{"id":259314,"date":"2024-04-11T06:45:03","date_gmt":"2024-04-10T22:45:03","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=259314"},"modified":"2024-04-10T19:52:20","modified_gmt":"2024-04-10T11:52:20","slug":"%e4%b8%8a%e6%b5%b7%e7%94%b5%e5%8a%9b%e5%a4%a7%e5%ad%a6%e8%85%90%e8%9a%80%e9%a1%b6%e5%88%8a%e3%80%8acorrosion-science%e3%80%8b%ef%bc%9a%e9%9d%a2%e5%90%91%e9%93%9d%e5%90%88%e9%87%91%e5%8f%8c%e6%9e%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=259314","title":{"rendered":"\u4e0a\u6d77\u7535\u529b\u5927\u5b66\u8150\u8680\u9876\u520a\u300aCorrosion Science\u300b\uff1a\u9762\u5411\u94dd\u5408\u91d1\u53cc\u6781\u677f\u8868\u9762\u9632\u62a4\u7528\u8d85\u8584MXene\u590d\u5408\u6d82\u5c42"},"content":{"rendered":"<p>\u4e8c\u7ef4Ti<sub>3<\/sub>C<sub>2<\/sub>T<sub>x<\/sub> MXene\u7531\u4e8e\u53ef\u8c03\u63a7\u7684\u7ed3\u6784\u548c\u8868\u9762\u5316\u5b66\u7279\u6027\u3001\u4f18\u5f02\u7684\u963b\u9694\u6027\u80fd\u3001\u9ad8\u5f84\u539a\u6bd4\u3001\u8d85\u8584\u539a\u5ea6\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u673a\u68b0\u6027\u80fd\u548c\u5c42\u95f4\u6613\u4e8e\u526a\u5207\u53d8\u5f62\u80fd\u529b\uff0c\u5177\u6709\u9632\u8150\u8010\u78e8\u6027\u80fd\u3002MXene\u590d\u5408\u6d82\u5c42\u53ef\u7528\u4e8e\u91d1\u5c5e\u8868\u9762\u9632\u62a4\u3002\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60(PEMFC)\u91d1\u5c5e\u53cc\u6781\u677f\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7684\u8150\u8680\u95ee\u9898\uff0c\u5236\u7ea6\u7535\u6c60\u4f7f\u7528\u6548\u7387\u3002\u5e38\u7528\u7684\u91d1\u5c5e\u3001\u9676\u74f7\u3001\u78b3\u57fa\u3001\u805a\u5408\u7269\u6d82\u5c42\uff0c\u4f9d\u7136\u5b58\u5728\u7eb3\u7c73\u586b\u6599\u96be\u4ee5\u5747\u5300\u5206\u6563\u3001\u5236\u5907\u6d41\u7a0b\u590d\u6742\u3001\u6d82\u5c42\u5236\u5907\u901f\u7387\u4f4e\u3001\u73af\u5883\u4e0d\u53cb\u597d\u548c\u6210\u672c\u9ad8\u7b49\u95ee\u9898\u3002\u540c\u65f6\uff0c\u6d82\u5c42\u539a\u5ea6\u5f71\u54cd\u53cc\u6781\u677f\u4f7f\u7528\u6027\u80fd\uff0c\u800c\u53cc\u6781\u677f\u8868\u9762\u9632\u62a4\u7528\u8d85\u8584\u590d\u5408\u6d82\u5c42\u7684\u6784\u5efa\u4ecd\u5b58\u5728\u6311\u6218\u3002\u56e0\u6b64\uff0c\u57fa\u4e8eMXene\u7c7b\u91d1\u5c5e\u5bfc\u7535\u6027\u3001\u5f3a\u963b\u9694\u6027\u53ca\u4f4e\u6469\u64e6\u7cfb\u6570\uff0c\u53ef\u901a\u8fc7\u7535\u6c89\u79ef\u6784\u5efa\u8d85\u8584MXene\u590d\u5408\u9632\u62a4\u6d82\u5c42\uff0c\u6709\u671b\u89e3\u51b3\u4ee5\u4e0a\u95ee\u9898\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259317\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-10.png\" alt=\"\" width=\"554\" height=\"381\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-10.png 554w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-10-300x206.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p><strong>\u4e0a\u6d77\u7535\u529b\u5927\u5b66\u3001\u4e0a\u6d77\u5e02\u7535\u529b\u6750\u6599\u9632\u62a4\u4e0e\u65b0\u6750\u6599\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u66f9\u6000\u6770<\/strong>\u8fd1\u5e74\u6765\u56f4\u7ed5MXene\u590d\u5408\u9632\u8150\u6d82\u5c42\u5f00\u5c55\u7814\u7a76\u3002\u5728\u524d\u671f\u7814\u7a76\u901a\u8fc7\u4e00\u6b65\u7535\u6c89\u79ef\u6784\u7b51\u4eff\u751f\u5206\u7ea7\u7ed3\u6784\u7684MXene\u590d\u5408\u6d82\u5c42\uff0c\u901a\u8fc7\u539f\u4f4d\u8150\u8680\u89c2\u6d4b\u63ed\u793aMXene\u6d82\u5c42\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u9632\u62a4\u673a\u5236\uff08<em>Journal of Colloid and Interface Science 2024, 685, 865-878<\/em>\uff09\u57fa\u7840\u4e0a\uff0c<strong>\u63d0\u51fa\u5229\u7528\u7535\u6c89\u79ef\u6cd5\u6784\u5efa\u8d85\u8584<\/strong><strong>MXene<\/strong><strong>\u9632\u8150\u8010\u78e8\u6d82\u5c42<\/strong>\uff0c\u7ed3\u5408\u539f\u4f4d\u8150\u8680\u89c2\u6d4b\u3001\u7535\u5316\u5b66\u5206\u6790\u3001\u8868\u9762\u5f62\u8c8c\u53ca\u7ec4\u5206\u5206\u6790\uff0c\u63ed\u793aMXene\u590d\u5408\u6d82\u5c42\u5728PEMFC\u73af\u5883\u4e0b\u7684\u9632\u62a4\u673a\u5236\u3002\u76f8\u5173\u6210\u679c\u201c<strong>Electrodeposited Ti<sub>3<\/sub>C<sub>2<\/sub>T<sub>x <\/sub>MXene composite coating toward superior surface protection on aluminum alloy in PEMFC environments<\/strong>\u201d\u8fd1\u671f\u5728\u8150\u8680\u9876\u520a\u300a<em>Corrosion Science<\/em>\u300b\u4e0a\u53d1\u8868\u3002\u8be5\u7814\u7a76\u5f97\u5230\u4e0a\u6d77\u5e02\u626c\u5e06\u8ba1\u5212\u3001\u4e0a\u6d77\u5e02\u7535\u529b\u6750\u6599\u9632\u62a4\u4e0e\u65b0\u6750\u6599\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7ecf\u8d39\u652f\u6301\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u662f\u4e0a\u6d77\u7535\u529b\u5927\u5b66\u73af\u5883\u4e0e\u5316\u5b66\u5de5\u7a0b\u5b66\u96622022\u7ea7\u7814\u7a76\u751f\u738b\u5929\u6b4c\uff0c\u901a\u8baf\u4f5c\u8005\u66f9\u6000\u6770\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259318\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-9.png\" alt=\"\" width=\"700\" height=\"502\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-9.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-9-300x215.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u7535\u6c89\u79ef\u5de5\u827a\u6784\u5efa\u8d85\u8584MXene\u590d\u5408\u6d82\u5c42\u3002\u76f8\u6bd4\u5176\u4ed6\u9632\u62a4\u6d82\u5c42\uff0c\u5728PEMFC\u73af\u5883\u4e0b\uff0cMXene\u590d\u5408\u6d82\u5c42\u7535\u6d41\u5bc6\u5ea6\u964d\u4f4e\u6548\u679c\u660e\u663e\uff0c\u540c\u65f6\u6d82\u5c42\u5c55\u73b0\u51fa\u7a33\u5b9a\u7684\u9632\u8150\u6027\u80fd\u3002MXene\u7684\u5f15\u5165\uff0c\u53ef\u63d0\u9ad8\u8868\u9762\u8010\u78e8\u6027\u3002\u901a\u8fc7\u8868\u9762\u6da6\u6e7f\u6027\u548c3D\u5171\u805a\u7126\u663e\u5fae\u955c\u5206\u6790\uff0c\u7a33\u5b9a\u7684\u8868\u9762\u758f\u6c34\u6027\u548c\u5b8c\u6574\u7684\u8986\u76d6\u8d4b\u4e88\u6d82\u5c42\u9ad8\u8010\u8680\u6027\u3002\u901a\u8fc7\u7535\u5316\u5b66\u5206\u6790\u3001\u5fae\u89c2\u7ed3\u6784\u548c\u8868\u9762\u7ec4\u6210\u8868\u5f81\u3001\u539f\u4f4d\u8150\u8680\u89c2\u6d4b\u63a2\u7a76\uff0c\u63ed\u793aMXene\u590d\u5408\u6d82\u5c42\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7684\u9632\u62a4\u673a\u5236\u3002MXene\u7eb3\u7c73\u7247\u63d0\u5347\u6d82\u5c42\u9632\u8150\u6027\u80fd\u7684\u4e3b\u8981\u539f\u56e0\u5f52\u7ed3\u4e8e\uff1a\u589e\u52a0\u6d82\u5c42\u539a\u5ea6\u3001\u964d\u4f4e\u6d82\u5c42\u5b54\u9699\u7387\u3001\u964d\u4f4e\u8150\u8680\u4ecb\u8d28\u7684\u6269\u6563\u7cfb\u6570\u3001\u589e\u5f3a\u6d82\u5c42\u4e0e\u57fa\u5e95\u7684\u7c98\u9644\u6027\u3001MXene\u90e8\u5206\u6c27\u5316\u5f62\u6210TiO<sub>2<\/sub>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259319\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-10.png\" alt=\"\" width=\"700\" height=\"325\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-10.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-10-300x139.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe1 \u8d85\u8584MXene\u590d\u5408\u6d82\u5c42\u5236\u5907\u53ca\u8868\u9762\u7ed3\u6784\u3001\u7ec4\u6210\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259320\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-10.png\" alt=\"\" width=\"700\" height=\"593\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-10.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-10-300x254.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe2 MXene\u590d\u5408\u6d82\u5c42\u8868\u9762\u5f62\u8c8c\u3001\u539a\u5ea6\u53ca\u6da6\u6e7f\u6027\u7535\u6c89\u79ef\u5236\u5907\u7684MXene\u590d\u5408\u6d82\u5c42\u5448\u73b0\u66f4\u81f4\u5bc6\u7684\u7ed3\u6784\uff0c\u6c34\u548c\u9178\u6027\u6db2\u6ef4\u7684\u8868\u9762\u63a5\u89e6\u89d2\u5206\u522b\u4e3a135\u00b0\u548c117\u00b0\uff0c\u76f8\u6bd4\u4e8e\u5bf9\u6bd4\u6837\u54c1\uff0c\u8868\u9762\u758f\u6db2\u6027\u660e\u663e\u589e\u52a0\u3002\u622a\u9762\u5f62\u8c8c\u56fe\u7ed3\u679cMXene\u590d\u5408\u6d82\u5c42\u7684\u539a\u5ea6\u63d0\u9ad8\u523010.6 \u03bcm\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259321\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/5-7.png\" alt=\"\" width=\"700\" height=\"585\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/5-7.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/5-7-300x251.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe3 MXene\u590d\u5408\u6d82\u5c42\u5728PEMFC\u73af\u5883\u4e0b\u7684\u7535\u5316\u5b66\u5206\u6790<\/p>\n<p>\u5728\u6a21\u62dfPEMFC\u9178\u6027\u6eb6\u6db20.5 M H<sub>2<\/sub>SO<sub>4<\/sub>+2ppm HF\u4e2d\uff0c\u7535\u6c89\u79efMXene\u590d\u5408\u6d82\u5c42\u8150\u8680\u7535\u6d41\u5bc6\u5ea6\u4e3a9.28\u00d710<sup>-7<\/sup> A\/cm<sup>2<\/sup>\u3002\u7ed3\u5408\u6781\u5316\u66f2\u7ebf\u6570\u636e\uff0c\u8ba1\u7b97\u5f97\u5230\u56db\u79cd\u6837\u54c1\u7684\u5b54\u9699\u7387\u5206\u522b\u4e3a0.899, 0.735, 3.20\u00d710<sup>-2<\/sup>, 9.15\u00d710<sup>-4<\/sup>\u3002EIS\u6d4b\u8bd5\u7ed3\u679c\u53ca\u62df\u5408\u6570\u636e\u663e\u793aMXene\u590d\u5408\u6d82\u5c42\u7684\u6d82\u5c42\u7535\u963b\u548c\u7535\u8377\u8f6c\u79fb\u7535\u963b\u5206\u522b\u4e3a3671 \u03a9\u2022cm<sup>2<\/sup>\u548c8265 \u03a9\u2022cm<sup>2<\/sup>\u300210.6 \u03bcm\u539a\u7684MXene\u590d\u5408\u6d82\u5c42\uff0c\u8150\u8680\u7535\u6d41\u5bc6\u5ea6\u964d\u4f4e\u6548\u679c\u76f8\u6bd4\u5176\u4ed6\u6d82\u5c42\u4f53\u7cfb\u66f4\u4e3a\u663e\u8457\u3002\u9178\u6027\u6eb6\u6db2\u4e2d\u7684\u6d78\u6ce1\u5b9e\u9a8c\u7535\u5316\u5b66\u7ed3\u679c\u663e\u793a\uff0c\u7535\u6c89\u79ef\u6784\u5efa\u7684\u8d85\u8584MXene\u590d\u5408\u6d82\u5c42\u4ecd\u663e\u793a\u51fa\u9ad8\u7684\u6d82\u5c42\u7535\u963b\u548c\u7535\u8377\u8f6c\u79fb\u7535\u963b\uff0c72h\u540e\u590d\u5408\u6d82\u5c42\u7684\u8150\u8680\u7535\u6d41\u5bc6\u5ea6\u4e3a9.39\u00d710<sup>-4<\/sup> A\/cm<sup>2<\/sup>\u3002\u9ad8\u6e29\uff0860\u2103\uff09MXene\u590d\u5408\u6d82\u5c42\u8150\u8680\u7535\u6d41\u5bc6\u5ea6\u4e3a4.04\u00d710<sup>-5<\/sup> A\/cm<sup>2<\/sup>\uff0c\u6d78\u6ce112h\u540e\uff0c\u6d82\u5c42\u7535\u6d41\u5bc6\u5ea6\u4e3a6.98\u00d710<sup>-3<\/sup> A\/cm<sup>2<\/sup>\uff0c\u4ecd\u4f4e\u4e8e\u5bf9\u6bd4\u6837\u54c1\u3002\u56e0\u6b64\uff0cMXene\u590d\u5408\u6d82\u5c42\u663e\u793a\u51fa\u9ad8\u7a33\u5b9a\u6027\u3002MXene\u7684\u5f15\u5165\uff0c\u6d82\u5c42\u78e8\u635f\u7387\u964d\u4f4e\u81f33.82 \u00d710<sup>-3<\/sup> mm<sup>3<\/sup>N<sup>-1<\/sup>m<sup>-1<\/sup>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259322\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/6-2.png\" alt=\"\" width=\"700\" height=\"671\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/6-2.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/6-2-300x288.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe4 MXene\u590d\u5408\u6d82\u5c42\u9178\u6027\u6761\u4ef6\u4e0b\u6d78\u6ce1\u540e\u7684\u8868\u9762\u5f62\u8c8c\u3001\u6da6\u6e7f\u6027\u53ca\u5316\u5b66\u7ec4\u6210\u5206\u6790<\/p>\n<p>\u5728\u9178\u6027\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u540e\uff0c\u5bf9\u6bd4\u6837\u54c1\u6d82\u5c42\u8868\u9762\u51fa\u73b0\u660e\u663e\u5b54\u6d1e\u548c\u5265\u79bb\uff0cMXene\u590d\u5408\u6d82\u5c42\u4ecd\u5448\u73b0\u5b8c\u6574\u8986\u76d6\u3002\u540c\u65f6\uff0c\u6da6\u6e7f\u6027\u6d4b\u8bd5\u8868\u660eMXene\u590d\u5408\u6d82\u5c42\u5bf9\u6c34\u548c\u9178\u6027\u6db2\u4f53\u4ecd\u5448\u73b0\u9ad8\u758f\u6c34\u6027\u3002\u8868\u9762\u5316\u5b66\u7ec4\u6210\u5206\u6790\u7ed3\u679c\u8bf4\u660eCe<sup>3+<\/sup>\u548cMXene\u5728\u6d82\u5c42\u8150\u8680\u9632\u62a4\u4e2d\u8d77\u5230\u5173\u952e\u4f5c\u7528\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259323\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/7.png\" alt=\"\" width=\"700\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/7.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/7-300x200.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe5 \u539f\u4f4d\u89c2\u6d4bMXene\u590d\u5408\u6d82\u5c42\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7684\u8150\u8680\u884c\u4e3a<\/p>\n<p>\u539f\u4f4d\u8150\u8680\u5b9e\u9a8c\u8bc1\u660eMXene\u590d\u5408\u6d82\u5c42\u80fd\u591f\u6709\u6548\u963b\u9694\u9178\u6027\u4ecb\u8d28\u7684\u6e17\u900f\uff0c\u5bf9Al\u5408\u91d1\u7684\u8150\u8680\u6709\u660e\u663e\u6291\u5236\u4f5c\u7528\u3002\u540c\u65f6\uff0c\u539f\u4f4d\u5b9e\u9a8c12h\uff0c\u6d82\u5c42\u4ecd\u8986\u76d6\u5b8c\u6574\uff0c\u4e0e\u57fa\u4f53\u7ed3\u5408\u826f\u597d\u3002\u5bf9\u6bd4\u6d82\u5c42\u5728\u5b9e\u9a8c2h\u51fa\u73b0\u5265\u79bb\u73b0\u8c61\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259324\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/8-1.jpg\" alt=\"\" width=\"700\" height=\"779\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/8-1.jpg 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/8-1-270x300.jpg 270w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe6 MXene\u590d\u5408\u6d82\u5c42\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u6d78\u6ce1\u524d\u540e\u5f62\u8c8c\u53d8\u5316\u53ca\u9632\u8150\u673a\u5236<\/p>\n<p>\u7ed3\u5408\u7535\u5316\u5b66\u5206\u6790\uff0c\u9488\u5bf9MXene\u590d\u5408\u6d82\u5c42\uff0cH<sup>+<\/sup>\u7684\u6269\u6563\u7cfb\u6570\u964d\u4f4e\u81f34.08\u00d710<sup>-16<\/sup> 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