{"id":259225,"date":"2024-04-08T06:42:18","date_gmt":"2024-04-07T22:42:18","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=259225"},"modified":"2024-04-07T16:04:46","modified_gmt":"2024-04-07T08:04:46","slug":"angew-chem-int-ed-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%e5%b1%82%e9%97%b4%e7%a9%ba%e9%9a%99%e7%9a%84%e5%ae%8c%e7%be%8e%e9%80%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=259225","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u57fa\u4e8e\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\u5c42\u95f4\u7a7a\u9699\u7684\u5b8c\u7f8e\u9009\u62e9\u6027\u4eff\u751f\u8d28\u5b50\u901a\u9053"},"content":{"rendered":"

\u5728\u751f\u7269\u4f53\u4e2d\uff0c\u8d28\u5b50\u7684\u6d53\u5ea6\u6bd4\u5176\u4ed6\u79bb\u5b50\u4f4e\u516d\u4e03\u4e2a\u6570\u91cf\u7ea7\u3002\u4e3a\u63a7\u5236\u8d28\u5b50\u4f20\u8f93\u3001\u7ef4\u6301pH\u5e73\u8861\uff0c\u751f\u7269\u8d28\u5b50\u901a\u9053\u5fc5\u987b\u5177\u6709\u51e0\u4e4e\u5b8c\u7f8e\u7684\u9009\u62e9\u6027\uff0c\u4ed6\u4eec\u5141\u8bb8\u8d28\u5b50\u5feb\u901f\u4f20\u8f93\uff0c\u4f46\u662f\u963b\u6b62\u5176\u4ed6\u4e00\u5207\u79bb\u5b50\u548c\u5206\u5b50\u7684\u4f20\u8f93\u3002\u5bf9\u4e8e\u4eba\u5de5\u6750\u6599\u6765\u8bf4\uff0c\u8981\u5b9e\u73b0\u8fd9\u4e00\u7279\u6027\u975e\u5e38\u56f0\u96be\u3002\u4e3a\u4e86\u5b9e\u73b0\u5b8c\u7f8e\u7684\u9009\u62e9\u6027\uff0c\u751f\u7269\u8d28\u5b50\u901a\u9053\u91c7\u7528\u4e86\u4e00\u79cd\u4e0e\u5176\u4ed6\u79bb\u5b50\u901a\u9053\u4e0d\u540c\u7684\u4f20\u8f93\u673a\u5236\uff0c\u5b83\u5e76\u4e0d\u9700\u8981\u4e00\u4e2a\u5f00\u653e\u7684\u901a\u9053\u6765\u4f20\u8f93\u7269\u8d28\uff0c\u800c\u662f\u5185\u90e8\u5f62\u6210\u4e00\u6761\u8fde\u7eed\u7684\u6c22\u952e\u7ebf\uff0c\u8d28\u5b50\u53ef\u4ee5\u5728\u7ebf\u4e0a\u8fde\u7eed\u8df3\u8dc3\uff0c\u8fd9\u79cd\u72ec\u7279\u7684\u673a\u5236\u53ef\u4ee5\u963b\u6b62\u79bb\u5b50\u548c\u6c34\u5206\u5b50\u7684\u8fc1\u79fb\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u5b8c\u7f8e\u7684\u8d28\u5b50\u9009\u62e9\u6027\u3002<\/p>\n

\u53d7\u6b64\u542f\u53d1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240\u7684\u9ad8\u519b\u7814\u7a76\u5458\u56e2\u961f\u548c\u56db\u5ddd\u5927\u5b66\u7684\u9ec4\u9752\u677e\u6559\u6388\u56e2\u961f\u5408\u4f5c\uff0c\u5229\u7528\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\uff08COF\uff09\u7684\u5c42\u95f4\u7a7a\u9699\u6784\u7b51\u4e86\u5177\u6709\u5b8c\u7f8e\u9009\u62e9\u6027\u7684\u4eff\u751f\u8d28\u5b50\u901a\u9053\u3002\u5728\u4ee5\u5f80\u7814\u7a76\u4e2d\uff0c\u4eba\u4eec\u4e00\u822c\u5229\u7528\u4e0eCOF\u819c\u5782\u76f4\u7684\u7eb3\u7c73\u5b54\u4f20\u8f93\u7269\u8d28\uff0c\u4f46\u8fd9\u4e9b\u5b54\u9053\u6bd4\u4e00\u822c\u79bb\u5b50\u548c\u5206\u5b50\u5927\uff0c\u96be\u4ee5\u963b\u6b62\u79bb\u5b50\u3001\u5206\u5b50\u7684\u4f20\u8f93\u3002\u7136\u800c\uff0c\u672c\u6587\u56e2\u961f\u8003\u8651\u5230COF\u5b9e\u9645\u4e0a\u662f\u4e00\u4e2a\u5c42\u5c42\u5806\u53e0\u7684\u6784\u578b\uff0c\u5c42\u4e0e\u5c42\u4e4b\u95f4\u6709\u7740\u6781\u7a84\u7684\u7a7a\u9699\uff0c\u8fd9\u4e9b\u7a7a\u9699\u7684\u9ad8\u5ea6\u6bd4\u9664\u8d28\u5b50\u5916\u7684\u4efb\u4f55\u7269\u8d28\u90fd\u8981\u5c0f\uff0c\u56e0\u6b64\u53ef\u4ee5\u5b9e\u73b0\u5b8c\u7f8e\u7684\u8d28\u5b50\u9009\u62e9\u6027\u3002<\/p>\n

\u5728\u5b9e\u9a8c\u4e2d\uff0c\u7814\u7a76\u56e2\u961f\u8bc1\u5b9e\u4e86\u4efb\u4f55\u79bb\u5b50\u6216\u5206\u5b50\u90fd\u65e0\u6cd5\u6269\u6563\u901a\u8fc7\uff0c\u4f46\u8d28\u5b50\u7684\u6269\u6563\u901f\u7387\u4e0e\u672c\u4f53\u6c34\u7684\u6269\u6563\u901f\u7387\u5904\u4e8e\u540c\u4e00\u6570\u91cf\u7ea7\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6c34\u5206\u5b50\u548c COF \u6750\u6599\u5f62\u6210\u6c22\u952e\u7ebf\uff0c\u4f7f\u5f97\u8d28\u5b50\u53ef\u4ee5\u8fde\u7eed\u8df3\u8dc3\u3002\u7814\u7a76\u8fdb\u4e00\u6b65\u53d1\u73b0\uff0c\u8d28\u5b50\u4f20\u8f93\u901f\u7387\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574\u5b98\u80fd\u56e2\u7684\u9178\u5ea6\u6765\u8c03\u8282\uff0c\u9178\u6027\u5f3a\u7684\u57fa\u56e2\u53ef\u4ee5\u63d0\u5347\u8d28\u5b50\u4f20\u8f93\u901f\u7387\uff0c\u4f46\u65e0\u8bba\u4f55\u79cd\u57fa\u56e2\uff0c\u8d28\u5b50\u7684\u5b8c\u7f8e\u9009\u62e9\u6bd4\u5747\u53ef\u4ee5\u4fdd\u6301\u3002<\/p>\n

\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u56db\u5ddd\u5927\u5b66\u4e0e\u4e2d\u79d1\u9662\u9752\u5c9b\u80fd\u6e90\u6240\u7684\u8054\u57f9\u535a\u58eb\u674e\u742a\u4ee5\u53ca\u9752\u5c9b\u80fd\u6e90\u6240\u535a\u540e\u9ad8\u5b8f\u98de\u3002\u5de5\u4f5c\u83b7\u5f97\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u4ee5\u53ca\u9752\u5c9b\u80fd\u6e90\u6240\uff08\u5c71\u4e1c\u80fd\u6e90\u7814\u7a76\u9662\uff09\u81ea\u4e3b\u90e8\u7f72\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 1.\u00a0TpPa-SO3<\/sub>H \u819c\u7684\u7ed3\u6784\u4e0e\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u56fe 2.\u00a0TpPa-SO3<\/sub>H \u5c42\u95f4\u7684\u5b8c\u7f8e\u9009\u62e9\u6027\u8d28\u5b50\u4f20\u8f93<\/p>\n

\"\"<\/p>\n

\u56fe 3. \u53ef\u8c03\u63a7\u7684\u8d28\u5b50\u6e17\u900f\u901f\u7387<\/p>\n

\u6587\u7ae0\u4fe1\u606f\uff1a<\/strong><\/p>\n

Qi Li1,2\u2020<\/sup>, Hongfei Gao2\u2020<\/sup>, Yongye Zhao2<\/sup>, Bo Zhou2<\/sup>, Lei Yu2<\/sup>, Qingsong Huang1*<\/sup>, Lei Jiang3<\/sup>, Jun Gao2, 4, 5*<\/sup>\u00a0Covalent Organic Framework Interlayer Spacings as Perfectly Selective Artificial Proton Channels. \u00a0Angew. Chem. Int. Ed.<\/i><\/em>\u00a02024<\/b><\/strong>, e202402094<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1a<\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202402094<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5728\u751f\u7269\u4f53\u4e2d\uff0c\u8d28\u5b50\u7684\u6d53\u5ea6\u6bd4\u5176\u4ed6\u79bb\u5b50\u4f4e\u516d\u4e03\u4e2a\u6570\u91cf\u7ea7\u3002\u4e3a\u63a7\u5236\u8d28\u5b50\u4f20\u8f93\u3001\u7ef4\u6301pH\u5e73\u8861\uff0c\u751f\u7269\u8d28\u5b50\u901a\u9053\u5fc5\u987b\u5177\u6709\u51e0\u4e4e\u5b8c\u7f8e\u7684\u9009\u62e9\u6027\uff0c\u4ed6\u4eec\u5141\u8bb8\u8d28\u5b50\u5feb\u901f\u4f20\u8f93\uff0c\u4f46\u662f\u963b\u6b62\u5176\u4ed6\u4e00\u5207\u79bb\u5b50\u548c…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-259225","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259225"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=259225"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259225\/revisions"}],"predecessor-version":[{"id":259230,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259225\/revisions\/259230"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=259225"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=259225"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=259225"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}