u8fc7\u539f\u4f4d\u751f\u957f\u6cd5\u8fdb\u884c\u9010\u4e00\u590d\u5408\u5236\u5907\u3002\u4e3a\u8fdb\u4e00\u6b65\u589e\u5f3a\u590d\u5408\u6750\u6599\u6c14\u4f53\u5438\u9644\u6027\u80fd\uff0c\u63d0\u51fa\u5229\u7528\u6c34\u5206\u5b50\u8bf1\u5bfcZIF-8\u7f3a\u9677\u4f4d\u4ea7\u751f\uff0c\u901a\u8fc7\u7f3a\u9677\u4f4d\u5f62\u6210\u5927\u91cf\u6d3b\u6027\u5438\u9644\u4f4d\u70b9\u4ece\u800c\u6781\u5927\u63d0\u5347\u4e86\u5ba4\u6e29\u4e0b\u5bf9NO2<\/sub>\u6c14\u4f53\u7684\u54cd\u5e94\u5f3a\u5ea6\u3002\u6700\u7ec8\u6240\u5236\u5907\u7684Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u53ef\u7528\u4e8e\u76d1\u6d4b\u73af\u5883\u4e2dNO2<\/sub>\u6c14\u4f53\u4ee5\u53ca\u5404\u7c7b\u8fd0\u52a8\u884c\u4e3a\u5bfc\u81f4\u7684\u5e94\u529b\u5e94\u53d8\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cAntibacterial defective-ZIF-8\/PPY\/BC-based flexible electronics as stress-strain and NO2<\/sub> gas sensors\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u4e8eWiley\u6750\u6599\u9886\u57df\u671f\u520a\u300aAdvanced Functional Materials\u300b\u4e0a\u3002<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u57fa\u4e8e\u5355\u4e2a\u67d4\u6027\u4f20\u611f\u5668\u540c\u6b65\u5b9e\u73b0\u5bf9NO2<\/sub>\u6c14\u4f53\u3001\u5e94\u529b\u5e94\u53d8\u6709\u6548\u611f\u77e5\u4e14\u7a7f\u6234\u6297\u83cc\u529f\u80fd\uff0c\u8fd9\u5c06\u6709\u6548\u89e3\u51b3\u76ee\u524d\u591a\u5668\u4ef6\u67d4\u6027\u4f20\u611f\u5668\u96c6\u6210\u4f7f\u7528\u4e2d\u7535\u8def\u67b6\u6784\u590d\u6742\u6613\u635f\u574f\u7684\u96be\u9898\u3002<\/p>\n

2\u3001\u5f15\u5165\u5bfc\u7535BC\u6784\u5efa\u5bfc\u7535\u7f51\u7edc\uff0c\u89e3\u51b3ZIF-8\u7535\u5b50\u957f\u7a0b\u8f93\u8fd0\u96be\u9898\uff0c\u5b9e\u73b0ZIF-8\u5ba4\u6e29\u7535\u5b66\u4f20\u611f\u4fe1\u53f7\u6355\u83b7\u3002<\/p>\n

3\u3001\u901a\u8fc7\u6c34\u5904\u7406\u6cd5\u5f15\u5165MOFs\u7f3a\u9677\uff0c\u8be5\u7f3a\u9677\u8c03\u63a7\u65b9\u6cd5\u7b80\u5355\u53ef\u63a7\u4e14\u5e72\u6270\u56e0\u7d20\u5c11\uff0c\u6709\u6548\u589e\u5f3aZIF-8\u6c14\u4f53\u5438\u9644\u6027\u80fd\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong> (a) Def-ZIF-8\/PPY\/BC\u590d\u5408\u6750\u6599\u5236\u5907\u5de5\u827a\u793a\u610f\u56fe;(b) ZIF-8\u4e0e\u6c34\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u5bfc\u81f4\u7f3a\u9677\u5f62\u6210\u7684\u793a\u610f\u56fe\u3002(L: 2-\u7532\u57fa\u54aa\u5511\u6709\u673a\u914d\u4f53)\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong>\u5404\u6837\u54c1SEM\u56fe\u50cf\u4e0eEDX\u7ed3\u679c\uff1a\uff08a\uff09BC\uff1b\uff08b\uff09PPY\/BC\uff1b\uff08c\uff09ZIF-8\/PPY\/BC\uff1b\uff08d\uff09Def-ZIF-8\/PPY\/BC\u3002<\/p>\n

\u5982\u56fe2\u6240\u793a\u5373\u4e3aBC\u3001PPY\/BC\u3001ZIF-8\/ PPY\/BC\u548cDef-ZIF-8\/PPY\/BC\u6837\u54c1\u5fae\u89c2\u5f62\u8c8cSEM\u548cEDX\u56fe\u3002\u7eafBC\uff08\u5982\u56fe2\uff08a\uff09\u6240\u793a\uff09\u7684\u7ea4\u7ef4\u675f\u76f8\u4e92\u4ea4\u9519\u5448\u73b0\u4e09\u7ef4\u7cbe\u7ec6\u7f51\u72b6\u7ed3\u6784\uff0c\u8fd9\u79cd\u758f\u677e\u591a\u5b54\u7ed3\u6784\u6709\u5229\u4e8eMOFs\u8d1f\u8f7d\u5e76\u4fc3\u8fdb\u6c14\u4f53\u5438\u9644\uff0c\u540c\u65f6\u4e5f\u4fdd\u8bc1\u4f20\u611f\u6750\u6599\u5177\u5907\u8f83\u597d\u7684\u67d4\u6027\u548c\u529b\u5b66\u5f3a\u5ea6\uff0c\u8fd9\u5bf9\u67d4\u6027\u4f20\u611f\u5668\u5236\u5907\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u80fd\u8c31\u7ed3\u679c\u663e\u793aDef-ZIF-8\/PPY\/BC\u4e2d\u6c27\uff08O\uff09\u5143\u7d20\u7684\u539f\u5b50\u6bd4\u75312.93%\u63d0\u9ad8\u81f37.24%\uff0cZn\u5143\u7d20\u542b\u91cf\u5219\u75317.04%\u964d\u81f31.27%\uff0c\u8fd9\u6781\u6709\u53ef\u80fd\u662f\u6c34\u5206\u5b50\u4ecb\u5165\u5f15\u5165\u7f9f\u57fa\u5bfc\u81f4\u4ef7\u952e\u65ad\u88c2\u800c\u4ea7\u751f\u4e86\u7f3a\u9677\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>(a)\u4e0d\u540cZIF-8\u8d1f\u8f7d\u4e0bDef-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5bf940 ppm NO2<\/sub>\u7684\u54cd\u5e94\u5f3a\u5ea6;(b)\u4e0d\u540c\u6c34\u5904\u7406\u65f6\u95f4(1-48h)\u4e0b\uff0cDef-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5bf940 ppm NO2<\/sub>\u7684\u54cd\u5e94\u5f3a\u5ea6;(c)Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5ba4\u6e29\u4e0b\u5bf9\u4e0d\u540cNO2<\/sub>\u6d53\u5ea6(5-80 ppm)\u7684\u5b9e\u65f6\u7535\u963b\u54cd\u5e94\u66f2\u7ebf;(d) ZIF-8\/PPY\/BC\u548cDef-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5ba4\u6e29\u4e0b\u5bf9\u4e0d\u540cNO2<\/sub>\u6d53\u5ea6(5-80 ppm)\u7684\u54cd\u5e94\u5f3a\u5ea6\u6bd4\u8f83;(e) Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5bf9\u5404\u79cd\u6c14\u4f53(10 ppm NO2<\/sub>\u3001100 ppm NH3<\/sub>\u3001200 ppm C2<\/sub>H4<\/sub>\u3001500 ppm\u4e19\u916e\u300110% CO2<\/sub>)\u7684\u9009\u62e9\u6027;(f)\u4e0d\u540c\u6e7f\u5ea6\u80cc\u666f(0-80%)\u4e0b\uff0cDef-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5bf940 ppm NO2<\/sub>\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf\u53d8\u5316;(g) Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5bf940 ppm NO2<\/sub>\u957f\u671f\u7a33\u5b9a\u6027\u54cd\u5e94\u5f3a\u5ea6\u6d4b\u8bd5\u3002<\/p>\n

\u5728\u4f20\u611f\u6750\u6599\u5ba4\u6e29\u6c14\u654f\u6027\u80fd\u68c0\u6d4b\u4e0a\uff0c Def-ZIF-8\/PPY\/BC\u4f20\u611f\u6750\u6599\u5bf9NO2<\/sub>\u6c14\u4f53\u7684\u5ba4\u6e29\u4f20\u611f\u6027\u80fd\u5982\u56fe3\u6240\u793a\u3002\u9996\u5148\uff0c\u901a\u8fc7\u8003\u5bdf\u4e0d\u540c\u5de5\u827a\u6761\u4ef6\u4e0bDef-ZIF-8\/PPY\/BC\u4f20\u611f\u6750\u6599\u6c14\u654f\u6027\u80fd\u8868\u73b0\u60c5\u51b5\uff0c\u4f18\u5316\u6750\u6599\u5236\u5907\u5de5\u827a\u3002\u5176\u6b21\uff0c\u6c14\u654f\u6d4b\u8bd5\u7ed3\u679c\u4e5f\u8868\u660e\u6240\u5236\u5907\u7684Def-ZIF-8\/PPY\/BC\u5bf9\u4e0d\u540c\u6d53\u5ea6NO2<\/sub>\u7684\u6c14\u654f\u54cd\u5e94\u5f3a\u5ea6\u663e\u8457\u9ad8\u4e8e\u672a\u7ecf\u8fc7\u6c34\u5904\u7406\u7684ZIF-8\/PPY\/BC\u4f20\u611f\u6750\u6599\u3002\u8fd9\u8868\u660e\u6c34\u5904\u7406\u540e\u80fd\u5927\u5e45\u5ea6\u63d0\u9ad8\u6240\u5236\u5907\u4f20\u611f\u6750\u6599\u5728\u5ba4\u6e29\u4e0b\u5bf9NO2<\/sub>\u7684\u6c14\u654f\u6027\u80fd\u3002\u6b64\u5916\uff0c\u5728\u6c14\u4f53\u9009\u62e9\u6027\u3001\u6297\u6e7f\u6027\u548c\u957f\u671f\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e0aDef-ZIF-8\/PPY\/BC\u4f20\u611f\u6750\u6599\u4e5f\u6709\u8f83\u597d\u8868\u73b0\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5e94\u529b\u5e94\u53d8\u4f20\u611f\u6027\u80fd\u8bc4\u4f30:(a)\u4e0d\u540c\u5f2f\u66f2\u9891\u7387(0.44 Hz, 0.81 Hz, 1.2 Hz)\u4e0b\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(b)\u4e0d\u540c\u5f2f\u66f2\u534a\u5f84(30mm\u300150mm)\u4e0b\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(c)\u624b\u6307\u91cd\u590d\u5f2f\u66f2\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(d)\u91cd\u590d\u6027\u624b\u81c2\u5f2f\u66f2\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(e)\u884c\u8d70\u884c\u4e3a\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(f)\u541e\u54bd\u884c\u4e3a\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(g)\u624b\u81c2\u808c\u8089\u5f62\u53d8\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf;(h) Def-ZIF-8\/PPY\/BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5e94\u529b\u5e94\u53d8\u4f20\u611f\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

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\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>Def-ZIF-8\/PPY\/ BC\u57fa\u67d4\u6027\u4f20\u611f\u5668\u5728\u5468\u671f\u6027\u5f2f\u66f2\u5e94\u529b(\u9891\u73871.2 Hz\uff0c\u534a\u5f8450 mm)\u4e0b\u5bf980ppm NO2<\/sub>\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf (\u9644\u56fe\u4e3a\u5468\u671f\u6027\u5e94\u529b\u53d8\u5316\u4e0b\u7684\u5b9e\u65f6\u54cd\u5e94\u66f2\u7ebf)\u3002<\/p>\n

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\"\"<\/p>\n

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\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

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