{"id":259602,"date":"2024-05-01T06:12:16","date_gmt":"2024-04-30T22:12:16","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=259602"},"modified":"2024-04-30T22:12:27","modified_gmt":"2024-04-30T14:12:27","slug":"%e9%9f%a9%e5%b8%83%e5%85%b4%e9%99%a2%e5%a3%abnat-chem-%ef%bc%9a%e5%88%86%e5%ad%90%e7%ad%9b%e5%82%ac%e5%8c%96%e5%ba%9f%e5%a1%91%e6%96%99%e5%88%86%e8%a7%a3%e5%88%b6%e5%8f%96%e6%b1%bd%e6%b2%b9%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=259602","title":{"rendered":"\u97e9\u5e03\u5174\u9662\u58ebNat. Chem.\uff1a\u5206\u5b50\u7b5b\u50ac\u5316\u5e9f\u5851\u6599\u5206\u89e3\u5236\u53d6\u6c7d\u6cb9\uff01"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u5851\u6599\u5e9f\u54c1\u9884\u8ba12050\u5e74\u5c06\u8fbe250\u4ebf\u5428\uff0c\u56e0\u6b64\u5f00\u53d1\u591a\u6837\u5316\u5e9f\u65e7\u5851\u6599\u56de\u6536\u6280\u672f\u8feb\u5728\u7709\u776b\u3002\u4f5c\u4e3a\u5851\u6599\u7684\u4e3b\u8981\u6210\u5206\uff0c\u805a\u70ef\u70c3\u5177\u6709\u60f0\u6027\u7684C-C\u952e\uff0c\u96be\u4ee5\u63a7\u5236\u5176\u5411\u76ee\u6807\u4ea7\u54c1\u7684\u8f6c\u5316\u3002\u73b0\u6709\u6280\u672f\u4f9d\u8d56\u4e8e\u6709\u673a\u91d1\u5c5e\u3001\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u548c\u590d\u6742\u7684\u5904\u7406\u8fc7\u7a0b\uff0c\u9762\u4e34\u5de5\u4e1a\u5316\u6311\u6218\u3002\u65b0\u5174\u6280\u672f\u901a\u8fc7\u5c06\u805a\u70ef\u70c3\u8f6c\u5316\u4e3a\u71c3\u6599\u7ea7\u78b3\u6c22\u5316\u5408\u7269\u7684\u65b0\u5174\u65b9\u6cd5\u663e\u793a\u51fa\u5de8\u5927\u7684\u5de5\u4e1a\u6f5c\u529b\u3002\u7136\u800c\uff0c\u71c3\u6599\u4e2d\u70f7\u70c3\u7684H\/C\u6bd4\u9ad8\u4e8e\u805a\u70ef\u70c3\uff08\u5206\u522b\u4e3a~2.2-2.3\u548c2.0\uff09\u3002\u56e0\u6b64\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u9700\u8981\u5916\u90e8H<sub>2<\/sub>\u6e90\u6216\u5bcc\u6c22\u5171\u53cd\u5e94\u7269\u6765\u4fc3\u8fdb\u8f6c\u5316\u3002\u4f8b\u5982\uff0c\u4f7f\u7528\u9ad8\u538b\u6c22\u5728\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4e0a\u5c06\u805a\u70ef\u70c3\u8f6c\u5316\u4e3a\u6db2\u6001\u71c3\u6599\u3002\u65e0\u9700\u5916\u90e8\u6c22\u6e90\u7684\u7cfb\u7edf\u5bf9\u5de5\u4e1a\u7279\u522b\u6709\u5438\u5f15\u529b\uff0c\u4f46\u76ee\u524d\u4ec5\u80fd\u751f\u6210\u957f\u94fe\u82b3\u70c3\u6216\u5728\u8f6c\u5316\u7387\u4f4e\u548c\u4ea7\u751f\u6325\u53d1\u6027\u6df7\u5408\u7269\u65b9\u9762\u53d7\u9650\u3002\u56e0\u6b64\uff0c\u6025\u9700\u5f00\u53d1\u5c06\u805a\u70ef\u70c3\u8f6c\u5316\u4e3a\u71c3\u6cb9\u7684\u9ad8\u6548\u3001\u7a33\u5065\u548c\u7ecf\u6d4e\u7684\u5de5\u827a\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u96be\u9898\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u6240\u97e9\u5e03\u5174\u9662\u58eb\u3001\u6797\u9f99\u98de\u7814\u7a76\u5458\u3001\u5317\u4eac\u5e08\u8303\u5927\u5b66\u97e9\u96ea\u6559\u6388\u3001\u5317\u4eac\u5927\u5b66\u6768\u56db\u6d77\u6559\u6388<\/strong>\u7b49\u4eba\u5728<em>Nature Chemistry<\/em>\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Upcycling of polyethylene to gasoline through a self-supplied hydrogen strategy in a layered self-pillared zeolite<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cdLSP-Z100\u81ea\u67f1\u5206\u5b50\u7b5b\uff08self-pillared zeolite\uff09\u5728240\u2103\u548c4 h\u6761\u4ef6\u4e0b\u50ac\u5316\u805a\u4e59\u70ef\u8f6c\u5316\u4e3a\u6c7d\u6cb9\uff0c\u9009\u62e9\u6027\u4e3a99%\uff0c\u4ea7\u7387\u4e3a80%\u3002\u5408\u6210\u7684\u6db2\u76f8\u4ea7\u7269\u4e2d\u7684\u4e3b\u8981\u4ea7\u54c1\u662f\u652f\u94fe\u70f7\u70c3\uff08\u9009\u62e9\u6027\u8fbe\u523072%\uff09\uff0c\u5176\u8f9b\u70f7\u503c\u8fbe\u523088.0\uff0c\u8fd9\u4e2a\u8f9b\u70f7\u503c\u4e0e\u5e02\u552e\u6c7d\u6cb9\uff0886.6\uff09\u975e\u5e38\u63a5\u8fd1\u3002\u901a\u8fc7\u975e\u5f39\u6027\u4e2d\u5b50\u6563\u5c04\u5149\u8c31\u3001\u5c0f\u89d2\u4e2d\u5b50\u6563\u5c04\u5149\u8c31\u3001\u56fa\u6001NMR\u3001XAS\u3001\u540c\u4f4d\u7d20\u6807\u8bb0\u7b49\u8868\u5f81\u6280\u672f\u624b\u6bb5\uff0c\u8868\u660e\u5206\u5b50\u7b5b\u7684\u4e09\u914d\u4f4dAl\u4f4d\u70b9\u6709\u52a9\u4e8e\u805a\u4e59\u70ef\u5206\u5b50\u6d3b\u5316\u3001\u968f\u540e\u5728Br\u00f6nsted\u9178\u4f4d\u70b9\u5207\u65ad\u03b2-\u5316\u5b66\u952e\u5e76\u53d1\u751f\u5f02\u6784\uff0c\u800c\u4e14\u901a\u8fc7\u81ea\u8eab\u63d0\u4f9b\u6c22\u7684\u65b9\u5f0f\u5728Al\u4f4d\u70b9\u53d1\u751f\u6c22\u5316\u7269\u8f6c\u79fb\uff0c\u9009\u62e9\u6027\u751f\u6210\u652f\u94fe\u70f7\u70c3\u3002\u672c\u7814\u7a76\u8868\u660e\u5c42\u72b6\u81ea\u67f1\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u5728\u5851\u6599\u5e9f\u7269\u56de\u6536\u9886\u57df\u5177\u6709\u91cd\u5927\u5e94\u7528\u524d\u666f\u3002\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u662f\u5316\u5b66\u7814\u7a76\u6240\u535a\u58eb\u7814\u7a76\u751f\u5c91\u6893\u6986\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259603\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/0-3.png\" alt=\"\" width=\"600\" height=\"338\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/0-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/0-3-300x169.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u6c34\u70ed\u6cd5\uff0c\u4ee5\u56db\u4e01\u57fa\u6c28\u57fa\u6c22\u6c27\u5316\u7269\u4f5c\u4e3a\u7ed3\u6784\u5bfc\u5411\u5242\uff0c\u6210\u529f\u5408\u6210\u4e86\u5177\u6709\u81ea\u652f\u6491\u5c42\u548cMFI\/MEL\u4e92\u751f\u7ed3\u6784\u7684LSP-Z100\u5206\u5b50\u7b5b\uff0c\u5b83\u62e5\u6709\u5927\u7684\u5916\u90e8\u8868\u9762\u79ef\u548c\u4ecb\u5b54\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259604\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-23.png\" alt=\"\" width=\"600\" height=\"561\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-23.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/1-23-300x281.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 \u00a0<\/strong><strong>\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8868\u5f81<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p>\u5c06\u5927\u5bc6\u5ea6\u805a\u4e59\u70ef\u4e0e\u50ac\u5316\u5242\u4ee55:1\u7684\u8d28\u91cf\u6bd4\u6df7\u5408\uff0c\u968f\u540e\u5728N<sub>2<\/sub>\u6c14\u6c1b\u52a0\u70ed240\u2103\u53cd\u5e944 h\u3002\u7814\u7a76\u4eba\u5458\u5206\u522b\u7814\u7a76LSP-Z100\u3001HZSM-5\u3001HY\u3001USY\u7b49\u5fae\u5b54\u5206\u5b50\u7b5b\u4ee5\u53caLSP\u3001meso-HY\u3001MCM-41\u3001SBA-15\u7b49\u4ecb\u5b54\u5206\u5b50\u7b5b\u50ac\u5316\u5242\uff0c\u53d1\u73b0\u53ea\u6709LSP-Z100\u5177\u6709\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259605\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-22.png\" alt=\"\" width=\"600\" height=\"480\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-22.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/2-22-300x240.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 \u00a0LSP-Z100<\/strong><strong>\u7684\u50ac\u5316\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\u7814\u7a76<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259606\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-25.png\" alt=\"\" width=\"600\" height=\"512\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-25.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/3-25-300x256.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 \u00a0<\/strong><strong>\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7814\u7a76<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u57fa\u4e8e\u539f\u4f4dINS\u8868\u5f81\u548cDFT\u7406\u8bba\u8ba1\u7b97\uff0c\u63d0\u51fa\u4e86LSP-Z100\u7684\u50ac\u5316\u53cd\u5e94\u673a\u7406\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-259607\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-21.png\" alt=\"\" width=\"600\" height=\"585\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/04\/4-21-300x293.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 \u00a0<\/strong><strong>\u53cd\u5e94\u673a\u7406\u7814\u7a76<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\uff0cLSP\u7ed3\u6784\u4e3a\u6750\u6599\u63d0\u4f9b\u4e86oFTAl\u4f4d\u70b9\u548c\u53ef\u63a5\u89e6\u7684Br\u00f6nsted\u9178\u4f4d\u70b9\uff0c\u4fc3\u8fdb\u4e86SSH\u6a21\u5f0f\u7684\u5b9e\u73b0\uff0c\u901a\u8fc7oFTAl\u4f4d\u70b9\u4e0a\u7684\u6c22\u62bd\u53d6\u3001Br\u00f6nsted\u9178\u4f4d\u70b9\u4e0a\u7684\u03b2-\u65ad\u88c2\/\u5f02\u6784\u5316\u4ee5\u53caoFTAl\u4f4d\u70b9\u4e0a\u7684\u6c22\u8f6c\u79fb\u5171\u540c\u4f5c\u7528\uff0c\u9ad8\u9009\u62e9\u6027\u548c\u4ea7\u7387\u5730\u751f\u6210\u6c7d\u6cb9\u3002\u6b64\u5916\uff0cLSP\u5206\u5b50\u7b5b\u5bf9\u4e8e\u4ece\u4f4e\u5bc6\u5ea6\u548c\u9ad8\u5bc6\u5ea6PE\u5e9f\u6599\uff08\u5360\u5f53\u4eca\u5851\u6599\u5e9f\u7269\u7ea625%\uff09\u751f\u4ea7\u5546\u7528\u7ea7\u6c7d\u6cb9\u5c55\u73b0\u51fa\u5353\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u3002\u8fd9\u4e00\u9014\u5f84\u7684\u6f5c\u5728\u5229\u6da6\u4f7f\u5176\u5177\u6709\u7ecf\u6d4e\u5438\u5f15\u529b\u3002\u4e0e\u4f20\u7edf\u7684\u57fa\u4e8e\u77f3\u6cb9\u7684\u8def\u7ebf\u76f8\u6bd4\uff0c\u57fa\u4e8ePE\u751f\u4ea7\u6c7d\u6cb9\u7684\u8def\u7ebf\u51cf\u5c11\u4e86\u78b3\u6392\u653e\u3002\u7ed3\u5408\u4f4e\u80fd\u8017\u8f93\u5165\u3001\u5ec9\u4ef7\u3001\u65e0\u8d35\u91d1\u5c5e\u4e14\u9ad8\u7a33\u5b9a\u6027\u7684\u50ac\u5316\u5242\u3001\u65e0\u9700\u5916\u90e8\u6c22\u6e90\u4ee5\u53ca\u4ea7\u54c1\u53ef\u76f4\u63a5\u4f5c\u4e3a\u4ea4\u901a\u71c3\u6599\u4f7f\u7528\uff0c\u6700\u5c0f\u5316\u73af\u5883\u5f71\u54cd\uff0c\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u8fc7\u201c\u5e9f\u7269\u8f6c\u5316\u5316\u5b66\u54c1\u201d\u7b56\u7565\u51cf\u8f7b\u672a\u6765\u5851\u6599\u6c61\u67d3\u7684\u6709\u5e0c\u671b\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41557-024-01506-z\" target=\"_blank\" rel=\"noopener\">Upcycling of polyethylene to gasoline through a self-supplied hydrogen strategy in a layered self-pillared zeolite<\/a> (<em>Nat. Chem.<\/em> <strong>2024<\/strong>, DOI: 10.1038\/s41557-024-01506-z)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 \u5851\u6599\u5e9f\u54c1\u9884\u8ba12050\u5e74\u5c06\u8fbe250\u4ebf\u5428\uff0c\u56e0\u6b64\u5f00\u53d1\u591a\u6837\u5316\u5e9f\u65e7\u5851\u6599\u56de\u6536\u6280\u672f\u8feb\u5728\u7709\u776b\u3002\u4f5c\u4e3a\u5851\u6599\u7684\u4e3b\u8981\u6210\u5206\uff0c\u805a\u70ef\u70c3\u5177\u6709\u60f0\u6027\u7684C-C\u952e\uff0c\u96be\u4ee5\u63a7\u5236\u5176\u5411\u76ee\u6807\u4ea7&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[5117],"class_list":["post-259602","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-5117"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259602"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=259602"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259602\/revisions"}],"predecessor-version":[{"id":259609,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/259602\/revisions\/259609"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=259602"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=259602"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=259602"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}